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TWI814340B - Semiconductor device and manufacturing method thereof - Google Patents

Semiconductor device and manufacturing method thereof Download PDF

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TWI814340B
TWI814340B TW111114109A TW111114109A TWI814340B TW I814340 B TWI814340 B TW I814340B TW 111114109 A TW111114109 A TW 111114109A TW 111114109 A TW111114109 A TW 111114109A TW I814340 B TWI814340 B TW I814340B
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gate
electrode
dielectric layer
metal oxide
layer
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TW202324757A (en
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江家維
黃震鑠
陳衍豪
范揚順
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友達光電股份有限公司
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Abstract

A semiconductor device includes a substrate, a first gate, a semiconductor layer, a first gate dielectric layer, a second gate dielectric layer, a source electrode, a drain electrode, and a piezoelectric device. The first gate is located on the substrate. The semiconductor channel overlaps the first gate electrode in the direction of the normal line of the top surface of the substrate. The first gate dielectric layer is located between the semiconductor channel and the first gate. The second gate dielectric layer is over the semiconductor channel. The source electrode and the drain electrode are electrically connected to the semiconductor channel. The piezoelectric device is located on the second gate dielectric layer and includes a metal oxide electrode, a piezoelectric material, and a top electrode stacked on each other. The semiconductor channel is located between the metal oxide electrode and the first gate.

Description

半導體裝置及其製造方法Semiconductor device and manufacturing method thereof

本發明是有關於一種半導體裝置,且特別是有關於一種包括壓電裝置的半導體裝置及其製造方法。The present invention relates to a semiconductor device, and in particular, to a semiconductor device including a piezoelectric device and a manufacturing method thereof.

目前,常見的薄膜電晶體通常以非晶矽半導體作為通道,其中非晶矽半導體由於製程簡單且成本低廉,因此以廣泛的應用於各種薄膜電晶體中。At present, common thin film transistors usually use amorphous silicon semiconductors as channels. Amorphous silicon semiconductors are widely used in various thin film transistors due to their simple manufacturing process and low cost.

隨著顯示技術的進步,顯示面板的解析度逐年提升。為了使畫素電路中的薄膜電晶體縮小,許多廠商致力於研發新的半導體材料,例如金屬氧化物半導體材料。在金屬氧化物半導體材料中,氧化銦鎵鋅(indium gallium zinc oxide,IGZO)同時具有面積小以及電子遷移率高的優點,因此被視為一種重要的新型半導體材料。With the advancement of display technology, the resolution of display panels is increasing year by year. In order to shrink thin film transistors in pixel circuits, many manufacturers are committed to developing new semiconductor materials, such as metal oxide semiconductor materials. Among metal oxide semiconductor materials, indium gallium zinc oxide (IGZO) has the advantages of small area and high electron mobility, so it is regarded as an important new semiconductor material.

本發明提供一種半導體裝置,會因應所受壓力的變化而改變汲極電流的大小。The present invention provides a semiconductor device that changes the drain current in response to changes in pressure.

本發明提供一種半導體裝置的製造方法,具有製程良率高以及生產成本低的優點。The present invention provides a method for manufacturing a semiconductor device, which has the advantages of high process yield and low production cost.

本發明的至少一實施例提供一種半導體裝置。半導體裝置包括基板、第一閘極、半導體層、第一閘介電層、第二閘介電層、源極、汲極以及壓電裝置。第一閘極位於基板之上。半導體層於基板的頂面的法線方向上重疊於第一閘極。第一閘介電層位於半導體層與第一閘極之間。第二閘介電層位於半導體層之上。源極以及汲極電性連接半導體層。壓電裝置位於第二閘介電層之上,且包括彼此堆疊的金屬氧化物電極、壓電材料以及頂電極。半導體層位於金屬氧化物電極與第一閘極之間。At least one embodiment of the present invention provides a semiconductor device. The semiconductor device includes a substrate, a first gate, a semiconductor layer, a first gate dielectric layer, a second gate dielectric layer, a source, a drain, and a piezoelectric device. The first gate is located on the substrate. The semiconductor layer overlaps the first gate in a normal direction of the top surface of the substrate. The first gate dielectric layer is located between the semiconductor layer and the first gate electrode. The second gate dielectric layer is located on the semiconductor layer. The source electrode and the drain electrode are electrically connected to the semiconductor layer. The piezoelectric device is located on the second gate dielectric layer and includes a metal oxide electrode, a piezoelectric material and a top electrode stacked on each other. The semiconductor layer is located between the metal oxide electrode and the first gate.

本發明的至少一實施例提供半導體裝置的製造方法,包括:形成第一閘極於基板之上;形成第一閘介電層於第一閘極之上;形成半導體層,於第一閘介電層之上,其中第一閘介電層位於半導體層與第一閘極之間;形成第二閘介電層於半導體層之上;形成源極以及汲極,其中源極以及汲極電性連接半導體層;形成壓電裝置於第二閘介電層之上,其中壓電裝置包括彼此堆疊的金屬氧化物電極、壓電材料以及頂電極,其中半導體層位於金屬氧化物電極與第一閘極之間。At least one embodiment of the present invention provides a method for manufacturing a semiconductor device, including: forming a first gate on a substrate; forming a first gate dielectric layer on the first gate; forming a semiconductor layer on the first gate dielectric. On the electrical layer, the first gate dielectric layer is located between the semiconductor layer and the first gate electrode; a second gate dielectric layer is formed on the semiconductor layer; a source electrode and a drain electrode are formed, wherein the source electrode and the drain electrode are electrically Sexually connecting the semiconductor layer; forming a piezoelectric device on the second gate dielectric layer, wherein the piezoelectric device includes metal oxide electrodes, piezoelectric materials and top electrodes stacked on each other, wherein the semiconductor layer is located between the metal oxide electrode and the first between gates.

圖1是依照本發明的一實施例的一種半導體裝置的剖面示意圖。FIG. 1 is a schematic cross-sectional view of a semiconductor device according to an embodiment of the present invention.

請參考圖1,半導體裝置10A包括基板100、第一閘極210、半導體層220、第一閘介電層110、第二閘介電層120、源極232、汲極234以及壓電裝置300。Referring to FIG. 1 , the semiconductor device 10A includes a substrate 100 , a first gate electrode 210 , a semiconductor layer 220 , a first gate dielectric layer 110 , a second gate dielectric layer 120 , a source electrode 232 , a drain electrode 234 and a piezoelectric device 300 .

基板100之材質可為玻璃、石英、有機聚合物或不透光/反射材料(例如:導電材料、金屬、晶圓、陶瓷或其他可適用的材料)或是其他可適用的材料。若使用導電材料或金屬時,則在基板100上覆蓋一層絕緣層(未繪示),以避免短路問題。The material of the substrate 100 may be glass, quartz, organic polymer, opaque/reflective material (such as conductive material, metal, wafer, ceramic or other applicable materials) or other applicable materials. If conductive materials or metals are used, an insulating layer (not shown) is covered on the substrate 100 to avoid short circuit problems.

第一閘極210位於基板100之上。第一閘極210的材料例如為鉻、金、銀、銅、錫、鉛、鉿、鎢、鉬、釹、鈦、鉭、鋁、鋅等金屬、上述合金、上述金屬氧化物、上述金屬氮化物或上述之組合或其他導電材料。在一些實施例中,第一閘極210與基板100之間還可以包括其他導電層以及絕緣層。The first gate 210 is located on the substrate 100 . The material of the first gate 210 is, for example, chromium, gold, silver, copper, tin, lead, hafnium, tungsten, molybdenum, neodymium, titanium, tantalum, aluminum, zinc and other metals, the above alloys, the above metal oxides, the above metal nitrogen compounds or a combination of the above or other conductive materials. In some embodiments, other conductive layers and insulating layers may also be included between the first gate 210 and the substrate 100 .

第一閘介電層110位於第一閘極210上,且覆蓋第一閘極210。第一閘介電層110包括無機材料(例如:氧化矽、氮化矽、氮氧化矽、氧化鉿、氧化鋁、其他合適的材料、或上述至少二種材料的堆疊層)、有機材料或其他合適的材料或上述之組合。The first gate dielectric layer 110 is located on the first gate 210 and covers the first gate 210 . The first gate dielectric layer 110 includes inorganic materials (such as silicon oxide, silicon nitride, silicon oxynitride, hafnium oxide, aluminum oxide, other suitable materials, or stacked layers of at least two of the above materials), organic materials, or other Suitable materials or a combination of the above.

半導體層220位於第一閘介電層110上。第一閘介電層110位於半導體層220與第一閘極210之間。半導體層220於基板100的頂面的法線方向ND上重疊於第一閘極210。半導體層220的材料例如包括金屬氧化物,例如銦鎵鋅氧化物(Indium gallium zinc oxide, IGZO)、銦鎢鋅氧化物(Indium tungsten zinc oxide, IWZO)或其他合適的金屬氧化物半導體材料。在本實施例中,半導體層220包括源極區222、汲極區226以及位於源極區222與汲極區226之間的通道區224。源極區222以及汲極區226例如為經氫摻雜的區域。通道區224在法線方向ND上重疊於第一閘極210。在本實施例中,部分源極區222與部分汲極區226也在法線方向ND上重疊於第一閘極210。The semiconductor layer 220 is located on the first gate dielectric layer 110 . The first gate dielectric layer 110 is located between the semiconductor layer 220 and the first gate electrode 210 . The semiconductor layer 220 overlaps the first gate 210 in the normal direction ND of the top surface of the substrate 100 . The material of the semiconductor layer 220 includes, for example, metal oxides, such as indium gallium zinc oxide (IGZO), indium tungsten zinc oxide (IWZO) or other suitable metal oxide semiconductor materials. In this embodiment, the semiconductor layer 220 includes a source region 222 , a drain region 226 , and a channel region 224 located between the source region 222 and the drain region 226 . The source region 222 and the drain region 226 are, for example, hydrogen-doped regions. The channel area 224 overlaps the first gate 210 in the normal direction ND. In this embodiment, part of the source region 222 and part of the drain region 226 also overlap the first gate 210 in the normal direction ND.

第二閘介電層120位於半導體層220之上,且覆蓋半導體層220。第二閘介電層120包括無機材料(例如:氧化矽、氮化矽、氮氧化矽、氧化鉿、氧化鋁、其他合適的材料、或上述至少二種材料的堆疊層)、有機材料或其他合適的材料或上述之組合。The second gate dielectric layer 120 is located on the semiconductor layer 220 and covers the semiconductor layer 220 . The second gate dielectric layer 120 includes inorganic materials (such as silicon oxide, silicon nitride, silicon oxynitride, hafnium oxide, aluminum oxide, other suitable materials, or stacked layers of at least two of the above materials), organic materials, or other Suitable materials or a combination of the above.

第二閘極240位於第二閘介電層120之上,且於法線方向ND上重疊於半導體層240的通道區224。第二閘極240的材料例如為鉻、金、銀、銅、錫、鉛、鉿、鎢、鉬、釹、鈦、鉭、鋁、鋅等金屬、上述合金、上述金屬氧化物、上述金屬氮化物或上述之組合或其他導電材料。當第二閘極240包含鋁元素時,第二閘極240可以充當氫阻擋層,藉此減少氫原子擴散至的通道區224中的機率。The second gate 240 is located on the second gate dielectric layer 120 and overlaps the channel region 224 of the semiconductor layer 240 in the normal direction ND. The material of the second gate 240 is, for example, chromium, gold, silver, copper, tin, lead, hafnium, tungsten, molybdenum, neodymium, titanium, tantalum, aluminum, zinc and other metals, the above alloys, the above metal oxides, the above metal nitrogen compounds or a combination of the above or other conductive materials. When the second gate 240 includes an aluminum element, the second gate 240 may act as a hydrogen barrier layer, thereby reducing the probability of hydrogen atoms diffusing into the channel region 224 .

層間介電層130位於第二閘介電層120上。層間介電層130包括重疊於半導體層220的通道區224以及第二閘極240的開口,第二閘極240位於前述開口的底部。兩個接觸孔貫穿層間介電層130以及第二閘介電層120,並延伸至半導體層220的源極區222與汲極區226。The interlayer dielectric layer 130 is located on the second gate dielectric layer 120 . The interlayer dielectric layer 130 includes an opening that overlaps the channel region 224 of the semiconductor layer 220 and the second gate 240 , and the second gate 240 is located at the bottom of the opening. The two contact holes penetrate the interlayer dielectric layer 130 and the second gate dielectric layer 120 and extend to the source region 222 and the drain region 226 of the semiconductor layer 220 .

層間介電層130包括無機材料(例如:氧化矽、氮化矽、氮氧化矽、氧化鉿、氧化鋁、其他合適的材料、或上述至少二種材料的堆疊層)、有機材料或其他合適的材料或上述之組合。在一些實施例中,層間介電層130中包括氫元素。在一些實施例中,在製造半導體裝置10A的過程中,透過熱處理製程使層間介電層130中的氫元素擴散至半導體層220的源極區222與汲極區226以及金屬氧化物電極310,但本發明不以此為限。在其他實施例中,透過氫電漿製程或其他摻雜製程使氫元素擴散至源極區222與汲極區226以及金屬氧化物電極310。The interlayer dielectric layer 130 includes inorganic materials (such as silicon oxide, silicon nitride, silicon oxynitride, hafnium oxide, aluminum oxide, other suitable materials, or stacked layers of at least two of the above materials), organic materials, or other suitable materials. materials or a combination of the above. In some embodiments, hydrogen is included in the interlayer dielectric layer 130 . In some embodiments, during the manufacturing process of the semiconductor device 10A, the hydrogen element in the interlayer dielectric layer 130 is diffused to the source region 222 and the drain region 226 of the semiconductor layer 220 and the metal oxide electrode 310 through a heat treatment process. However, the present invention is not limited to this. In other embodiments, the hydrogen element is diffused into the source region 222 and the drain region 226 and the metal oxide electrode 310 through a hydrogen plasma process or other doping processes.

源極232以及汲極234填入貫穿層間介電層130以及第二閘介電層120的兩個接觸孔,以分別電性連接半導體層220的源極區222與汲極區226。源極232以及汲極234的材料例如為鉻、金、銀、銅、錫、鉛、鉿、鎢、鉬、釹、鈦、鉭、鋁、鋅等金屬、上述合金、上述金屬氧化物、上述金屬氮化物或上述之組合或其他導電材料。The source electrode 232 and the drain electrode 234 are filled in the two contact holes penetrating the interlayer dielectric layer 130 and the second gate dielectric layer 120 to electrically connect the source electrode region 222 and the drain electrode region 226 of the semiconductor layer 220 respectively. The source electrode 232 and the drain electrode 234 are made of, for example, chromium, gold, silver, copper, tin, lead, hafnium, tungsten, molybdenum, neodymium, titanium, tantalum, aluminum, zinc and other metals, the above alloys, the above metal oxides, the above Metal nitrides or combinations of the above or other conductive materials.

壓電裝置300位於第二閘介電層120之上,且包括彼此堆疊的金屬氧化物電極310、壓電材料320以及頂電極330。The piezoelectric device 300 is located on the second gate dielectric layer 120 and includes a metal oxide electrode 310, a piezoelectric material 320 and a top electrode 330 stacked on each other.

金屬氧化物電極310填入層間介電層130的開口中,以電性連接第二閘極240。在本實施例中,金屬氧化物電極310直接接觸第二閘極240。在本實施例中,層間介電層130的開口的底部的寬度等於金屬氧化物電極310的寬度,也可以說金屬氧化物電極310填滿整個層間介電層130的開口的底部。在一些實施例中,金屬氧化物電極310包括經氟處理的銦鎵鋅氧化物。半導體層220位於金屬氧化物電極310與第一閘極210之間。The metal oxide electrode 310 is filled in the opening of the interlayer dielectric layer 130 to electrically connect the second gate electrode 240 . In this embodiment, the metal oxide electrode 310 directly contacts the second gate 240 . In this embodiment, the width of the bottom of the opening of the interlayer dielectric layer 130 is equal to the width of the metal oxide electrode 310 . It can also be said that the metal oxide electrode 310 fills the entire bottom of the opening of the interlayer dielectric layer 130 . In some embodiments, metal oxide electrode 310 includes fluorine-treated indium gallium zinc oxide. The semiconductor layer 220 is located between the metal oxide electrode 310 and the first gate 210 .

壓電材料320位於金屬氧化物電極310上。在一些實施例中,壓電材料320包括聚合物或聚合物與陶瓷材料的複合材料。舉例來說,壓電材料320包括P(VDF-TrFE)或P(VDF-TrFE)與鋯鈦酸鉛(PZT)的複合材料。Piezoelectric material 320 is located on metal oxide electrode 310. In some embodiments, piezoelectric material 320 includes a polymer or a composite of a polymer and a ceramic material. For example, the piezoelectric material 320 includes P(VDF-TrFE) or a composite material of P(VDF-TrFE) and lead zirconate titanate (PZT).

頂電極330位於壓電材料320上。在一些實施例中,頂電極330與源極232皆電性連接至一參考電壓,例如接地電壓。在一些實施例中,頂電極330的材料例如為鉻、金、銀、銅、錫、鉛、鉿、鎢、鉬、釹、鈦、鉭、鋁、鋅等金屬、上述合金、上述金屬氧化物、上述金屬氮化物或上述之組合或其他導電材料。在本實施例中,頂電極330的側邊與壓電材料320的側邊對齊,但本發明不以此為限。在其他實施例中,頂電極330的側邊與壓電材料320的側邊不對齊。Top electrode 330 is located on piezoelectric material 320. In some embodiments, the top electrode 330 and the source electrode 232 are both electrically connected to a reference voltage, such as ground voltage. In some embodiments, the material of the top electrode 330 is, for example, chromium, gold, silver, copper, tin, lead, hafnium, tungsten, molybdenum, neodymium, titanium, tantalum, aluminum, zinc and other metals, the above alloys, the above metal oxides , the above metal nitride or a combination of the above or other conductive materials. In this embodiment, the sides of the top electrode 330 are aligned with the sides of the piezoelectric material 320, but the invention is not limited thereto. In other embodiments, the sides of top electrode 330 are not aligned with the sides of piezoelectric material 320 .

圖2A至圖2K是圖1的半導體裝置的製造方法的剖面示意圖。2A to 2K are schematic cross-sectional views of the manufacturing method of the semiconductor device of FIG. 1 .

請參考圖2A,形成第一閘極210於基板100之上。接著,形成第一閘介電層110於第一閘極210之上。Referring to FIG. 2A , a first gate 210 is formed on the substrate 100 . Next, a first gate dielectric layer 110 is formed on the first gate electrode 210 .

請參考圖2B,形成半導體層220’於第一閘介電層110之上,其中第一閘介電層110位於半導體層220’與第一閘極210之間。接著,形成第二閘介電層120於半導體層220’之上。Referring to FIG. 2B, a semiconductor layer 220' is formed on the first gate dielectric layer 110, where the first gate dielectric layer 110 is located between the semiconductor layer 220' and the first gate electrode 210. Next, a second gate dielectric layer 120 is formed on the semiconductor layer 220'.

請參考圖2C,形成第二閘極240於第二閘介電層120之上。接著,以第二閘極240為罩幕,對半導體層220’執行摻雜製程P,以形成包括源極區222、汲極區226以及通道區224的半導體層220。在一些實施例中,摻雜製程P例如為氫電漿製程。Referring to FIG. 2C , a second gate 240 is formed on the second gate dielectric layer 120 . Next, using the second gate 240 as a mask, a doping process P is performed on the semiconductor layer 220' to form the semiconductor layer 220 including the source region 222, the drain region 226 and the channel region 224. In some embodiments, the doping process P is, for example, a hydrogen plasma process.

在本實施例中,第二閘介電層120包覆半導體層220’,但本發明不以此為限。在其他實施例中,圖案化第二閘介電層120,使第二閘介電層120暴露出不重疊於第二閘極240的半導體層220’。在一些實施例中,在圖案化第二閘介電層120之後才對半導體層220’進行摻雜製程P。In this embodiment, the second gate dielectric layer 120 covers the semiconductor layer 220', but the invention is not limited thereto. In other embodiments, the second gate dielectric layer 120 is patterned so that the second gate dielectric layer 120 exposes the semiconductor layer 220' that does not overlap the second gate electrode 240. In some embodiments, the doping process P is performed on the semiconductor layer 220' after patterning the second gate dielectric layer 120.

請參考圖2D,形成層間介電層130於第二閘極240以及第二閘介電層120之上。層間介電層130覆蓋第二閘極240。Referring to FIG. 2D , an interlayer dielectric layer 130 is formed on the second gate 240 and the second gate dielectric layer 120 . The interlayer dielectric layer 130 covers the second gate 240 .

請參考圖2E,形成貫穿層間介電層130以及第二閘介電層120的第一接觸孔TH1以及第二接觸孔TH2。Referring to FIG. 2E , a first contact hole TH1 and a second contact hole TH2 penetrating the interlayer dielectric layer 130 and the second gate dielectric layer 120 are formed.

請參考圖2F,形成源極232以及汲極234。源極232以及汲極234屬於相同圖案化導電層。源極232以及汲極234分別填入第一接觸孔TH1以及第二接觸孔TH2以電性連接半導體層220的源極區222以及汲極區226。Referring to FIG. 2F, a source electrode 232 and a drain electrode 234 are formed. The source electrode 232 and the drain electrode 234 belong to the same patterned conductive layer. The source electrode 232 and the drain electrode 234 are respectively filled in the first contact hole TH1 and the second contact hole TH2 to electrically connect the source electrode region 222 and the drain electrode region 226 of the semiconductor layer 220 .

請參考圖2G,於層間介電層130中形成開口OP1,開口1暴露出第二閘極240的至少部分頂面。在本實施例中,在形成源極232以及汲極234之後才於層間介電層130中形成開口OP1,藉此避免形成源極232以及汲極234時的蝕刻製程傷害到第二閘極240的頂面。Referring to FIG. 2G , an opening OP1 is formed in the interlayer dielectric layer 130 , and the opening 1 exposes at least part of the top surface of the second gate 240 . In this embodiment, the opening OP1 is formed in the interlayer dielectric layer 130 after the source electrode 232 and the drain electrode 234 are formed, thereby preventing the second gate electrode 240 from being damaged by the etching process when the source electrode 232 and the drain electrode 234 are formed. the top surface.

請參考圖2H至圖2K以及圖1,形成壓電裝置300於第二閘極240之上。Referring to FIGS. 2H to 2K and FIG. 1 , the piezoelectric device 300 is formed on the second gate 240 .

請先參考圖2H,形成金屬氧化物材料層310’’於開口OP1中。在本實施例中,金屬氧化物材料層310’’延伸至開口OP1外,並覆蓋層間介電層130、源極232以及汲極234。Please refer to FIG. 2H first, forming a metal oxide material layer 310'' in the opening OP1. In this embodiment, the metal oxide material layer 310″ extends outside the opening OP1 and covers the interlayer dielectric layer 130, the source electrode 232 and the drain electrode 234.

接著請參考圖2I,對金屬氧化物材料層310’’進行氟處理。例如以氟電漿處理金屬氧化物材料層310’’,以獲得經氟處理的金屬氧化物材料層310’。Next, please refer to FIG. 2I to perform fluorine treatment on the metal oxide material layer 310''. For example, the metal oxide material layer 310' is treated with fluorine plasma to obtain a fluorine-treated metal oxide material layer 310'.

接著請參考圖2J,圖案化經氟處理的金屬氧化物材料層310’,以獲得金屬氧化物電極310。在本實施例中,金屬氧化物電極310中的氟含量大於半導體層220中的氟含量。在一些實施例中,未對金屬氧化物電極310進行氫摻雜,因此,金屬氧化物電極310中的氫含量小於源極區222以及汲極區226中的氫含量,但本發明不以此為限。在其他實施例中,在進行氟處理之前或之後進行氫摻雜製程,因此,金屬氧化物電極310中的氫含量大於或等於源極區222以及汲極區226中的氫含量。Next, referring to FIG. 2J, the fluorine-treated metal oxide material layer 310' is patterned to obtain a metal oxide electrode 310. In this embodiment, the fluorine content in the metal oxide electrode 310 is greater than the fluorine content in the semiconductor layer 220 . In some embodiments, the metal oxide electrode 310 is not hydrogen-doped. Therefore, the hydrogen content in the metal oxide electrode 310 is less than the hydrogen content in the source region 222 and the drain region 226 , but this is not the case in the present invention. is limited. In other embodiments, a hydrogen doping process is performed before or after the fluorine treatment. Therefore, the hydrogen content in the metal oxide electrode 310 is greater than or equal to the hydrogen content in the source region 222 and the drain region 226 .

請參考圖2K,形成壓電材料320於金屬氧化物電極310上。在本實施例中,由於金屬氧化物電極310的表面經過氟處理,壓電材料在經過熱退火結晶化的過程中氟的擴散會在壓電材料中形成碳氟鍵結(C-F, C-F 2)、碳氟氫鍵結(C-FH),因此可以提升壓電材料320的結晶性。 Referring to FIG. 2K , a piezoelectric material 320 is formed on the metal oxide electrode 310 . In this embodiment, since the surface of the metal oxide electrode 310 is treated with fluorine, the diffusion of fluorine during the thermal annealing and crystallization process of the piezoelectric material will form carbon-fluorine bonds (CF, CF 2 ) in the piezoelectric material. , carbon-fluorine hydrogen bonding (C-FH), so the crystallinity of the piezoelectric material 320 can be improved.

最後請回到圖1,形成頂電極330於壓電材料320上。至此,半導體裝置10A大致完成。Finally, please return to FIG. 1 to form a top electrode 330 on the piezoelectric material 320. At this point, the semiconductor device 10A is substantially completed.

圖3是依照本發明的一實施例的一種半導體裝置的剖面示意圖。在此必須說明的是,圖3的實施例沿用圖1的實施例的元件標號與部分內容,其中採用相同或近似的標號來表示相同或近似的元件,並且省略了相同技術內容的說明。關於省略部分的說明可參考前述實施例,在此不贅述。FIG. 3 is a schematic cross-sectional view of a semiconductor device according to an embodiment of the present invention. It must be noted here that the embodiment of FIG. 3 follows the component numbers and part of the content of the embodiment of FIG. 1 , where the same or similar numbers are used to represent the same or similar elements, and descriptions of the same technical content are omitted. For descriptions of omitted parts, reference may be made to the foregoing embodiments and will not be described again here.

圖3的半導體裝置10B與圖1的半導體裝置10A的主要差異在於:半導體裝置10B的金屬氧化物電極310的寬度大於層間介電層130的開口OP1的底部的寬度。金屬氧化物電極310例如沿著開口OP1的側面延伸至層間介電層130的頂面。The main difference between the semiconductor device 10B of FIG. 3 and the semiconductor device 10A of FIG. 1 is that the width of the metal oxide electrode 310 of the semiconductor device 10B is greater than the width of the bottom of the opening OP1 of the interlayer dielectric layer 130 . The metal oxide electrode 310 extends, for example, along the side of the opening OP1 to the top surface of the interlayer dielectric layer 130 .

圖4是依照本發明的一實施例的一種半導體裝置的剖面示意圖。在此必須說明的是,圖4的實施例沿用圖1的實施例的元件標號與部分內容,其中採用相同或近似的標號來表示相同或近似的元件,並且省略了相同技術內容的說明。關於省略部分的說明可參考前述實施例,在此不贅述。FIG. 4 is a schematic cross-sectional view of a semiconductor device according to an embodiment of the present invention. It must be noted here that the embodiment of FIG. 4 follows the component numbers and part of the content of the embodiment of FIG. 1 , where the same or similar numbers are used to represent the same or similar elements, and the description of the same technical content is omitted. For descriptions of omitted parts, reference may be made to the foregoing embodiments and will not be described again here.

圖4的半導體裝置10C與圖1的半導體裝置10A的主要差異在於:半導體裝置10C的金屬氧化物電極310的寬度小於層間介電層130的開口OP1的底部的寬度。金屬氧化物電極310例如未接觸或部分接觸開口OP1的側面,且壓電材料320例如接觸第二閘極240的部分頂面。The main difference between the semiconductor device 10C of FIG. 4 and the semiconductor device 10A of FIG. 1 is that the width of the metal oxide electrode 310 of the semiconductor device 10C is smaller than the width of the bottom of the opening OP1 of the interlayer dielectric layer 130 . For example, the metal oxide electrode 310 does not contact or partially contacts the side surface of the opening OP1 , and the piezoelectric material 320 contacts, for example, part of the top surface of the second gate 240 .

圖5是依照本發明的一實施例的一種半導體裝置的剖面示意圖。在此必須說明的是,圖5的實施例沿用圖1的實施例的元件標號與部分內容,其中採用相同或近似的標號來表示相同或近似的元件,並且省略了相同技術內容的說明。關於省略部分的說明可參考前述實施例,在此不贅述。FIG. 5 is a schematic cross-sectional view of a semiconductor device according to an embodiment of the present invention. It must be noted here that the embodiment of FIG. 5 follows the component numbers and part of the content of the embodiment of FIG. 1 , where the same or similar numbers are used to represent the same or similar elements, and descriptions of the same technical content are omitted. For descriptions of omitted parts, reference may be made to the foregoing embodiments and will not be described again here.

圖5的半導體裝置10D與圖1的半導體裝置10A的主要差異在於:半導體裝置10D的壓電裝置300a的金屬氧化物電極310a直接形成於第二閘介電層120上。換句話說,半導體裝置10D不包括第二閘極(如圖1的第二閘極240)。在本實施例中,金屬氧化物電極310a例如為經氫參雜以及經氟處理的金屬氧化物(例如銦鎵鋅氧化物或銦鎢鋅氧化物)。The main difference between the semiconductor device 10D of FIG. 5 and the semiconductor device 10A of FIG. 1 is that the metal oxide electrode 310 a of the piezoelectric device 300 a of the semiconductor device 10D is directly formed on the second gate dielectric layer 120 . In other words, the semiconductor device 10D does not include the second gate (the second gate 240 of FIG. 1 ). In this embodiment, the metal oxide electrode 310a is, for example, a hydrogen-doped and fluorine-treated metal oxide (such as indium gallium zinc oxide or indium tungsten zinc oxide).

圖6A至圖6I是圖5的半導體裝置的製造方法的剖面示意圖。6A to 6I are schematic cross-sectional views of the manufacturing method of the semiconductor device of FIG. 5 .

圖6A接續了圖2B的製程。請參考圖6A,形成金屬氧化物材料層310’’於第二閘介電層120上。金屬氧化物材料層310’’在基板100的頂面的法線方向ND上重疊於整個半導體層220’。Figure 6A continues the process of Figure 2B. Referring to FIG. 6A, a metal oxide material layer 310″ is formed on the second gate dielectric layer 120. The metal oxide material layer 310'' overlaps the entire semiconductor layer 220' in the normal direction ND of the top surface of the substrate 100.

請參考圖6B,對金屬氧化物材料層310’’進行氟處理。例如以氟電漿處理金屬氧化物材料層310’’,以獲得經氟處理的金屬氧化物材料層310’。由於金屬氧化物材料層310’’覆蓋半導體層220’,藉此可以降低氟元素擴散至半導體層220’的機率。Referring to FIG. 6B, the metal oxide material layer 310″ is subjected to fluorine treatment. For example, the metal oxide material layer 310' is treated with fluorine plasma to obtain a fluorine-treated metal oxide material layer 310'. Since the metal oxide material layer 310'' covers the semiconductor layer 220', the probability of fluorine element diffusing into the semiconductor layer 220' can be reduced.

接著請參考圖6C,圖案化經氟處理的金屬氧化物材料層310’,以獲得金屬氧化物電極310。金屬氧化物電極310形成於第二閘介電層120上。Next, referring to FIG. 6C, the fluorine-treated metal oxide material layer 310' is patterned to obtain a metal oxide electrode 310. The metal oxide electrode 310 is formed on the second gate dielectric layer 120 .

請參考圖6D,以金屬氧化物電極310為罩幕,對半導體層220’執行摻雜製程P,以形成包括源極區222、汲極區226以及通道區224的半導體層220。在一些實施例中,摻雜製程P例如為氫電漿製程。在本實施例中,金屬氧化物電極310經摻雜製程P後變成經氫參雜的金屬氧化物電極310a。Referring to FIG. 6D, using the metal oxide electrode 310 as a mask, a doping process P is performed on the semiconductor layer 220' to form the semiconductor layer 220 including the source region 222, the drain region 226 and the channel region 224. In some embodiments, the doping process P is, for example, a hydrogen plasma process. In this embodiment, the metal oxide electrode 310 becomes a hydrogen-doped metal oxide electrode 310a after undergoing the doping process P.

在本實施例中,經氫參雜的金屬氧化物電極310a中的氟含量大於半導體層220中的氟含量。In this embodiment, the fluorine content in the hydrogen-doped metal oxide electrode 310 a is greater than the fluorine content in the semiconductor layer 220 .

請參考圖6E,形成層間介電層130於金屬氧化物電極310a以及第二閘介電層120之上。層間介電層130覆蓋金屬氧化物電極310a。Referring to FIG. 6E, an interlayer dielectric layer 130 is formed on the metal oxide electrode 310a and the second gate dielectric layer 120. The interlayer dielectric layer 130 covers the metal oxide electrode 310a.

請參考圖6F,形成貫穿層間介電層130以及第二閘介電層120的第一接觸孔TH1以及第二接觸孔TH2。第一接觸孔TH1以及第二接觸孔TH2暴露出半導體層220的源極區222以及汲極區226。Referring to FIG. 6F , a first contact hole TH1 and a second contact hole TH2 penetrating the interlayer dielectric layer 130 and the second gate dielectric layer 120 are formed. The first contact hole TH1 and the second contact hole TH2 expose the source region 222 and the drain region 226 of the semiconductor layer 220 .

請參考圖6G,形成源極232以及汲極234。源極232以及汲極234屬於相同圖案化導電層。源極232以及汲極234分別填入第一接觸孔TH1以及第二接觸孔TH2以電性連接半導體層220的源極區222以及汲極區226。Referring to FIG. 6G , source 232 and drain 234 are formed. The source electrode 232 and the drain electrode 234 belong to the same patterned conductive layer. The source electrode 232 and the drain electrode 234 are respectively filled in the first contact hole TH1 and the second contact hole TH2 to electrically connect the source electrode region 222 and the drain electrode region 226 of the semiconductor layer 220 .

請參考圖6H,於層間介電層130中形成開口OP1,開口OP1暴露出金屬氧化物電極310a。在本實施例中,在形成源極232以及汲極234之後才於層間介電層130中形成開口OP1,藉此避免形成源極232以及汲極234時的蝕刻製程傷害到金屬氧化物電極310a,但本發明不以此為限。在其他實施例中,第一接觸孔TH1第二接觸孔TH2以及開口OP1透過同一次蝕刻製程形成。Referring to FIG. 6H, an opening OP1 is formed in the interlayer dielectric layer 130, and the opening OP1 exposes the metal oxide electrode 310a. In this embodiment, the opening OP1 is formed in the interlayer dielectric layer 130 after the source electrode 232 and the drain electrode 234 are formed, thereby preventing the metal oxide electrode 310a from being damaged by the etching process during the formation of the source electrode 232 and the drain electrode 234. , but the present invention is not limited to this. In other embodiments, the first contact hole TH1, the second contact hole TH2 and the opening OP1 are formed through the same etching process.

請參考圖6I,形成壓電材料320於金屬氧化物電極310a上。在本實施例中,由於金屬氧化物電極310a的表面經過氟處理,壓電材料在經過熱退火結晶化的過程中氟的擴散會在壓電材料中形成碳氟鍵結(C-F, C-F 2)、碳氟氫鍵結(C-FH),因此可以提升壓電材料320的結晶性。 Referring to FIG. 6I, a piezoelectric material 320 is formed on the metal oxide electrode 310a. In this embodiment, since the surface of the metal oxide electrode 310a is treated with fluorine, the diffusion of fluorine during the thermal annealing and crystallization process of the piezoelectric material will form carbon-fluorine bonds (CF, CF 2 ) in the piezoelectric material. , carbon-fluorine hydrogen bonding (C-FH), so the crystallinity of the piezoelectric material 320 can be improved.

最後請回到圖5,形成頂電極330於壓電材料320上。至此,半導體裝置10D大致完成。Finally, please return to FIG. 5 to form a top electrode 330 on the piezoelectric material 320. At this point, the semiconductor device 10D is substantially completed.

圖7是依照本發明的一實施例的一種半導體裝置的第二閘極或金屬氧化物電極電壓變化與汲極電流變化的曲線圖。圖8是依照本發明的一實施例的一種半導體裝置的時間與汲極電流變化的波型圖。FIG. 7 is a graph illustrating voltage changes and drain current changes of the second gate or metal oxide electrode of a semiconductor device according to an embodiment of the present invention. FIG. 8 is a waveform diagram of time and drain current changes of a semiconductor device according to an embodiment of the present invention.

請參考圖7,橫軸為第二閘極或金屬氧化物電極的電壓V TG,縱軸為汲極電流(I D)。 Please refer to Figure 7. The horizontal axis is the voltage V TG of the second gate or metal oxide electrode, and the vertical axis is the drain current ( ID ).

在未對壓電裝置施加額外壓力時,半導體裝置的電壓-電流曲線符合圖7中的實線;在對壓電裝置施加額外壓力時,半導體裝置的電壓-電流曲線符合圖7中的虛線。當固定第一閘極的電壓,使半導體裝置處於亞閾值區(Subthreshold region)時,對壓電裝置施加額外壓力後,汲極電流會由I 1減少至I 2,I 1與I 2之間具有電流變化ΔI,透過量測電流變化ΔI,可以得知外界對壓電裝置施加的額外壓力為多少。 When no additional pressure is applied to the piezoelectric device, the voltage-current curve of the semiconductor device conforms to the solid line in Figure 7; when additional pressure is applied to the piezoelectric device, the voltage-current curve of the semiconductor device conforms to the dotted line in Figure 7. When the voltage of the first gate is fixed so that the semiconductor device is in the subthreshold region, and additional pressure is applied to the piezoelectric device, the drain current will decrease from I 1 to I 2 , between I 1 and I 2 There is a current change ΔI. By measuring the current change ΔI, we can know how much additional pressure the outside world exerts on the piezoelectric device.

在本實施例中,由於對壓電裝置施加額外壓力後,壓電材料靠進金屬氧化物電極的一側出現正電壓,且壓電材料靠進頂電極的一側出現負電壓,因此圖7中的虛線相較於實線向右偏移,即施壓後之汲極電流下降。額外施加壓力時所產生的正負電壓與壓電材料之極化方向有關,因此,在其他實施例中,對壓電裝置施加額外壓力後,壓電材料靠進金屬氧化物電極的一側出現負電壓,且壓電材料靠進頂電極的一側出現正電壓,此時虛線將會相較於實線向左偏移,即施壓後之汲極電流上升。In this embodiment, since additional pressure is applied to the piezoelectric device, a positive voltage appears on the side of the piezoelectric material that enters the metal oxide electrode, and a negative voltage appears on the side of the piezoelectric material that enters the top electrode. Therefore, Figure 7 The dotted line in is shifted to the right compared to the solid line, that is, the drain current decreases after applying pressure. The positive and negative voltages generated when additional pressure is applied are related to the polarization direction of the piezoelectric material. Therefore, in other embodiments, after additional pressure is applied to the piezoelectric device, a negative voltage appears on the side of the piezoelectric material that is close to the metal oxide electrode. voltage, and a positive voltage appears on the side of the piezoelectric material that is close to the top electrode. At this time, the dotted line will shift to the left compared to the solid line, that is, the drain current will increase after the pressure is applied.

綜上所述,本發明的半導體裝置會因應所受壓力的變化而改變汲極電流的大小。此外,本發明的半導體裝置具有製程良率高以及生產成本低的優點。In summary, the semiconductor device of the present invention changes the drain current in response to changes in pressure. In addition, the semiconductor device of the present invention has the advantages of high process yield and low production cost.

10A, 10B, 10C, 10D:半導體裝置 100:基板 110:第一閘介電層 120:第二閘介電層 130:層間介電層 210:第一閘極 220’, 220:半導體層 222:源極區 224:通道區 226:汲極區 232:源極 234:汲極 240:第二閘極 300, 300a:壓電裝置 310’, 310’’:金屬氧化物材料層 310, 310a:金屬氧化物電極 320:壓電材料 330:頂電極 ND:法線方向 OP1:開口 P:摻雜製程 TH1:第一接觸孔 TH2:第二接觸孔 10A, 10B, 10C, 10D: Semiconductor devices 100:Substrate 110: First gate dielectric layer 120: Second gate dielectric layer 130: Interlayer dielectric layer 210: first gate 220’, 220: Semiconductor layer 222: Source region 224: Passage area 226: Drainage area 232:Source 234:Jiji 240: Second gate 300, 300a: Piezoelectric device 310’, 310’’: metal oxide material layer 310, 310a: Metal oxide electrode 320: Piezoelectric materials 330:Top electrode ND: normal direction OP1: Open your mouth P: doping process TH1: first contact hole TH2: Second contact hole

圖1是依照本發明的一實施例的一種半導體裝置的剖面示意圖。 圖2A至圖2K是圖1的半導體裝置的製造方法的剖面示意圖。 圖3是依照本發明的一實施例的一種半導體裝置的剖面示意圖。 圖4是依照本發明的一實施例的一種半導體裝置的剖面示意圖。 圖5是依照本發明的一實施例的一種半導體裝置的剖面示意圖。 圖6A至圖6I是圖5的半導體裝置的製造方法的剖面示意圖。 圖7是依照本發明的一實施例的一種半導體裝置的第二閘極或金屬氧化物電極電壓變化與汲極電流變化的曲線圖。 圖8是依照本發明的一實施例的一種半導體裝置的時間與汲極電流變化的波型圖。 FIG. 1 is a schematic cross-sectional view of a semiconductor device according to an embodiment of the present invention. 2A to 2K are schematic cross-sectional views of the manufacturing method of the semiconductor device of FIG. 1 . FIG. 3 is a schematic cross-sectional view of a semiconductor device according to an embodiment of the present invention. FIG. 4 is a schematic cross-sectional view of a semiconductor device according to an embodiment of the present invention. FIG. 5 is a schematic cross-sectional view of a semiconductor device according to an embodiment of the present invention. 6A to 6I are schematic cross-sectional views of the manufacturing method of the semiconductor device of FIG. 5 . FIG. 7 is a graph illustrating voltage changes and drain current changes of the second gate or metal oxide electrode of a semiconductor device according to an embodiment of the present invention. FIG. 8 is a waveform diagram of time and drain current changes of a semiconductor device according to an embodiment of the present invention.

10A:半導體裝置 10A:Semiconductor device

100:基板 100:Substrate

110:第一閘介電層 110: First gate dielectric layer

120:第二閘介電層 120: Second gate dielectric layer

130:層間介電層 130: Interlayer dielectric layer

210:第一閘極 210: first gate

220:半導體層 220: Semiconductor layer

222:源極區 222: Source region

224:通道區 224: Passage area

226:汲極區 226: Drainage area

232:源極 232:Source

234:汲極 234:Jiji

240:第二閘極 240: Second gate

300:壓電裝置 300: Piezoelectric device

310:金屬氧化物電極 310: Metal oxide electrode

320:壓電材料 320: Piezoelectric materials

330:頂電極 330:Top electrode

ND:法線方向 ND: normal direction

Claims (10)

一種半導體裝置,包括:一基板;一第一閘極,位於該基板之上;一半導體層,於該基板的頂面的一法線方向上重疊於該第一閘極;一第一閘介電層,位於該半導體層與該第一閘極之間;一第二閘介電層,位於該半導體層之上;一源極以及一汲極,電性連接該半導體層;一層間介電層,位於該第二閘介電層上,其中該層間介電層包括重疊於該半導體層的一開口;以及一壓電裝置,位於該第二閘介電層之上,且包括彼此堆疊的一金屬氧化物電極、一壓電材料以及一頂電極,其中該半導體層位於該金屬氧化物電極與該第一閘極之間,且該金屬氧化物電極填入該開口中。 A semiconductor device includes: a substrate; a first gate located on the substrate; a semiconductor layer overlapping the first gate in a normal direction on the top surface of the substrate; a first gate An electrical layer is located between the semiconductor layer and the first gate; a second gate dielectric layer is located on the semiconductor layer; a source electrode and a drain electrode are electrically connected to the semiconductor layer; an interlayer dielectric layer a layer located on the second gate dielectric layer, wherein the interlayer dielectric layer includes an opening overlapping the semiconductor layer; and a piezoelectric device located on the second gate dielectric layer and including stacked A metal oxide electrode, a piezoelectric material and a top electrode, wherein the semiconductor layer is located between the metal oxide electrode and the first gate, and the metal oxide electrode fills the opening. 如請求項1所述的半導體裝置,其中該半導體層的材料包括銦鎵鋅氧化物,且該金屬氧化物電極包括經氟處理的銦鎵鋅氧化物。 The semiconductor device of claim 1, wherein the material of the semiconductor layer includes indium gallium zinc oxide, and the metal oxide electrode includes fluorine-treated indium gallium zinc oxide. 如請求項1所述的半導體裝置,其中該半導體層包括經氫摻雜的一源極區、經氫摻雜的一汲極區以及位於該源極區與該汲極區之間的一通道區,且該金屬氧化物電極經氫摻雜。 The semiconductor device of claim 1, wherein the semiconductor layer includes a hydrogen-doped source region, a hydrogen-doped drain region, and a channel between the source region and the drain region. area, and the metal oxide electrode is hydrogen doped. 如請求項1所述的半導體裝置,更包括:一第二閘極,於該法線方向上重疊於該半導體層,且該金屬氧化物電極直接接觸該第二閘極。 The semiconductor device of claim 1, further comprising: a second gate overlapping the semiconductor layer in the normal direction, and the metal oxide electrode directly contacts the second gate. 如請求項1所述的半導體裝置,其中該金屬氧化物電極的寬度小於、大於或等於該層間介電層的該開口的底部的寬度。 The semiconductor device of claim 1, wherein the width of the metal oxide electrode is less than, greater than, or equal to the width of the bottom of the opening of the interlayer dielectric layer. 一種半導體裝置的製造方法,包括:形成一第一閘極於一基板之上;形成一第一閘介電層於該第一閘極之上;形成一半導體層於該第一閘介電層之上,其中該第一閘介電層位於該半導體層與該第一閘極之間;形成一第二閘介電層於該半導體層之上;形成一源極以及一汲極,其中該源極以及該汲極電性連接該半導體層;以及形成一壓電裝置於該第二閘介電層之上,其中該壓電裝置包括彼此堆疊的一金屬氧化物電極、一壓電材料以及一頂電極,其中該半導體層位於該金屬氧化物電極與該第一閘極之間,其中在形成該金屬氧化物電極之前或之後形成一層間介電層於該第二閘介電層上,其中該層間介電層包括重疊於該半導體層的一開口,且該金屬氧化物電極位於該開口中。 A method of manufacturing a semiconductor device, including: forming a first gate on a substrate; forming a first gate dielectric layer on the first gate; forming a semiconductor layer on the first gate dielectric layer above, wherein the first gate dielectric layer is located between the semiconductor layer and the first gate electrode; a second gate dielectric layer is formed on the semiconductor layer; a source electrode and a drain electrode are formed, wherein the The source electrode and the drain electrode are electrically connected to the semiconductor layer; and a piezoelectric device is formed on the second gate dielectric layer, wherein the piezoelectric device includes a metal oxide electrode stacked on each other, a piezoelectric material and a top electrode, wherein the semiconductor layer is located between the metal oxide electrode and the first gate electrode, wherein an interlayer dielectric layer is formed on the second gate dielectric layer before or after forming the metal oxide electrode, The interlayer dielectric layer includes an opening overlapping the semiconductor layer, and the metal oxide electrode is located in the opening. 如請求項6所述的半導體裝置的製造方法,其中形成該壓電裝置的方法包括: 形成該金屬氧化物電極於該第二閘介電層之上;形成該壓電材料於該金屬氧化物電極之上;以及形成該頂電極於該壓電材料之上。 The manufacturing method of a semiconductor device as claimed in claim 6, wherein the method of forming the piezoelectric device includes: The metal oxide electrode is formed on the second gate dielectric layer; the piezoelectric material is formed on the metal oxide electrode; and the top electrode is formed on the piezoelectric material. 如請求項7所述的半導體裝置的製造方法,更包括:在形成該金屬氧化物電極之後,以該金屬氧化物電極為罩幕,對該半導體層執行一摻雜製程。 The method of manufacturing a semiconductor device as claimed in claim 7, further comprising: after forming the metal oxide electrode, using the metal oxide electrode as a mask to perform a doping process on the semiconductor layer. 如請求項6所述的半導體裝置的製造方法,更包括:形成一第二閘極於該第二閘介電層之上;以及形成該壓電裝置於該第二閘極之上。 The method of manufacturing a semiconductor device according to claim 6, further comprising: forming a second gate on the second gate dielectric layer; and forming the piezoelectric device on the second gate. 如請求項9所述的半導體裝置的製造方法,更包括:在形成該壓電裝置之前,以該第二閘極為罩幕,對該半導體層執行一摻雜製程。 The manufacturing method of a semiconductor device as claimed in claim 9, further comprising: before forming the piezoelectric device, using the second gate as a mask to perform a doping process on the semiconductor layer.
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