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IT1270125B - Processo per la ( co) polimerizzazione di olefine - Google Patents

Processo per la ( co) polimerizzazione di olefine

Info

Publication number
IT1270125B
IT1270125B ITMI942028A ITMI942028A IT1270125B IT 1270125 B IT1270125 B IT 1270125B IT MI942028 A ITMI942028 A IT MI942028A IT MI942028 A ITMI942028 A IT MI942028A IT 1270125 B IT1270125 B IT 1270125B
Authority
IT
Italy
Prior art keywords
stage
polymerization
olefine
arilic
alchylic
Prior art date
Application number
ITMI942028A
Other languages
English (en)
Inventor
Gianni Collina
Occo Tiziano Dall
Maurizio Galimberti
Enrico Albizzati
Luciano Noristi
Original Assignee
Spherilene Srl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Spherilene Srl filed Critical Spherilene Srl
Publication of ITMI942028A0 publication Critical patent/ITMI942028A0/it
Priority to ITMI942028A priority Critical patent/IT1270125B/it
Priority to US08/461,691 priority patent/US5648422A/en
Priority to PT95935892T priority patent/PT742801E/pt
Priority to DK95935892T priority patent/DK0742801T3/da
Priority to AT95935892T priority patent/ATE200499T1/de
Priority to CN95191444A priority patent/CN1070505C/zh
Priority to AU38033/95A priority patent/AU694276B2/en
Priority to CA002178077A priority patent/CA2178077A1/en
Priority to FI962329A priority patent/FI962329A7/fi
Priority to SK872-96A priority patent/SK281619B6/sk
Priority to PL95314853A priority patent/PL314853A1/xx
Priority to HU9601834A priority patent/HU216285B/hu
Priority to DE69520662T priority patent/DE69520662T2/de
Priority to PCT/EP1995/003896 priority patent/WO1996011218A1/en
Priority to MX9602148A priority patent/MX9602148A/es
Priority to JP51231496A priority patent/JP3897359B2/ja
Priority to BR9506402A priority patent/BR9506402A/pt
Priority to ES95935892T priority patent/ES2156948T3/es
Priority to RU96115290/04A priority patent/RU2171265C2/ru
Priority to CZ19961994A priority patent/CZ287739B6/cs
Priority to KR1019960702939A priority patent/KR100399625B1/ko
Priority to EP95935892A priority patent/EP0742801B1/en
Priority to ZA958316A priority patent/ZA958316B/xx
Priority to PH51428A priority patent/PH31450A/en
Priority to MYPI95002960A priority patent/MY112181A/en
Priority to IL11551595A priority patent/IL115515A/xx
Priority to TR95/01214A priority patent/TR199501214A2/xx
Publication of ITMI942028A1 publication Critical patent/ITMI942028A1/it
Priority to NO19962298A priority patent/NO311179B1/no
Priority to BG100674A priority patent/BG100674A/bg
Application granted granted Critical
Publication of IT1270125B publication Critical patent/IT1270125B/it
Priority to US08/865,079 priority patent/US6028140A/en
Priority to GR20010400559T priority patent/GR3035745T3/el

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/05—Transitioning, i.e. transition from one catalyst to another with use of a deactivating agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PROCESSO MULTISTADIO PER LA POLIMERIZZAZIONE DI UNA O PIU' OLEFINE DI FORMULA CH2 = CH2, IN CUI H E' IDROGENO OPPURE UN GRUPPO ALCHILICO, CICLOALCHILICO O ARILICO AVENTE DA 1 A 10 ATOMI DI CARBONIO, COMPRENDENTE:(A) UN PRIMO STADIO DI POLIMERIZZAZIONE, IN CUI, IN PRESENZA DI CATALIZZATORI AL TITANIO O AL VANADIO, VIENE PREPARATO UN PRIMO POLIMERO OLEFINICO;(B) UNO STADIO DI TRATTAMENTO IN CUI VIENE DISATTIVATO IL CATALIZZATORE PRECEDENTEMENTE UTILIZZATO ED IN CUI UN COMPOSTO METALLOCENICO VIENE SUPPORTATO SUL POLIMERO OLEFINICO PRODOTTO SULLO STADIO (A); E (C) UN SECONDO STADIO DI POLIMERIZZAZIONE IN CUI VENFONO POLIMERIZZATE UNA O PIU' OLEFINE IN PRESENZA DEL PRODOTTO OTTENUTO DALLO STADIO (B).
ITMI942028A 1994-10-05 1994-10-05 Processo per la ( co) polimerizzazione di olefine IT1270125B (it)

Priority Applications (31)

Application Number Priority Date Filing Date Title
ITMI942028A IT1270125B (it) 1994-10-05 1994-10-05 Processo per la ( co) polimerizzazione di olefine
US08/461,691 US5648422A (en) 1994-10-05 1995-06-05 Process for the (co)polymerization of olefins
BR9506402A BR9506402A (pt) 1994-10-05 1995-10-02 Processo para a (co) polimerizaçao de olefinas
ES95935892T ES2156948T3 (es) 1994-10-05 1995-10-02 Procedimiento para la (co)polimerizacion de olefinas.
AT95935892T ATE200499T1 (de) 1994-10-05 1995-10-02 Verfahren zur copolymerisation von olefinen
CN95191444A CN1070505C (zh) 1994-10-05 1995-10-02 烯烃(共)聚合方法
AU38033/95A AU694276B2 (en) 1994-10-05 1995-10-02 Process for the (co)polymerization of olefins
CA002178077A CA2178077A1 (en) 1994-10-05 1995-10-02 Process for the (co)polymerization of olefins
FI962329A FI962329A7 (fi) 1994-10-05 1995-10-02 Menetelmä olefiinien (ko)polymeroimiseksi
SK872-96A SK281619B6 (sk) 1994-10-05 1995-10-02 Viacstupňový spôsob polymerizácie jedného alebo viacerých olefínov
PL95314853A PL314853A1 (en) 1994-10-05 1995-10-02 Method of (co)polymerising olefines
HU9601834A HU216285B (hu) 1994-10-05 1995-10-02 Eljárás olefinek (ko)polimerizálására, és az így előállított polimerek
DE69520662T DE69520662T2 (de) 1994-10-05 1995-10-02 Verfahren zur copolymerisation von olefinen
PCT/EP1995/003896 WO1996011218A1 (en) 1994-10-05 1995-10-02 Process for the (co)polymerization of olefins
MX9602148A MX9602148A (es) 1994-10-05 1995-10-02 Procedimiento para la copolimerizacion de olefinas.
JP51231496A JP3897359B2 (ja) 1994-10-05 1995-10-02 オレフィンの（共）重合法
PT95935892T PT742801E (pt) 1994-10-05 1995-10-02 Processo para a (co)polimerizacao de olefinas
DK95935892T DK0742801T3 (da) 1994-10-05 1995-10-02 Fremgangsmåde til (co)polymerisation af olefiner
RU96115290/04A RU2171265C2 (ru) 1994-10-05 1995-10-02 Способ (со)полимеризации олефинов
CZ19961994A CZ287739B6 (en) 1994-10-05 1995-10-02 Multistage polymerization process of olefins and olefin homopolymers or copolymers obtained thereby
KR1019960702939A KR100399625B1 (ko) 1994-10-05 1995-10-02 올레핀의(공)중합방법
EP95935892A EP0742801B1 (en) 1994-10-05 1995-10-02 Process for the (co)polymerization of olefins
ZA958316A ZA958316B (en) 1994-10-05 1995-10-03 Process for the (co)polyrization of olefins
PH51428A PH31450A (en) 1994-10-05 1995-10-04 Process for the (co) polymerization of olefins.
MYPI95002960A MY112181A (en) 1994-10-05 1995-10-04 Process for the (co) polymerization of olefins
IL11551595A IL115515A (en) 1994-10-05 1995-10-05 Process for the (CO) polymerization of olefins
TR95/01214A TR199501214A2 (tr) 1994-10-05 1995-10-05 Olefinlerin (ko) polimerizasyonuna mahsus yöntem.
NO19962298A NO311179B1 (no) 1994-10-05 1996-06-04 Fremgangsmåte for (ko)polymerisering av olefiner
BG100674A BG100674A (bg) 1994-10-05 1996-06-24 Метод за (съ)полимеризация на олефини
US08/865,079 US6028140A (en) 1994-10-05 1997-05-29 Process for the (co)polymerization of olefins
GR20010400559T GR3035745T3 (en) 1994-10-05 2001-04-12 Process for the (co)polymerization of olefins

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI942028A IT1270125B (it) 1994-10-05 1994-10-05 Processo per la ( co) polimerizzazione di olefine

Publications (3)

Publication Number Publication Date
ITMI942028A0 ITMI942028A0 (it) 1994-10-05
ITMI942028A1 ITMI942028A1 (it) 1996-04-05
IT1270125B true IT1270125B (it) 1997-04-28

Family

ID=11369652

Family Applications (1)

Application Number Title Priority Date Filing Date
ITMI942028A IT1270125B (it) 1994-10-05 1994-10-05 Processo per la ( co) polimerizzazione di olefine

Country Status (29)

Country Link
US (2) US5648422A (it)
EP (1) EP0742801B1 (it)
JP (1) JP3897359B2 (it)
KR (1) KR100399625B1 (it)
CN (1) CN1070505C (it)
AT (1) ATE200499T1 (it)
AU (1) AU694276B2 (it)
BG (1) BG100674A (it)
BR (1) BR9506402A (it)
CA (1) CA2178077A1 (it)
CZ (1) CZ287739B6 (it)
DE (1) DE69520662T2 (it)
DK (1) DK0742801T3 (it)
ES (1) ES2156948T3 (it)
FI (1) FI962329A7 (it)
GR (1) GR3035745T3 (it)
HU (1) HU216285B (it)
IL (1) IL115515A (it)
IT (1) IT1270125B (it)
MY (1) MY112181A (it)
NO (1) NO311179B1 (it)
PH (1) PH31450A (it)
PL (1) PL314853A1 (it)
PT (1) PT742801E (it)
RU (1) RU2171265C2 (it)
SK (1) SK281619B6 (it)
TR (1) TR199501214A2 (it)
WO (1) WO1996011218A1 (it)
ZA (1) ZA958316B (it)

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