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TWI841954B - Active device substrate and manufacturing method thereof - Google Patents

Active device substrate and manufacturing method thereof Download PDF

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TWI841954B
TWI841954B TW111115389A TW111115389A TWI841954B TW I841954 B TWI841954 B TW I841954B TW 111115389 A TW111115389 A TW 111115389A TW 111115389 A TW111115389 A TW 111115389A TW I841954 B TWI841954 B TW I841954B
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gate
semiconductor layer
layer
drain
source
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TW202324737A (en
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范揚順
黃震鑠
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友達光電股份有限公司
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Priority to US17/882,623 priority patent/US20230187455A1/en
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Abstract

An active device substrate includes a substrate, a first semiconductor device and a second semiconductor device. The first semiconductor device and the second semiconductor device are disposed above the substrate. The first semiconductor device includes a first gate, a first semiconductor layer, a first source and a first drain. A first gate dielectric structure is sandwiched between the first gate and the first semiconductor layer. The first gate dielectric structure includes a stack of a portion of a gate dielectric layer and a portion of a ferroelectric material layer. The second semiconductor device is electrically connected to the first semiconductor device and includes a second gate, a second semiconductor layer, a second source and a second drain. Another part of the ferroelectric material layer is sandwiched between the second gate and the second semiconductor layer.

Description

主動元件基板及其製造方法Active element substrate and manufacturing method thereof

本發明是有關於一種主動元件基板及其製造方法。 The present invention relates to an active component substrate and a manufacturing method thereof.

由於包含金屬氧化物半導體的薄膜電晶體易受到環境中的氧氣、氫氣和水的影響,使其在長時間使用之後,容易出現性能衰退,影響薄膜電晶體的電性。舉例來說,在包含薄膜電晶體陣列的顯示裝置中,若部分的薄膜電晶體的金屬氧化物半導體出現性能衰退,容易使顯示裝置所顯示的畫面產生不均勻(Mura)的問題。一般來說,為了減少這種不均勻的問題,會將畫素電路連接至外部晶片,並透過外部補償記憶體儲存大量的電流資訊。前述電流資訊經演算法演算以得到補償電流或電壓,再將補償電流或電壓回饋至畫素電路中。然而,外部晶片的電路設計複雜,且成本高。 Since thin film transistors containing metal oxide semiconductors are easily affected by oxygen, hydrogen and water in the environment, their performance is prone to degradation after long-term use, affecting the electrical properties of the thin film transistors. For example, in a display device containing a thin film transistor array, if the metal oxide semiconductors of some thin film transistors have performance degradation, it is easy to cause unevenness (Mura) in the picture displayed by the display device. Generally speaking, in order to reduce this uneven problem, the pixel circuit is connected to an external chip, and a large amount of current information is stored through an external compensation memory. The above-mentioned current information is calculated by an algorithm to obtain a compensation current or voltage, and then the compensation current or voltage is fed back to the pixel circuit. However, the circuit design of the external chip is complex and costly.

本發明提供一種主動元件基板,能節省外部記憶體的生 產成本。 The present invention provides an active component substrate that can save the production cost of external memory.

本發明提供一種主動元件基板製造方法,能節省外部記憶體的生產成本。 The present invention provides a method for manufacturing an active component substrate, which can save the production cost of external memory.

本發明的至少一實施例提供一種主動元件基板。主動元件基板包括基板、第一半導體元件以及第二半導體元件。第一半導體元件以及第二半導體元件設置於基板之上。第一半導體元件包括第一閘極、第一半導體層、第一源極以及第一汲極。第一閘極與第一半導體層之間夾有閘介電結構。閘介電結構包括閘介電層的一部分與鐵電材料層的一部分的堆疊。第一源極以及第一汲極電性連接至第一半導體層。第二半導體元件電性連接至第一半導體元件,且包括第二閘極、第二半導體層、第二源極以及第二汲極。第二閘極與第二半導體層之間夾有鐵電材料層的另一部分。第二源極以及第二汲極電性連接至第二半導體層。 At least one embodiment of the present invention provides an active element substrate. The active element substrate includes a substrate, a first semiconductor element and a second semiconductor element. The first semiconductor element and the second semiconductor element are arranged on the substrate. The first semiconductor element includes a first gate, a first semiconductor layer, a first source and a first drain. A gate dielectric structure is sandwiched between the first gate and the first semiconductor layer. The gate dielectric structure includes a stack of a portion of the gate dielectric layer and a portion of the ferroelectric material layer. The first source and the first drain are electrically connected to the first semiconductor layer. The second semiconductor element is electrically connected to the first semiconductor element and includes a second gate, a second semiconductor layer, a second source and a second drain. Another portion of the ferroelectric material layer is sandwiched between the second gate and the second semiconductor layer. The second source and the second drain are electrically connected to the second semiconductor layer.

本發明的至少一實施例提供一種主動元件基板的製造方法,包括:形成第一半導體層以及第二半導體層於基板之上;形成閘介電層於第一半導體層上;形成鐵電材料層於閘介電層以及第二半導體層上;形成第一閘極以及第二閘極於鐵電材料層上,其中閘介電層位於第一閘極與第一半導體層之間,且鐵電材料層位於第一閘極與第一半導體層之間以及第二閘極與第二半導體層之間;形成電性連接至第一半導體層的第一源極以及第一汲極;形成電性連接至第二半導體層第二源極以及第二汲極。 At least one embodiment of the present invention provides a method for manufacturing an active element substrate, comprising: forming a first semiconductor layer and a second semiconductor layer on a substrate; forming a gate dielectric layer on the first semiconductor layer; forming a ferroelectric material layer on the gate dielectric layer and the second semiconductor layer; forming a first gate and a second gate on the ferroelectric material layer, wherein the gate dielectric layer is located between the first gate and the first semiconductor layer, and the ferroelectric material layer is located between the first gate and the first semiconductor layer and between the second gate and the second semiconductor layer; forming a first source and a first drain electrically connected to the first semiconductor layer; forming a second source and a second drain electrically connected to the second semiconductor layer.

10,20:主動元件基板 10,20: Active component substrate

100:基板 100: Substrate

102:緩衝層 102: Buffer layer

112,112’:第一半導體層 112,112’: first semiconductor layer

112a:第一源極區 112a: First source region

112b:第一通道區 112b: First channel area

112c:第一汲極區 112c: First drain region

114,114’:第二半導體層 114,114’: Second semiconductor layer

114a:第二源極區 114a: Second source region

114b:第二通道區 114b: Second channel area

114c:第二汲極區 114c: Second drain region

116,116’:第三半導體層 116,116’: The third semiconductor layer

116a:第三源極區 116a: The third source region

116b:第三通道區 116b: Third channel area

116c:第三汲極區 116c: The third drain area

120:閘介電層 120: Gate dielectric layer

122:第一閘介電圖案 122: First gate dielectric pattern

124:第二閘介電圖案 124: Second gate dielectric pattern

140:鐵電材料層 140: Ferroelectric material layer

142:第一鐵電材料圖案 142: The first ferroelectric material pattern

144:第二鐵電材料圖案 144: Second ferroelectric material pattern

150:層間介電層 150: Interlayer dielectric layer

a:第一節點 a:First node

b:第二節點 b: Second node

c:第三節點 c: The third node

Cst:儲存電容 Cst: Storage capacitor

D1:第一汲極 D1: First drain

D2:第二汲極 D2: Second drain

D3:第三汲極 D3: Third drain

EL:發光元件 EL: light emitting element

G1:第一閘極 G1: First gate

G2:第二閘極 G2: Second gate

G3:第三閘極 G3: The third gate

GI:閘介電結構 GI: Gate dielectric structure

ND:法線方向 ND: Normal direction

O1,O2,O3,O4,O5,O6,OP:開口 O1,O2,O3,O4,O5,O6,OP: Open

PX:畫素電路 PX: Pixel circuit

S1:第一源極 S1: First source

S2:第二源極 S2: Second source

S3:第三源極 S3: The third source

T1:第一半導體元件 T1: First semiconductor element

T2:第二半導體元件 T2: Second semiconductor element

T3:第三半導體元件 T3: The third semiconductor element

VS1,Vdata,VDD,VS2,Vsus,VSS:電壓 VS1 , V data , V DD , VS2 , V sus , V SS : voltage

圖1是依照本發明的一實施例的一種主動元件基板的剖面示意圖。 Figure 1 is a schematic cross-sectional view of an active element substrate according to an embodiment of the present invention.

圖2A至圖2F是圖1的主動元件基板的製造方法的剖面示意圖。 Figures 2A to 2F are cross-sectional schematic diagrams of the manufacturing method of the active element substrate of Figure 1.

圖3是依照本發明的一實施例的一種主動元件基板的剖面示意圖。 Figure 3 is a schematic cross-sectional view of an active element substrate according to an embodiment of the present invention.

圖4A至圖4D是圖3的主動元件基板的製造方法的剖面示意圖。 Figures 4A to 4D are cross-sectional schematic diagrams of the manufacturing method of the active element substrate of Figure 3.

圖5是依照本發明的一實施例的一種畫素電路的等效電路示意圖。 Figure 5 is a schematic diagram of an equivalent circuit of a pixel circuit according to an embodiment of the present invention.

圖6是依照本發明的一實施例的一種顯示裝置在圖5的畫素電路設置下的畫素補償操作流程圖。 FIG6 is a flowchart of a pixel compensation operation of a display device according to an embodiment of the present invention under the pixel circuit setting of FIG5.

圖1是依照本發明的一實施例的一種主動元件基板的剖面示意圖。 Figure 1 is a schematic cross-sectional view of an active element substrate according to an embodiment of the present invention.

請參考圖1,主動元件基板10包括基板100、第一半導體元件T1以及第二半導體元件T2。在本實施例中,主動元件基板10還包括第三半導體元件T3以及緩衝層102。在一些實施例中,第二半導體元件T2透過圖式中未繪示的導電構件而電性連接 至第一半導體元件T1。在一些實施例中,第二半導體元件T2透過圖式中未繪示的導電構件而電性連接至第三半導體元件T3。在一些實施例中,第三半導體元件T3透過圖式中未繪示的導電構件而電性連接至第一半導體元件T1。 Referring to FIG. 1 , the active element substrate 10 includes a substrate 100, a first semiconductor element T1, and a second semiconductor element T2. In this embodiment, the active element substrate 10 further includes a third semiconductor element T3 and a buffer layer 102. In some embodiments, the second semiconductor element T2 is electrically connected to the first semiconductor element T1 through a conductive member not shown in the figure. In some embodiments, the second semiconductor element T2 is electrically connected to the third semiconductor element T3 through a conductive member not shown in the figure. In some embodiments, the third semiconductor element T3 is electrically connected to the first semiconductor element T1 through a conductive member not shown in the figure.

基板100之材質可為玻璃、石英、有機聚合物或是不透光/反射材料(例如:導電材料、金屬、晶圓、陶瓷或其他可適用的材料)或是其他可適用的材料。若使用導電材料或金屬時,則在基板100上覆蓋一層絕緣層(未繪示),以避免短路問題。在一些實施例中,基板100為軟性基板,且基板100的材料例如為聚乙烯對苯二甲酸酯(polyethylene terephthalate,PET)、聚二甲酸乙二醇酯(polyethylene naphthalate,PEN)、聚酯(polyester,PES)、聚甲基丙烯酸甲酯(polymethylmethacrylate,PMMA)、聚碳酸酯(polycarbonate,PC)、聚醯亞胺(polyimide,PI)或金屬軟板(Metal Foil)或其他可撓性材質。緩衝層102位於基板100上,緩衝層102的材質可以包括氮化矽、氧化矽、氮氧化矽或其他合適的材料或上述材料的堆疊層,但本發明不以此為限。 The material of the substrate 100 may be glass, quartz, organic polymer, or opaque/reflective material (e.g., conductive material, metal, wafer, ceramic, or other applicable material) or other applicable materials. If a conductive material or metal is used, an insulating layer (not shown) is covered on the substrate 100 to avoid short circuit problems. In some embodiments, the substrate 100 is a flexible substrate, and the material of the substrate 100 is, for example, polyethylene terephthalate (PET), polyethylene naphthalate (PEN), polyester (PES), polymethylmethacrylate (PMMA), polycarbonate (PC), polyimide (PI), metal foil, or other flexible materials. The buffer layer 102 is located on the substrate 100. The material of the buffer layer 102 may include silicon nitride, silicon oxide, silicon oxynitride or other suitable materials or stacked layers of the above materials, but the present invention is not limited thereto.

第一半導體元件T1、第二半導體元件T2以及第三半導體元件T3設置於基板100以及緩衝層102之上。第一半導體元件T1包括第一閘極G1、第一半導體層112、第一源極S1以及第一汲極D1。第二半導體元件T2包括第二閘極G2、第二半導體層114、第二源極S2以及第二汲極D2。第三半導體元件T3包括第三閘極G3、第三半導體層116、第三源極S3以及第三汲極D3。 The first semiconductor element T1, the second semiconductor element T2 and the third semiconductor element T3 are disposed on the substrate 100 and the buffer layer 102. The first semiconductor element T1 includes a first gate G1, a first semiconductor layer 112, a first source S1 and a first drain D1. The second semiconductor element T2 includes a second gate G2, a second semiconductor layer 114, a second source S2 and a second drain D2. The third semiconductor element T3 includes a third gate G3, a third semiconductor layer 116, a third source S3 and a third drain D3.

第一半導體層112、第二半導體層114以及第三半導體層116設置於基板100與緩衝層102上。第一半導體層112包括第一源極區112a、第一汲極區112c及位於第一源極區112a與第一汲極區112c之間的第一通道區112b。第二半導體層114包括第二源極區114a、第二汲極區114c及位於第二源極區114a與第二汲極區114c之間的第二通道區114b。第三半導體層116包括第三源極區116a、第三汲極區116c及位於第三源極區116a與第三汲極區116c之間的第三通道區116b。 The first semiconductor layer 112, the second semiconductor layer 114 and the third semiconductor layer 116 are disposed on the substrate 100 and the buffer layer 102. The first semiconductor layer 112 includes a first source region 112a, a first drain region 112c and a first channel region 112b located between the first source region 112a and the first drain region 112c. The second semiconductor layer 114 includes a second source region 114a, a second drain region 114c and a second channel region 114b located between the second source region 114a and the second drain region 114c. The third semiconductor layer 116 includes a third source region 116a, a third drain region 116c, and a third channel region 116b located between the third source region 116a and the third drain region 116c.

第一閘極G1在基板100的頂面的法線方向ND上重疊於第一半導體層112的第一通道區112b,且第一閘極G1與第一半導體層112之間夾有閘介電結構GI。閘介電結構包括閘介電層120的一部分與鐵電材料層140的一部分的堆疊。閘介電層120覆蓋第一半導體層112的上表面與側壁,且鐵電材料層140位於閘介電層120的上表面。 The first gate G1 overlaps the first channel region 112b of the first semiconductor layer 112 in the normal direction ND of the top surface of the substrate 100, and a gate dielectric structure GI is sandwiched between the first gate G1 and the first semiconductor layer 112. The gate dielectric structure includes a stack of a portion of the gate dielectric layer 120 and a portion of the ferroelectric material layer 140. The gate dielectric layer 120 covers the upper surface and sidewalls of the first semiconductor layer 112, and the ferroelectric material layer 140 is located on the upper surface of the gate dielectric layer 120.

第二閘極G2在基板100的頂面的法線方向ND上重疊於第二半導體層114的第二通道區114b,且第二閘極G2與第二半導體層114之間夾有鐵電材料層140的另一部分。閘介電層120覆蓋第二半導體層116的側壁,且鐵電材料層140接觸第二半導體層114的上表面。在一些實施例中,鐵電材料層140自第一閘極G1與閘介電層120之間連續地延伸至第二閘極G2以及第二半導體層114之間。 The second gate G2 overlaps the second channel region 114b of the second semiconductor layer 114 in the normal direction ND of the top surface of the substrate 100, and another portion of the ferroelectric material layer 140 is sandwiched between the second gate G2 and the second semiconductor layer 114. The gate dielectric layer 120 covers the sidewalls of the second semiconductor layer 116, and the ferroelectric material layer 140 contacts the upper surface of the second semiconductor layer 114. In some embodiments, the ferroelectric material layer 140 extends continuously from between the first gate G1 and the gate dielectric layer 120 to between the second gate G2 and the second semiconductor layer 114.

第三閘極G3在基板100的頂面的法線方向ND上重疊於 第三半導體層116的第三通道區116b,且第三閘極G3與第三半導體層116之間夾有閘介電層120的另一部分。閘介電層120覆蓋第三半導體層116的上表面與側壁。 The third gate G3 overlaps the third channel region 116b of the third semiconductor layer 116 in the normal direction ND of the top surface of the substrate 100, and another part of the gate dielectric layer 120 is sandwiched between the third gate G3 and the third semiconductor layer 116. The gate dielectric layer 120 covers the upper surface and sidewalls of the third semiconductor layer 116.

在一些實施例中,第一閘極G1與第一半導體層112之間的距離大於第二閘極G2與第二半導體層114之間的距離以及第三閘極G3與第三半導體層116之間的距離。 In some embodiments, the distance between the first gate G1 and the first semiconductor layer 112 is greater than the distance between the second gate G2 and the second semiconductor layer 114 and the distance between the third gate G3 and the third semiconductor layer 116.

在一實施例中,第一半導體層112、第二半導體層114以及第三半導體層116的材料包括單晶矽、多晶矽、微晶矽、有機半導體材料、金屬氧化物半導體材料(例如:氧化銦鎵鋅(IGZO)、氧化銦錫鋅(ITZO)、氧化鋁鋅錫(AZTO)、氧化銦鎢鋅(IWZO)等四元金屬化合物或包含鎵(Ga)、鋅(Zn)、銦(In)、錫(Sn)、鋁(Al)、鎢(W)中之任三者的三元金屬構成的氧化物)或其他合適的材料。在一些實施例中,第一半導體層112、第二半導體層114以及第三半導體層116包括成分相同或不同的材料。在一些實施例中,第一半導體層112、第二半導體層114以及第三半導體層116包括相同或不同的厚度。 In one embodiment, the materials of the first semiconductor layer 112, the second semiconductor layer 114, and the third semiconductor layer 116 include single crystal silicon, polycrystalline silicon, microcrystalline silicon, organic semiconductor materials, metal oxide semiconductor materials (for example, quaternary metal compounds such as indium gallium zinc oxide (IGZO), indium tin zinc oxide (ITZO), aluminum zinc tin oxide (AZTO), indium tungsten zinc oxide (IWZO), or oxides composed of ternary metals including any three of gallium (Ga), zinc (Zn), indium (In), tin (Sn), aluminum (Al), and tungsten (W)) or other suitable materials. In some embodiments, the first semiconductor layer 112, the second semiconductor layer 114, and the third semiconductor layer 116 include materials with the same or different compositions. In some embodiments, the first semiconductor layer 112, the second semiconductor layer 114, and the third semiconductor layer 116 include the same or different thicknesses.

在一實施例中,第一閘極G1、第二閘極G2以及第三閘極G3的材料可包括金屬,例如鉻(Cr)、金(Au)、銀(Ag)、銅(Cu)、錫(Sn)、鉛(Pb)、鉿(Hf)、鎢(W)、鉬(Mo)、釹(Nd)、鈦(Ti)、鉭(Ta)、鋁(Al)、鋅(Zn)或上述金屬的任意組合之合金或上述金屬及/或合金之疊層,但本發明不以此為限。第一閘極G1、第二閘極G2以及第三閘極G3也可以使用其他 導電材料,例如:金屬的氮化物、金屬的氧化物、金屬的氮氧化物、金屬與其它導電材料的堆疊層或是其他具有導電性質之材料。在一些實施例中,第一閘極G1、第二閘極G2以及第三閘極G3包括成分相同或不同的材料。在一些實施例中,第一閘極G1、第二閘極G2以及第三閘極G3包括相同或不同的厚度。 In one embodiment, the materials of the first gate G1, the second gate G2 and the third gate G3 may include metals, such as chromium (Cr), gold (Au), silver (Ag), copper (Cu), tin (Sn), lead (Pb), tungsten (W), molybdenum (Mo), neodymium (Nd), titanium (Ti), tantalum (Ta), aluminum (Al), zinc (Zn) or alloys of any combination of the above metals or stacked layers of the above metals and/or alloys, but the present invention is not limited thereto. The first gate G1, the second gate G2 and the third gate G3 may also use other conductive materials, such as metal nitrides, metal oxides, metal oxynitrides, stacked layers of metals and other conductive materials, or other materials with conductive properties. In some embodiments, the first gate G1, the second gate G2, and the third gate G3 include materials of the same or different compositions. In some embodiments, the first gate G1, the second gate G2, and the third gate G3 include the same or different thicknesses.

在一些實施例中,閘介電層120的材料例如為氧化矽、氮化矽、氮氧化矽或其他合適的材料。在一些實施例中,閘介電層120的厚度為50奈米至100奈米。 In some embodiments, the material of the gate dielectric layer 120 is, for example, silicon oxide, silicon nitride, silicon oxynitride, or other suitable materials. In some embodiments, the thickness of the gate dielectric layer 120 is 50 nanometers to 100 nanometers.

在一些實施例中,鐵電材料層140的材料包括NixMgyZn0.98-yO或HfzZr1-zO2,其中x為0.01至0.05,y為0.05至0.15,z為0.4至0.6。在一些實施例中,鐵電材料層140的厚度為5奈米至50奈米。 In some embodiments, the material of the ferroelectric material layer 140 includes Ni x Mg y Zn 0.98-y O or Hf z Zr 1-z O 2 , wherein x is 0.01 to 0.05, y is 0.05 to 0.15, and z is 0.4 to 0.6. In some embodiments, the thickness of the ferroelectric material layer 140 is 5 nm to 50 nm.

層間介電層150設置於第一閘極G1、第二閘極G2、第三閘極G3、鐵電材料層140以及閘介電層120之上,且覆蓋第一閘極G1、第二閘極G2、第三閘極G3、鐵電材料層140以及閘介電層120。層間介電層150的材料例如為氧化矽、氮化矽、氮氧化矽或其他合適的材料。 The interlayer dielectric layer 150 is disposed on the first gate G1, the second gate G2, the third gate G3, the ferroelectric material layer 140 and the gate dielectric layer 120, and covers the first gate G1, the second gate G2, the third gate G3, the ferroelectric material layer 140 and the gate dielectric layer 120. The material of the interlayer dielectric layer 150 is, for example, silicon oxide, silicon nitride, silicon oxynitride or other suitable materials.

層間介電層150、鐵電材料層140以及閘介電層120中的開口O1、O2分別重疊於第一源極區112a及第一汲極區112c。第一源極S1與第一汲極D1位於層間介電層150上,且分別填入開口O1、O2以電性連接至第一半導體層112的第一源極區112a及第一汲極區112c。 The openings O1 and O2 in the interlayer dielectric layer 150, the ferroelectric material layer 140, and the gate dielectric layer 120 overlap the first source region 112a and the first drain region 112c, respectively. The first source S1 and the first drain D1 are located on the interlayer dielectric layer 150, and are filled in the openings O1 and O2, respectively, to be electrically connected to the first source region 112a and the first drain region 112c of the first semiconductor layer 112.

層間介電層150、鐵電材料層140以及閘介電層120中的開口O3、O4分別重疊於第二源極區114a及第二汲極區114c。第二源極S2與第二汲極D2位於層間介電層150上,且分別填入開口O3、O4以電性連接至第二半導體層114的第二源極區114a及第二汲極區114c。 The openings O3 and O4 in the interlayer dielectric layer 150, the ferroelectric material layer 140, and the gate dielectric layer 120 overlap the second source region 114a and the second drain region 114c, respectively. The second source S2 and the second drain D2 are located on the interlayer dielectric layer 150, and are filled in the openings O3 and O4, respectively, to be electrically connected to the second source region 114a and the second drain region 114c of the second semiconductor layer 114.

需注意的是,雖然在圖1中,鐵電材料層140被第一源極S1、第一汲極D1、第二源極S2以及第二汲極D2分隔成多個區塊,但鐵電材料層140實際上為連續的結構。換句話說,鐵電材料層140環繞第一源極S1、第一汲極D1、第二源極S2以及第二汲極D2,且第一源極S1、第一汲極D1、第二源極S2以及第二汲極D2穿過鐵電材料層140。 It should be noted that, although in FIG. 1 , the ferroelectric material layer 140 is divided into multiple blocks by the first source S1, the first drain D1, the second source S2, and the second drain D2, the ferroelectric material layer 140 is actually a continuous structure. In other words, the ferroelectric material layer 140 surrounds the first source S1, the first drain D1, the second source S2, and the second drain D2, and the first source S1, the first drain D1, the second source S2, and the second drain D2 pass through the ferroelectric material layer 140.

層間介電層150以及閘介電層120中的開口O5、O6分別重疊於第三源極區116a及第三汲極區116c。第三源極S3與第三汲極D3位於層間介電層150上,且分別填入開口O5、O6以電性連接至第三半導體層116的第三源極區116a及第三汲極區116c。 The openings O5 and O6 in the interlayer dielectric layer 150 and the gate dielectric layer 120 overlap the third source region 116a and the third drain region 116c, respectively. The third source S3 and the third drain D3 are located on the interlayer dielectric layer 150, and are filled in the openings O5 and O6, respectively, to be electrically connected to the third source region 116a and the third drain region 116c of the third semiconductor layer 116.

在一實施例中,第一源極S1、第一汲極D1、第二源極S2、第二汲極D2、第三源極S3與第三汲極D3的材料可包括金屬,例如鉻、金、銀、銅、錫、鉛、鉿、鎢、鉬、釹、鈦、鉭、鋁、鋅或上述金屬的任意組合之合金或上述金屬及/或合金之疊層,但本發明不以此為限。第一源極S1、第一汲極D1、第二源極S2、第二汲極D2、第三源極S3與第三汲極D3也可以使用其他導電材 料,例如:金屬的氮化物、金屬的氧化物、金屬的氮氧化物、金屬與其它導電材料的堆疊層或是其他具有導電性質之材料。在一些實施例中,第一源極S1、第一汲極D1、第二源極S2、第二汲極D2、第三源極S3與第三汲極D3包括成分相同或不同的材料。在一些實施例中,第一源極S1、第一汲極D1、第二源極S2、第二汲極D2、第三源極S3與第三汲極D3包括相同或不同的厚度。 In one embodiment, the materials of the first source S1, the first drain D1, the second source S2, the second drain D2, the third source S3 and the third drain D3 may include metals, such as chromium, gold, silver, copper, tin, lead, uranium, tungsten, molybdenum, neodymium, titanium, tantalum, aluminum, zinc or alloys of any combination of the above metals or stacked layers of the above metals and/or alloys, but the present invention is not limited thereto. The first source S1, the first drain D1, the second source S2, the second drain D2, the third source S3 and the third drain D3 may also use other conductive materials, such as metal nitrides, metal oxides, metal oxynitrides, stacked layers of metals and other conductive materials, or other materials with conductive properties. In some embodiments, the first source S1, the first drain D1, the second source S2, the second drain D2, the third source S3, and the third drain D3 include materials of the same or different compositions. In some embodiments, the first source S1, the first drain D1, the second source S2, the second drain D2, the third source S3, and the third drain D3 include the same or different thicknesses.

基於上述,第一半導體元件T1的第一閘極G1與第一半導體層112之間的閘介電結構GI包括閘介電層120與鐵電材料層140,因此,可以藉由負電容效應(negative capacitor effect)讓第一半導體元件T1的次臨界擺幅(sub-threshold swing)小於60mV/dec,且使得第一閘極G1與第一半導體層112之間的鐵電材料層140的遲滯效應減小。此外,由於第二半導體元件T2的第二閘極G2與第二半導體層116之間夾有鐵電材料層140,因此,第二半導體元件T2除了可以作為驅動元件以外,還具有儲存電流資訊或電壓資訊的功能。最後,第三半導體元件T3的第三閘極G3與第三半導體層116之間夾有閘介電層120,可以提供穩定的正向或反向電流。 Based on the above, the gate dielectric structure GI between the first gate G1 of the first semiconductor element T1 and the first semiconductor layer 112 includes the gate dielectric layer 120 and the ferroelectric material layer 140. Therefore, the sub-threshold swing of the first semiconductor element T1 can be made less than 60mV/dec by the negative capacitor effect, and the hysteresis effect of the ferroelectric material layer 140 between the first gate G1 and the first semiconductor layer 112 can be reduced. In addition, since the ferroelectric material layer 140 is sandwiched between the second gate G2 of the second semiconductor element T2 and the second semiconductor layer 116, the second semiconductor element T2 can not only serve as a driving element, but also has the function of storing current information or voltage information. Finally, the gate dielectric layer 120 is sandwiched between the third gate G3 of the third semiconductor element T3 and the third semiconductor layer 116, which can provide a stable forward or reverse current.

圖2A至圖2F是圖1的主動元件基板10的製造方法的剖面示意圖。 Figures 2A to 2F are cross-sectional schematic diagrams of the manufacturing method of the active element substrate 10 of Figure 1.

請參考圖2A,形成第一半導體層112’、第二半導體層114’以及第三半導體層116’於基板100之上。在本實施例中,第一半導體層112’、第二半導體層114’以及第三半導體層116’形成於緩 衝層102上。在一些實施例中,形成第一半導體層112’、第二半導體層114’以及第三半導體層116’的方法包括以下步驟:首先,在基板110及緩衝層102上形成毯覆的半導體材料層(未繪示);接著,利用微影製程,在半導體材料層上形成圖案化光阻(未繪示);繼之,利用圖案化光阻作為罩幕,來對半導體材料層進行濕式或乾式蝕刻製程,以形成第一半導體層112’、第二半導體層114’以及第三半導體層116’;之後,移除圖案化光阻。換句話說,第一半導體層112’、第二半導體層114’以及第三半導體層116’例如為同時形成。 2A , a first semiconductor layer 112 ′, a second semiconductor layer 114 ′, and a third semiconductor layer 116 ′ are formed on a substrate 100. In this embodiment, the first semiconductor layer 112 ′, the second semiconductor layer 114 ′, and the third semiconductor layer 116 ′ are formed on a buffer layer 102. In some embodiments, the method for forming the first semiconductor layer 112', the second semiconductor layer 114' and the third semiconductor layer 116' includes the following steps: first, a blanket semiconductor material layer (not shown) is formed on the substrate 110 and the buffer layer 102; then, a patterned photoresist (not shown) is formed on the semiconductor material layer by a lithography process; then, the patterned photoresist is used as a mask to perform a wet or dry etching process on the semiconductor material layer to form the first semiconductor layer 112', the second semiconductor layer 114' and the third semiconductor layer 116'; thereafter, the patterned photoresist is removed. In other words, the first semiconductor layer 112', the second semiconductor layer 114' and the third semiconductor layer 116' are formed at the same time, for example.

請參考圖2B,形成閘介電層120於第一半導體層112’以及第三半導體層116’上。在一些實施例中,形成閘介電層120的方法包括以下步驟:首先,在第一半導體層112’、第二半導體層114’、第三半導體層116’以及緩衝層102上形成毯覆的介電材料層(未繪示);接著,利用微影製程,在介電材料層上形成圖案化光阻(未繪示);繼之,利用圖案化光阻作為罩幕,來對介電材料層進行濕式或乾式蝕刻製程,以形成包括開口OP的閘介電層120,其中開口OP暴露出第二半導體層114’;之後,移除圖案化光阻。在一些實施例中,開口OP的長度小於第二半導體層114’的長度,且閘介電層120覆蓋第二半導體層114’的側壁以及部分表面。在一些實施例中,開口OP的長度大於第二半導體層114’的長度,且閘介電層120不接觸第二半導體層114’。在一些實施例中,閘介電層120的材料可為不含氫的氧化物,藉此避免閘介 電層120中的氫原子在製程中擴散至第一半導體層112’、第二半導體層114’以及第三半導體層116’中。 Referring to FIG. 2B , a gate dielectric layer 120 is formed on the first semiconductor layer 112’ and the third semiconductor layer 116’. In some embodiments, the method for forming the gate dielectric layer 120 includes the following steps: first, a blanket dielectric material layer (not shown) is formed on the first semiconductor layer 112', the second semiconductor layer 114', the third semiconductor layer 116' and the buffer layer 102; then, a patterned photoresist (not shown) is formed on the dielectric material layer by a lithography process; then, the patterned photoresist is used as a mask to perform a wet or dry etching process on the dielectric material layer to form a gate dielectric layer 120 including an opening OP, wherein the opening OP exposes the second semiconductor layer 114'; thereafter, the patterned photoresist is removed. In some embodiments, the length of the opening OP is less than the length of the second semiconductor layer 114', and the gate dielectric layer 120 covers the sidewalls and a portion of the surface of the second semiconductor layer 114'. In some embodiments, the length of the opening OP is greater than the length of the second semiconductor layer 114', and the gate dielectric layer 120 does not contact the second semiconductor layer 114'. In some embodiments, the material of the gate dielectric layer 120 may be a hydrogen-free oxide, thereby preventing hydrogen atoms in the gate dielectric layer 120 from diffusing into the first semiconductor layer 112', the second semiconductor layer 114', and the third semiconductor layer 116' during the manufacturing process.

請參考圖2C,形成鐵電材料層140於閘介電層120以及第二半導體層114’上。鐵電材料層140填入閘介電層120的開口OP中以接觸第二半導體層114’。在一些實施例中,形成鐵電材料層140的方法包括以下步驟:首先,在閘介電層120以及第二半導體層114’上形成毯覆的鐵電材料層(未繪示);接著,利用微影製程,在鐵電材料層上形成圖案化光阻(未繪示);繼之,利用圖案化光阻作為罩幕,來對鐵電材料層進行濕式或乾式蝕刻製程,以形成不重疊於第三半導體層116’的鐵電材料層140;之後,移除圖案化光阻。 2C , a ferroelectric material layer 140 is formed on the gate dielectric layer 120 and the second semiconductor layer 114′. The ferroelectric material layer 140 is filled into the opening OP of the gate dielectric layer 120 to contact the second semiconductor layer 114′. In some embodiments, the method of forming the ferroelectric material layer 140 includes the following steps: first, a blanket ferroelectric material layer (not shown) is formed on the gate dielectric layer 120 and the second semiconductor layer 114'; then, a patterned photoresist (not shown) is formed on the ferroelectric material layer by a lithography process; then, the ferroelectric material layer is subjected to a wet or dry etching process using the patterned photoresist as a mask to form the ferroelectric material layer 140 that does not overlap the third semiconductor layer 116'; then, the patterned photoresist is removed.

請參考圖2D,形成第一閘極G1以及第二閘極G2於鐵電材料層140上,且形成第三閘極G3於閘介電層120上。閘介電層120位於第一閘極G1與第一半導體層112之間以及第三閘極G3與第三半導體層116之間,鐵電材料層140位於第一閘極G1與第一半導體層112之間以及第二閘極G2與第二半導體層114之間。在一些實施例中,形成第一閘極G1、第二閘極G2以及第三閘極G3的方法包括以下步驟:首先,在閘介電層120以及鐵電材料層140上形成毯覆的導電材料層(未繪示);接著,利用微影製程,在導電材料層上形成圖案化光阻(未繪示);繼之,利用圖案化光阻作為罩幕,來對導電材料層進行濕式或乾式蝕刻製程,以形成第一閘極G1、第二閘極G2以及第三閘極G3;之後,移除圖案化 光阻。換句話說,第一閘極G1、第二閘極G2以及第三閘極G3例如為同時形成。 2D , a first gate G1 and a second gate G2 are formed on the ferroelectric material layer 140, and a third gate G3 is formed on the gate dielectric layer 120. The gate dielectric layer 120 is located between the first gate G1 and the first semiconductor layer 112 and between the third gate G3 and the third semiconductor layer 116, and the ferroelectric material layer 140 is located between the first gate G1 and the first semiconductor layer 112 and between the second gate G2 and the second semiconductor layer 114. In some embodiments, the method for forming the first gate G1, the second gate G2, and the third gate G3 includes the following steps: first, a blanket conductive material layer (not shown) is formed on the gate dielectric layer 120 and the ferroelectric material layer 140; then, a patterned photoresist (not shown) is formed on the conductive material layer by a lithography process; then, the conductive material layer is subjected to a wet or dry etching process using the patterned photoresist as a mask to form the first gate G1, the second gate G2, and the third gate G3; then, the patterned photoresist is removed. In other words, the first gate G1, the second gate G2, and the third gate G3 are formed at the same time, for example.

接著,以第一閘極G1、第二閘極G2以及第三閘極G3為遮罩,對第一半導體層112’、第二半導體層114’以及第三半導體層116’進行摻雜製程P,以形成包括第一源極區112a、第一通道區112b與第一汲極區112c的第一半導體層112、包括第二源極區114a、第二通道區114b與第二汲極區114c的第二半導體層114以及包括第三源極區116a、第三通道區116b與第三汲極區116c的第三半導體層116。在一些實施例中,摻雜製程P包括氫電漿製程或離子植入製程。 Next, the first gate G1, the second gate G2 and the third gate G3 are used as masks to perform a doping process P on the first semiconductor layer 112', the second semiconductor layer 114' and the third semiconductor layer 116' to form a first semiconductor layer 112 including a first source region 112a, a first channel region 112b and a first drain region 112c, a second semiconductor layer 114 including a second source region 114a, a second channel region 114b and a second drain region 114c, and a third semiconductor layer 116 including a third source region 116a, a third channel region 116b and a third drain region 116c. In some embodiments, the doping process P includes a hydrogen plasma process or an ion implantation process.

請參考圖2E,形成層間介電層150於閘介電層120以及鐵電材料層140之上。在一些實施例中,層間介電層150為不含氫的絕緣層,藉此避免層間介電層150中的氫原子擴散至第一半導體層112、第二半導體層114以及第三半導體層116,但本發明不以此為限。在一些實施例中,層間介電層150中含有氫原子,因此,可以藉由熱處理使氫原子擴散至第一半導體層112、第二半導體層114以及第三半導體層116中,以調整第一半導體層112、第二半導體層114以及第三半導體層116的電阻率。在一些實施例中,當使用層間介電層150中的氫原子進行第一半導體層112、第二半導體層114以及第三半導體層116的摻雜時,可以省略圖2D的摻雜製程P。 2E , an interlayer dielectric layer 150 is formed on the gate dielectric layer 120 and the ferroelectric material layer 140. In some embodiments, the interlayer dielectric layer 150 is an insulating layer that does not contain hydrogen, thereby preventing hydrogen atoms in the interlayer dielectric layer 150 from diffusing into the first semiconductor layer 112, the second semiconductor layer 114, and the third semiconductor layer 116, but the present invention is not limited thereto. In some embodiments, the interlayer dielectric layer 150 contains hydrogen atoms, so the hydrogen atoms can be diffused into the first semiconductor layer 112, the second semiconductor layer 114, and the third semiconductor layer 116 by heat treatment to adjust the resistivity of the first semiconductor layer 112, the second semiconductor layer 114, and the third semiconductor layer 116. In some embodiments, when the first semiconductor layer 112, the second semiconductor layer 114, and the third semiconductor layer 116 are doped using the hydrogen atoms in the interlayer dielectric layer 150, the doping process P of FIG. 2D can be omitted.

請參考圖2F,形成開口O1、O2、O3、O4、O5、O6,方 法包括以下步驟:首先,利用微影製程,在層間介電層150上形成圖案化光阻(未繪示);繼之,利用圖案化光阻作為罩幕,來進行濕式或乾式蝕刻製程,以於層間介電層150、鐵電材料層140以及閘介電層120中形成開口O1、O2、O3、O4、O5、O6;之後,移除圖案化光阻。 Referring to FIG. 2F , the method for forming openings O1, O2, O3, O4, O5, and O6 includes the following steps: first, using a lithography process to form a patterned photoresist (not shown) on the interlayer dielectric layer 150; then, using the patterned photoresist as a mask to perform a wet or dry etching process to form openings O1, O2, O3, O4, O5, and O6 in the interlayer dielectric layer 150, the ferroelectric material layer 140, and the gate dielectric layer 120; then, removing the patterned photoresist.

開口O1、O2貫穿層間介電層150、鐵電材料層140以及閘介電層120,以分別暴露出第一半導體層112的第一源極區112a與第一汲極區112c。開口O3、O4貫穿層間介電層150、鐵電材料層140以及閘介電層120,以分別暴露出第二半導體層114的第二源極區114a與第二汲極區114c。開口O5、O6貫穿層間介電層150以及閘介電層120,以分別暴露出第三半導體層116的第三源極區116a與第三汲極區116c。 Openings O1 and O2 penetrate the interlayer dielectric layer 150, the ferroelectric material layer 140, and the gate dielectric layer 120 to expose the first source region 112a and the first drain region 112c of the first semiconductor layer 112, respectively. Openings O3 and O4 penetrate the interlayer dielectric layer 150, the ferroelectric material layer 140, and the gate dielectric layer 120 to expose the second source region 114a and the second drain region 114c of the second semiconductor layer 114, respectively. Openings O5 and O6 penetrate the interlayer dielectric layer 150 and the gate dielectric layer 120 to expose the third source region 116a and the third drain region 116c of the third semiconductor layer 116, respectively.

最後請回到圖1,形成第一源極S1、第一汲極D1、第二源極S2、第二汲極D2、第三源極S3以及第三汲極D3於層間介電層150上。第一源極S1以及第一汲極D1分別填入開口O1、O2。第二源極S2以及第二汲極D2分別填入開口O3、O4。第三源極S3以及第三汲極D3分別填入開口O5、O6。在一些實施例中,形成第一源極S1、第一汲極D1、第二源極S2、第二汲極D2、第三源極S3以及第三汲極D3的方法包括以下步驟:首先,在層間介電層150上形成毯覆的導電材料層(未繪示);接著,利用微影製程,在導電材料層上形成圖案化光阻(未繪示);繼之,利用圖案化光阻作為罩幕,來對導電材料層進行濕式或乾式蝕刻製 程,以形成第一源極S1、第一汲極D1、第二源極S2、第二汲極D2、第三源極S3以及第三汲極D3;之後,移除圖案化光阻。換句話說,第一源極S1、第一汲極D1、第二源極S2、第二汲極D2、第三源極S3以及第三汲極D3例如為同時形成。 Finally, please return to FIG. 1 to form a first source S1, a first drain D1, a second source S2, a second drain D2, a third source S3, and a third drain D3 on the interlayer dielectric layer 150. The first source S1 and the first drain D1 are filled into the openings O1 and O2, respectively. The second source S2 and the second drain D2 are filled into the openings O3 and O4, respectively. The third source S3 and the third drain D3 are filled into the openings O5 and O6, respectively. In some embodiments, the method of forming the first source S1, the first drain D1, the second source S2, the second drain D2, the third source S3 and the third drain D3 includes the following steps: first, forming a blanket conductive material layer (not shown) on the interlayer dielectric layer 150; then, forming a patterned photoresist (not shown) on the conductive material layer by a lithography process; then, using the patterned photoresist as a mask, performing a wet or dry etching process on the conductive material layer to form the first source S1, the first drain D1, the second source S2, the second drain D2, the third source S3 and the third drain D3; and then, removing the patterned photoresist. In other words, the first source S1, the first drain D1, the second source S2, the second drain D2, the third source S3 and the third drain D3 are formed at the same time, for example.

經過上述製程後可大致上完成主動元件基板10的製作。 After the above process, the production of the active element substrate 10 can be basically completed.

圖3是依照本發明的一實施例的一種主動元件基板20的剖面示意圖。在此必須說明的是,圖3的實施例沿用圖1的實施例的元件標號與部分內容,其中採用相同或近似的標號來表示相同或近似的元件,並且省略了相同技術內容的說明。關於省略部分的說明可參考前述實施例,在此不贅述。 FIG3 is a schematic cross-sectional view of an active element substrate 20 according to an embodiment of the present invention. It must be noted that the embodiment of FIG3 uses the component numbers and some contents of the embodiment of FIG1, wherein the same or similar numbers are used to represent the same or similar components, and the description of the same technical contents is omitted. The description of the omitted parts can be referred to the aforementioned embodiments, which will not be elaborated here.

圖3的主動元件基板20與圖1的主動元件基板10的主要差異在於:主動元件基板20的閘介電層120對齊第一通道區112b以及第三通道區116b,且鐵電材料層140對齊第一通道區112b以及第二通道區114b。 The main difference between the active device substrate 20 of FIG. 3 and the active device substrate 10 of FIG. 1 is that the gate dielectric layer 120 of the active device substrate 20 is aligned with the first channel region 112b and the third channel region 116b, and the ferroelectric material layer 140 is aligned with the first channel region 112b and the second channel region 114b.

請參考圖3,閘介電層120包括第一閘介電圖案122以及第二閘介電圖案124,其中第一閘介電圖案122以及第二閘介電圖案124彼此分離。鐵電材料層140包括第一鐵電材料圖案142以及第二鐵電材料圖案144,其中第一鐵電材料圖案142以及第二鐵電材料圖案144彼此分離。 Referring to FIG. 3 , the gate dielectric layer 120 includes a first gate dielectric pattern 122 and a second gate dielectric pattern 124, wherein the first gate dielectric pattern 122 and the second gate dielectric pattern 124 are separated from each other. The ferroelectric material layer 140 includes a first ferroelectric material pattern 142 and a second ferroelectric material pattern 144, wherein the first ferroelectric material pattern 142 and the second ferroelectric material pattern 144 are separated from each other.

第一閘介電圖案122以及第一鐵電材料圖案142在基板100的頂面的法線方向ND上重疊於第一閘極G1以及第一通道區112b,且第一閘介電圖案122以及第一鐵電材料圖案142位於第 一閘極G1以及第一通道區112b之間,並構成閘介電結構GI。第一閘介電圖案122的側壁以及第一鐵電材料圖案142的側壁對齊於第一閘極G1的側壁。 The first gate dielectric pattern 122 and the first ferroelectric material pattern 142 overlap the first gate G1 and the first channel region 112b in the normal direction ND of the top surface of the substrate 100, and the first gate dielectric pattern 122 and the first ferroelectric material pattern 142 are located between the first gate G1 and the first channel region 112b, and form a gate dielectric structure GI. The sidewalls of the first gate dielectric pattern 122 and the sidewalls of the first ferroelectric material pattern 142 are aligned with the sidewalls of the first gate G1.

第二鐵電材料圖案144在基板100的頂面的法線方向ND上重疊於第二閘極G2以及第二通道區114b,且第二鐵電材料圖案144位於第二閘極G2以及第二通道區114b之間。第二鐵電材料圖案144的側壁對齊於第二閘極G2的側壁。 The second ferroelectric material pattern 144 overlaps the second gate G2 and the second channel region 114b in the normal direction ND of the top surface of the substrate 100, and the second ferroelectric material pattern 144 is located between the second gate G2 and the second channel region 114b. The sidewall of the second ferroelectric material pattern 144 is aligned with the sidewall of the second gate G2.

第二閘介電圖案124在基板100的頂面的法線方向ND上重疊於第三閘極G3以及第三通道區116b,且第二閘介電圖案124位於第三閘極G3以及第三通道區116b之間。第二閘介電圖案124的側壁對齊於第三閘極G3的側壁。 The second gate dielectric pattern 124 overlaps the third gate G3 and the third channel region 116b in the normal direction ND of the top surface of the substrate 100, and the second gate dielectric pattern 124 is located between the third gate G3 and the third channel region 116b. The sidewall of the second gate dielectric pattern 124 is aligned with the sidewall of the third gate G3.

在本實施例中,閘介電層120以及鐵電材料層140不重疊於第一源極區112a、第一汲極區112c、第二源極區114a、第二汲極區114c、第三源極區116a以及第三汲極區116c,因此,可以避免閘介電層120以及鐵電材料層140影響第一源極區112a、第一汲極區112c、第二源極區114a、第二汲極區114c、第三源極區116a以及第三汲極區116c的摻雜濃度,也可以避免摻雜製程對閘介電層120以及鐵電材料層140造成的負面影響。 In this embodiment, the gate dielectric layer 120 and the ferroelectric material layer 140 do not overlap the first source region 112a, the first drain region 112c, the second source region 114a, the second drain region 114c, the third source region 116a, and the third drain region 116c. The material layer 140 affects the doping concentration of the first source region 112a, the first drain region 112c, the second source region 114a, the second drain region 114c, the third source region 116a and the third drain region 116c, and can also avoid the negative impact of the doping process on the gate dielectric layer 120 and the ferroelectric material layer 140.

圖4A至圖4D是圖3的主動元件基板的製造方法的剖面示意圖。 Figures 4A to 4D are cross-sectional schematic diagrams of the manufacturing method of the active element substrate of Figure 3.

請參考圖4A,接續圖2C的步驟,形成第一閘極G1以及第二閘極G2於鐵電材料層140上,且形成第三閘極G3於閘介電 層120上。接著以第一閘極G1、第二閘極G2以及第三閘極G3為遮罩,圖案化閘介電層120以及鐵電材料層140,以形成第一閘介電圖案122、第二閘介電圖案124、第一鐵電材料圖案142以及第二鐵電材料圖案144。 Please refer to FIG. 4A , continuing the step of FIG. 2C , a first gate G1 and a second gate G2 are formed on the ferroelectric material layer 140, and a third gate G3 is formed on the gate dielectric layer 120. Then, the gate dielectric layer 120 and the ferroelectric material layer 140 are patterned using the first gate G1, the second gate G2 and the third gate G3 as masks to form a first gate dielectric pattern 122, a second gate dielectric pattern 124, a first ferroelectric material pattern 142 and a second ferroelectric material pattern 144.

接著請參考圖4B,以第一閘極G1、第二閘極G2以及第三閘極G3為遮罩,對第一半導體層112’、第二半導體層114’以及第三半導體層116’進行摻雜製程P,以形成包括第一源極區112a、第一通道區112b與第一汲極區112c的第一半導體層112、包括第二源極區114a、第二通道區114b與第二汲極區114c的第二半導體層114以及包括第三源極區116a、第三通道區116b與第三汲極區116c的第三半導體層116。在一些實施例中,摻雜製程P包括氫電漿製程或離子植入製程。 Next, please refer to Figure 4B. With the first gate G1, the second gate G2 and the third gate G3 as masks, a doping process P is performed on the first semiconductor layer 112', the second semiconductor layer 114' and the third semiconductor layer 116' to form a first semiconductor layer 112 including a first source region 112a, a first channel region 112b and a first drain region 112c, a second semiconductor layer 114 including a second source region 114a, a second channel region 114b and a second drain region 114c, and a third semiconductor layer 116 including a third source region 116a, a third channel region 116b and a third drain region 116c. In some embodiments, the doping process P includes a hydrogen plasma process or an ion implantation process.

請參考圖4C,形成層間介電層150於閘介電層120以及鐵電材料層140之上。層間介電層150接觸第一源極區112a、第一汲極區112c、第二源極區114a、第二汲極區114c、第三源極區116a以及第三汲極區116c。在一些實施例中,層間介電層150中含有氫原子,因此,可以藉由熱處理使氫原子擴散至第一半導體層112、第二半導體層114以及第三半導體層116中,以調整第一半導體層112、第二半導體層114以及第三半導體層116的電阻率。在一些實施例中,藉由層間介電層150中的氫原子進行摻雜製程,因此可以省略圖4B的摻雜製程P。 4C , an interlayer dielectric layer 150 is formed on the gate dielectric layer 120 and the ferroelectric material layer 140. The interlayer dielectric layer 150 contacts the first source region 112a, the first drain region 112c, the second source region 114a, the second drain region 114c, the third source region 116a, and the third drain region 116c. In some embodiments, the interlayer dielectric layer 150 contains hydrogen atoms, and thus, the hydrogen atoms can be diffused into the first semiconductor layer 112, the second semiconductor layer 114, and the third semiconductor layer 116 by heat treatment to adjust the resistivity of the first semiconductor layer 112, the second semiconductor layer 114, and the third semiconductor layer 116. In some embodiments, the doping process is performed by hydrogen atoms in the interlayer dielectric layer 150, so the doping process P of FIG. 4B can be omitted.

請參考圖4D,形成開口O1、O2、O3、O4、O5、O6於 層間介電層150中。 Please refer to FIG. 4D , openings O1, O2, O3, O4, O5, and O6 are formed in the interlayer dielectric layer 150.

最後請回到圖3,形成第一源極S1、第一汲極D1、第二源極S2、第二汲極D2、第三源極S3以及第三汲極D3於層間介電層150上。第一源極S1以及第一汲極D1分別填入開口O1、O2,以電性連接至第一半導體層112的第一源極區112a與第一汲極區112c。第二源極S2以及第二汲極D2分別填入開口O3、O4,以電性連接至第二半導體層114的第二源極區114a與第二汲極區114c。第三源極S3以及第三汲極D3分別填入開口O5、O6,以電性連接至第三半導體層116的第三源極區116a與第三汲極區116c。 Finally, please return to FIG. 3 to form a first source S1, a first drain D1, a second source S2, a second drain D2, a third source S3, and a third drain D3 on the interlayer dielectric layer 150. The first source S1 and the first drain D1 are filled into the openings O1 and O2, respectively, to be electrically connected to the first source region 112a and the first drain region 112c of the first semiconductor layer 112. The second source S2 and the second drain D2 are filled into the openings O3 and O4, respectively, to be electrically connected to the second source region 114a and the second drain region 114c of the second semiconductor layer 114. The third source S3 and the third drain D3 are filled into the openings O5 and O6 respectively to be electrically connected to the third source region 116a and the third drain region 116c of the third semiconductor layer 116.

經過上述製程後可大致上完成主動元件基板20的製作。 After the above process, the production of the active element substrate 20 can be basically completed.

圖5是依照本發明的一實施例的一種畫素電路PX的等效電路示意圖。圖5的畫素電路PX例如是前述任一實施例中的主動元件基板上的畫素電路PX。 FIG5 is a schematic diagram of an equivalent circuit of a pixel circuit PX according to an embodiment of the present invention. The pixel circuit PX of FIG5 is, for example, a pixel circuit PX on an active element substrate in any of the aforementioned embodiments.

請參考圖5,畫素電路PX包括第一半導體元件T1、第二半導體元件T2、第三半導體元件T3、儲存電容Cst及發光元件EL。 Please refer to Figure 5, the pixel circuit PX includes a first semiconductor element T1, a second semiconductor element T2, a third semiconductor element T3, a storage capacitor Cst and a light-emitting element EL.

第一半導體元件T1可作為開關電晶體使用。第一半導體元件T1的第一閘極電性連接於電壓VS1(例如為掃描線電壓),第一半導體元件T1的第一汲極(或第一源極)電性連接於電壓Vdata(例如為資料線電壓),第一半導體元件T1的第一源極(或第一汲極)電性連接於第一節點a。 The first semiconductor element T1 can be used as a switch transistor. The first gate of the first semiconductor element T1 is electrically connected to the voltage V S1 (for example, the scanning line voltage), the first drain (or the first source) of the first semiconductor element T1 is electrically connected to the voltage V data (for example, the data line voltage), and the first source (or the first drain) of the first semiconductor element T1 is electrically connected to the first node a.

第二半導體元件T2具有驅動電晶體以及記憶體的功能。第二半導體元件T2的第二閘極電性連接於第一節點a。第二半導體元件T2的第二汲極電性連接於電壓VDD,第二半導體元件T2的第二源極電性連接於第二節點b。 The second semiconductor element T2 has the functions of a driving transistor and a memory. The second gate of the second semiconductor element T2 is electrically connected to the first node a. The second drain of the second semiconductor element T2 is electrically connected to the voltage V DD , and the second source of the second semiconductor element T2 is electrically connected to the second node b.

第三半導體元件T3例如可作為感測電晶體使用。第三半導體元件T3的第三閘極電性連接於電壓VS2,第三半導體元件T3的第三汲極電性連接於第三節點c,第三半導體元件T3的第三源極電性連接於電壓Vsus。電壓VS2用於控制第三半導體元件T3的開關,以透過第三半導體元件T3將驅動電流的資訊傳送給外部晶片。 The third semiconductor element T3 can be used as a sensing transistor, for example. The third gate of the third semiconductor element T3 is electrically connected to the voltage V S2 , the third drain of the third semiconductor element T3 is electrically connected to the third node c, and the third source of the third semiconductor element T3 is electrically connected to the voltage V sus . The voltage V S2 is used to control the switch of the third semiconductor element T3, so as to transmit the information of the driving current to the external chip through the third semiconductor element T3.

儲存電容Cst的一端電性連接於第一節點a,儲存電容Cst的另一端電性連接於第三節點c。第二節點b與第三節點c電性相連。由於第二半導體元件T2的第二閘極電性連接至儲存電容Cst,即使關閉第一半導體元件T1,第二半導體元件T2仍可持續導通一小段時間。 One end of the storage capacitor Cst is electrically connected to the first node a, and the other end of the storage capacitor Cst is electrically connected to the third node c. The second node b is electrically connected to the third node c. Since the second gate of the second semiconductor element T2 is electrically connected to the storage capacitor Cst, even if the first semiconductor element T1 is turned off, the second semiconductor element T2 can continue to be turned on for a short period of time.

發光元件EL的一端電性連接於第二節點b,發光元件EL的另一端電性連接於電壓VSS。發光元件EL的亮度會因為通過第二半導體元件T2之驅動電流的大小不同而改變。發光元件EL例如是微型發光二極體、有機發光二極體或其他發光元件。 One end of the light emitting element EL is electrically connected to the second node b, and the other end of the light emitting element EL is electrically connected to the voltage V SS . The brightness of the light emitting element EL will change due to the different magnitudes of the driving current passing through the second semiconductor element T2 . The light emitting element EL is, for example, a micro light emitting diode, an organic light emitting diode or other light emitting element.

在本實施例中,在第一節點a處,第一半導體元件T1的第一源極(或第一汲極)、第二半導體元件T2的第二閘極以及儲存電容Cst的一端彼此電性連接。在第二節點b處,第二半導體 元件T2的第二源極以及發光元件EL的一端彼此電性連接。在第三節點c處,第三半導體元件T3的第三汲極以及儲存電容Cst的另一端彼此電性連接。第三半導體元件T3的第三汲極透過第三節點c以及第二節點b而電性連接至第二半導體元件T2的第二源極。 In this embodiment, at the first node a, the first source (or first drain) of the first semiconductor element T1, the second gate of the second semiconductor element T2, and one end of the storage capacitor Cst are electrically connected to each other. At the second node b, the second source of the second semiconductor element T2 and one end of the light-emitting element EL are electrically connected to each other. At the third node c, the third drain of the third semiconductor element T3 and the other end of the storage capacitor Cst are electrically connected to each other. The third drain of the third semiconductor element T3 is electrically connected to the second source of the second semiconductor element T2 through the third node c and the second node b.

圖6是依照本發明的一實施例的一種顯示裝置在圖5的畫素電路設置下的畫素補償操作流程圖。 FIG6 is a flowchart of a pixel compensation operation of a display device according to an embodiment of the present invention under the pixel circuit setting of FIG5.

以下簡述顯示裝置在畫素電路PX的設置下,畫素補償的操作方式,請同時參考圖5及圖6。首先,顯示裝置為關閉狀態,使畫素電路PX在背景執行灰階(grey level)感測。灰階感測的方式例如是將第一半導體元件T1、第二半導體元件T2及第三半導體元件T3開啟,以使通過第一半導體元件T1的驅動電壓和第二半導體元件T2的驅動電流可以透過第三半導體元件T3傳送給外部晶片。 The following briefly describes the operation of pixel compensation in the display device under the setting of the pixel circuit PX, please refer to Figure 5 and Figure 6. First, the display device is in a closed state, so that the pixel circuit PX performs gray level sensing in the background. The gray level sensing method is, for example, to turn on the first semiconductor element T1, the second semiconductor element T2 and the third semiconductor element T3, so that the driving voltage through the first semiconductor element T1 and the driving current of the second semiconductor element T2 can be transmitted to the external chip through the third semiconductor element T3.

接著,外部晶片透過訊號處理及演算,建立出對應模型,進而計算出對應的補償資訊。之後,再將補償資訊寫入畫素電路PX中。舉例來說,開啟第一半導體元件T1以及第二半導體元件T2以及第三半導體元件T3,以將外部晶片計算出的補償資訊寫入第二半導體元件T2中的鐵電材料層。具體地說,透過極化第二半導體元件T2中的鐵電材料層,使訊息記載於第二半導體元件T2中。在一些實施例中,打開第三半導體元件T3以減少第二半導體元件T2的源極與汲極之間的電壓差,或進一步使第二半導體元件T2的源極與汲極之間不具電壓差。 Then, the external chip establishes a corresponding model through signal processing and calculation, and then calculates the corresponding compensation information. After that, the compensation information is written into the pixel circuit PX. For example, the first semiconductor element T1, the second semiconductor element T2, and the third semiconductor element T3 are turned on to write the compensation information calculated by the external chip into the ferroelectric material layer in the second semiconductor element T2. Specifically, by polarizing the ferroelectric material layer in the second semiconductor element T2, the information is recorded in the second semiconductor element T2. In some embodiments, the third semiconductor element T3 is turned on to reduce the voltage difference between the source and the drain of the second semiconductor element T2, or further to eliminate the voltage difference between the source and the drain of the second semiconductor element T2.

接著,開啟顯示裝置。由於補償資訊已經寫入第二半導體元件T2,通過第二半導體元件T2的驅動電流的大小可以被調整,進而達成畫素補償的功能。在一些實施例中,在開啟顯示裝置時,第三半導體元件T3為關斷狀態。 Next, the display device is turned on. Since the compensation information has been written into the second semiconductor element T2, the size of the driving current through the second semiconductor element T2 can be adjusted, thereby achieving the function of pixel compensation. In some embodiments, when the display device is turned on, the third semiconductor element T3 is in the off state.

綜上所述,本發明的第二半導體元件T2具有記憶體的功能,因而不需要在外部晶片中設置補償記憶體,使整體系統簡化、成本降低。 In summary, the second semiconductor element T2 of the present invention has the function of a memory, so there is no need to set up a compensation memory in an external chip, which simplifies the overall system and reduces costs.

10:主動元件基板 10: Active component substrate

100:基板 100: Substrate

102:緩衝層 102: Buffer layer

112:第一半導體層 112: First semiconductor layer

112a:第一源極區 112a: First source region

112b:第一通道區 112b: First channel area

112c:第一汲極區 112c: First drain region

114:第二半導體層 114: Second semiconductor layer

114a:第二源極區 114a: Second source region

114b:第二通道區 114b: Second channel area

114c:第二汲極區 114c: Second drain region

116:第三半導體層 116: Third semiconductor layer

116a:第三源極區 116a: The third source region

116b:第三通道區 116b: Third channel area

116c:第三汲極區 116c: The third drain area

120:閘介電層 120: Gate dielectric layer

140:鐵電材料層 140: Ferroelectric material layer

150:層間介電層 150: Interlayer dielectric layer

D1:第一汲極 D1: First drain

D2:第二汲極 D2: Second drain

D3:第三汲極 D3: Third drain

G1:第一閘極 G1: First gate

G2:第二閘極 G2: Second gate

G3:第三閘極 G3: The third gate

GI:閘介電結構 GI: Gate dielectric structure

ND:法線方向 ND: Normal direction

O1,O2,O3,O4,O5,O6:開口 O1,O2,O3,O4,O5,O6: Open

S1:第一源極 S1: First source

S2:第二源極 S2: Second source

S3:第三源極 S3: The third source

T1:第一半導體元件 T1: First semiconductor element

T2:第二半導體元件 T2: Second semiconductor element

T3:第三半導體元件 T3: The third semiconductor element

Claims (16)

一種主動元件基板,包括:一基板;一第一半導體元件,設置於該基板之上,其中該第一半導體元件包括:一第一閘極以及一第一半導體層,其中該第一閘極與該第一半導體層之間夾有一閘介電結構,其中該閘介電結構包括一閘介電層的一部分與一鐵電材料層的一部分的堆疊;一第一源極以及一第一汲極,電性連接至該第一半導體層;以及一第二半導體元件,設置於該基板之上,且電性連接至該第一半導體元件,其中該第二半導體元件包括:一第二閘極以及一第二半導體層,其中該第二閘極與該第二半導體層之間夾有該鐵電材料層的另一部分,其中該第一閘極與該第一半導體層之間的距離大於該第二閘極與該第二半導體層之間的距離;一第二源極以及一第二汲極,電性連接至該第二半導體層。 An active device substrate comprises: a substrate; a first semiconductor device disposed on the substrate, wherein the first semiconductor device comprises: a first gate and a first semiconductor layer, wherein a gate dielectric structure is sandwiched between the first gate and the first semiconductor layer, wherein the gate dielectric structure comprises a stack of a portion of a gate dielectric layer and a portion of a ferroelectric material layer; a first source and a first drain electrically connected to the first semiconductor layer; and a second semiconductor layer. The body element is disposed on the substrate and electrically connected to the first semiconductor element, wherein the second semiconductor element includes: a second gate and a second semiconductor layer, wherein another portion of the ferroelectric material layer is sandwiched between the second gate and the second semiconductor layer, wherein the distance between the first gate and the first semiconductor layer is greater than the distance between the second gate and the second semiconductor layer; a second source and a second drain, electrically connected to the second semiconductor layer. 如請求項1所述的主動元件基板,其中該鐵電材料層自該第一閘極與該閘介電層之間延伸至該第二閘極以及該第二半導體層之間。 An active device substrate as described in claim 1, wherein the ferroelectric material layer extends from between the first gate and the gate dielectric layer to between the second gate and the second semiconductor layer. 如請求項1所述的主動元件基板,其中該鐵電材料層環繞該第一源極、該第一汲極、該第二源極以及該第二汲極。 An active device substrate as described in claim 1, wherein the ferroelectric material layer surrounds the first source, the first drain, the second source and the second drain. 如請求項1所述的主動元件基板,其中該第一源極、該第一汲極、該第二源極以及該第二汲極穿過該鐵電材料層。 An active device substrate as described in claim 1, wherein the first source, the first drain, the second source and the second drain pass through the ferroelectric material layer. 如請求項1所述的主動元件基板,其中該鐵電材料層包括:一第一鐵電材料圖案,重疊於該第一閘極;以及一第二鐵電材料圖案,重疊於該第二閘極,其中該第一鐵電材料圖案分離於該第二鐵電材料圖案。 An active device substrate as described in claim 1, wherein the ferroelectric material layer includes: a first ferroelectric material pattern overlapping the first gate; and a second ferroelectric material pattern overlapping the second gate, wherein the first ferroelectric material pattern is separated from the second ferroelectric material pattern. 如請求項5所述的主動元件基板,其中該第一鐵電材料圖案的側壁與該第一閘極的側壁對齊,且該第二鐵電材料圖案的側壁與該第二閘極的側壁對齊。 An active device substrate as described in claim 5, wherein the sidewall of the first ferroelectric material pattern is aligned with the sidewall of the first gate, and the sidewall of the second ferroelectric material pattern is aligned with the sidewall of the second gate. 如請求項1所述的主動元件基板,其中該第一半導體元件的次臨界擺幅小於60mV/dec。 An active element substrate as described in claim 1, wherein the subcritical swing of the first semiconductor element is less than 60mV/dec. 如請求項1所述的主動元件基板,其中該鐵電材料層的材料包括NixMgyZn0.98-yO或HfzZr1-zO2,其中x為0.01至0.05,y為0.05至0.15,z為0.4至0.6。 The active device substrate as claimed in claim 1, wherein the material of the ferroelectric material layer comprises Ni x Mg y Zn 0.98-y O or Hf z Zr 1-z O 2 , wherein x is 0.01 to 0.05, y is 0.05 to 0.15, and z is 0.4 to 0.6. 如請求項1所述的主動元件基板,其中該鐵電材料層的厚度為5奈米至50奈米,且該閘介電層的厚度為50奈米至100奈米。 An active device substrate as described in claim 1, wherein the thickness of the ferroelectric material layer is 5 nm to 50 nm, and the thickness of the gate dielectric layer is 50 nm to 100 nm. 如請求項1所述的主動元件基板,更包括:一第三半導體元件,設置於該基板之上,且電性連接至該第二半導體元件,其中該第三半導體元件包括:一第三閘極以及一第三半導體層,其中該第三閘極與該第三半導體層之間夾有該閘介電層的另一部分;一第三源極以及一第三汲極,電性連接至該第三半導體層。 The active device substrate as described in claim 1 further includes: a third semiconductor device disposed on the substrate and electrically connected to the second semiconductor device, wherein the third semiconductor device includes: a third gate and a third semiconductor layer, wherein another portion of the gate dielectric layer is sandwiched between the third gate and the third semiconductor layer; a third source and a third drain, electrically connected to the third semiconductor layer. 如請求項11所述的主動元件基板,其中該第一汲極電性連接至該第二閘極,且該第三汲極電性連接至該第二源極。 An active device substrate as described in claim 11, wherein the first drain is electrically connected to the second gate, and the third drain is electrically connected to the second source. 一種主動元件基板的製造方法,包括:形成一第一半導體層以及一第二半導體層於一基板之上;形成一閘介電層於該第一半導體層上;形成一鐵電材料層於該閘介電層以及該第二半導體層上;形成一第一閘極以及一第二閘極於該鐵電材料層上,其中該閘介電層位於該第一閘極與該第一半導體層之間,且該鐵電材料層位於該第一閘極與該第一半導體層之間以及該第二閘極與該第二半導體層之間;形成電性連接至該第一半導體層的一第一源極以及一第一汲極;以及形成電性連接至該第二半導體層一第二源極以及一第二汲極。 A method for manufacturing an active element substrate includes: forming a first semiconductor layer and a second semiconductor layer on a substrate; forming a gate dielectric layer on the first semiconductor layer; forming a ferroelectric material layer on the gate dielectric layer and the second semiconductor layer; forming a first gate and a second gate on the ferroelectric material layer, wherein the gate dielectric layer is located at The first gate is between the first semiconductor layer, and the ferroelectric material layer is between the first gate and the first semiconductor layer and between the second gate and the second semiconductor layer; a first source and a first drain are formed which are electrically connected to the first semiconductor layer; and a second source and a second drain are formed which are electrically connected to the second semiconductor layer. 如請求項12所述的主動元件基板的製造方法,更包括:以該第一閘極以及該第二閘極為遮罩,對該第一半導體層以及該第二半導體層執行一摻雜製程。 The manufacturing method of the active element substrate as described in claim 12 further includes: using the first gate and the second gate as masks to perform a doping process on the first semiconductor layer and the second semiconductor layer. 如請求項12所述的主動元件基板的製造方法,更包括:以該第一閘極以及該第二閘極為遮罩,圖案化該閘介電層以及該鐵電材料層。 The manufacturing method of the active device substrate as described in claim 12 further includes: using the first gate and the second gate as masks to pattern the gate dielectric layer and the ferroelectric material layer. 如請求項12所述的主動元件基板的製造方法,其中該閘介電層包括暴露出該第二半導體層的一開口,且該鐵電材料層填入該開口中以接觸該第二半導體層。 A method for manufacturing an active device substrate as described in claim 12, wherein the gate dielectric layer includes an opening exposing the second semiconductor layer, and the ferroelectric material layer is filled in the opening to contact the second semiconductor layer. 如請求項12所述的主動元件基板的製造方法,更包括:形成一第三半導體層於該基板之上,其中該第一半導體層、該第二半導體層以及該第三半導體層同時形成;形成該閘介電層於該第三半導體層上;形成一第三閘極於該閘介電層上,其中該第一閘極、該第二閘極以及該第三閘極同時形成;以及形成電性連接至該第三半導體層一第三源極以及一第三汲極,其中該第一源極、該第一汲極、該第二源極、該第二汲極、該第三源極以及該第三汲極同時形成。 The manufacturing method of the active element substrate as described in claim 12 further includes: forming a third semiconductor layer on the substrate, wherein the first semiconductor layer, the second semiconductor layer and the third semiconductor layer are formed at the same time; forming the gate dielectric layer on the third semiconductor layer; forming a third gate on the gate dielectric layer, wherein the first gate, the second gate and the third gate are formed at the same time; and forming a third source and a third drain electrically connected to the third semiconductor layer, wherein the first source, the first drain, the second source, the second drain, the third source and the third drain are formed at the same time.
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