IL104562A - Components of catalysts for the polymerization of olefins - Google Patents
Components of catalysts for the polymerization of olefinsInfo
- Publication number
- IL104562A IL104562A IL10456293A IL10456293A IL104562A IL 104562 A IL104562 A IL 104562A IL 10456293 A IL10456293 A IL 10456293A IL 10456293 A IL10456293 A IL 10456293A IL 104562 A IL104562 A IL 104562A
- Authority
- IL
- Israel
- Prior art keywords
- compound
- components according
- spherical components
- alkyl
- weight
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 38
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 32
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 7
- 239000010936 titanium Substances 0.000 claims abstract description 51
- 239000011148 porous material Substances 0.000 claims abstract description 42
- 150000001875 compounds Chemical class 0.000 claims abstract description 28
- 239000011777 magnesium Substances 0.000 claims abstract description 22
- 150000003609 titanium compounds Chemical class 0.000 claims abstract description 19
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 15
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 8
- 239000005977 Ethylene Substances 0.000 claims description 41
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 39
- 229910052719 titanium Inorganic materials 0.000 claims description 27
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical group CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 26
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 24
- 238000006243 chemical reaction Methods 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 20
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 18
- 125000004432 carbon atom Chemical group C* 0.000 claims description 18
- 125000000217 alkyl group Chemical group 0.000 claims description 15
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 15
- -1 alkyl radical Chemical group 0.000 claims description 14
- 150000005840 aryl radicals Chemical group 0.000 claims description 11
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- 230000002140 halogenating effect Effects 0.000 claims description 6
- 230000001603 reducing effect Effects 0.000 claims description 6
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 6
- 229910003074 TiCl4 Inorganic materials 0.000 claims description 5
- 125000005843 halogen group Chemical group 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- 150000001993 dienes Chemical class 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 229920001198 elastomeric copolymer Polymers 0.000 claims description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims 1
- 150000007513 acids Chemical class 0.000 claims 1
- 150000008378 aryl ethers Chemical class 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 125000001309 chloro group Chemical group Cl* 0.000 claims 1
- 229920001038 ethylene copolymer Polymers 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 claims 1
- 239000007787 solid Substances 0.000 abstract description 14
- 238000009826 distribution Methods 0.000 abstract description 8
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 84
- 229920000642 polymer Polymers 0.000 description 31
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 30
- 238000003756 stirring Methods 0.000 description 15
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 13
- 229910052753 mercury Inorganic materials 0.000 description 13
- 239000012071 phase Substances 0.000 description 10
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 10
- 229910003910 SiCl4 Inorganic materials 0.000 description 9
- 229920001903 high density polyethylene Polymers 0.000 description 9
- 229920000092 linear low density polyethylene Polymers 0.000 description 9
- FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 8
- 239000007789 gas Substances 0.000 description 8
- 239000004700 high-density polyethylene Substances 0.000 description 8
- 239000004707 linear low-density polyethylene Substances 0.000 description 8
- 235000011147 magnesium chloride Nutrition 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 238000007334 copolymerization reaction Methods 0.000 description 7
- 239000000725 suspension Substances 0.000 description 7
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 6
- 239000007791 liquid phase Substances 0.000 description 6
- 239000008096 xylene Substances 0.000 description 6
- 230000000877 morphologic effect Effects 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 239000001294 propane Substances 0.000 description 5
- 239000011949 solid catalyst Substances 0.000 description 5
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 238000007669 thermal treatment Methods 0.000 description 4
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 3
- 239000003638 chemical reducing agent Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000007429 general method Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000005049 silicon tetrachloride Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000001694 spray drying Methods 0.000 description 2
- 238000001291 vacuum drying Methods 0.000 description 2
- 238000013022 venting Methods 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- OUPPKRIDJAMCCA-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)-2,3-dimethylbutane Chemical compound COCC(C)(C(C)C)COC OUPPKRIDJAMCCA-UHFFFAOYSA-N 0.000 description 1
- 239000005046 Chlorosilane Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229910010062 TiCl3 Inorganic materials 0.000 description 1
- 239000004708 Very-low-density polyethylene Substances 0.000 description 1
- 238000002083 X-ray spectrum Methods 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000007860 aryl ester derivatives Chemical class 0.000 description 1
- XOMRTUIUGUAFNI-UHFFFAOYSA-N bis(2-methylpropyl) benzene-1,2-dicarboxylate;dioctyl benzene-1,2-dicarboxylate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C.CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC XOMRTUIUGUAFNI-UHFFFAOYSA-N 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical class Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 description 1
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 229920013728 elastomeric terpolymer Polymers 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002689 maleic acids Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000003022 phthalic acids Chemical class 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000002459 porosimetry Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 229920001866 very low density polyethylene Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI920194A IT1262934B (it) | 1992-01-31 | 1992-01-31 | Componenti e catalizzatori per la polimerizzazione di olefine |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| IL104562A true IL104562A (en) | 1995-10-31 |
Family
ID=11361767
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL10456293A IL104562A (en) | 1992-01-31 | 1993-01-29 | Components of catalysts for the polymerization of olefins |
Country Status (21)
| Country | Link |
|---|---|
| US (2) | US5585317A (pt) |
| EP (1) | EP0553806B1 (pt) |
| JP (1) | JP3285637B2 (pt) |
| KR (1) | KR100250336B1 (pt) |
| CN (2) | CN1032063C (pt) |
| AT (1) | ATE165843T1 (pt) |
| AU (1) | AU655526B2 (pt) |
| BR (1) | BR9300391A (pt) |
| CA (1) | CA2088525A1 (pt) |
| DE (1) | DE69318318T2 (pt) |
| DK (1) | DK0553806T3 (pt) |
| ES (1) | ES2117061T3 (pt) |
| FI (1) | FI106310B (pt) |
| IL (1) | IL104562A (pt) |
| IT (1) | IT1262934B (pt) |
| MX (1) | MX9300533A (pt) |
| MY (1) | MY109025A (pt) |
| NO (1) | NO300274B1 (pt) |
| RU (1) | RU2118330C1 (pt) |
| TW (1) | TW222652B (pt) |
| ZA (1) | ZA93664B (pt) |
Families Citing this family (166)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1262935B (it) * | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1254279B (it) * | 1992-03-13 | 1995-09-14 | Montecatini Tecnologie Srl | Procedimento per la polimerizzazione in fase gas delle olefine |
| IT1256648B (it) * | 1992-12-11 | 1995-12-12 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione delle olefine |
| ITMI922919A1 (it) * | 1992-12-21 | 1994-06-22 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1269194B (it) * | 1994-01-21 | 1997-03-21 | Spherilene Srl | Composizioni polimeriche ad elevata processabilita' basate su lldpe |
| IT1269931B (it) * | 1994-03-29 | 1997-04-16 | Spherilene Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1269837B (it) * | 1994-05-26 | 1997-04-15 | Spherilene Srl | Componenti e catalizzatori per la polimerizzazione delle olefine |
| US5455303A (en) | 1994-06-20 | 1995-10-03 | Montell North America Inc. | Linear low density polyethylene based compositions with improved optics |
| IT1270070B (it) | 1994-07-08 | 1997-04-28 | Spherilene Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1273660B (it) * | 1994-07-20 | 1997-07-09 | Spherilene Srl | Procedimento per la preparazione di polimeri amorfi del propilene |
| IT1270125B (it) * | 1994-10-05 | 1997-04-28 | Spherilene Srl | Processo per la ( co) polimerizzazione di olefine |
| IT1274469B (it) * | 1995-05-11 | 1997-07-17 | Spherilene Spa | Composizioni poliolefiniche vulcanizzabili dinamicamente |
| IT1275573B (it) * | 1995-07-20 | 1997-08-07 | Spherilene Spa | Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine |
| IT1276121B1 (it) * | 1995-11-14 | 1997-10-24 | Montell Technology Company Bv | Film multistrato estensibili |
| IT1276120B1 (it) * | 1995-11-14 | 1997-10-24 | Montell Technology Company Bv | Film multistrato estensibili basati su lldpe |
| IT1281198B1 (it) | 1995-12-18 | 1998-02-17 | Montell Technology Company Bv | Film termoretraibili basati su composizioni poliolefiniche comprendenti un copolimero lineare dell'etilene con alfa-olefine |
| US5990034A (en) * | 1996-12-06 | 1999-11-23 | Asahi Kasei Kogyo Kabushiki Kaisha | Olefin polymerization catalyst |
| IT1292109B1 (it) | 1997-06-09 | 1999-01-25 | Montell North America Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1292108B1 (it) | 1997-06-09 | 1999-01-25 | Montell North America Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1292107B1 (it) * | 1997-06-09 | 1999-01-25 | Montell North America Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1292138B1 (it) * | 1997-06-12 | 1999-01-25 | Montell Technology Company Bv | Film multistrato estensibili |
| US5952423A (en) * | 1997-07-18 | 1999-09-14 | Baxter International Inc. | Plastic compositions for medical containers and methods for providing such containers and for storing red blood cells |
| US6468258B1 (en) | 1997-07-18 | 2002-10-22 | Baxter International Inc. | Plastic compositions including vitamin E for medical containers and methods for providing such compositions and containers |
| AU9262498A (en) * | 1997-09-03 | 1999-03-22 | Montell Technology Company B.V. | Components and catalysts for the polymerization of olefins |
| JP3406488B2 (ja) * | 1997-09-05 | 2003-05-12 | 東京エレクトロン株式会社 | 真空処理装置 |
| DE69910511T2 (de) | 1998-03-05 | 2004-06-17 | Basell Poliolefine Italia S.P.A. | Polybutene-1 (co)polymere und verfahren zu ihrer herstellung |
| ES2198098T3 (es) | 1998-03-09 | 2004-01-16 | Basell Poliolefine Italia S.P.A. | Procedimiento multietapas para la polimerizacion de olefinas. |
| SG73622A1 (en) * | 1998-03-11 | 2000-06-20 | Sumitomo Chemical Co | Solid catalyst component and catalyst for olefin polymerization and process for producing olefin polymer |
| ES2364330T3 (es) * | 1998-03-23 | 2011-08-31 | Basell Poliolefine Italia S.R.L. | Componentes catalíticos prepolimerizados para la polimerización de olefinas. |
| KR100334165B1 (ko) | 1998-04-17 | 2002-11-27 | 삼성종합화학주식회사 | 에틸렌 중합 및 에틸렌/α-올레핀 공중합용 담지촉매의 제조방법 |
| EP0994905B1 (en) | 1998-05-06 | 2004-01-21 | Basell Poliolefine Italia S.p.A. | Catalyst components for the polymerization of olefins |
| CN1268962A (zh) | 1998-05-06 | 2000-10-04 | 蒙特尔技术有限公司 | 聚烯烃组合物和由其制得的薄膜 |
| IT1301990B1 (it) | 1998-08-03 | 2000-07-20 | Licio Zambon | Catalizzatori per la polimerizzazione delle olefine. |
| DE69918662T2 (de) | 1998-11-04 | 2005-08-11 | Basell Poliolefine Italia S.P.A. | Bestandteile und katalysatoren für die olefinpolymerisation |
| AU3960500A (en) | 1999-03-09 | 2000-09-28 | Basell Technology Company B.V. | Multi-stage process for the (co)polymerization of olefins |
| JP4537587B2 (ja) | 1999-03-15 | 2010-09-01 | バセル テクノロジー カンパニー ビー．ブイ． | オレフィンの重合用成分および触媒 |
| ATE335014T1 (de) | 1999-04-15 | 2006-08-15 | Basell Poliolefine Srl | Bestandteile und katalysatoren für die olefinpolymerisation |
| US6265037B1 (en) | 1999-04-16 | 2001-07-24 | Andersen Corporation | Polyolefin wood fiber composite |
| KR100524293B1 (ko) | 1999-05-27 | 2005-10-26 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합용 촉매 |
| KR100546499B1 (ko) | 1999-05-27 | 2006-01-26 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합용 촉매 |
| CA2340908A1 (en) * | 1999-06-18 | 2000-12-28 | Basell Technology Company B.V. | Catalyst components for the polymerization of olefins and catalysts therefrom obtained |
| HUP0202584A3 (en) | 1999-09-10 | 2003-10-28 | Basell Technology Co Bv | Catalyst for the polymerization of olefins |
| WO2001032718A1 (en) | 1999-10-23 | 2001-05-10 | Samsung General Chemicals Co., Ltd. | An improved catalyst for homo- and co-polymerization of olefin |
| KR100361224B1 (ko) | 1999-12-01 | 2002-11-29 | 삼성종합화학주식회사 | 에틸렌 중합 및 공중합용 촉매의 제조방법 |
| AU2849701A (en) | 2000-02-02 | 2001-08-14 | Basell Technology Company B.V. | Components and catalysts for the polymerization of olefins |
| CN1162454C (zh) | 2000-03-22 | 2004-08-18 | 巴塞尔技术有限公司 | 全同立构丙烯聚合物和全同立构规整度降低的软丙烯聚合物的热塑性组合物及其制备方法 |
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| IT1230134B (it) * | 1989-04-28 | 1991-10-14 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine. |
| US5221651A (en) * | 1989-04-28 | 1993-06-22 | Himont Incorporated | Component and catalysts for the polymerization of olefins |
| IT1231768B (it) * | 1989-08-02 | 1991-12-21 | Himont Inc | Composizioni polipropileniche adatte alla modifica di bitumi. |
| FR2651234B1 (fr) * | 1989-08-29 | 1993-03-12 | Bp Chem Int Ltd | Procede de fabrication en phase gazeuse de copolymeres du propylene a l'aide d'un systeme catalytique de haute activite. |
| IT1236509B (it) * | 1989-10-06 | 1993-03-11 | Francesco Masi | Procedimento per la preparazione di copolimeri etilene-butene-1 con densita' ultra-bassa. |
| CN1022170C (zh) * | 1990-06-08 | 1993-09-22 | 河北机电学院 | 滚挤异型钢管装置 |
| US5229342A (en) * | 1990-10-18 | 1993-07-20 | Shell Oil Company | Olefin polymerization catalyst |
| US5141910A (en) * | 1990-10-18 | 1992-08-25 | Shell Oil Company | Olefin polymerization catalyst |
| IT1245249B (it) * | 1991-03-27 | 1994-09-13 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1245250B (it) * | 1991-03-27 | 1994-09-13 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1262935B (it) * | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
-
1992
- 1992-01-31 IT ITMI920194A patent/IT1262934B/it active IP Right Grant
-
1993
- 1993-01-28 EP EP93101284A patent/EP0553806B1/en not_active Expired - Lifetime
- 1993-01-28 AT AT93101284T patent/ATE165843T1/de not_active IP Right Cessation
- 1993-01-28 DE DE69318318T patent/DE69318318T2/de not_active Expired - Lifetime
- 1993-01-28 DK DK93101284T patent/DK0553806T3/da active
- 1993-01-28 ES ES93101284T patent/ES2117061T3/es not_active Expired - Lifetime
- 1993-01-29 JP JP01420393A patent/JP3285637B2/ja not_active Expired - Lifetime
- 1993-01-29 BR BR9300391A patent/BR9300391A/pt not_active IP Right Cessation
- 1993-01-29 RU RU93004501A patent/RU2118330C1/ru not_active IP Right Cessation
- 1993-01-29 IL IL10456293A patent/IL104562A/en not_active IP Right Cessation
- 1993-01-29 FI FI930403A patent/FI106310B/fi not_active IP Right Cessation
- 1993-01-29 ZA ZA93664A patent/ZA93664B/xx unknown
- 1993-01-30 CN CN93102504A patent/CN1032063C/zh not_active Expired - Fee Related
- 1993-01-30 CN CN 95115110 patent/CN1036461C/zh not_active Expired - Fee Related
- 1993-01-30 KR KR1019930001257A patent/KR100250336B1/ko not_active Expired - Lifetime
- 1993-01-30 MY MYPI93000152A patent/MY109025A/en unknown
- 1993-01-30 TW TW082100610A patent/TW222652B/zh active
- 1993-02-01 CA CA002088525A patent/CA2088525A1/en not_active Abandoned
- 1993-02-01 NO NO930348A patent/NO300274B1/no unknown
- 1993-02-01 AU AU32157/93A patent/AU655526B2/en not_active Ceased
- 1993-02-01 MX MX9300533A patent/MX9300533A/es not_active IP Right Cessation
-
1995
- 1995-07-10 US US08/500,032 patent/US5585317A/en not_active Expired - Lifetime
-
1996
- 1996-09-11 US US08/712,425 patent/US5726261A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| FI930403L (fi) | 1993-08-01 |
| KR100250336B1 (ko) | 2000-04-01 |
| KR930016443A (ko) | 1993-08-26 |
| AU655526B2 (en) | 1994-12-22 |
| JP3285637B2 (ja) | 2002-05-27 |
| MY109025A (en) | 1996-11-30 |
| EP0553806B1 (en) | 1998-05-06 |
| ES2117061T3 (es) | 1998-08-01 |
| CN1117499A (zh) | 1996-02-28 |
| NO930348D0 (no) | 1993-02-01 |
| DK0553806T3 (da) | 1998-10-07 |
| US5726261A (en) | 1998-03-10 |
| US5585317A (en) | 1996-12-17 |
| IT1262934B (it) | 1996-07-22 |
| TW222652B (pt) | 1994-04-21 |
| RU2118330C1 (ru) | 1998-08-27 |
| BR9300391A (pt) | 1993-08-03 |
| ITMI920194A1 (it) | 1993-07-31 |
| DE69318318D1 (de) | 1998-06-10 |
| FI930403A0 (fi) | 1993-01-29 |
| ATE165843T1 (de) | 1998-05-15 |
| NO930348L (no) | 1993-08-02 |
| ITMI920194A0 (it) | 1992-01-31 |
| JPH0665314A (ja) | 1994-03-08 |
| DE69318318T2 (de) | 1998-11-19 |
| ZA93664B (en) | 1993-09-02 |
| CN1032063C (zh) | 1996-06-19 |
| CN1075485A (zh) | 1993-08-25 |
| NO300274B1 (no) | 1997-05-05 |
| MX9300533A (es) | 1994-07-29 |
| CA2088525A1 (en) | 1993-08-01 |
| FI106310B (fi) | 2001-01-15 |
| CN1036461C (zh) | 1997-11-19 |
| EP0553806A1 (en) | 1993-08-04 |
| AU3215793A (en) | 1993-08-05 |
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| FF | Patent granted | ||
| HC | Change of name of proprietor(s) | ||
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| RH1 | Patent not in force |