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AR084400A1 - Compuestos de hetaril(tio)carboxamida para controlar plagas de invertebrados - Google Patents

Compuestos de hetaril(tio)carboxamida para controlar plagas de invertebrados

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Publication number
AR084400A1
AR084400A1 ARP110102667A ARP110102667A AR084400A1 AR 084400 A1 AR084400 A1 AR 084400A1 AR P110102667 A ARP110102667 A AR P110102667A AR P110102667 A ARP110102667 A AR P110102667A AR 084400 A1 AR084400 A1 AR 084400A1
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Argentina
Prior art keywords
alkyl
haloalkyl
cycloalkyl
alkoxy
phenyl
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ARP110102667A
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Basf Se
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/58—1,2-Diazines; Hydrogenated 1,2-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/60—1,4-Diazines; Hydrogenated 1,4-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/76—1,3-Oxazoles; Hydrogenated 1,3-oxazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P33/00—Antiparasitic agents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
    • C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
    • C07D403/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
    • C07D403/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/14—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D407/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group C07D405/00
    • C07D407/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group C07D405/00 containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
    • C07D413/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
    • C07D417/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
    • C07D417/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
    • C07D417/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing three or more hetero rings

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  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Environmental Sciences (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Veterinary Medicine (AREA)
  • General Chemical & Material Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Tropical Medicine & Parasitology (AREA)
  • Public Health (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Medicinal Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Thiazole And Isothizaole Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)

Abstract

También un método para controlar plagas de invertebrados, un método para proteger material de propagación de plantas y/o las plantas que crecen de él, material de propagación de plantas, que comprende al menos un compuesto de hetaril(tio)carboxamida, un método para tratar o proteger a un animal de la infestación o infección por parásitos y una composición agrícola que contiene al menos uno de estos compuestos.Reivindicación 1: Hetaril(tio)carboxamida compuestos caracterizados por la fórmula (1) en donde X es S ó O; R1 es CN, alquilo C1-10, haloalquilo C1-10, alquenilo C2-10, haloalquenilo C2-10, alquinilo C2-10, haloalquinilo C2-10, alquilen C1-5-CN, alquilen C1-5-ORa, C(Y)Rb, alquilen C1-5-C(Y)Rb, C(Y)ORc, alquilen C1-5-C(Y)ORc, S(O)mRd, alquilen C1-5-NReRf, C(Y)NRgRh, alquilen C1-5-C(Y)NRgRh, S(O)mNReRf, C(Y)NRiNReRf, alquilen C1-5-S(O)mRd, alquilen C1-5-S(O)mNReRd, alquilen C1-5-C(Y)NRiNReRf, fenilo, heterociclilo, hetarilo, fenil-alquilo C1-5, cicloalquilo C3-10, cicloalquil C3-10-alquilo C1-5, fenoxi-alquilo C1-5, heterociclil-alquilo C1-5, hetaril-alquilo C1-5, en donde el anillo de los últimos nueve radicales mencionados puede no estar sustituido o puede llevar 1, 2, 3, 4 ó 5 sustituyentes iguales o diferentes seleccionados de los radicales Ry; A es hetarilo de 5 ó 6 miembros que tiene un resto de heteroátomo que está seleccionado del grupo que consiste en O, S, N o N-RN como miembro del anillo y 0, 1 ó 2 otros restos heteroatómicos N como miembros del anillo y que también tiene 2, 3, 4 ó 5 átomos de carbono como miembros del anillo donde los miembros del anillo del átomo de carbono puede no estar sustituido o 1, 2, 3 ó 4 de los miembros del anillo del átomo de carbono llevan un radical RA como un sustituyente, donde RA está seleccionado del grupo que consiste en halógeno, CN, NO2, alquilo C1-10, alquenilo C2-10 y alquinilo C2-10, en donde los últimos tres radicales mencionados pueden no estar sustituidos, pueden estar parcial o completamente halogenados o puede llevar 1, 2 ó 3 sustituyentes iguales o diferentes Rx, y también del grupo que consiste en ORa, C(Y)Rb, C(Y)ORc, S(O)mRd, NReRf, heterociclilo, fenilo, hetarilo, cicloalquilo C3-10 y cicloalquenilo C5-10, en donde los últimos cinco radicales mencionados puede no estar sustituido o puede llevar 1, 2, 3, 4 ó 5 sustituyentes iguales o diferentes Ry; y RN está seleccionado del grupo que consiste en hidrógeno, CN, NO2, alquilo C1-10, alquenilo C2-10 y alquinilo C2-10, en donde los últimos tres radicales mencionados pueden no estar sustituidos, pueden estar parcial o completamente halogenados o puede llevar 1, 2 ó 3 sustituyentes iguales o diferentes Rx, y también del grupo que consiste en ORa, C(Y)Rb, C(Y)ORc, S(O)mRd, NReRf, C(Y)NRgRh, S(O)mNReRf, C(Y)NRiNReRf, alquilen C1-5-ORa, alquilen C1-5-CN, alquilen C1-5-C(Y)Rb, alquilen C1-5-C(Y)ORc, alquilen C1-5-NReRf, alquilen C1-5-C(Y)NRgRh, alquilen C1-5-S(O)mRd, alquilen C1-5-S(O)mNReRf, alquilen C1-5-NRiNReRf, heterociclilo, hetarilo, cicloalquilo C3-10, cicloalquenilo C5-10, heterociclil-alquilo C1-5, hetaril-alquilo C1-5, cicloalquil C3-10- alquilo C1-5, cicloalquenil C5-10-alquilo C1-5, fenil-alquilo C1-5 y fenilo, en donde los anillos de los últimos diez radicales mencionados puede no estar sustituido o puede llevar 1, 2, 3, 4 ó 5 sustituyentes iguales o diferentes Ry; y donde m es 0, 1 ó 2; Y es O ó S; Ra, Rb, Rc están seleccionados, de modo independiente entre sí, de hidrógeno, alquilo C1-4, haloalquilo C1-4, cicloalquilo C3-6, cicloalquil C3-6-metilo, halocicloalquilo C3-6, alquenilo C2-4, haloalquenilo C2-4, alquinilo C2-4, alcoxi C1-4-alquilo C1-4, fenilo, hetarilo, heterociclilo, fenil-alquilo C1-4, hetaril-alquilo C1-4 y heterociclil-alquilo C1-4, en donde el anillo en los últimos seis radicales mencionados puede no estar sustituido o puede llevar 1, 2, 3, 4 o 5 sustituyentes que, de modo independiente entre sí, están seleccionados de halógeno, ciano, nitro, alquilo C1-4, haloalquilo C1-4, alcoxi C1-4 y haloalcoxi C1-4; Rd está seleccionado de alquilo C1-4, haloalquilo C1-4, cicloalquilo C3-6, cicloalquil C3-6-metilo, halocicloalquilo C3-6, alquenilo C2-4, haloalquenilo C2-4, alquinilo C2-4, alcoxi C1-4-alquilo C1-4, fenilo, hetarilo, heterociclilo, fenil-alquilo C1-4, hetaril-alquilo C1-4 y heterociclil-alquileno C1-4,donde el anillo en los últimos seis radicales mencionados puede no estar sustituido o puede llevar 1, 2, 3, 4 ó 5 sustituyentes que están seleccionados, de modo independiente entre si, de halógeno, ciano, nitro, alquilo C1-4, haloalquilo C1-4, alcoxi C1-4 y haloalcoxi C1-4; Re, Rf están seleccionados, de modo independiente entre sí, de hidrógeno, alquilo C1-4, haloalquilo C1-4, cicloalquilo C3-6, cicloalquil C3-6-metilo, halocicloalquilo C3-6, alquenilo C2-4, haloalquenilo C2-4, alquinilo C2-4, alcoxi C1-4-alquilo C1-4, alquil C1-4-carbonilo, haloalquil C1-4-carbonilo, alquil C1-4-sulfonilo, haloalquil C1-4-sulfonilo, fenilo, fenilcarbonilo, fenilsulfonilo, hetarilo, hetarilcarbonilo, hetarilsulfonilo, heterociclilo, heterociclilcarbonilo, heterociclilsulfonilo, fenil-alquilo C1-4, hetaril-alquilo C1-4 y heterociclil-alquilo C1-4, en donde el anillo en los últimos doce radicales mencionados puede no estar sustituido o puede llevar 1, 2, 3, 4 ó 5 sustituyentes que, de modo independiente entre sí, están seleccionados de halógeno, ciano, nitro, alquilo C1-4, haloalquilo C1-4, alcoxi C1-4 y haloalcoxi C1-4; o Re y Rf junto con el átomo de nitrógeno al que están unidos forman un heterociclo saturado o insaturado de 5 ó 6 miembros, que puede llevar otro heteroátomo seleccionado de O, S y N como un átomo del miembro del anillo y en donde el heterociclo puede no estar sustituido o puede llevar 1, 2, 3, 4 ó 5 sustituyentes que están seleccionados, de modo independiente entre sí, de halógeno, ciano, nitro, alquilo C1-4, haloalquilo C1-4, alcoxi C1-4 y haloalcoxi C1-4; Rg y Rh están seleccionados, de modo independiente entre sí, de hidrógeno, alquilo C1-4, haloalquilo C1-4, cicloalquilo C3-6, halocicloalquilo C3-6, alquenilo C2-4, haloalquenilo C2-4, alquinilo C2-4, alcoxi C1-4-alquilo C1-4, fenilo, hetarilo, heterociclilo, fenil-alquilo C1-4, hetaril-alquilo C1-4 y heterociclil-alquilo C1-4, en donde el anillo en los últimos seis radicales mencionados puede no estar sustituido o puede llevar 1, 2, 3, 4 o 5 sustituyentes que están seleccionados, de modo independiente entre sí, de halógeno, ciano, nitro, alquilo C1-4, haloalquilo C1-4, alcoxi C1-4 y haloalcoxi C1-4; Ri está seleccionado de hidrógeno, alquilo C1-4, haloalquilo C1-4, cicloalquilo C3-6, cicloalquil C3-6-metilo, halocicloalquilo C3-6, alquenilo C2-4, haloalquenilo C2-4, alquinilo C2-4, alcoxi C1-4-alquilo C1-4, fenilo y fenilalquilo C1-4, en donde el anillo fenilo en los dos últimos radicales mencionados puede no estar sustituido o puede llevar 1, 2, 3, 4 ó 5 sustituyentes que están seleccionados, de modo independiente entre sí, de halógeno, ciano, nitro, alquilo C1-4, haloalquilo C1-4, alcoxi C1-4 y haloalcoxi C1-4; Rx están seleccionados, de modo independiente entre sí, de ciano, nitro, alcoxi C1-4, haloalcoxi C1-4, alquil C1-4-tio, haloalquil C1-4-tio, alquil C1-4-sulfinilo, haloalquil C1-4-sulfinilo, alquil C1-4-sulfonilo, haloalquil C1-4-sulfonilo, alquil C1-10-carbonilo, cicloalquilo C3-6, heterociclilo de 5 a 7 miembros, fenilo, cicloalcoxi C3-8, heterocicliloxi de 3 a 6 miembros y fenoxi, en donde los últimos seis radicales mencionados puede no estar sustituido o puede llevar 1, 2, 3, 4 ó 5 radicales seleccionados del grupo que consiste en halógeno, ciano, nitro, alquilo C1-4, haloalquilo C1-4, alcoxi C1-4 y haloalcoxi C1-4; Ry está seleccionado de halógeno, ciano, nitro, alquilo C1-4, haloalquilo C1-4, alcoxi C1-4, haloalcoxi C1-4, S(O)mRd, S(O)mNReRf, alquil C1-4-carbonilo, haloalquil C1-4-carbonilo, alcoxi C1-4-carbonilo, haloalcoxi C1-4-carbonilo, cicloalquilo C3-6, halocicloalquilo C3-6, alquenilo C2-4, haloalquenilo C2-4, alquinilo C2-4, alcoxi C1-4-alquilo C1-4, cicloalquilo C3-6, heterociclilo de 5 a 7 miembros, hetarilo, fenilo, cicloalcoxi C3-6, heterocicliloxi de 3 a 6 miembros, hetariloxi y fenoxi, en donde los últimos 8 radicales mencionados puede no estar sustituido o puede llevar 1, 2, 3, 4 ó 5 radicales seleccionados de halógeno, ciano, nitro, alquilo C1-4, haloalquilo C1-4, alcoxi C1-4 y haloalcoxi C1-4; y sus sales, sus N-óxidos, sus tautómeros y las sales de dichos N-óxidos o tautómeros.
ARP110102667A 2010-07-22 2011-07-22 Compuestos de hetaril(tio)carboxamida para controlar plagas de invertebrados AR084400A1 (es)

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EP (1) EP2595981B1 (es)
JP (1) JP2013532643A (es)
KR (1) KR20130129907A (es)
CN (1) CN103003263B (es)
AR (1) AR084400A1 (es)
AU (1) AU2011281688A1 (es)
BR (1) BR112013001475B1 (es)
CA (1) CA2804163A1 (es)
CL (1) CL2013000059A1 (es)
CR (1) CR20130042A (es)
EA (1) EA201201673A1 (es)
ES (1) ES2531448T3 (es)
MX (1) MX2013000394A (es)
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PT3300602T (pt) * 2012-06-20 2020-06-17 Basf Se Misturas pesticidas que compreendem um composto de pirazol
US9701659B2 (en) 2014-05-19 2017-07-11 Syngenta Participations Ag Insecticidally active amide derivatives with sulfur-substituted phenyl or pyridine groups
EP3227285B1 (en) * 2014-12-01 2022-08-10 Syngenta Participations AG Pesticidally active amide heterocyclic derivatives with sulphur containing substituents
UA127604C2 (uk) * 2017-12-21 2023-11-01 Басф Се Пестицидні сполуки

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ES2531448T3 (es) 2015-03-16
AU2011281688A1 (en) 2013-02-07
US20130116264A1 (en) 2013-05-09
US9247745B2 (en) 2016-02-02
CA2804163A1 (en) 2012-01-26
CR20130042A (es) 2013-03-05
BR112013001475A2 (pt) 2016-05-31
WO2012010534A1 (en) 2012-01-26
EP2595981A1 (en) 2013-05-29
CL2013000059A1 (es) 2014-02-21
KR20130129907A (ko) 2013-11-29
MX2013000394A (es) 2013-01-28
ZA201301311B (en) 2014-04-30
JP2013532643A (ja) 2013-08-19
BR112013001475A8 (pt) 2017-11-14
CN103003263B (zh) 2015-07-22
EA201201673A1 (ru) 2013-06-28
BR112013001475B1 (pt) 2018-04-24

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