TWI877927B - Semiconductor device and manufacturing method thereof - Google Patents
Semiconductor device and manufacturing method thereof Download PDFInfo
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本發明是有關於一種半導體裝置及其製造方法。 The present invention relates to a semiconductor device and a method for manufacturing the same.
目前,一般的薄膜電晶體通常使用非晶矽半導體作為通道材料。由於非晶矽半導體製程簡單、成本低廉,因此被廣泛應用於各種薄膜電晶體中。然而,隨著顯示技術的不斷進步,顯示面板的解析度也不斷提升。為了縮小畫素電路中薄膜電晶體的尺寸,眾多製造商正致力於研發具有更高載子遷移率的半導體材料,其中包括金屬氧化物半導體材料。 At present, general thin film transistors usually use amorphous silicon semiconductors as channel materials. Due to the simple process and low cost of amorphous silicon semiconductors, they are widely used in various thin film transistors. However, with the continuous advancement of display technology, the resolution of display panels is also constantly improving. In order to reduce the size of thin film transistors in pixel circuits, many manufacturers are committed to developing semiconductor materials with higher carrier mobility, including metal oxide semiconductor materials.
這些新型半導體材料的研發旨在提升薄膜電晶體的性能,進而增強顯示器件的整體效能。金屬氧化物半導體材料具有卓越電子遷移率,能夠應對不斷提升的解析度需求。因此,製造商尋求這些新材料以實現更小、更高效的畫素配置,同時確保顯示品質的持續提升。這也推動了半導體材料領域的技術創新和製程改進。 The research and development of these new semiconductor materials aims to improve the performance of thin film transistors and thus enhance the overall performance of display devices. Metal oxide semiconductor materials have excellent electron mobility and can cope with the ever-increasing resolution requirements. Therefore, manufacturers seek these new materials to achieve smaller and more efficient pixel configurations while ensuring continued improvement in display quality. This also promotes technological innovation and process improvements in the field of semiconductor materials.
本發明提供一種半導體裝置,具有高開啟電流(Ion)、高臨界電壓(Vth)、低漏電流(Ioff)以及佔地面積小的優點。 The present invention provides a semiconductor device having the advantages of high turn-on current (I on ), high critical voltage (Vth), low leakage current (I off ) and small footprint.
本發明提供一種半導體裝置的製造方法,具有高良率以及高對位精度的優點。 The present invention provides a method for manufacturing a semiconductor device, which has the advantages of high yield and high alignment accuracy.
本發明的至少一實施例提供一種半導體裝置,其包括基板、第一源極/汲極、第一絕緣結構、第二源極/汲極、第二絕緣結構、第三源極/汲極、半導體結構、閘介電層以及閘極。第一源極/汲極位於基板之上。第一絕緣結構位於第一源極/汲極上,且具有重疊於第一源極/汲極的頂面的第一通孔。第一通孔於基板上的正投影圖案完全位於第一源極/汲極於基板上的正投影圖案內。第二源極/汲極位於第一絕緣結構上,且具有重疊於第一通孔的第二通孔。第二絕緣結構位於第二源極/汲極上,且具有重疊於第二通孔的第三通孔。第三源極/汲極位於第二絕緣結構上,且具有重疊於第三通孔的第四通孔。半導體結構,從第一通孔內之第一源極/汲極的頂面沿著第一通孔的側壁向上延伸,並連續且依序地沿著第二通孔的側壁、第三通孔的側壁以及第四通孔的側壁延伸至第三源極/汲極的頂面。閘介電層位於半導體結構上。閘極位於閘介電層上。 At least one embodiment of the present invention provides a semiconductor device, which includes a substrate, a first source/drain, a first insulating structure, a second source/drain, a second insulating structure, a third source/drain, a semiconductor structure, a gate dielectric layer, and a gate. The first source/drain is located on the substrate. The first insulating structure is located on the first source/drain and has a first through hole overlapping the top surface of the first source/drain. The orthographic projection pattern of the first through hole on the substrate is completely located within the orthographic projection pattern of the first source/drain on the substrate. The second source/drain is located on the first insulating structure and has a second through hole overlapping the first through hole. The second insulating structure is located on the second source/drain and has a third through hole overlapping the second through hole. The third source/drain is located on the second insulating structure and has a fourth through hole overlapping the third through hole. The semiconductor structure extends upward from the top surface of the first source/drain in the first through hole along the side wall of the first through hole, and continuously and sequentially extends along the side wall of the second through hole, the side wall of the third through hole, and the side wall of the fourth through hole to the top surface of the third source/drain. The gate dielectric layer is located on the semiconductor structure. The gate is located on the gate dielectric layer.
本發明的至少一實施例提供一種半導體裝置的製造方法,其包括以下步驟。依序形成第一導電層、第一絕緣層、第二導電層、第二絕緣層以及第三導電層。對第一導電層、第一絕緣 層、第二導電層、第二絕緣層以及第三導電層執行多次蝕刻製程,以獲得第一源極/汲極、具有第一通孔的第一絕緣結構、具有第二通孔的第二源極/汲極、具有第三通孔的第二絕緣結構以及具有第四通孔的第三源極/汲極,其中執行多次蝕刻製程的方法包括以下步驟。形成圖案化光阻層於第三導電層上。以圖案化光阻層為罩幕對第三導電層執行第一濕蝕刻製程以獲得第三源極/汲極。以圖案化光阻層為罩幕對第二絕緣層執行第一乾蝕刻製程,以獲得中介絕緣結構,中介絕緣結構具有重疊於第四通孔的開口,且開口的寬度小於第四通孔的寬度。以中介絕緣結構以及圖案化光阻層為罩幕對第二導電層執行第二乾蝕刻製程或第二濕蝕刻製程,以獲得第二源極/汲極。移除圖案化光阻層。以第三源極/汲極為罩幕對中介絕緣結構執行第三乾蝕刻製程,以獲得第二絕緣結構。以第二源極/汲極為罩幕對第一絕緣層執行第四乾蝕刻製程,以獲得第一絕緣結構。形成半導體結構於第一通孔、第二通孔、第三通孔以及第四通孔中。形成閘介電層於半導體結構上。形成閘極於閘介電層上。 At least one embodiment of the present invention provides a method for manufacturing a semiconductor device, which includes the following steps. A first conductive layer, a first insulating layer, a second conductive layer, a second insulating layer, and a third conductive layer are sequentially formed. Multiple etching processes are performed on the first conductive layer, the first insulating layer, the second conductive layer, the second insulating layer, and the third conductive layer to obtain a first source/drain, a first insulating structure with a first through hole, a second source/drain with a second through hole, a second insulating structure with a third through hole, and a third source/drain with a fourth through hole, wherein the method for performing multiple etching processes includes the following steps. A patterned photoresist layer is formed on the third conductive layer. A first wet etching process is performed on the third conductive layer using the patterned photoresist layer as a mask to obtain a third source/drain. A first dry etching process is performed on the second insulating layer using the patterned photoresist layer as a mask to obtain an intermediate insulating structure, wherein the intermediate insulating structure has an opening overlapping the fourth through hole, and the width of the opening is smaller than the width of the fourth through hole. A second dry etching process or a second wet etching process is performed on the second conductive layer using the intermediate insulating structure and the patterned photoresist layer as masks to obtain a second source/drain. The patterned photoresist layer is removed. Perform a third dry etching process on the intermediate insulating structure using the third source/drain as a mask to obtain a second insulating structure. Perform a fourth dry etching process on the first insulating layer using the second source/drain as a mask to obtain a first insulating structure. Form a semiconductor structure in the first through hole, the second through hole, the third through hole, and the fourth through hole. Form a gate dielectric layer on the semiconductor structure. Form a gate on the gate dielectric layer.
本發明的至少一實施例提供一種半導體裝置的製造方法,其包括以下步驟。依序形成第一導電層、第一絕緣層、第二導電層、第二絕緣層以及第三導電層。對第一導電層、第一絕緣層、第二導電層、第二絕緣層以及第三導電層執行多次蝕刻製程,以獲得第一源極/汲極、具有第一通孔的第一絕緣結構、具有第二通孔的第二源極/汲極、具有第三通孔的第二絕緣結構以及具 有第四通孔的第三源極/汲極,其中執行多次蝕刻製程的方法包括以下步驟。於第二導電層上形成第一圖案化光阻層。以第一圖案化光阻層為罩幕對第二導電層執行第一蝕刻製程,以獲得第二源極/汲極。第二源極/汲極為罩幕對第一絕緣層執行第二蝕刻製程,以獲得第一絕緣結構。依序形成第二絕緣層以及第三導電層於第二源極/汲極上方。於第三導電層上形成第二圖案化光阻層。以第二圖案化光阻層為罩幕對第三導電層執行第三蝕刻製程,以獲得第三源極/汲極。以第三源極/汲極為罩幕對第二絕緣層執行第四蝕刻製程,以獲得第二絕緣結構。形成半導體結構於第一通孔、第二通孔、第三通孔以及第四通孔中。形成閘介電層於半導體結構上。形成閘極於閘介電層上。 At least one embodiment of the present invention provides a method for manufacturing a semiconductor device, which includes the following steps: forming a first conductive layer, a first insulating layer, a second conductive layer, a second insulating layer, and a third conductive layer in sequence; performing multiple etching processes on the first conductive layer, the first insulating layer, the second conductive layer, the second insulating layer, and the third conductive layer to obtain a first source/drain, a first insulating structure with a first through hole, a second source/drain with a second through hole, a second insulating structure with a third through hole, and a third source/drain with a fourth through hole, wherein the method for performing multiple etching processes includes the following steps. A first patterned photoresist layer is formed on the second conductive layer. A first etching process is performed on the second conductive layer using the first patterned photoresist layer as a mask to obtain a second source/drain. A second etching process is performed on the first insulating layer using the second source/drain as a mask to obtain a first insulating structure. A second insulating layer and a third conductive layer are sequentially formed above the second source/drain. A second patterned photoresist layer is formed on the third conductive layer. A third etching process is performed on the third conductive layer using the second patterned photoresist layer as a mask to obtain a third source/drain. Perform a fourth etching process on the second insulating layer using the third source/drain as a mask to obtain a second insulating structure. Form a semiconductor structure in the first through hole, the second through hole, the third through hole, and the fourth through hole. Form a gate dielectric layer on the semiconductor structure. Form a gate on the gate dielectric layer.
10,10A,20:半導體裝置 10,10A,20:Semiconductor devices
100:基板 100: Substrate
210,210A:第一源極/汲極 210,210A: First source/drain
210t,230t:頂面 210t,230t:Top
210w,310w,220w,320w,230w:外側側壁 210w, 310w, 220w, 320w, 230w: outer side wall
210’:第一導電層 210’: First conductive layer
220,220A:第二源極/汲極 220,220A: Second source/drain
220’:第二導電層 220’: Second conductive layer
222,232,232’:凹槽 222,232,232’: groove
230:第三源極/汲極 230: Third source/drain
230’:第三導電層 230’: The third conductive layer
310,310A:第一絕緣結構 310,310A: First insulation structure
310’:第一絕緣層 310’: First insulating layer
320:第二絕緣結構 320: Second insulation structure
320’:第二絕緣層 320’: Second insulating layer
320”:中介絕緣結構 320”: Intermediate insulation structure
330:閘介電層 330: Gate dielectric layer
400,400A:半導體結構 400,400A:Semiconductor structure
410,410A:第一半導體層 410,410A: First semiconductor layer
420,420A:第二半導體層 420,420A: Second semiconductor layer
430,430A:第三半導體層 430,430A: Third semiconductor layer
500,500A:閘極 500,500A: Gate
CL:中心線 CL: Center Line
D1,D1’,D2:深度 D1, D1’, D2: Depth
H1,H1A:第一通孔 H1, H1A: First through hole
H2,H2A:第二通孔 H2, H2A: Second through hole
H3:第三通孔 H3: The third through hole
H4:第四通孔 H4: Fourth through hole
ND:法線方向 ND: Normal direction
O,P:開口 O,P: Open
O1:第一開口 O1: First opening
PR:圖案化光阻層 PR: Patterned photoresist layer
PR1:第一圖案化光阻層 PR1: First patterned photoresist layer
PR2:第二圖案化光阻層 PR2: Second patterned photoresist layer
T1:第一電晶體 T1: First transistor
T2:第二電晶體 T2: Second transistor
w1,w2,w3:寬度 w1,w2,w3:width
圖1A是依照本發明的一實施例的一種半導體裝置的上視示意圖。 FIG1A is a schematic top view of a semiconductor device according to an embodiment of the present invention.
圖1B是沿著圖1A的線A-A’的剖面示意圖。 FIG1B is a schematic cross-sectional view along line A-A’ of FIG1A .
圖2A是依照本發明的一實施例的一種半導體裝置的等效電路圖。 FIG2A is an equivalent circuit diagram of a semiconductor device according to an embodiment of the present invention.
圖2B是依照本發明的一實施例的一種半導體裝置的等效電路圖。 FIG2B is an equivalent circuit diagram of a semiconductor device according to an embodiment of the present invention.
圖3A至圖12A是依照本發明的一實施例的一種半導體裝置 的製造方法的上視示意圖。 Figures 3A to 12A are top-view schematic diagrams of a method for manufacturing a semiconductor device according to an embodiment of the present invention.
圖3B至圖12B分別是沿著圖3A至圖12A的線A-A’的剖面示意圖。 Figures 3B to 12B are schematic cross-sectional views along lines A-A’ of Figures 3A to 12A, respectively.
圖13A是依照本發明的一實施例的另一種半導體裝置的上視示意圖。 FIG13A is a top view schematic diagram of another semiconductor device according to an embodiment of the present invention.
圖13B是沿著圖13A的線A-A’的剖面示意圖。 FIG13B is a schematic cross-sectional view along line A-A’ of FIG13A .
圖14A至圖14I是依照本發明的另一實施例的一種半導體裝置的製造方法的剖面示意圖。 Figures 14A to 14I are cross-sectional schematic diagrams of a method for manufacturing a semiconductor device according to another embodiment of the present invention.
圖15A至圖15B是依照本發明的另一實施例的一種半導體裝置的製造方法的剖面示意圖。 Figures 15A and 15B are cross-sectional schematic diagrams of a method for manufacturing a semiconductor device according to another embodiment of the present invention.
圖1A是依照本發明的一實施例的一種半導體裝置10的上視示意圖。圖1B是沿著圖1A的線A-A’的剖面示意圖。請參考圖1A與圖1B,半導體裝置10包括第一源極/汲極210、第一絕緣結構310、第二源極/汲極220、第二絕緣結構320、第三源極/汲極230、半導體結構400、閘介電層330以及閘極500。 FIG. 1A is a schematic top view of a semiconductor device 10 according to an embodiment of the present invention. FIG. 1B is a schematic cross-sectional view along line A-A' of FIG. 1A. Referring to FIG. 1A and FIG. 1B, the semiconductor device 10 includes a first source/drain 210, a first insulating structure 310, a second source/drain 220, a second insulating structure 320, a third source/drain 230, a semiconductor structure 400, a gate dielectric layer 330, and a gate 500.
基板100例如為硬質基板(rigid substrate),且其材質可為玻璃、石英、有機聚合物或不透光/反射材料(例如:導電材料、金屬、晶圓、陶瓷或其他可適用的材料)或是其他可適用的材料。然而,本發明不以此為限,在其他實施例中,基板100也可以是可撓式基板(flexible substrate)或是可拉伸基板。舉例來 說,可撓式基板以及可拉伸基板的材料包括聚醯亞胺(polyimide,PI)、聚二甲基矽氧烷(polydimethylsiloxane,PDMS)、聚乙烯對苯二甲酸酯(polyethylene terephthalate,PET)、聚二甲酸乙二醇酯(polyethylene naphthalate,PEN)、聚酯(polyester,PES)、聚甲基丙烯酸甲酯(polymethylmethacrylate,PMMA)、聚碳酸酯(polycarbonate,PC)、聚胺酯(polyurethane PU)或其他合適的材料。 The substrate 100 is, for example, a rigid substrate, and its material may be glass, quartz, organic polymer or opaque/reflective material (e.g., conductive material, metal, wafer, ceramic or other applicable material) or other applicable material. However, the present invention is not limited thereto, and in other embodiments, the substrate 100 may also be a flexible substrate or a stretchable substrate. For example, the materials of the flexible substrate and the stretchable substrate include polyimide (PI), polydimethylsiloxane (PDMS), polyethylene terephthalate (PET), polyethylene naphthalate (PEN), polyester (PES), polymethylmethacrylate (PMMA), polycarbonate (PC), polyurethane PU or other suitable materials.
在本實施例中,第一源極/汲極210、第一絕緣結構310、第二源極/汲極220、第二絕緣結構320以及第三源極/汲極230在基板100上沿著基板100的頂面的法線方向ND依序堆疊。 In this embodiment, the first source/drain 210, the first insulating structure 310, the second source/drain 220, the second insulating structure 320 and the third source/drain 230 are stacked in sequence on the substrate 100 along the normal direction ND of the top surface of the substrate 100.
第一源極/汲極210位於基板100之上。在本實施例中,第一源極/汲極210直接接觸基板100的頂面,但本發明不以此為限。在其他實施例中,第一源極/汲極210與基板100之間可以額外包括緩衝層(未釋出),緩衝層例如用來做為氫阻擋層及/或金屬離子阻擋層。 The first source/drain 210 is located on the substrate 100. In this embodiment, the first source/drain 210 directly contacts the top surface of the substrate 100, but the present invention is not limited thereto. In other embodiments, a buffer layer (not released) may be additionally included between the first source/drain 210 and the substrate 100, and the buffer layer is used, for example, as a hydrogen barrier layer and/or a metal ion barrier layer.
第一絕緣結構310位於第一源極/汲極210上,且具有重疊於第一源極/汲極210的頂面210t的第一通孔H1。第一通孔H1於基板100上的正投影圖案完全位於第一源極/汲極210於基板100上的正投影圖案內。 The first insulating structure 310 is located on the first source/drain 210 and has a first through hole H1 overlapping the top surface 210t of the first source/drain 210. The orthographic projection pattern of the first through hole H1 on the substrate 100 is completely located within the orthographic projection pattern of the first source/drain 210 on the substrate 100.
第二源極/汲極220位於第一絕緣結構310上,且具有重疊於第一通孔H1的第二通孔H2。第一通孔H1的寬度w1小於 或等於第二通孔H2的寬度w2。在本實施例中,第二源極/汲極220對齊於第一絕緣結構310,且第二通孔H2對齊於第一通孔H1。在一些實施例中,第一通孔H1的寬度w1大於2微米。 The second source/drain 220 is located on the first insulating structure 310 and has a second through hole H2 overlapping the first through hole H1. The width w1 of the first through hole H1 is less than or equal to the width w2 of the second through hole H2. In this embodiment, the second source/drain 220 is aligned with the first insulating structure 310, and the second through hole H2 is aligned with the first through hole H1. In some embodiments, the width w1 of the first through hole H1 is greater than 2 microns.
第二絕緣結構320位於第二源極/汲極220上,且具有重疊於第二通孔H2的第三通孔H3。第二通孔H2的寬度w2小於第三通孔H3的寬度w3,且第二源極/汲極220的部分頂面位於第三通孔H3的底部。 The second insulating structure 320 is located on the second source/drain 220 and has a third through hole H3 overlapping the second through hole H2. The width w2 of the second through hole H2 is smaller than the width w3 of the third through hole H3, and part of the top surface of the second source/drain 220 is located at the bottom of the third through hole H3.
第三源極/汲極230位於第二絕緣結構320上,且具有重疊於第三通孔H3的第四通孔H4。第三通孔H3的寬度w3小於或等於第四通孔H4的寬度w4。在本實施例中,第三源極/汲極230對齊於第二絕緣結構320,且第四通孔H4對齊於第三通孔H3。 The third source/drain 230 is located on the second insulating structure 320 and has a fourth through hole H4 overlapping the third through hole H3. The width w3 of the third through hole H3 is less than or equal to the width w4 of the fourth through hole H4. In this embodiment, the third source/drain 230 is aligned with the second insulating structure 320, and the fourth through hole H4 is aligned with the third through hole H3.
在一些實施例中,第一源極/汲極210、第二源極/汲極220以及第三源極/汲極230各自的材料例如包括鉻、金、銀、銅、錫、鉛、鉿、鎢、鉬、釹、鈦、鉭、鋁、鋅、鎳等金屬、上述合金、上述金屬氧化物、上述金屬氮化物或上述之組合或其他導電材料。第一源極/汲極210、第二源極/汲極220以及第三源極/汲極230的材料彼此相同或不同。第一源極/汲極210、第二源極/汲極220以及第三源極/汲極230各自可具有單層結構或多層結構。 In some embodiments, the materials of the first source/drain 210, the second source/drain 220, and the third source/drain 230 include, for example, metals such as chromium, gold, silver, copper, tin, lead, cobalt, tungsten, molybdenum, neodymium, titanium, tantalum, aluminum, zinc, nickel, the above alloys, the above metal oxides, the above metal nitrides, or the above combinations or other conductive materials. The materials of the first source/drain 210, the second source/drain 220, and the third source/drain 230 are the same or different from each other. The first source/drain 210, the second source/drain 220, and the third source/drain 230 may each have a single-layer structure or a multi-layer structure.
在一些實施例中,第一絕緣結構310以及第二絕緣結構320各自的材料例如包括氧化矽、氮氧化矽、氮化矽、氧化鋁、 氧化鉿、氧化鋯或其他合適的材料或前述材料的組合。在一些實施例中,第一絕緣結構310以及第二絕緣結構320的材料包括氧化物(例如氧化矽),且可作為儲氧/補氧層使用,藉此可在製造過程中調節半導體結構400中的氧濃度。在一些實施例中,第一絕緣結構310以及第二絕緣結構320各自可具有單層結構或多層結構。當第一絕緣結構310以及第二絕緣結構320具有多層結構時,可以搭配使用氧化物層(例如氧化矽層)與氮化物層(例如氮化矽層)以優化半導體裝置10的性能。舉例來說,氧化物層可以作為儲氧/補氧層使用,而氮化物層可以作為氫阻擋層或金屬離子阻擋層使用。 In some embodiments, the materials of the first insulating structure 310 and the second insulating structure 320 include, for example, silicon oxide, silicon oxynitride, silicon nitride, aluminum oxide, beta oxide, zirconium oxide or other suitable materials or combinations of the foregoing materials. In some embodiments, the materials of the first insulating structure 310 and the second insulating structure 320 include oxides (such as silicon oxide) and can be used as oxygen storage/oxygen replenishing layers, thereby adjusting the oxygen concentration in the semiconductor structure 400 during the manufacturing process. In some embodiments, the first insulating structure 310 and the second insulating structure 320 can each have a single-layer structure or a multi-layer structure. When the first insulating structure 310 and the second insulating structure 320 have a multi-layer structure, an oxide layer (such as a silicon oxide layer) and a nitride layer (such as a silicon nitride layer) can be used in combination to optimize the performance of the semiconductor device 10. For example, the oxide layer can be used as an oxygen storage/replenishing layer, and the nitride layer can be used as a hydrogen barrier layer or a metal ion barrier layer.
半導體結構400從第一通孔H1內之第一源極/汲極210的頂面210t沿著第一通孔H1的側壁向上延伸,並連續且依序地沿著第二通孔H2的側壁、第三通孔H3的側壁以及第四通孔H4的側壁延伸至第三源極/汲極230的頂面230t。半導體結構400接觸第一源極/汲極210、第二源極/汲極220以及第三源極/汲極230。在一些實施例中,第一通孔H1、第二通孔H2、第三通孔H3以及第四通孔H4於上視圖中的形狀為圓形,但本發明不以此為限。在其他實施例中,第一通孔H1、第二通孔H2、第三通孔H3以及第四通孔H4於上視圖中的形狀為矩形、橢圓形或其他幾何形狀。 The semiconductor structure 400 extends upward from the top surface 210t of the first source/drain 210 in the first through hole H1 along the side wall of the first through hole H1, and continuously and sequentially extends along the side wall of the second through hole H2, the side wall of the third through hole H3, and the side wall of the fourth through hole H4 to the top surface 230t of the third source/drain 230. The semiconductor structure 400 contacts the first source/drain 210, the second source/drain 220, and the third source/drain 230. In some embodiments, the shapes of the first through hole H1, the second through hole H2, the third through hole H3, and the fourth through hole H4 in the top view are circular, but the present invention is not limited thereto. In other embodiments, the shapes of the first through hole H1, the second through hole H2, the third through hole H3 and the fourth through hole H4 in the top view are rectangular, elliptical or other geometric shapes.
在一些實施例中,半導體結構400的材料包括包含鎵(Ga)、鋅(Zn)、銦(In)、錫(Sn)、鋁(Al)、鎢(W)中之 三者以上的氧化物(例如銦鎵鋅錫氧化物(IGZTO)、銦鎵鋅氧化物(IGZO)、銦錫鋅氧化物(ITZO)、鋁鋅錫氧化物(AZTO)、銦鎢鋅氧化物(IWZO)、銦鎵氧化物(IGO)等金屬氧化物)或鑭系稀土摻雜金屬氧化物(例如Ln-IZO)或其他合適的金屬氧化物或上述材料的組合。 In some embodiments, the material of the semiconductor structure 400 includes an oxide of three or more of gallium (Ga), zinc (Zn), indium (In), tin (Sn), aluminum (Al), and tungsten (W) (e.g., metal oxides such as indium gallium zinc tin oxide (IGZTO), indium gallium zinc oxide (IGZO), indium tin zinc oxide (ITZO), aluminum zinc tin oxide (AZTO), indium tungsten zinc oxide (IWZO), and indium gallium oxide (IGO)) or a rare earth-doped metal oxide (e.g., Ln-IZO) or other suitable metal oxides or a combination of the above materials.
半導體結構400具有單層結構或多層結構。在本實施例中,半導體結構400包括於第一源極/汲極210上方依序堆疊之第一半導體層410、第二半導體層420以及第三半導體層430。在一些實施例中,第一半導體層410、第二半導體層420以及第三半導體層430包含相同或不同的材料。在一些實施例中,第一半導體層410、第二半導體層420以及第三半導體層430包含相同的金屬元素,但具有不同的氧濃度。 The semiconductor structure 400 has a single-layer structure or a multi-layer structure. In the present embodiment, the semiconductor structure 400 includes a first semiconductor layer 410, a second semiconductor layer 420, and a third semiconductor layer 430 sequentially stacked above the first source/drain 210. In some embodiments, the first semiconductor layer 410, the second semiconductor layer 420, and the third semiconductor layer 430 include the same or different materials. In some embodiments, the first semiconductor layer 410, the second semiconductor layer 420, and the third semiconductor layer 430 include the same metal element but have different oxygen concentrations.
在一些實施例中,半導體結構400於基板100上的正投影形狀為圓形,但本發明不以此為限。在其他實施例中,半導體結構400於基板100上的正投影形狀為矩形、橢圓形或其他幾何形狀。 In some embodiments, the orthographic projection shape of the semiconductor structure 400 on the substrate 100 is circular, but the present invention is not limited thereto. In other embodiments, the orthographic projection shape of the semiconductor structure 400 on the substrate 100 is rectangular, elliptical or other geometric shapes.
閘介電層330位於半導體結構400上。閘介電層330的材料包括氧化矽、氮氧化矽、氮化矽、氧化鋁、氧化鉿、氧化鋯或其他合適的材料或前述材料的組合。在一些實施例中,閘介電層330的厚度小於或等於第一絕緣結構310的厚度以及第二絕緣結構320的厚度,但本發明不以此為限。 The gate dielectric layer 330 is located on the semiconductor structure 400. The material of the gate dielectric layer 330 includes silicon oxide, silicon oxynitride, silicon nitride, aluminum oxide, einsteinium oxide, zirconium oxide or other suitable materials or a combination of the foregoing materials. In some embodiments, the thickness of the gate dielectric layer 330 is less than or equal to the thickness of the first insulating structure 310 and the thickness of the second insulating structure 320, but the present invention is not limited thereto.
在一些實施例中,閘介電層330從第三源極/汲極230的 頂面230t往下延伸,並依序接觸第三源極/汲極230的外側側壁230w、第二絕緣結構320的外側側壁320w、第二源極/汲極220的外側側壁220w、第一絕緣結構310的外側側壁310w以及第一源極/汲極210的外側側壁210w,但本發明不以此為限。 In some embodiments, the gate dielectric layer 330 extends downward from the top surface 230t of the third source/drain 230 and sequentially contacts the outer sidewall 230w of the third source/drain 230, the outer sidewall 320w of the second insulating structure 320, the outer sidewall 220w of the second source/drain 220, the outer sidewall 310w of the first insulating structure 310, and the outer sidewall 210w of the first source/drain 210, but the present invention is not limited thereto.
閘極500位於閘介電層330上。在一些實施例中,閘介電層330以及閘極500部分填入第一通孔H1、第二通孔H2、第三通孔H3以及第四通孔H4中。在一些實施例中,閘極500的長度大於第四通孔H4的寬度w4,藉此較佳的覆蓋整個第四通孔H4。 The gate 500 is located on the gate dielectric layer 330. In some embodiments, the gate dielectric layer 330 and the gate 500 are partially filled into the first through hole H1, the second through hole H2, the third through hole H3 and the fourth through hole H4. In some embodiments, the length of the gate 500 is greater than the width w4 of the fourth through hole H4, thereby preferably covering the entire fourth through hole H4.
在一些實施例中,閘極500的材料例如包括鉻、金、銀、銅、錫、鉛、鉿、鎢、鉬、釹、鈦、鉭、鋁、鋅、鎳等金屬、上述合金、上述金屬氧化物、上述金屬氮化物或上述之組合或其他導電材料。閘極500可具有單層結構或多層結構。 In some embodiments, the material of the gate 500 includes, for example, metals such as chromium, gold, silver, copper, tin, lead, uranium, tungsten, molybdenum, neodymium, titanium, tantalum, aluminum, zinc, nickel, the above alloys, the above metal oxides, the above metal nitrides, or the above combinations or other conductive materials. The gate 500 may have a single-layer structure or a multi-layer structure.
在本實施例中,半導體裝置10的等效電路圖實際上等同於串接在一起的第一電晶體T1以及第二電晶體T2,如圖2A與圖2B所示。第一電晶體T1以及第二電晶體T2共用同一個閘極,如圖1B所示的閘極500。第一電晶體T1以及第二電晶體T2共用其中一個源極/汲極,如圖1B所示的第二源極/汲極220。 In this embodiment, the equivalent circuit diagram of the semiconductor device 10 is actually equivalent to a first transistor T1 and a second transistor T2 connected in series, as shown in FIG. 2A and FIG. 2B. The first transistor T1 and the second transistor T2 share the same gate, such as the gate 500 shown in FIG. 1B. The first transistor T1 and the second transistor T2 share one of the source/drain, such as the second source/drain 220 shown in FIG. 1B.
在本實施例中,電流從第一源極/汲極210流至第三源極/汲極230(或從第三源極/汲極230流至第一源極/汲極210)需要兩次的經過半導體結構400,其中一次是經過第一源極/汲極210與第二源極/汲極220之間的半導體結構400,而另外一次則 是經過第二源極/汲極220與第三源極/汲極230之間的半導體結構400。通過這樣的設置,半導體裝置10具有高開啟電流(Ion)、高臨界電壓(Vth)以及低漏電流(Ioff)的優點。 In this embodiment, the current needs to pass through the semiconductor structure 400 twice when flowing from the first source/drain 210 to the third source/drain 230 (or from the third source/drain 230 to the first source/drain 210), one time passing through the semiconductor structure 400 between the first source/drain 210 and the second source/drain 220, and the other time passing through the semiconductor structure 400 between the second source/drain 220 and the third source/drain 230. With such a configuration, the semiconductor device 10 has the advantages of high turn-on current (I on ), high critical voltage (Vth), and low leakage current (I off ).
在一些實施例中,第二源極/汲極220可以不連接至其他訊號線,如圖2A所示。在其他實施例中,第二源極/汲極220連接至其他訊號線,如圖2B所示。 In some embodiments, the second source/drain 220 may not be connected to other signal lines, as shown in FIG. 2A. In other embodiments, the second source/drain 220 is connected to other signal lines, as shown in FIG. 2B.
在本實施例中,通過使第一源極/汲極210、第一絕緣結構310、第二源極/汲極220、第二絕緣結構320以及第三源極/汲極230在基板100上堆疊設置可以有效的減少設置半導體裝置10所需的佔地面積。具體地說,相較於將第一電晶體T1以及第二電晶體T2設置於同一平面上,半導體裝置10利用堆疊的設計可以減少串接在一起的第一電晶體T1以及第二電晶體T2所需要的佔地面積。 In this embodiment, the first source/drain 210, the first insulating structure 310, the second source/drain 220, the second insulating structure 320 and the third source/drain 230 are stacked on the substrate 100 to effectively reduce the area required for setting the semiconductor device 10. Specifically, compared with setting the first transistor T1 and the second transistor T2 on the same plane, the semiconductor device 10 can reduce the area required for the first transistor T1 and the second transistor T2 connected in series by using the stacking design.
圖3A至圖12A是圖1A與圖1B的半導體裝置10的製造方法的上視示意圖。圖3B至圖12B分別是沿著圖3A至圖12A的線A-A’的剖面示意圖。請參考圖3A與圖3B,形成第一導電層210’於基板100上方。 FIG. 3A to FIG. 12A are top views of the manufacturing method of the semiconductor device 10 of FIG. 1A and FIG. 1B. FIG. 3B to FIG. 12B are cross-sectional views along the line A-A' of FIG. 3A to FIG. 12A, respectively. Referring to FIG. 3A and FIG. 3B, a first conductive layer 210' is formed above the substrate 100.
請參考圖4A與圖4B,對第一導電層210’執行蝕刻製程以獲得第一源極/汲極210。 Please refer to FIG. 4A and FIG. 4B , an etching process is performed on the first conductive layer 210' to obtain the first source/drain 210.
請參考圖5A與圖5B,形成第一絕緣層310’於第一源極/汲極210上方。第一絕緣層310’例如具有單層或多層結構。形成第二導電層220’於第一絕緣層310’上方。於第二導電層220’上 形成第一圖案化光阻層PR1。在本實施例中,第一圖案化光阻層PR1具有第一開口O1。第一開口O1於基板100上的正投影位於第一源極/汲極210於基板100上的正投影中。 Referring to FIG. 5A and FIG. 5B , a first insulating layer 310' is formed on the first source/drain 210. The first insulating layer 310' has, for example, a single-layer or multi-layer structure. A second conductive layer 220' is formed on the first insulating layer 310'. A first patterned photoresist layer PR1 is formed on the second conductive layer 220'. In this embodiment, the first patterned photoresist layer PR1 has a first opening O1. The orthographic projection of the first opening O1 on the substrate 100 is located in the orthographic projection of the first source/drain 210 on the substrate 100.
請參考圖6A與圖6B,以第一圖案化光阻層PR1為罩幕對第二導電層220’執行第一蝕刻製程,以獲得第二源極/汲極220。第二源極/汲極220的第二通孔H2對齊於第一開口O1。在一些實施例中,第一蝕刻製程包括乾蝕刻製程或濕蝕刻製程。在一些實施例中,在獲得第二源極/汲極220之後,可選地移除第一圖案化光阻層PR1。移除第一圖案化光阻層PR1的方法包括灰化製程或其他合適的製程。 Referring to FIG. 6A and FIG. 6B , a first etching process is performed on the second conductive layer 220' using the first patterned photoresist layer PR1 as a mask to obtain the second source/drain 220. The second through hole H2 of the second source/drain 220 is aligned with the first opening O1. In some embodiments, the first etching process includes a dry etching process or a wet etching process. In some embodiments, after obtaining the second source/drain 220, the first patterned photoresist layer PR1 is optionally removed. The method of removing the first patterned photoresist layer PR1 includes an ashing process or other suitable processes.
請參考圖7A與圖7B,以第二源極/汲極220為罩幕對第一絕緣層310’執行第二蝕刻製程,以獲得第一絕緣結構310,並暴露出第一源極/汲極210。在本實施例中,利用自對準的方式形成第一絕緣結構310,第一絕緣結構310的第一通孔H1對齊於第二源極/汲極220的第二通孔H2。在一些實施例中,第二蝕刻製程包括乾蝕刻製程或濕蝕刻製程。 Please refer to FIG. 7A and FIG. 7B , the second etching process is performed on the first insulating layer 310' using the second source/drain 220 as a mask to obtain the first insulating structure 310 and expose the first source/drain 210. In this embodiment, the first insulating structure 310 is formed by a self-alignment method, and the first through hole H1 of the first insulating structure 310 is aligned with the second through hole H2 of the second source/drain 220. In some embodiments, the second etching process includes a dry etching process or a wet etching process.
在本實施例中,是在第二蝕刻製程之前移除第一圖案化光阻層PR1(請參考圖5B),但本發明不以此為限。在其他實施例中,在第二蝕刻製程之後移除第一圖案化光阻層PR1。 In this embodiment, the first patterned photoresist layer PR1 is removed before the second etching process (see FIG. 5B ), but the present invention is not limited thereto. In other embodiments, the first patterned photoresist layer PR1 is removed after the second etching process.
請參考圖8A與圖8B,依序形成第二絕緣層320’以及第三導電層230’於第二源極/汲極220上。在本實施例中,第二絕緣層320’填入第二通孔H2以及第一通孔H1中。於第三導電層 230’上形成第二圖案化光阻層PR2。在本實施例中,第二圖案化光阻層PR2具有第二開口O2。第二開口O2於基板100上的正投影至少部分重疊於第二通孔H2以及第一通孔H1於基板100上的正投影。 Referring to FIG. 8A and FIG. 8B , a second insulating layer 320' and a third conductive layer 230' are sequentially formed on the second source/drain 220. In this embodiment, the second insulating layer 320' is filled into the second through hole H2 and the first through hole H1. A second patterned photoresist layer PR2 is formed on the third conductive layer 230'. In this embodiment, the second patterned photoresist layer PR2 has a second opening O2. The orthographic projection of the second opening O2 on the substrate 100 at least partially overlaps the orthographic projection of the second through hole H2 and the first through hole H1 on the substrate 100.
請參考圖9A與圖9B,以第二圖案化光阻層PR2為罩幕對第三導電層230’執行第三蝕刻製程,以獲得第三源極/汲極230。第三源極/汲極230的第二四通孔H4對齊於第二開口O2。在一些實施例中,第三蝕刻製程包括乾蝕刻製程或濕蝕刻製程。在一些實施例中,在獲得第三源極/汲極230之後,可選地移除第二圖案化光阻層PR2。移除第二圖案化光阻層PR2的方法包括灰化製程或其他合適的製程。 Referring to FIG. 9A and FIG. 9B , a third etching process is performed on the third conductive layer 230' using the second patterned photoresist layer PR2 as a mask to obtain the third source/drain 230. The second four-hole H4 of the third source/drain 230 is aligned with the second opening O2. In some embodiments, the third etching process includes a dry etching process or a wet etching process. In some embodiments, after obtaining the third source/drain 230, the second patterned photoresist layer PR2 is optionally removed. The method of removing the second patterned photoresist layer PR2 includes an ashing process or other suitable processes.
請參考圖10A與圖10B,以第三源極/汲極230為罩幕對第二絕緣層320’執行第四蝕刻製程,以獲得第二絕緣結構320,並暴露出第一源極/汲極210以及第二源極/汲極220。在本實施例中,利用自對準的方式形成第二絕緣結構320,第二絕緣結構320的第三通孔H3對齊於第三源極/汲極230的第四通孔H4。在一些實施例中,第四蝕刻製程包括乾蝕刻製程或濕蝕刻製程。 Please refer to FIG. 10A and FIG. 10B , the fourth etching process is performed on the second insulating layer 320' using the third source/drain 230 as a mask to obtain the second insulating structure 320, and expose the first source/drain 210 and the second source/drain 220. In this embodiment, the second insulating structure 320 is formed by a self-alignment method, and the third through hole H3 of the second insulating structure 320 is aligned with the fourth through hole H4 of the third source/drain 230. In some embodiments, the fourth etching process includes a dry etching process or a wet etching process.
在本實施例中,是在第四蝕刻製程之前移除第二圖案化光阻層PR2(請參考圖8B),但本發明不以此為限。在其他實施例中,在第四蝕刻製程之後移除第二圖案化光阻層PR2。 In this embodiment, the second patterned photoresist layer PR2 is removed before the fourth etching process (see FIG. 8B ), but the present invention is not limited thereto. In other embodiments, the second patterned photoresist layer PR2 is removed after the fourth etching process.
在本實施例中,第四通孔H4的中心對齊第二通孔H2 的中心,但本發明不以此為限。在本實施例中,由於是通過兩次不同的黃光製程以形成第二源極/汲極220以及第三源極/汲極230,因此,第二源極/汲極220的第二通孔H2以及第三源極/汲極230的第四通孔H4可能會因為製程誤差而產生偏移,導致第四通孔H4的中心不對齊第二通孔H2的中心。 In this embodiment, the center of the fourth through hole H4 is aligned with the center of the second through hole H2, but the present invention is not limited thereto. In this embodiment, since the second source/drain 220 and the third source/drain 230 are formed by two different photolithography processes, the second through hole H2 of the second source/drain 220 and the fourth through hole H4 of the third source/drain 230 may be offset due to process errors, resulting in the center of the fourth through hole H4 not being aligned with the center of the second through hole H2.
請參考圖11A與圖11B,形成第一半導體材料層410’於第一源極/汲極210的頂面、第一通孔H1的側壁、第二通孔H2的側壁、第三通孔H3的側壁、第四通孔H4的側壁以及第三源極/汲極230的頂面上。形成第二半導體材料層420’於第一半導體材料層410’上。形成第三半導體材料層430’於第二半導體材料層420’上。 Referring to FIG. 11A and FIG. 11B , a first semiconductor material layer 410' is formed on the top surface of the first source/drain 210, the side wall of the first through hole H1, the side wall of the second through hole H2, the side wall of the third through hole H3, the side wall of the fourth through hole H4, and the top surface of the third source/drain 230. A second semiconductor material layer 420' is formed on the first semiconductor material layer 410'. A third semiconductor material layer 430' is formed on the second semiconductor material layer 420'.
請參考圖12A與圖12B,圖案化第一半導體材料層410’、第二半導體材料層420’以及第三半導體材料層430’以形成包含第一半導體層410、第二半導體層420以及第三半導體層430的半導體結構400。 Referring to FIG. 12A and FIG. 12B , the first semiconductor material layer 410 ', the second semiconductor material layer 420 ', and the third semiconductor material layer 430 ' are patterned to form a semiconductor structure 400 including the first semiconductor layer 410, the second semiconductor layer 420, and the third semiconductor layer 430.
在一些實施例中,於第三半導體材料層430’上形成圖案化光阻層(未繪出),並利用圖案化光阻層為罩幕蝕刻第一半導體材料層410’、第二半導體材料層420’以及第三半導體材料層430’以分別形成第一半導體層410、第二半導體層420以及第三半導體層430。因此,第一半導體層410、第二半導體層420以及第三半導體層430於基板100上具有實質上相同的正投影圖案。 In some embodiments, a patterned photoresist layer (not shown) is formed on the third semiconductor material layer 430', and the patterned photoresist layer is used as a mask to etch the first semiconductor material layer 410', the second semiconductor material layer 420' and the third semiconductor material layer 430' to form the first semiconductor layer 410, the second semiconductor layer 420 and the third semiconductor layer 430 respectively. Therefore, the first semiconductor layer 410, the second semiconductor layer 420 and the third semiconductor layer 430 have substantially the same orthographic projection pattern on the substrate 100.
在一些實施例中,在形成半導體結構400之後,執行第一退火製程使半導體結構400或環境中的氧擴散並儲存於第一絕緣結構310以及第二絕緣結構320中。 In some embodiments, after forming the semiconductor structure 400, a first annealing process is performed to diffuse oxygen in the semiconductor structure 400 or the environment and store it in the first insulating structure 310 and the second insulating structure 320.
最後,回到圖1A與圖1B,形成閘介電層330於半導體結構400上。形成閘極500於閘介電層330上。 Finally, returning to FIG. 1A and FIG. 1B , a gate dielectric layer 330 is formed on the semiconductor structure 400. A gate 500 is formed on the gate dielectric layer 330.
在一些實施例中,在形成閘極500之前,執行第二退火製程使儲存於第一絕緣結構310以及第二絕緣結構320中的氧擴散至半導體結構400中,進而減少半導體結構400接觸第一絕緣結構310以及第二絕緣結構320的部分(即做為半導體通道區的部分)中的氧空缺,並提升其電阻率,藉此減少漏電流的問題。 In some embodiments, before forming the gate 500, a second annealing process is performed to diffuse the oxygen stored in the first insulating structure 310 and the second insulating structure 320 into the semiconductor structure 400, thereby reducing the oxygen vacancies in the portion of the semiconductor structure 400 that contacts the first insulating structure 310 and the second insulating structure 320 (i.e., the portion that serves as the semiconductor channel region) and increasing its resistivity, thereby reducing the leakage current problem.
圖13A是依照本發明的一實施例的另一種半導體裝置10A的上視示意圖。圖13B是沿著圖13A的線A-A’的剖面示意圖。在此必須說明的是,圖13A和圖13B的實施例沿用圖1A至圖12B的實施例的元件標號與部分內容,其中採用相同或近似的標號來表示相同或近似的元件,並且省略了相同技術內容的說明。關於省略部分的說明可參考前述實施例,在此不贅述。 FIG. 13A is a schematic top view of another semiconductor device 10A according to an embodiment of the present invention. FIG. 13B is a schematic cross-sectional view along line A-A' of FIG. 13A. It must be noted that the embodiments of FIG. 13A and FIG. 13B use the component numbers and partial contents of the embodiments of FIG. 1A to FIG. 12B, wherein the same or similar numbers are used to represent the same or similar components, and the description of the same technical contents is omitted. The description of the omitted parts can be referred to the aforementioned embodiments, which will not be elaborated here.
請參考圖13A與圖13B,在本實施例中,半導體裝置10A包括第一源極/汲極210A、第一絕緣結構310A、第二源極/汲極220A、半導體結構400A、閘介電層330以及閘極500A。 Referring to FIG. 13A and FIG. 13B , in this embodiment, the semiconductor device 10A includes a first source/drain 210A, a first insulating structure 310A, a second source/drain 220A, a semiconductor structure 400A, a gate dielectric layer 330, and a gate 500A.
在一些實施例中,圖13A和圖13B的半導體裝置10A與圖1A和圖1B的半導體裝置10共用部分的製程。舉例來說,在圖3A至圖4B的步驟中,圖案化第一導電層210’以同時形成 半導體裝置10的第一源極/汲極210以及半導體裝置10A的第一源極/汲極210A。 In some embodiments, the semiconductor device 10A of FIGS. 13A and 13B shares some of the manufacturing processes with the semiconductor device 10 of FIGS. 1A and 1B. For example, in the steps of FIGS. 3A to 4B, the first conductive layer 210' is patterned to simultaneously form the first source/drain 210 of the semiconductor device 10 and the first source/drain 210A of the semiconductor device 10A.
在圖5A至圖6B的步驟中,圖案化第二導電層220’以同時形成半導體裝置10的第二源極/汲極220以及半導體裝置10A的第二源極/汲極220A。 In the steps of FIG. 5A to FIG. 6B , the second conductive layer 220' is patterned to simultaneously form the second source/drain 220 of the semiconductor device 10 and the second source/drain 220A of the semiconductor device 10A.
在圖7A與圖7B的步驟中,圖案化第一絕緣層310’以同時形成半導體裝置10的第一絕緣結構310以及半導體裝置10A的第一絕緣結構310A。 In the steps of FIG. 7A and FIG. 7B , the first insulating layer 310' is patterned to simultaneously form the first insulating structure 310 of the semiconductor device 10 and the first insulating structure 310A of the semiconductor device 10A.
在圖9A至圖10B的步驟中,移除半導體裝置10A的第二源極/汲極220A上方的第三導電層230’以及第二絕緣層320’。 In the steps of FIG. 9A to FIG. 10B , the third conductive layer 230' and the second insulating layer 320' above the second source/drain 220A of the semiconductor device 10A are removed.
在圖11A至圖12B的步驟中,圖案化第一半導體材料層410’、第二半導體材料層420’以及第三半導體材料層430’以形成包含第一半導體層410A、第二半導體層420A以及第三半導體層430A的半導體結構400A。半導體結構400A填入第一絕緣結構310A的第一通孔H1A中以及第二源極/汲極220A的第二通孔H2A中。 In the steps of FIG. 11A to FIG. 12B, the first semiconductor material layer 410', the second semiconductor material layer 420' and the third semiconductor material layer 430' are patterned to form a semiconductor structure 400A including the first semiconductor layer 410A, the second semiconductor layer 420A and the third semiconductor layer 430A. The semiconductor structure 400A is filled into the first through hole H1A of the first insulating structure 310A and the second through hole H2A of the second source/drain 220A.
形成閘介電層330以覆蓋圖1A和圖1B的半導體結構400以及圖13A和圖13B的半導體結構400A。形成閘極500A於半導體結構400A上,且閘極500A重疊於半導體結構400A。在一些實施例中,圖1A和圖1B的閘極500以及圖13A和圖13B的閘極500A可同時形成。 A gate dielectric layer 330 is formed to cover the semiconductor structure 400 of FIGS. 1A and 1B and the semiconductor structure 400A of FIGS. 13A and 13B. A gate 500A is formed on the semiconductor structure 400A, and the gate 500A overlaps the semiconductor structure 400A. In some embodiments, the gate 500 of FIGS. 1A and 1B and the gate 500A of FIGS. 13A and 13B may be formed simultaneously.
在一些實施例中,圖13A和圖13B的半導體裝置10A 與圖1A和圖1B的半導體裝置10彼此電性連接或電性獨立。半導體裝置10A與半導體裝置10可以依照需求而設置於不同的位置。舉例來說,當半導體裝置10A與半導體裝置10皆設置於顯示裝置中時,半導體裝置10A與半導體裝置10因應實際需求而設置於顯示裝置的顯示區及/或周邊區中。 In some embodiments, the semiconductor device 10A of FIG. 13A and FIG. 13B is electrically connected to or electrically independent of the semiconductor device 10 of FIG. 1A and FIG. 1B. The semiconductor device 10A and the semiconductor device 10 can be disposed at different locations according to requirements. For example, when the semiconductor device 10A and the semiconductor device 10 are both disposed in a display device, the semiconductor device 10A and the semiconductor device 10 are disposed in a display area and/or a peripheral area of the display device according to actual requirements.
圖14A至圖14I是依照本發明的另一實施例的一種半導體裝置的製造方法的剖面示意圖。在此必須說明的是,圖14A至圖14I的實施例沿用圖1A至圖12B的實施例的元件標號與部分內容,其中採用相同或近似的標號來表示相同或近似的元件,並且省略了相同技術內容的說明。關於省略部分的說明可參考前述實施例,在此不贅述。 Figures 14A to 14I are cross-sectional schematic diagrams of a method for manufacturing a semiconductor device according to another embodiment of the present invention. It must be noted that the embodiments of Figures 14A to 14I use the component numbers and partial contents of the embodiments of Figures 1A to 12B, wherein the same or similar numbers are used to represent the same or similar components, and the description of the same technical contents is omitted. For the description of the omitted parts, please refer to the aforementioned embodiments, which will not be elaborated here.
請參考圖14A,依序形成第一導電層、第一絕緣層310’、第二導電層220’、第二絕緣層320’以及第三導電層230’。在本實施例中,在形成第一絕緣層310’之前,先執行蝕刻製程以圖案化第一導電層,藉此形成第一源極/汲極210,如圖3A至圖4B所示。 Referring to FIG. 14A , a first conductive layer, a first insulating layer 310’, a second conductive layer 220’, a second insulating layer 320’ and a third conductive layer 230’ are sequentially formed. In this embodiment, before forming the first insulating layer 310’, an etching process is first performed to pattern the first conductive layer, thereby forming a first source/drain 210, as shown in FIGS. 3A to 4B .
接著請參考圖14B,形成圖案化光阻層PR於第三導電層230’上。在本實施例中,圖案化光阻層PR具有開口O。開口O於基板100上的正投影位於第一源極/汲極210於基板100上的正投影中。 Next, please refer to FIG. 14B to form a patterned photoresist layer PR on the third conductive layer 230'. In this embodiment, the patterned photoresist layer PR has an opening O. The orthographic projection of the opening O on the substrate 100 is located in the orthographic projection of the first source/drain 210 on the substrate 100.
接著請參考圖14C,以圖案化光阻層PR為罩幕對第三導電層230’執行第一濕蝕刻製程,以獲得第三源極/汲極230。在 一些實施例中,第三源極/汲極230與位於其底下之第二絕緣層320’在第一濕蝕刻製程中具有高蝕刻選擇比。第三源極/汲極230在第一濕蝕刻製程中的蝕刻速率大於第二絕緣層320’在第一濕蝕刻製程中的蝕刻速率。在一些實施例中,第一濕蝕刻製程所用的蝕刻劑包括鋁酸、銅酸、草酸、銀酸或其他合適的蝕刻劑或前述的組合。 Next, please refer to FIG. 14C , and the third conductive layer 230' is subjected to a first wet etching process using the patterned photoresist layer PR as a mask to obtain the third source/drain 230. In some embodiments, the third source/drain 230 and the second insulating layer 320' thereunder have a high etching selectivity in the first wet etching process. The etching rate of the third source/drain 230 in the first wet etching process is greater than the etching rate of the second insulating layer 320' in the first wet etching process. In some embodiments, the etchant used in the first wet etching process includes aluminum acid, copper acid, oxalic acid, silver acid or other suitable etchants or a combination thereof.
在本實施例中,第三源極/汲極230會因為側蝕刻而內縮,以形成由圖案化光阻層PR的底面、第三源極/汲極230的側壁以及第二絕緣層320’的頂面所構成的凹槽232。在一些實施例中,凹槽232的深度D1為0.1微米至1微米。深度D1為第三源極/汲極230的側壁與圖案化光阻層PR的側壁之間的水平距離。 In this embodiment, the third source/drain 230 is retracted due to side etching to form a groove 232 formed by the bottom surface of the patterned photoresist layer PR, the sidewall of the third source/drain 230, and the top surface of the second insulating layer 320'. In some embodiments, the depth D1 of the groove 232 is 0.1 micron to 1 micron. The depth D1 is the horizontal distance between the sidewall of the third source/drain 230 and the sidewall of the patterned photoresist layer PR.
在一些實施例中,圖案化光阻層PR以及第二絕緣層320’也可能會在第一濕蝕刻製程中被局部蝕刻,然而由於第三導電層230’在第一濕蝕刻製程中的蝕刻速率明顯快於圖案化光阻層PR以及第二絕緣層320’在第一濕蝕刻製程中的蝕刻速率,因此有利於凹槽232的形成。 In some embodiments, the patterned photoresist layer PR and the second insulating layer 320' may also be partially etched in the first wet etching process. However, since the etching rate of the third conductive layer 230' in the first wet etching process is significantly faster than the etching rate of the patterned photoresist layer PR and the second insulating layer 320' in the first wet etching process, it is beneficial to form the groove 232.
在本實施例中,第三源極/汲極230具有第四通孔H4。凹槽232可視為第四通孔H4的一部分。 In this embodiment, the third source/drain 230 has a fourth through hole H4. The groove 232 can be regarded as a part of the fourth through hole H4.
請參考圖14D,以圖案化光阻層PR為罩幕對第二絕緣層320’執行第一乾蝕刻製程,以獲得中介絕緣結構320”。中介絕緣結構320”具有重疊於第四通孔H4的開口P,且開口P的寬 度w3’小於第四通孔H4的寬度w4。在本實施例中,第一乾蝕刻製程為異向性蝕刻,由於圖案化光阻層PR遮蔽了第三源極/汲極230,第三源極/汲極230幾乎不會在第一乾蝕刻製程受到損傷。介絕緣結構320”例如對齊於圖案化光阻層PR。 Referring to FIG. 14D , the second insulating layer 320' is subjected to a first dry etching process using the patterned photoresist layer PR as a mask to obtain an intermediate insulating structure 320". The intermediate insulating structure 320" has an opening P overlapping the fourth through hole H4, and the width w3' of the opening P is smaller than the width w4 of the fourth through hole H4. In this embodiment, the first dry etching process is anisotropic etching. Since the patterned photoresist layer PR shields the third source/drain 230, the third source/drain 230 is hardly damaged in the first dry etching process. The intermediate insulating structure 320" is, for example, aligned with the patterned photoresist layer PR.
請參考圖14E,以中介絕緣結構320”以及圖案化光阻層PR為罩幕對第二導電層220’執行第二乾蝕刻製程,以獲得第二源極/汲極220。在本實施例中,第二乾蝕刻製程為異向性蝕刻,由於圖案化光阻層PR遮蔽了第三源極/汲極230,第三源極/汲極230幾乎不會在第二乾蝕刻製程受到損傷。中介絕緣結構320”的開口P例如對齊於第二源極/汲極220的第二通孔H2。 Please refer to FIG. 14E , the second conductive layer 220' is subjected to a second dry etching process using the intermediate insulating structure 320" and the patterned photoresist layer PR as a mask to obtain the second source/drain 220. In this embodiment, the second dry etching process is anisotropic etching. Since the patterned photoresist layer PR shields the third source/drain 230, the third source/drain 230 is hardly damaged in the second dry etching process. The opening P of the intermediate insulating structure 320" is aligned with the second through hole H2 of the second source/drain 220, for example.
請參考圖14F,移除圖案化光阻層PR。以第三源極/汲極230為罩幕對中介絕緣結構320”執行第三乾蝕刻製程,以獲得第二絕緣結構320。以第二源極/汲極220為罩幕對第一絕緣層310’執行第四乾蝕刻製程,以獲得第一絕緣結構310。在一些實施例中,第三乾蝕刻製程以及第四乾蝕刻製程為同時執行。 Please refer to FIG. 14F to remove the patterned photoresist layer PR. The third source/drain 230 is used as a mask to perform a third dry etching process on the intermediate insulating structure 320” to obtain the second insulating structure 320. The second source/drain 220 is used as a mask to perform a fourth dry etching process on the first insulating layer 310’ to obtain the first insulating structure 310. In some embodiments, the third dry etching process and the fourth dry etching process are performed simultaneously.
在本實施例中,由於第一絕緣結構310、第二源極/汲極220、第二絕緣結構320以及第三源極/汲極230的製造過程利用了同一個圖案化光阻層PR,因此第一絕緣結構310的第一通孔H1、第二源極/汲極220的第二通孔H2、第二絕緣結構320的第三通孔H3以及第三源極/汲極230的第四通孔H4具有更好的對稱性。舉例來說,第一通孔H1、第二通孔H2、第三通孔H3以及第四通孔H4基於中心線CL而具有左右對稱的結構。在一些 實施例中,第一通孔H1的中心、第二通孔H2的中心、第三通孔H3的中心以及第四通孔H4的中心彼此對齊。 In this embodiment, since the manufacturing process of the first insulating structure 310, the second source/drain 220, the second insulating structure 320 and the third source/drain 230 utilizes the same patterned photoresist layer PR, the first through hole H1 of the first insulating structure 310, the second through hole H2 of the second source/drain 220, the third through hole H3 of the second insulating structure 320 and the fourth through hole H4 of the third source/drain 230 have better symmetry. For example, the first through hole H1, the second through hole H2, the third through hole H3 and the fourth through hole H4 have a left-right symmetric structure based on the center line CL. In some embodiments, the center of the first through hole H1, the center of the second through hole H2, the center of the third through hole H3, and the center of the fourth through hole H4 are aligned with each other.
在一些實施例中,第四通孔H4的寬度w4與第二通孔H2的寬度w2的差值為2微米至3微米。 In some embodiments, the difference between the width w4 of the fourth through hole H4 and the width w2 of the second through hole H2 is 2 microns to 3 microns.
請參考圖14G,形成半導體結構400於第一通孔H1、第二通孔H2、第三通孔H3以及第四通孔H4中。在本實施例中,半導體結構400具有單層結構,但本發明不以此為限。在其他實施例中,半導體結構400具有多層結構。 Referring to FIG. 14G , a semiconductor structure 400 is formed in the first through hole H1, the second through hole H2, the third through hole H3, and the fourth through hole H4. In this embodiment, the semiconductor structure 400 has a single-layer structure, but the present invention is not limited thereto. In other embodiments, the semiconductor structure 400 has a multi-layer structure.
在一些實施例中,在形成半導體結構400之後,執行第一退火製程使半導體結構400或環境中的氧擴散並儲存於第一絕緣結構310以及第二絕緣結構320中。 In some embodiments, after forming the semiconductor structure 400, a first annealing process is performed to diffuse oxygen in the semiconductor structure 400 or the environment and store it in the first insulating structure 310 and the second insulating structure 320.
請參考圖14H,形成閘介電層330於半導體結構400上。最後,形成閘極500於閘介電層330上以獲得半導體裝置20,如圖14I所示。在一些實施例中,在形成閘極500之前,執行第二退火製程使儲存於第一絕緣結構310以及第二絕緣結構320中的氧擴散至半導體結構400中,進而減少半導體結構400接觸第一絕緣結構310以及第二絕緣結構320的部分(即做為半導體通道區的部分)中的氧空缺,並提升其電阻率,藉此減少漏電流的問題。在一些實施例中,半導體裝置20的等效電路圖如圖2A或圖2B所示。半導體裝置20具有高開啟電流(Ion)、高臨界電壓(Vth)以及低漏電流(Ioff)的優點。 Referring to FIG. 14H , a gate dielectric layer 330 is formed on the semiconductor structure 400. Finally, a gate 500 is formed on the gate dielectric layer 330 to obtain the semiconductor device 20, as shown in FIG. 14I . In some embodiments, before forming the gate 500, a second annealing process is performed to diffuse the oxygen stored in the first insulating structure 310 and the second insulating structure 320 into the semiconductor structure 400, thereby reducing oxygen vacancies in the portion of the semiconductor structure 400 that contacts the first insulating structure 310 and the second insulating structure 320 (i.e., the portion that serves as the semiconductor channel region), and increasing its resistivity, thereby reducing the problem of leakage current. In some embodiments, the equivalent circuit diagram of the semiconductor device 20 is shown in FIG2A or FIG2B. The semiconductor device 20 has the advantages of high turn-on current (I on ), high critical voltage (Vth), and low leakage current (I off ).
在本實施例中,通過使第一源極/汲極210、第一絕緣結 構310、第二源極/汲極220、第二絕緣結構320以及第三源極/汲極230在基板100上堆疊設置可以有效的減少設置半導體裝置20所需的佔地面積。 In this embodiment, the first source/drain 210, the first insulating structure 310, the second source/drain 220, the second insulating structure 320 and the third source/drain 230 are stacked on the substrate 100 to effectively reduce the area required for setting up the semiconductor device 20.
圖15A至圖15B是依照本發明的另一實施例的一種半導體裝置的製造方法的剖面示意圖。在此必須說明的是,圖15A至圖15B的實施例沿用圖14A至圖14I的實施例的元件標號與部分內容,其中採用相同或近似的標號來表示相同或近似的元件,並且省略了相同技術內容的說明。關於省略部分的說明可參考前述實施例,在此不贅述。 FIG. 15A to FIG. 15B are cross-sectional schematic diagrams of a method for manufacturing a semiconductor device according to another embodiment of the present invention. It must be noted that the embodiment of FIG. 15A to FIG. 15B uses the component numbers and partial contents of the embodiment of FIG. 14A to FIG. 14I, wherein the same or similar numbers are used to represent the same or similar components, and the description of the same technical content is omitted. The description of the omitted part can be referred to the aforementioned embodiment, and will not be repeated here.
圖15A接續了圖14D的步驟,以中介絕緣結構320”以及圖案化光阻層PR為罩幕對第二導電層220’執行第二濕蝕刻製程,以獲得第二源極/汲極220。在一些實施例中,第二源極/汲極220與位於其底下之第一絕緣層310’在第二濕蝕刻製程中具有高蝕刻選擇比。第二源極/汲極220在第二濕蝕刻製程中的蝕刻速率大於第一絕緣層310’在第二濕蝕刻製程中的蝕刻速率。在一些實施例中,第二濕蝕刻製程所用的蝕刻劑包括鋁酸、銅酸、草酸、銀酸或其他合適的蝕刻劑或前述的組合。 FIG. 15A is a continuation of the step of FIG. 14D , wherein a second wet etching process is performed on the second conductive layer 220′ using the intermediate insulating structure 320″ and the patterned photoresist layer PR as a mask to obtain the second source/drain 220. In some embodiments, the second source/drain 220 and the first insulating layer 310′ thereunder are separated from each other during the second wet etching process. The process has a high etching selectivity. The etching rate of the second source/drain 220 in the second wet etching process is greater than the etching rate of the first insulating layer 310' in the second wet etching process. In some embodiments, the etchant used in the second wet etching process includes aluminum acid, copper acid, oxalic acid, silver acid or other suitable etchants or a combination of the foregoing.
在本實施例中,第二源極/汲極220會因為側蝕刻而內縮,以形成由中介絕緣結構320”的底面、第二源極/汲極220的側壁以及第一絕緣層310’的頂面所構成的凹槽222。在一些實施例中,凹槽222的深度D2為0.1微米至0.5微米。深度D2為第二源極/汲極220的側壁與中介絕緣結構320”的側壁之間的水 平距離。 In this embodiment, the second source/drain 220 is retracted due to side etching to form a groove 222 formed by the bottom surface of the intermediate insulating structure 320", the sidewall of the second source/drain 220 and the top surface of the first insulating layer 310'. In some embodiments, the depth D2 of the groove 222 is 0.1 micron to 0.5 micron. The depth D2 is the horizontal distance between the sidewall of the second source/drain 220 and the sidewall of the intermediate insulating structure 320".
在一些實施例中,圖案化光阻層PR、中介絕緣結構320”以及第一絕緣層310’也可能會在第二濕蝕刻製程中被局部蝕刻,然而由於第二導電層220’在第二濕蝕刻製程中的蝕刻速率明顯快於中介絕緣結構320”以及第一絕緣層310’在第二濕蝕刻製程中的蝕刻速率,因此有利於凹槽222的形成。 In some embodiments, the patterned photoresist layer PR, the intermediate insulating structure 320″ and the first insulating layer 310′ may also be partially etched in the second wet etching process. However, since the etching rate of the second conductive layer 220′ in the second wet etching process is significantly faster than the etching rate of the intermediate insulating structure 320″ and the first insulating layer 310′ in the second wet etching process, it is beneficial to the formation of the groove 222.
在本實施例中,第二源極/汲極220具有第二通孔H2。凹槽222可視為第二通孔H2的一部分。 In this embodiment, the second source/drain 220 has a second through hole H2. The groove 222 can be regarded as a part of the second through hole H2.
在本實施例中,第三源極/汲極230也有可能在第二濕蝕刻製程中被進一步蝕刻,使凹槽232’的深度進一步增加至深度D1’。在一些實施例中,凹槽232’的深度D1’為0.1微米至1微米。 In this embodiment, the third source/drain 230 may also be further etched in the second wet etching process, so that the depth of the groove 232' is further increased to the depth D1'. In some embodiments, the depth D1' of the groove 232' is 0.1 micron to 1 micron.
請參考圖15B,移除圖案化光阻層PR。以第三源極/汲極230為罩幕對中介絕緣結構320”執行第三乾蝕刻製程,以獲得第二絕緣結構320。以第二源極/汲極220為罩幕對第一絕緣層310’執行第四乾蝕刻製程,以獲得第一絕緣結構310。在一些實施例中,第三乾蝕刻製程以及第四乾蝕刻製程為同時執行。 Please refer to FIG. 15B to remove the patterned photoresist layer PR. The third source/drain 230 is used as a mask to perform a third dry etching process on the intermediate insulating structure 320” to obtain the second insulating structure 320. The second source/drain 220 is used as a mask to perform a fourth dry etching process on the first insulating layer 310’ to obtain the first insulating structure 310. In some embodiments, the third dry etching process and the fourth dry etching process are performed simultaneously.
在本實施例中,由於第一絕緣結構310、第二源極/汲極220、第二絕緣結構320以及第三源極/汲極230的製造過程利用了同一個圖案化光阻層PR,因此第一絕緣結構310的第一通孔H1、第二源極/汲極220的第二通孔H2、第二絕緣結構320的第三通孔H3以及第三源極/汲極230的第四通孔H4具有更好的對 稱性。舉例來說,第一通孔H1、第二通孔H2、第三通孔H3以及第四通孔H4基於中心線CL而具有左右對稱的結構。在一些實施例中,第一通孔H1的中心、第二通孔H2的中心、第三通孔H3的中心以及第四通孔H4的中心彼此對齊。 In this embodiment, since the manufacturing process of the first insulating structure 310, the second source/drain 220, the second insulating structure 320 and the third source/drain 230 uses the same patterned photoresist layer PR, the first through hole H1 of the first insulating structure 310, the second through hole H2 of the second source/drain 220, the third through hole H3 of the second insulating structure 320 and the fourth through hole H4 of the third source/drain 230 have better symmetry. For example, the first through hole H1, the second through hole H2, the third through hole H3 and the fourth through hole H4 have a left-right symmetric structure based on the center line CL. In some embodiments, the center of the first through hole H1, the center of the second through hole H2, the center of the third through hole H3, and the center of the fourth through hole H4 are aligned with each other.
最後,執行如14G至圖14I所示的步驟以形成半導體結構400、閘介電層300以及閘極500。 Finally, the steps shown in FIG. 14G to FIG. 14I are performed to form the semiconductor structure 400, the gate dielectric layer 300 and the gate 500.
綜上所述,在本發明的實施例的半導體裝置中,第一源極/汲極、第一絕緣結構、第二源極/汲極、第二絕緣結構以及第三源極/汲極堆疊設置,藉此可以有效的減少設置半導體裝置所需的佔地面積。 In summary, in the semiconductor device of the embodiment of the present invention, the first source/drain, the first insulating structure, the second source/drain, the second insulating structure and the third source/drain are stacked, thereby effectively reducing the area required for setting up the semiconductor device.
10:半導體裝置 10: Semiconductor devices
100:基板 100: Substrate
210:第一源極/汲極 210: First source/drain
210t,230t:頂面 210t,230t:Top
210w,310w,220w,320w,230w:外側側壁 210w, 310w, 220w, 320w, 230w: outer side wall
220:第二源極/汲極 220: Second source/drain
230:第三源極/汲極 230: Third source/drain
310:第一絕緣結構 310: First insulation structure
320:第二絕緣結構 320: Second insulation structure
330:閘介電層 330: Gate dielectric layer
400:半導體結構 400:Semiconductor structure
410:第一半導體層 410: First semiconductor layer
420:第二半導體層 420: Second semiconductor layer
430:第三半導體層 430: Third semiconductor layer
500:閘極 500: Gate
H1:第一通孔 H1: First through hole
H2:第二通孔 H2: Second through hole
H3:第三通孔 H3: The third through hole
H4:第四通孔 H4: Fourth through hole
ND:法線方向 ND: Normal direction
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