DE3206265C2 - Freifließende, sprühgetrocknete Hohlkügelchen zur Herstellung gerüststoffhaltiger Waschmittelteilchen, Verfahren zur Herstellung derselben und Verwendung dieser zur Bildung von Waschmittel mit nichtionischen Waschaktivstoffen - Google Patents

Freifließende, sprühgetrocknete Hohlkügelchen zur Herstellung gerüststoffhaltiger Waschmittelteilchen, Verfahren zur Herstellung derselben und Verwendung dieser zur Bildung von Waschmittel mit nichtionischen Waschaktivstoffen

Info

Publication number: DE3206265C2
Authority: DE; Germany
Prior art keywords: sodium; zeolite; weight; detergent; hollow beads
Prior art date: 1981-02-26
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

DE3206265A

Other languages

German (de)

English (en)

Other versions

DE3206265A1 (de

Inventor

Sue Wilson North Brunswick N.J. Giordano

John Jerome Trenton N.J. Grecsek

Seymour Somerset N.J. Grey

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Colgate Palmolive Co

Original Assignee

Colgate Palmolive Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-02-26

Filing date

1982-02-20

Publication date

1987-04-09

1982-02-20 Application filed by Colgate Palmolive Co filed Critical Colgate Palmolive Co

1982-11-04 Publication of DE3206265A1 publication Critical patent/DE3206265A1/de

1987-04-09 Application granted granted Critical

1987-04-09 Publication of DE3206265C2 publication Critical patent/DE3206265C2/de

Status Expired legal-status Critical Current

Links

239000003599 detergent Substances 0.000 title claims abstract description 140
239000011324 bead Substances 0.000 title claims description 103
239000002245 particle Substances 0.000 title claims description 23
238000000034 method Methods 0.000 title claims description 15
230000008569 process Effects 0.000 title claims description 14
239000013543 active substance Substances 0.000 title claims description 7
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 96
239000010457 zeolite Substances 0.000 claims abstract description 95
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 89
229910021536 Zeolite Inorganic materials 0.000 claims abstract description 85
229920000058 polyacrylate Polymers 0.000 claims abstract description 56
239000000440 bentonite Substances 0.000 claims abstract description 49
229910000278 bentonite Inorganic materials 0.000 claims abstract description 49
SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 49
229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 48
239000004115 Sodium Silicate Substances 0.000 claims abstract description 34
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 33
229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 33
239000000126 substance Substances 0.000 claims abstract description 22
UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims abstract description 21
239000000203 mixture Substances 0.000 claims description 94
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 72
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 56
239000000047 product Substances 0.000 claims description 52
235000012216 bentonite Nutrition 0.000 claims description 51
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 32
235000017557 sodium bicarbonate Nutrition 0.000 claims description 28
229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 28
238000005406 washing Methods 0.000 claims description 25
239000011734 sodium Substances 0.000 claims description 23
239000007787 solid Substances 0.000 claims description 23
229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 19
NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 18
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 17
239000003795 chemical substances by application Substances 0.000 claims description 17
108090000790 Enzymes Proteins 0.000 claims description 16
102000004190 Enzymes Human genes 0.000 claims description 16
230000036571 hydration Effects 0.000 claims description 15
238000006703 hydration reaction Methods 0.000 claims description 15
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 13
229910052708 sodium Inorganic materials 0.000 claims description 13
239000007921 spray Substances 0.000 claims description 13
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 12
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims description 12
229910001424 calcium ion Inorganic materials 0.000 claims description 12
239000004480 active ingredient Substances 0.000 claims description 10
238000010521 absorption reaction Methods 0.000 claims description 9
239000002736 nonionic surfactant Substances 0.000 claims description 9
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 8
230000000694 effects Effects 0.000 claims description 8
230000008961 swelling Effects 0.000 claims description 8
229910004298 SiO 2 Inorganic materials 0.000 claims description 7
238000005342 ion exchange Methods 0.000 claims description 7
229910000019 calcium carbonate Inorganic materials 0.000 claims description 6
239000004927 clay Substances 0.000 claims description 6
239000007859 condensation product Substances 0.000 claims description 6
239000012736 aqueous medium Substances 0.000 claims description 5
125000004432 carbon atom Chemical group C* 0.000 claims description 5
230000007797 corrosion Effects 0.000 claims description 4
238000005260 corrosion Methods 0.000 claims description 4
150000002191 fatty alcohols Chemical class 0.000 claims description 4
150000004760 silicates Chemical class 0.000 claims description 4
229910019142 PO4 Inorganic materials 0.000 claims description 3
230000008901 benefit Effects 0.000 claims description 3
230000008021 deposition Effects 0.000 claims description 3
238000002360 preparation method Methods 0.000 claims description 3
239000002689 soil Substances 0.000 claims description 3
KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 2
230000002411 adverse Effects 0.000 claims description 2
235000012211 aluminium silicate Nutrition 0.000 claims description 2
229910000323 aluminium silicate Inorganic materials 0.000 claims description 2
229940043430 calcium compound Drugs 0.000 claims description 2
150000001674 calcium compounds Chemical class 0.000 claims description 2
239000004753 textile Substances 0.000 claims description 2
239000010452 phosphate Substances 0.000 claims 2
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 claims 1
238000006243 chemical reaction Methods 0.000 claims 1
235000014113 dietary fatty acids Nutrition 0.000 claims 1
239000000194 fatty acid Substances 0.000 claims 1
229930195729 fatty acid Natural products 0.000 claims 1
150000004665 fatty acids Chemical class 0.000 claims 1
230000002401 inhibitory effect Effects 0.000 claims 1
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims 1
229910052622 kaolinite Inorganic materials 0.000 claims 1
229910001425 magnesium ion Inorganic materials 0.000 claims 1
239000003352 sequestering agent Substances 0.000 claims 1
239000001488 sodium phosphate Substances 0.000 claims 1
229910000162 sodium phosphate Inorganic materials 0.000 claims 1
RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims 1
239000007788 liquid Substances 0.000 abstract description 19
YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 abstract description 8
229940092782 bentonite Drugs 0.000 description 35
235000017550 sodium carbonate Nutrition 0.000 description 33
238000001694 spray drying Methods 0.000 description 31
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 29
239000000463 material Substances 0.000 description 25
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 24
238000002156 mixing Methods 0.000 description 22
238000007792 addition Methods 0.000 description 16
239000002304 perfume Substances 0.000 description 15
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 14
229940088598 enzyme Drugs 0.000 description 14
239000000843 powder Substances 0.000 description 14
235000019341 magnesium sulphate Nutrition 0.000 description 13
230000015572 biosynthetic process Effects 0.000 description 12
230000001965 increasing effect Effects 0.000 description 12
238000012360 testing method Methods 0.000 description 12
IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 11
238000001035 drying Methods 0.000 description 10
229960003390 magnesium sulfate Drugs 0.000 description 10
229910052943 magnesium sulfate Inorganic materials 0.000 description 10
239000002002 slurry Substances 0.000 description 10
235000013799 ultramarine blue Nutrition 0.000 description 10
239000007864 aqueous solution Substances 0.000 description 9
239000000499 gel Substances 0.000 description 9
238000012545 processing Methods 0.000 description 9
239000012467 final product Substances 0.000 description 8
239000011521 glass Substances 0.000 description 8
239000000654 additive Substances 0.000 description 7
239000000975 dye Substances 0.000 description 7
238000009472 formulation Methods 0.000 description 7
239000000049 pigment Substances 0.000 description 7
CNGYZEMWVAWWOB-VAWYXSNFSA-N 5-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-[(e)-2-[4-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound N=1C(NC=2C=C(C(\C=C\C=3C(=CC(NC=4N=C(N=C(NC=5C=CC=CC=5)N=4)N(CCO)CCO)=CC=3)S(O)(=O)=O)=CC=2)S(O)(=O)=O)=NC(N(CCO)CCO)=NC=1NC1=CC=CC=C1 CNGYZEMWVAWWOB-VAWYXSNFSA-N 0.000 description 6
-1 Epsom salts Chemical compound 0.000 description 6
238000000354 decomposition reaction Methods 0.000 description 6
238000004519 manufacturing process Methods 0.000 description 6
239000001509 sodium citrate Substances 0.000 description 6
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 6
239000000243 solution Substances 0.000 description 6
230000002745 absorbent Effects 0.000 description 5
239000002250 absorbent Substances 0.000 description 5
QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Substances CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 5
239000004744 fabric Substances 0.000 description 5
229910010272 inorganic material Inorganic materials 0.000 description 5
239000011147 inorganic material Substances 0.000 description 5
229920000742 Cotton Polymers 0.000 description 4
239000006057 Non-nutritive feed additive Substances 0.000 description 4
108091005804 Peptidases Proteins 0.000 description 4
102000035195 Peptidases Human genes 0.000 description 4
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
238000004140 cleaning Methods 0.000 description 4
159000000000 sodium salts Chemical class 0.000 description 4
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
241000212342 Sium Species 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
239000004902 Softening Agent Substances 0.000 description 3
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
239000011575 calcium Substances 0.000 description 3
229910052791 calcium Inorganic materials 0.000 description 3
ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
239000000428 dust Substances 0.000 description 3
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 3
238000005507 spraying Methods 0.000 description 3
229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 2
230000000996 additive effect Effects 0.000 description 2
230000001070 adhesive effect Effects 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
230000000844 anti-bacterial effect Effects 0.000 description 2
238000013459 approach Methods 0.000 description 2
239000000292 calcium oxide Substances 0.000 description 2
OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
150000001860 citric acid derivatives Chemical class 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
239000000945 filler Substances 0.000 description 2
230000006872 improvement Effects 0.000 description 2
239000000395 magnesium oxide Substances 0.000 description 2
239000002609 medium Substances 0.000 description 2
239000002808 molecular sieve Substances 0.000 description 2
230000000704 physical effect Effects 0.000 description 2
230000009467 reduction Effects 0.000 description 2
239000000523 sample Substances 0.000 description 2
239000004576 sand Substances 0.000 description 2
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
239000004408 titanium dioxide Substances 0.000 description 2
239000005995 Aluminium silicate Substances 0.000 description 1
108091005658 Basic proteases Proteins 0.000 description 1
229910052684 Cerium Inorganic materials 0.000 description 1
244000248349 Citrus limon Species 0.000 description 1
235000005979 Citrus limon Nutrition 0.000 description 1
241001366278 Leptotes marina Species 0.000 description 1
241001676573 Minium Species 0.000 description 1
IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
101150112468 OR51E2 gene Proteins 0.000 description 1
239000004111 Potassium silicate Substances 0.000 description 1
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
238000009825 accumulation Methods 0.000 description 1
150000001252 acrylic acid derivatives Chemical class 0.000 description 1
239000000853 adhesive Substances 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
229910052910 alkali metal silicate Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
239000004411 aluminium Substances 0.000 description 1
230000003625 amylolytic effect Effects 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
125000003710 aryl alkyl group Chemical group 0.000 description 1
239000012752 auxiliary agent Substances 0.000 description 1
239000002585 base Substances 0.000 description 1
108010019077 beta-Amylase Proteins 0.000 description 1
238000005282 brightening Methods 0.000 description 1
BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
229910002092 carbon dioxide Inorganic materials 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
HFNQLYDPNAZRCH-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O.OC(O)=O HFNQLYDPNAZRCH-UHFFFAOYSA-N 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical class O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 description 1
150000001767 cationic compounds Chemical class 0.000 description 1
ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
239000002738 chelating agent Substances 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
229910052681 coesite Inorganic materials 0.000 description 1
239000003086 colorant Substances 0.000 description 1
239000013068 control sample Substances 0.000 description 1
238000005536 corrosion prevention Methods 0.000 description 1
229910052906 cristobalite Inorganic materials 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
230000007423 decrease Effects 0.000 description 1
239000008367 deionised water Substances 0.000 description 1
229910021641 deionized water Inorganic materials 0.000 description 1
GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
ONCZQWJXONKSMM-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4].[Si+4].[Si+4].[Si+4] ONCZQWJXONKSMM-UHFFFAOYSA-N 0.000 description 1
SYHPANJAVIEQQL-UHFFFAOYSA-N dicarboxy carbonate Chemical group OC(=O)OC(=O)OC(O)=O SYHPANJAVIEQQL-UHFFFAOYSA-N 0.000 description 1
229940079919 digestives enzyme preparation Drugs 0.000 description 1
239000002270 dispersing agent Substances 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000009826 distribution Methods 0.000 description 1
239000011363 dried mixture Substances 0.000 description 1
230000002708 enhancing effect Effects 0.000 description 1
238000003912 environmental pollution Methods 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000009969 flowable effect Effects 0.000 description 1
GNBHRKFJIUUOQI-UHFFFAOYSA-N fluorescein Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC=C(O)C=C1OC1=CC(O)=CC=C21 GNBHRKFJIUUOQI-UHFFFAOYSA-N 0.000 description 1
239000007850 fluorescent dye Substances 0.000 description 1
239000006260 foam Substances 0.000 description 1
230000005484 gravity Effects 0.000 description 1
150000004677 hydrates Chemical class 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
230000003993 interaction Effects 0.000 description 1
239000001095 magnesium carbonate Substances 0.000 description 1
229910000021 magnesium carbonate Inorganic materials 0.000 description 1
229960005336 magnesium citrate Drugs 0.000 description 1
239000004337 magnesium citrate Substances 0.000 description 1
235000002538 magnesium citrate Nutrition 0.000 description 1
OUHCLAKJJGMPSW-UHFFFAOYSA-L magnesium;hydrogen carbonate;hydroxide Chemical compound O.[Mg+2].[O-]C([O-])=O OUHCLAKJJGMPSW-UHFFFAOYSA-L 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
238000005259 measurement Methods 0.000 description 1
CKFGINPQOCXMAZ-UHFFFAOYSA-N methanediol Chemical compound OCO CKFGINPQOCXMAZ-UHFFFAOYSA-N 0.000 description 1
150000004682 monohydrates Chemical class 0.000 description 1
229910052901 montmorillonite Inorganic materials 0.000 description 1
SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
235000019645 odor Nutrition 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
239000011368 organic material Substances 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920000867 polyelectrolyte Polymers 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
159000000001 potassium salts Chemical class 0.000 description 1
235000019353 potassium silicate Nutrition 0.000 description 1
NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
229910052913 potassium silicate Inorganic materials 0.000 description 1
230000002028 premature Effects 0.000 description 1
229940024999 proteolytic enzymes for treatment of wounds and ulcers Drugs 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
210000002374 sebum Anatomy 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
229940080314 sodium bentonite Drugs 0.000 description 1
229910000280 sodium bentonite Inorganic materials 0.000 description 1
229910000031 sodium sesquicarbonate Inorganic materials 0.000 description 1
235000018341 sodium sesquicarbonate Nutrition 0.000 description 1
235000019351 sodium silicates Nutrition 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
238000007711 solidification Methods 0.000 description 1
230000008023 solidification Effects 0.000 description 1
239000002904 solvent Substances 0.000 description 1
229910052682 stishovite Inorganic materials 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
239000000725 suspension Substances 0.000 description 1
229920002994 synthetic fiber Polymers 0.000 description 1
239000004758 synthetic textile Substances 0.000 description 1
230000009974 thixotropic effect Effects 0.000 description 1
238000012546 transfer Methods 0.000 description 1
229910052905 tridymite Inorganic materials 0.000 description 1
PLSARIKBYIPYPF-UHFFFAOYSA-H trimagnesium dicitrate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O PLSARIKBYIPYPF-UHFFFAOYSA-H 0.000 description 1
WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1
238000005303 weighing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0084—Antioxidants; Free-radical scavengers
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/02—Preparation in the form of powder by spray drying
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Biochemistry (AREA)
Detergent Compositions (AREA)

DE3206265A 1981-02-26 1982-02-20 Freifließende, sprühgetrocknete Hohlkügelchen zur Herstellung gerüststoffhaltiger Waschmittelteilchen, Verfahren zur Herstellung derselben und Verwendung dieser zur Bildung von Waschmittel mit nichtionischen Waschaktivstoffen Expired DE3206265C2 (de)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date
US23861981A	1981-02-26	1981-02-26
US23862081A	1981-02-26	1981-02-26
US27955081A	1981-07-01	1981-07-01

Publications (2)

Publication Number	Publication Date
DE3206265A1 DE3206265A1 (de)	1982-11-04
DE3206265C2 true DE3206265C2 (de)	1987-04-09

Family

ID=27399126

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DE3206265A Expired DE3206265C2 (de)	1981-02-26	1982-02-20	Freifließende, sprühgetrocknete Hohlkügelchen zur Herstellung gerüststoffhaltiger Waschmittelteilchen, Verfahren zur Herstellung derselben und Verwendung dieser zur Bildung von Waschmittel mit nichtionischen Waschaktivstoffen

Country Status (22)

Country	Link
AT (1)	AT388172B (da)
AU (1)	AU549000B2 (da)
BR (1)	BR8200996A (da)
CA (1)	CA1188953A (da)
CH (1)	CH652416A5 (da)
DE (1)	DE3206265C2 (da)
DK (1)	DK160885C (da)
DO (1)	DOP1982003096A (da)
ES (1)	ES8305412A1 (da)
FR (1)	FR2500475B1 (da)
GB (1)	GB2097419B (da)
GR (1)	GR76028B (da)
HK (1)	HK36190A (da)
IE (1)	IE52739B1 (da)
IT (1)	IT1147643B (da)
MX (1)	MX158565A (da)
NL (1)	NL8200804A (da)
NO (1)	NO153736C (da)
NZ (1)	NZ199773A (da)
PT (1)	PT74486B (da)
SE (2)	SE452773B (da)
ZW (2)	ZW3282A1 (da)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3206379A1 (de) *	1981-02-26	1982-12-02	Colgate-Palmolive Co., 10022 New York, N.Y.	Freifliessende spruehgetrocknete hohlkuegelchen und aus ihnen herstellbare waschmittelzusammensetzungen

Families Citing this family (48)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
ATE20476T1 (de) *	1983-04-08	1986-07-15	Procter & Gamble	Granulierte detergenszusammensetzungen, welche ein gemischtes polymerzusatzsystem enthalten.
US4490271A (en) *	1983-06-30	1984-12-25	The Procter & Gamble Company	Detergent compositions containing polyethylene glycol and polyacrylate
US4510066A (en) *	1983-07-06	1985-04-09	Colgate-Palmolive Company	Retarding setting of crutcher slurry for manufacturing base beads for detergent compositions
FR2568790B1 (fr) *	1984-08-10	1990-01-12	Rhone Poulenc Chim Base	Procede d'obtention d'une suspension aqueuse stable et pompable de zeolite et suspension ainsi obtenue
DE3444960A1 (de) *	1984-12-10	1986-06-12	Henkel KGaA, 4000 Düsseldorf	Koerniges adsorptionsmittel
SE466963B (sv) *	1984-12-24	1992-05-04	Colgate Palmolive Co	Textilmjukgoerande hoegverkande flytande detergent med stabil viskositet
CA1297376C (en) *	1985-11-01	1992-03-17	David Philip Jones	Detergent compositions, components therefor, and processes for theirpreparation
GB8526999D0 (en) *	1985-11-01	1985-12-04	Unilever Plc	Detergent compositions
DE3545947A1 (de) *	1985-12-23	1987-07-02	Henkel Kgaa	Phosphatfreies, granulares waschmittel
GB8607388D0 (en) *	1986-03-25	1986-04-30	Unilever Plc	Activator compositions
CA1286563C (en) *	1986-04-04	1991-07-23	Jan Hendrik Eertink	Detergent powders and processes for preparing them
GB8609044D0 (en) *	1986-04-14	1986-05-21	Unilever Plc	Detergent powders
DE3641314A1 (de) *	1986-12-03	1988-06-09	Henkel Kgaa	Waeschenachbehandlungsmittel auf der basis von schichtsilikat
GB8709057D0 (en) *	1987-04-15	1987-05-20	Unilever Plc	Composition for softening fabrics
DE3715052A1 (de) *	1987-05-06	1988-11-17	Degussa	Koerniges adsorptionsmittel
DE3717227A1 (de) *	1987-05-21	1988-12-01	Henkel Kgaa	Phosphatfreies waschmittel mit reduzierter inkrustierungstendenz
DE3818660A1 (de) *	1987-06-05	1988-12-15	Colgate Palmolive Co	Freifliessendes, pulvriges geschirrwaschmittel und verfahren zur herstellung desselben
GB2194793A (en) *	1987-10-15	1988-03-16	Unilever Plc	Mottled liquid detergents
GB8823008D0 (en) *	1988-09-30	1988-11-09	Unilever Plc	Composition for softening fabrics
DE3835918A1 (de) *	1988-10-21	1990-04-26	Henkel Kgaa	Verfahren zur herstellung von tensidhaltigen granulaten
GB8918984D0 (en) *	1989-08-21	1989-10-04	Unilever Plc	Detergent compositions
DE3943019A1 (de) *	1989-12-27	1991-07-04	Henkel Kgaa	Granulares, avivierend wirkendes waschmitteladditiv und verfahren zu seiner herstellung
GB9008462D0 (en) *	1990-04-12	1990-06-13	Ecc Int Ltd	Granules for detergent compositions
DE69112970T2 (de) *	1990-09-28	1996-03-21	Kao Corp	Nichtionische pulverförmige Detergentzusammensetzung.
AU649504B2 (en) *	1991-07-03	1994-05-26	Kao Corporation	Nonionic powder detergent composition
AU3524093A (en) *	1992-03-27	1993-09-30	Kao Corporation	Nonionic powdery detergent composition and process for producing the same
AU4324693A (en) *	1992-06-18	1994-01-04	Unilever Plc	Machine dishwashing composition
AU660101B2 (en) *	1992-08-07	1995-06-08	Colgate-Palmolive Company, The	Heavy duty laundry detergent compositions of reduced dye transfer properties
TR27896A (tr) *	1993-08-05	1995-10-11	Colgate Palmolive Co	Boya transferi özellikleri düsürülmüs agir is camasir deterjani bilesimleri.
DE19538029A1 (de) *	1995-10-12	1997-04-17	Sued Chemie Ag	Waschmittelzusatz
DE19538028A1 (de) *	1995-10-12	1997-04-17	Sued Chemie Ag	Waschmittelzusatz
US5726142A (en) *	1995-11-17	1998-03-10	The Dial Corp	Detergent having improved properties and method of preparing the detergent
US5962389A (en) *	1995-11-17	1999-10-05	The Dial Corporation	Detergent having improved color retention properties
DE19858888A1 (de) *	1998-12-19	2000-06-21	Henkel Kgaa	Verhinderung von Ablagerungen
CN1163580C (zh) *	1998-12-28	2004-08-25	花王株式会社	表面活性剂载体颗粒的制造方法
GB2348435A (en) *	1999-04-01	2000-10-04	Procter & Gamble	Softening compositions
GB2348434A (en) *	1999-04-01	2000-10-04	Procter & Gamble	Detergent compositions
EP1104803B1 (en) *	1999-06-14	2007-03-07	Kao Corporation	Granules for carrying surfactant and method for producing the same
EP1104806A4 (en) *	1999-06-14	2004-07-28	Kao Corp	BASE GRANULATE AND PARTICULATE DETERGENT
US6333005B1 (en) *	1999-06-16	2001-12-25	Hercules Incorporated	Methods of preventing scaling involving inorganic compositions in combination with copolymers of maleic anhydride and isobutylene, and compositions therefor
JP3249815B2 (ja) *	1999-06-16	2002-01-21	花王株式会社	洗剤添加用粒子群
DE19938640A1 (de) *	1999-08-14	2001-02-15	Henkel Kgaa	Verhinderung von Ablagerungen
DE10032127A1 (de) *	2000-07-05	2002-01-24	Henkel Kgaa	Mechanisch stabile Soda-Partikel
DE10040631A1 (de) *	2000-08-16	2002-03-07	Wolfram Koch	Vergilbungshemmer für Blue Denim Textilien
EP1987120B2 (en) *	2006-02-24	2013-09-11	Unilever PLC	Fast release granules
JP5388860B2 (ja) *	2007-11-16	2014-01-15	花王株式会社	洗剤ビルダー顆粒
US20240156100A1 (en) *	2022-11-11	2024-05-16	Ken W Donovan	Odor and microbial mitigation solution
CN121219390A (zh) *	2023-05-22	2025-12-26	巴斯夫欧洲公司	固体洗涤剂配制品

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4166039A (en) *	1973-10-15	1979-08-28	The Proctor & Gamble Company	Detergent composition and process
DE2547389A1 (de) *	1975-10-23	1977-05-05	Henkel & Cie Gmbh	Phosphatfreies waschmittel
NZ188469A (en) *	1977-10-06	1980-12-19	Colgate Palmolive Co	Detergent composition comprising a univalent cation-exchanging zeolite a nonionic detergent and builder salts
US4303556A (en) *	1977-11-02	1981-12-01	The Procter & Gamble Company	Spray-dried detergent compositions
GB2063289B (en) *	1979-11-13	1984-02-22	Unilever Ltd	Low phosphate spray-dried powders

1982
- 1982-02-09 AU AU80283/82A patent/AU549000B2/en not_active Ceased
- 1982-02-10 DO DO1982003096A patent/DOP1982003096A/es unknown
- 1982-02-17 GR GR67338A patent/GR76028B/el unknown
- 1982-02-18 NZ NZ199773A patent/NZ199773A/en unknown
- 1982-02-20 DE DE3206265A patent/DE3206265C2/de not_active Expired
- 1982-02-23 ZW ZW32/82A patent/ZW3282A1/xx unknown
- 1982-02-23 ZW ZW33/82A patent/ZW3382A1/xx unknown
- 1982-02-24 AT AT0069082A patent/AT388172B/de not_active IP Right Cessation
- 1982-02-24 CH CH1136/82A patent/CH652416A5/de not_active IP Right Cessation
- 1982-02-25 BR BR8200996A patent/BR8200996A/pt not_active IP Right Cessation
- 1982-02-25 PT PT74486A patent/PT74486B/pt not_active IP Right Cessation
- 1982-02-25 IT IT47865/82A patent/IT1147643B/it active
- 1982-02-25 CA CA000397017A patent/CA1188953A/en not_active Expired
- 1982-02-25 FR FR8203113A patent/FR2500475B1/fr not_active Expired
- 1982-02-25 DK DK083382A patent/DK160885C/da active
- 1982-02-25 SE SE8201170A patent/SE452773B/sv not_active IP Right Cessation
- 1982-02-25 NO NO820589A patent/NO153736C/no unknown
- 1982-02-25 ES ES509904A patent/ES8305412A1/es not_active Expired
- 1982-02-26 NL NL8200804A patent/NL8200804A/nl active Search and Examination
- 1982-02-26 GB GB8205685A patent/GB2097419B/en not_active Expired
- 1982-02-26 MX MX191612A patent/MX158565A/es unknown
- 1982-02-26 IE IE433/82A patent/IE52739B1/en not_active IP Right Cessation
1987
- 1987-09-08 SE SE8703474A patent/SE502089C2/sv not_active IP Right Cessation
1990
- 1990-05-10 HK HK361/90A patent/HK36190A/xx unknown

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3206379A1 (de) *	1981-02-26	1982-12-02	Colgate-Palmolive Co., 10022 New York, N.Y.	Freifliessende spruehgetrocknete hohlkuegelchen und aus ihnen herstellbare waschmittelzusammensetzungen

Also Published As

Publication number	Publication date
IT1147643B (it)	1986-11-19
SE8703474D0 (sv)	1987-09-08
NL8200804A (nl)	1982-09-16
IE52739B1 (en)	1988-02-03
NO153736C (no)	1986-05-14
FR2500475A1 (fr)	1982-08-27
NO820589L (no)	1982-08-27
DOP1982003096A (es)	1987-11-17
MX158565A (es)	1989-02-15
ES509904A0 (es)	1983-04-01
AU8028382A (en)	1982-09-02
DE3206265A1 (de)	1982-11-04
ES8305412A1 (es)	1983-04-01
CA1188953A (en)	1985-06-18
GB2097419A (en)	1982-11-03
NO153736B (no)	1986-02-03
IE820433L (en)	1982-08-26
GR76028B (da)	1984-08-03
SE452773B (sv)	1987-12-14
BR8200996A (pt)	1983-01-04
DK160885C (da)	1991-10-21
SE8703474L (sv)	1987-09-08
AT388172B (de)	1989-05-10
ZW3382A1 (en)	1982-06-16
AU549000B2 (en)	1986-01-09
IT8247865A0 (it)	1982-02-25
SE502089C2 (sv)	1995-08-14
DK160885B (da)	1991-04-29
ZW3282A1 (en)	1982-07-21
DK83382A (da)	1982-08-27
HK36190A (en)	1990-05-18
FR2500475B1 (fr)	1985-06-28
GB2097419B (en)	1985-04-17
CH652416A5 (de)	1985-11-15
ATA69082A (de)	1988-10-15
SE8201170L (sv)	1982-08-27
NZ199773A (en)	1984-11-09
PT74486B (en)	1983-09-01

Publication	Publication Date	Title
DE3206265C2 (de)	1987-04-09	Freifließende, sprühgetrocknete Hohlkügelchen zur Herstellung gerüststoffhaltiger Waschmittelteilchen, Verfahren zur Herstellung derselben und Verwendung dieser zur Bildung von Waschmittel mit nichtionischen Waschaktivstoffen
DE3206379C2 (da)	1991-03-07
DE69315075T2 (de)	1998-05-14	Teilchenförmige waschmittelzusammensetzungen mit einem gehalt an polyvinylpyrrolidon
DE3324258A1 (de)	1984-01-12	Nichtionogene waschmittelzusammensetzung mit verbesserter schmutzauswaschbarkeit
DE2549337C2 (de)	1983-07-14	Verfahren zur Herstellung von Alumosilikat enthaltenden Waschmittelgranulaten
DE3727727A1 (de)	1988-03-03	Schmutzfreisetzungsfoerderndes pet-poet copolymeres verfahren zum herstellen und anwendung desselben in waschmitteln
CH658467A5 (de)	1986-11-14	Fluessiges, gewebeweichmachendes vollwaschmittel und verfahren zu seiner herstellung.
DE2843390C2 (da)	1987-06-25
DE3607833A1 (de)	1986-09-18	Textilweichmachende teilchenfoermige waschmittelzusammensetzung
DE3518100A1 (de)	1985-12-05	Gewebeweichmachendes builderhaltiges waschmittel
DE69836022T2 (de)	2007-05-10	Pulverförmige waschmittelzusammensetzung
DE69532586T3 (de)	2014-03-13	Waschverfahren
AT394380B (de)	1992-03-25	Teilchenfoermiges und weichmachendes grobwaschmittel fuer textilien, verfahren zu seiner herstellung, agglomerierte bentonitteilchen fuer das waschmittel und verfahren zu ihrer herstellung
DE69229301T2 (de)	1999-12-09	Zeolitharmes oder zeolithfreies Waschmittel
AT394863B (de)	1992-07-10	Textilweichmachendes fluessiges vollwaschmittel
CH643294A5 (de)	1984-05-30	Frei fliessendes phosphatfreies teilchenfoermiges waschmittel mit hohem schuettgewicht.
EP0544670B1 (de)	1994-07-20	Sprühgetrocknetes, avivierend wirkendes waschmitteladditiv
DE3516823A1 (de)	1985-12-05	Teilchenfoermiges waschmittelprodukt
DE2656009A1 (de)	1977-06-23	Phosphatfreies grobwaschmittel
DE3420656A1 (de)	1984-12-13	Textilweich- und -flauschigmachendes teilchenfoermiges waschmittel
WO1991009927A1 (de)	1991-07-11	Granulares, avivierend wirkendes waschmitteladditiv und verfahren zu seiner herstellung
DE3516548A1 (de)	1985-12-05	Teilchenfoermiges waschmittelprodukt mit einem gehalt an builder und nichtionischem tensid
WO1993017089A1 (de)	1993-09-02	Verfahren zur herstellung niederalkalischer, aktivchlor-, silikat-, und phosphatfreier maschinengeschirrspülmittel in form von schwergranulaten
DE2655578A1 (de)	1977-06-16	Verfahren zur wiederaufbereitung von waschmittelpulvern
DE3518656A1 (de)	1985-12-05	Bleichendes waschmittel

Legal Events

Date	Code	Title	Description
1983-05-26	8110	Request for examination paragraph 44
1987-01-08	Q176	The application caused the suspense of an application	Ref document number: 3206379 Country of ref document: DE
1987-04-09	D2	Grant after examination
1987-10-01	8364	No opposition during term of opposition
1992-07-23	8328	Change in the person/name/address of the agent	Free format text: STOLBERG-WERNIGERODE, GRAF ZU, U., DIPL.-CHEM. DR.RER.NAT. SUCHANTKE, J., DIPL.-ING. HUBER, A., DIPL.-ING. KAMEKE, VON, A., DIPL.-CHEM. DR.RER.NAT., PAT.-ANWAELTE, 2000 HAMBURG
1996-02-15	8339	Ceased/non-payment of the annual fee

DE3206265C2 - Freifließende, sprühgetrocknete Hohlkügelchen zur Herstellung gerüststoffhaltiger Waschmittelteilchen, Verfahren zur Herstellung derselben und Verwendung dieser zur Bildung von Waschmittel mit nichtionischen Waschaktivstoffen - Google Patents

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Applications Claiming Priority (3)

Publications (2)

Family

ID=27399126

Family Applications (1)

Country Status (22)

Cited By (1)

Families Citing this family (48)

Family Cites Families (5)

Cited By (1)

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