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AR108557A1 - Uracilpiridinas herbicidas - Google Patents

Uracilpiridinas herbicidas

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Publication number
AR108557A1
AR108557A1 ARP170101387A ARP170101387A AR108557A1 AR 108557 A1 AR108557 A1 AR 108557A1 AR P170101387 A ARP170101387 A AR P170101387A AR P170101387 A ARP170101387 A AR P170101387A AR 108557 A1 AR108557 A1 AR 108557A1
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AR
Argentina
Prior art keywords
alkyl
alkoxy
group
silyl
halogen
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ARP170101387A
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English (en)
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Basf Se
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Publication of AR108557A1 publication Critical patent/AR108557A1/es

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/72—Nitrogen atoms
    • C07D213/73—Unsubstituted amino or imino radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/72—Nitrogen atoms
    • C07D213/75—Amino or imino radicals, acylated by carboxylic or carbonic acids, or by sulfur or nitrogen analogues thereof, e.g. carbamates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

Uracilpiridinas y los intermediarios para preparar las mismas, composiciones que las comprenden y su uso como herbicidas, es decir, para controlar plantas dañinas, y a un método para controlar la vegetación no deseada, que comprende permitir que una cantidad eficaz como herbicida de al menos una uracilpiridina de la fórmula (1) actúe en las plantas, en sus semillas y/o en su hábitat. Reivindicación 1: Uracilpiridinas caracterizadas por la fórmula (1), en donde las variables tienen los siguientes significados: R¹ es hidrógeno, NH₂, C₁₋₆-alquilo o C₃₋₆-alquinilo; R² es hidrógeno, C₁₋₆-alquilo o C₁₋₆-haloalquilo; R³ es hidrógeno o C₁₋₆-alquilo; R⁴ es H o halógeno; R⁵ es halógeno, CN, NO₂, NH₂, CF₃ o C(=S)NH₂; R⁶ es H, halógeno, CN, C₁₋₃-alquilo, C₁₋₃-haloalquilo, C₁₋₃-alcoxi, C₁₋₃-haloalcoxi, C₁₋₃-alquiltio, (C₁₋₃-alquil)amino, di(C₁₋₃-alquil)amino, C₁₋₃-alcoxi-C₁₋₃-alquilo, C₁₋₃-alcoxicarbonilo; R⁷ es H, halógeno, C₁₋₃-alquilo, C₁₋₃-alcoxi; R⁸ es OR⁹, SR⁹, NR¹⁰R¹¹, NR⁹OR⁹, NR⁹S(O)₂R¹⁰ o NR⁹S(O)₂NR¹⁰R¹¹, en donde R⁹ es hidrógeno, C₁₋₆-alquilo, C₃₋₆-alquenilo, C₃₋₆-alquinilo, C₁₋₆-haloalquilo, C₃₋₆-haloalquenilo, C₃₋₆-haloalquinilo, C₁₋₆-cianoalquilo, C₁₋₆-alcoxi-C₁₋₆-alquilo, C₁₋₆-alcoxi-C₁₋₆-alcoxi-C₁₋₆-alquilo, di(C₁₋₆-alcoxi)C₁₋₆-alquilo, C₁₋₆-haloalcoxi-C₁₋₆-alquilo, C₃₋₆-alqueniloxi-C₁₋₆-alquilo, C₃₋₆-haloalqueniloxi-C₁₋₆-alquilo, C₃₋₆-alqueniloxi-C₁₋₆-alcoxi-C₁₋₆-alquilo, C₁₋₆-alquiltio-C₁₋₆-alquilo, C₁₋₆-alquilsulfinil-C₁₋₆-alquilo, C₁₋₆-alquilsulfonil-C₁₋₆-alquilo, C₁₋₆-alquilcarbonil-C₁₋₆-alquilo, C₁₋₆-alcoxicarbonil-C₁₋₆-alquilo, C₁₋₆-haloalcoxicarbonil-C₁₋₆-alquilo, C₃₋₆-alqueniloxicarbonil-C₁₋₆-alquilo, C₃₋₆-alquiniloxicarbonil-C₁₋₆-alquilo, amino, (C₁₋₆-alquil)amino, di(C₁₋₆-alquil)amino, (C₁₋₆-alquilcarbonil)amino, amino-C₁₋₆-alquilo, (C₁₋₆-alquil)amino-C₁₋₆-alquilo, di(C₁₋₆-alquil)amino-C₁₋₆-alquilo, aminocarbonil-C₁₋₆-alquilo, (C₁₋₆-alquil)aminocarbonil-C₁₋₆-alquilo, di(C₁₋₆-alquil)aminocarbonil-C₁₋₆-alquilo, -N=CR¹²R¹³, en donde R¹² y R¹³ son, independientemente entre sí, H, C₁₋₄-alquilo o fenilo; C₃₋₆-cicloalquilo, C₃₋₆-cicloalquil-C₁₋₆-alquilo, C₃₋₆-heterociclilo, C₃₋₆-heterociclil-C₁₋₆-alquilo, fenilo, fenil-C₁₋₄-alquilo o un heteroarilo de 5 ó 6 miembros, en donde cada anillo de cicloalquilo, heterociclilo, fenilo o heteroarilo se puede sustituir con 1 a 4 sustituyentes seleccionados de R¹⁴ o un carbociclo de 3 a 7 miembros, en donde el carbociclo tiene, opcionalmente, además de átomos de carbono, 1 ó 2 miembros del anillo seleccionados del grupo que consiste en -N(R¹²)-, -N=N-, -C(=O)-, -O- y -S-, y en donde el carbociclo se sustituye opcionalmente con 1 a 4 sustituyentes seleccionados de R¹⁴; en donde R¹⁴ es halógeno, NO₂, CN, C₁₋₄-alquilo, C₁₋₄-haloalquilo, C₁₋₄-alcoxi o C₁₋₄-alcoxicarbonilo; R¹⁰, R¹¹ son, independientemente entre sí, R⁹, o juntos forman un carbociclo de 3 a 7 miembros, en donde el carbociclo tiene, opcionalmente, además de átomos de carbono, 1 ó 2 miembros del anillo seleccionados del grupo que consiste en -N(R¹²)-, -N=N-, -C(=O)-, -O- y -S-, y en donde el carbociclo se sustituye opcionalmente con 1 a 4 sustituyentes seleccionados de R¹⁴; n es 1 a 3; Q es CH₂, O, S, SO, SO₂, NH o (C₁₋₃-alquil)N; W es O ó S; X es NH, NCH₃, O ó S; Y es O ó S, Z es fenilo, piridilo, piridazinilo, pirimidinilo o pirazinilo, cada uno de los cuales se sustituye opcionalmente con 1 a 4 sustituyentes seleccionados del grupo que consiste en halógeno, CN, C₁₋₆-alquilo, C₁₋₆-haloalquilo, C₁₋₆-alcoxi, C₁₋₆-haloalcoxi; que incluyen sus derivados o sales aceptables en la agricultura, siempre que los compuestos de la fórmula (1) tengan un grupo carboxilo. Reivindicación 9: Haluros ácidos caracterizados por la fórmula (2), en donde R¹, R², R³, R⁴, R⁵, R⁶, R⁷, n, Q, W, X, Y y Z son como se definen en cualquiera de las reivindicaciones 1 a 8, y L¹ es halógeno. Reivindicación 10: lntermediarios de la fórmula (3), en donde R¹, R², R³, R⁴, R⁵, Q, X, Y y Z son como se definen en cualquiera de las reivindicaciones 1 a 8, e I¹ es H o PG, en donde PG es un grupo protector seleccionado del grupo que consiste en C₁₋₆-alquilo, C₁₋₆-cianoalquilo, C₁₋₆-haloalquilo, C₁₋₆-alquiltio-C₁₋₄-alquilo, C₁₋₆-alcoxi-C₁₋₄-alquilo, C₁₋₆-alcoxi-C₁₋₄-alcoxi-C₁₋₄-alquilo, (tri-C₁₋₆-alquil)silil-C₁₋₄-alquilo, (tri-C₁₋₆-alquil)silil-C₁₋₄-alquiloxi-C₁₋₄-alquilo, C₂₋₆-alquenilo, C₃₋₆-alquinilo, C₃₋₆-cicloalquilo, C₃₋₆-cicloalquil-C₁₋₄-alquilo, C₅₋₆-cicloalquenilo, tetrahidropiranilo, (tri-C₁₋₆-alquil)sililo, [(difenil)(C₁₋₄-alquil)]sililo, formilo, C₁₋₆-alquil-carbonilo, C₁₋₆-alquil-O-carbonilo, C₂₋₆-alquenil-O-carbonilo, [(difenilo)(C₁₋₄-alquil)]silil-C₁₋₄-alquilo, fenil-C₁₋₄-alquilo, feniltio-C₁₋₆-alquilo, fenilcarbonilo, en donde cada anillo de fenilo se puede sustituir con 1 a 3 sustituyentes seleccionados del grupo que consiste en halógeno, CN, NO₂, C₁₋₄-alquilo y C₁₋₄-alcoxi; lo que incluye sus sales. Reivindicación 11: lntermediarios caracterizados por la fórmula (4), en donde R⁴, R⁵, R⁶, R⁷, R⁸, n, Q, W, X, Y y Z son como se definen en cualquiera de las reivindicaciones 1 a 8, e I² es H; y I³ es H o C(=Y)L², en donde Y es O ó S, y L² es C₁₋₆-alcoxi, C₁₋₆-alquiltio o ariloxi, en donde la porción arilo puede ser, en sí misma, parcial o totalmente halogenada y/o se puede sustituir con 1 a 3 sustituyentes del grupo de ciano, nitro, C₁₋₄-alquilo, C₁₋₄-alcoxi y C₁₋₄-alquiltio; o I² e I³, junto con el átomo de N al que están unidos, forman un grupo “YCN”, en donde Y es O ó S, o un grupo “PGN”, que es un sustituyente amina protegida seleccionado del grupo que consiste en N3, carbamatos alifáticos o aromáticos, amidas alifáticas o aromáticas, N-C₁₋₆-alquil-aminas, N-aril-aminas o heteroarilamidas, lo que incluye sus sales. Reivindicación 12: lntermediarios caracterizados por la fórmula (5), en donde R⁴, R⁵, Q, X y Z son como se definen en cualquiera de las reivindicaciones 1 a 8, y PG es un grupo protector seleccionado del grupo que consiste en C₁₋₆-alquilo, C₁₋₆-cianoalquilo, C₁₋₆-haloalquilo, C₁₋₆-alquiltio-C₁₋₄-alquilo, C₁₋₆-alcoxi-C₁₋₄-alquilo, C₁₋₆-alcoxi-C₁₋₄-alcoxi-C₁₋₄-alquilo, (tri-C₁₋₆-alquil)silil-C₁₋₄-alquilo, (tri-C₁₋₆-alquil)silil-C₁₋₄-alquiloxi-C₁₋₄-alquilo, C₂₋₆-alquenilo, C₃₋₆-alquinilo, C₃₋₆-cicloalquilo, C₃₋₆-cicloalquil-C₁₋₄-alquilo, C₅₋₆-cicloalquenilo, tetrahidropiranilo, (tri-C₁₋₆-alquil)sililo, [(difenil)(C₁₋₄-alquil)]sililo, formilo, C₁₋₆-alquil-carbonilo, C₁₋₆-alquil-O-carbonilo, C₂₋₆-alquenil-O-carbonilo, [(difenilo)(C₁₋₄-alquil)]silil-C₁₋₄-alquilo, fenil-C₁₋₄-alquilo, feniltio-C₁₋₆-alquilo, fenilcarbonilo, en donde cada anillo de fenilo se puede sustituir con 1 a 3 sustituyentes seleccionados del grupo que consiste en halógeno, CN, NO₂, C₁₋₄-alquilo y C₁₋₄-alcoxi; I² H; e I³ H o C(=Y)L², en donde Y es O ó S, y L² es C₁₋₆-alcoxi, C₁₋₆-alquiltio o ariloxi, en donde la porción arilo puede ser, en sí misma, parcial o totalmente halogenada y/o se puede sustituir con 1 a 3 sustituyentes del grupo de ciano, nitro, C₁₋₄-alquilo, C₁₋₄-alcoxi y C₁₋₄-alquiltio; o I² e I³, junto con el átomo de N al que están unidos, forman un grupo “YCN”, en donde Y es O ó S, o un grupo “PGN”, que es un sustituyente amina protegida seleccionado del grupo que consiste en N₃, carbamatos alifáticos o aromáticos, amidas alifáticas o aromáticas, N-C₁₋₆-alquil-aminas, N-aril-aminas o heteroarilamidas, lo que incluye sus sales.
ARP170101387A 2016-05-24 2017-05-23 Uracilpiridinas herbicidas AR108557A1 (es)

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EP16171063 2016-05-24

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JP (1) JP7195932B2 (es)
KR (1) KR102420191B1 (es)
CN (2) CN114249710B (es)
AR (1) AR108557A1 (es)
AU (1) AU2017269746B2 (es)
BR (1) BR112018074118B1 (es)
CL (1) CL2018003343A1 (es)
CO (1) CO2018012810A2 (es)
CR (1) CR20180596A (es)
DK (1) DK3464261T3 (es)
EA (1) EA201892649A1 (es)
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