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MX2017009161A - Procedimiento continuo para prepara etilenglicol a partir de una fuente de carbohidratos. - Google Patents

Procedimiento continuo para prepara etilenglicol a partir de una fuente de carbohidratos.

Info

Publication number
MX2017009161A
MX2017009161A MX2017009161A MX2017009161A MX2017009161A MX 2017009161 A MX2017009161 A MX 2017009161A MX 2017009161 A MX2017009161 A MX 2017009161A MX 2017009161 A MX2017009161 A MX 2017009161A MX 2017009161 A MX2017009161 A MX 2017009161A
Authority
MX
Mexico
Prior art keywords
ethylene glycol
carbohydrate source
continuous process
hydrogen
stirred tank
Prior art date
Application number
MX2017009161A
Other languages
English (en)
Other versions
MX375208B (es
Inventor
Gerardus Johannes Maria Gruter
Cornelis Van Der Waal Jan
Original Assignee
Avantium Knowledge Centre Bv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=52781246&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=MX2017009161(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Avantium Knowledge Centre Bv filed Critical Avantium Knowledge Centre Bv
Publication of MX2017009161A publication Critical patent/MX2017009161A/es
Publication of MX375208B publication Critical patent/MX375208B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0053—Details of the reactor
    • B01J19/0066—Stirrers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B31/00—Reduction in general
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/20—Dihydroxylic alcohols
    • C07C31/202—Ethylene glycol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/00033—Continuous processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/30—Tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with noble metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Se prepara el etilenglicol a partir de una fuente de carbohidratos mediante la reacción de la fuente de carbohidratos con hidrógeno en un procedimiento continuo; en donde el hidrógeno, la fuente de carbohidratos y un diluyente líquido se suministran continuamente en un reactor de tanque agitado continuo en donde un sistema catalizador está presente, cuyo sistema catalizador comprende un compuesto de tungsteno y por lo menos una hidrogenólisis de metal seleccionado de los grupos 8, 9 o 10 de la Tabla Periódica de Elementos, para lograr la reacción entre la fuente de carbohidratos e hidrógeno con etilenglicol; en donde se remueve continuamente una mezcla de productos que comprende etilenglicol y diluyente del reactor de tanque agitado continuo y en donde se agrega continuamente o periódicamente por lo menos un compuesto de tungsteno al reactor de tanque agitado continuo (CSTR).
MX2017009161A 2015-01-13 2016-01-13 Procedimiento continuo para preparar etilenglicol a partir de una fuente de carbohidratos. MX375208B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL2014121 2015-01-13
PCT/NL2016/050029 WO2016114661A1 (en) 2015-01-13 2016-01-13 Continuous process for preparing ethylene glycol from a carbohydrate source

Publications (2)

Publication Number Publication Date
MX2017009161A true MX2017009161A (es) 2018-02-01
MX375208B MX375208B (es) 2025-03-06

Family

ID=52781246

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2017009161A MX375208B (es) 2015-01-13 2016-01-13 Procedimiento continuo para preparar etilenglicol a partir de una fuente de carbohidratos.

Country Status (15)

Country Link
US (1) US10138184B2 (es)
EP (1) EP3245181B1 (es)
JP (1) JP6553743B2 (es)
KR (1) KR20170105063A (es)
CN (1) CN107406358B (es)
AU (1) AU2016207242B2 (es)
BR (1) BR112017014945B1 (es)
CA (1) CA2973556C (es)
LT (1) LT3245181T (es)
MX (1) MX375208B (es)
MY (1) MY185257A (es)
PL (1) PL3245181T3 (es)
SG (1) SG11201705686RA (es)
UA (1) UA118147C2 (es)
WO (1) WO2016114661A1 (es)

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WO2017070071A1 (en) 2015-10-20 2017-04-27 Shell Oil Company Process for the production of glycols
CN116730800B (zh) 2016-06-03 2025-07-25 泰恩工艺技术有限公司 将产生己醛糖的碳水化合物高度选择性地转化为乙二醇的连续方法
US10472310B2 (en) 2016-06-03 2019-11-12 Iowa Corn Promotion Board Continuous processes for the highly selective conversion of sugars to propylene glycol or mixtures of propylene glycol and ethylene glycol
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BR112019004044B1 (pt) * 2016-08-30 2022-11-29 Shell Internationale Research Maatschappij B.V. Processo para produzir etileno glicol de uma alimentação de carboidrato
CN108070075A (zh) 2016-11-09 2018-05-25 可口可乐公司 生物基meg和聚酯纤维组合物以及制造它们的方法
CN108070079A (zh) 2016-11-09 2018-05-25 可口可乐公司 生物基meg和pet组合物以及制造它们的方法
CA3044135A1 (en) * 2016-12-07 2018-06-14 Shell Internationale Research Maatschappij B.V. Process for the preparation of glycols
CN111868018B (zh) * 2018-03-14 2023-08-04 阿凡田知识中心有限公司 用于生产乙二醇的方法
EP3765431B1 (en) * 2018-03-14 2022-05-04 Avantium Knowledge Centre B.V. Continuous or semi-continuous process for the preparation of ethylene glycol
WO2019175365A1 (en) 2018-03-14 2019-09-19 Avantium Knowledge Centre B.V. Process for the production of ethylene glycol and heterogeneous catalyst composition
CN110882710B (zh) * 2018-09-07 2022-10-21 中国石油化工股份有限公司 碳化物基催化剂及其制备方法以及甘油氢解方法
EP3849960A1 (en) 2018-09-13 2021-07-21 Shell Internationale Research Maatschappij B.V. Start-up process for the production of glycols
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EP4003946A1 (en) 2019-07-31 2022-06-01 Avantium Knowledge Centre B.V. Process for preparing alkylene glycol from a carbohydrate source comprising hemicellulose, cellulose and lignin
US11319268B2 (en) * 2019-09-24 2022-05-03 Iowa Corn Promotion Board Continuous, carbohydrate to ethylene glycol processes
CN112619660B (zh) * 2019-09-24 2022-10-11 中国石油化工股份有限公司 用于合成乙二醇的催化剂及其制备方法和应用
PL4107141T3 (pl) * 2020-02-17 2024-09-30 Avantium Knowledge Centre B.V. Sposób wytwarzania mieszaniny glikoli alkilenowych ze źródła węglowodanowego o zmniejszonej selektywności względem poliolowych produktów ubocznych
US20230038706A1 (en) * 2020-02-17 2023-02-09 Avantium Knowledge Centre B.V. Process for preparing alkylene glycol mixture from a carbohydrate source with increased selectivity for glycerol
US11319269B2 (en) 2020-09-24 2022-05-03 Iowa Corn Promotion Board Continuous processes for the selective conversion of aldohexose-yielding carbohydrate to ethylene glycol using low concentrations of retro-aldol catalyst
US11680031B2 (en) 2020-09-24 2023-06-20 T. EN Process Technology, Inc. Continuous processes for the selective conversion of aldohexose-yielding carbohydrate to ethylene glycol using low concentrations of retro-aldol catalyst
WO2022064039A1 (en) 2020-09-28 2022-03-31 Avantium Knowledge Centre B.V. Process for recovering and regenerating a catalyst from ash
BR112023004203A2 (pt) 2020-09-28 2023-04-11 Avantium Knowledge Centre Bv Processo para produzir etilenoglicol e/ou propilenoglicol e/ou glicerol
WO2022223577A1 (en) 2021-04-21 2022-10-27 Avantium Knowledge Centre B.V. Process and equipment for producing glycols from carbohydrates and hydrogen with reactor off-gas treatment and hydrogen production
EP4466245A1 (en) * 2022-01-19 2024-11-27 T.En Process Technology, Inc. Processes for making ethylene glycol and/or propylene glycol from aldose- and/or ketose-yielding carbohydrates with integrated tungsten catalyst recovery
WO2023186840A1 (en) 2022-03-29 2023-10-05 Avantium Knowledge Centre B.V. Process for preparing ethylene glycol from a carbohydrate source and hydrogen in a continuous way
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WO2025026823A1 (en) 2023-08-01 2025-02-06 Avantium Knowledge Centre B.V. Process for reducing the amount of 2,3-pentanediol from propylene glycol
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SG11201609633PA (en) 2014-05-19 2016-12-29 Iowa Corn Promotion Board Process for the continuous production of ethylene glycol from carbohydrates
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CN107406359A (zh) * 2015-01-13 2017-11-28 阿凡田知识中心有限公司 从碳水化合物制备乙二醇的工艺
EP3245182B1 (en) * 2015-01-13 2019-10-23 Avantium Knowledge Centre B.v. Process for preparing ethylene glycol from a carbohydrate
CN107438591B (zh) 2015-01-13 2020-10-16 阿凡田知识中心有限公司 从碳水化合物源制备乙二醇的工艺

Also Published As

Publication number Publication date
KR20170105063A (ko) 2017-09-18
MY185257A (en) 2021-04-30
WO2016114661A1 (en) 2016-07-21
US10138184B2 (en) 2018-11-27
JP6553743B2 (ja) 2019-07-31
LT3245181T (lt) 2020-02-25
AU2016207242A1 (en) 2017-08-03
AU2016207242B2 (en) 2018-09-13
UA118147C2 (uk) 2018-11-26
BR112017014945B1 (pt) 2021-06-08
EP3245181A1 (en) 2017-11-22
SG11201705686RA (en) 2017-08-30
MX375208B (es) 2025-03-06
US20180002259A1 (en) 2018-01-04
EP3245181B1 (en) 2019-10-23
CN107406358B (zh) 2020-12-08
BR112017014945A2 (pt) 2018-03-13
CA2973556C (en) 2019-04-30
CN107406358A (zh) 2017-11-28
JP2018501321A (ja) 2018-01-18
PL3245181T3 (pl) 2020-06-29
CA2973556A1 (en) 2016-07-21

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