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MX2016013210A - Deshidratacion de un alcohol de azucar con combinacion mixta de catalizadores de acido. - Google Patents

Deshidratacion de un alcohol de azucar con combinacion mixta de catalizadores de acido.

Info

Publication number
MX2016013210A
MX2016013210A MX2016013210A MX2016013210A MX2016013210A MX 2016013210 A MX2016013210 A MX 2016013210A MX 2016013210 A MX2016013210 A MX 2016013210A MX 2016013210 A MX2016013210 A MX 2016013210A MX 2016013210 A MX2016013210 A MX 2016013210A
Authority
MX
Mexico
Prior art keywords
acid
sugar alcohol
dehydration
acid catalysts
pka
Prior art date
Application number
MX2016013210A
Other languages
English (en)
Other versions
MX386276B (es
Inventor
Sanborn Alexandra
Howard Stephen
Stensrud Kenneth
Hagberg Erik
Original Assignee
Archer Daniels Midland Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from PCT/US2014/033580 external-priority patent/WO2015156802A1/en
Priority claimed from PCT/US2014/033581 external-priority patent/WO2015156803A1/en
Application filed by Archer Daniels Midland Co filed Critical Archer Daniels Midland Co
Publication of MX2016013210A publication Critical patent/MX2016013210A/es
Publication of MX386276B publication Critical patent/MX386276B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D1/00—Evaporating
    • B01D1/22—Evaporating by bringing a thin layer of the liquid into contact with a heated surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08—Selective adsorption, e.g. chromatography
    • B01D15/10—Selective adsorption, e.g. chromatography characterised by constructional or operational features
    • B01D15/18—Selective adsorption, e.g. chromatography characterised by constructional or operational features relating to flow patterns
    • B01D15/1814—Recycling of the fraction to be distributed
    • B01D15/1821—Simulated moving beds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08—Selective adsorption, e.g. chromatography
    • B01D15/26—Selective adsorption, e.g. chromatography characterised by the separation mechanism
    • B01D15/36—Selective adsorption, e.g. chromatography characterised by the separation mechanism involving ionic interaction, e.g. ion-exchange, ion-pair, ion-suppression or ion-exclusion
    • B01D15/361—Ion-exchange
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/10—Vacuum distillation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B01J27/043—Sulfides with iron group metals or platinum group metals
    • B01J27/045—Platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/053—Sulfates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B01J31/0225—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B01J31/0225—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
    • B01J31/0227—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts being perfluorinated, i.e. comprising at least one perfluorinated moiety as substructure in case of polyfunctional compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/04—Ortho-condensed systems
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
    • B01J2231/4277—C-X Cross-coupling, e.g. nucleophilic aromatic amination, alkoxylation or analogues
    • B01J2231/4288—C-X Cross-coupling, e.g. nucleophilic aromatic amination, alkoxylation or analogues using O nucleophiles, e.g. alcohols, carboxylates, esters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/001—General concepts, e.g. reviews, relating to catalyst systems and methods of making them, the concept being defined by a common material or method/theory
    • B01J2531/002—Materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/001—General concepts, e.g. reviews, relating to catalyst systems and methods of making them, the concept being defined by a common material or method/theory
    • B01J2531/002—Materials
    • B01J2531/007—Promoter-type Additives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Medicinal Preparation (AREA)

Abstract

Se describe un procedimiento para preparar productos de deshidratación cíclica a partir de alcoholes de azúcar. El procedimiento implica usar una mezcla de reacción de catalizador de ácido mixto que contiene un ácido reductor, que tiene un pka de aproximadamente 1.0-1.5, y al menos un ácido de Brønsted fuerte o un ácido de Lewis, que tiene una pka = 0 o ambos ácidos en una disolución para deshidratar y cerrar en anillo dicho alcohol de azúcar. De manera sinérgica, la catálisis por ácido mixto puede producir mayores cantidades del productos deseado a niveles similares de recuento de composición que cualquiera de los catalizadores de ácido componentes actuando solos.
MX2016013210A 2014-04-10 2014-12-12 Deshidratacion de un alcohol de azucar con combinacion mixta de catalizadores de acido. MX386276B (es)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
PCT/US2014/033580 WO2015156802A1 (en) 2014-04-10 2014-04-10 Synthesis of reduced sugar alcohols, furan derivatives
PCT/US2014/033581 WO2015156803A1 (en) 2014-04-10 2014-04-10 Synthesis of r-glucosides, sugar alcohols, reduced sugar alcohols, and furan derivatives of reduced sugar alcohols
PCT/US2014/066298 WO2015156839A1 (en) 2014-04-10 2014-11-19 Phosphonic acid catalyst in dehydrative cyclization of 5 and 6 carbon polyols with improved color and product accountability
PCT/US2014/070050 WO2015156846A1 (en) 2014-04-10 2014-12-12 Dehydration of a sugar alcohol with mixed combination of acid catalysts

Publications (2)

Publication Number Publication Date
MX2016013210A true MX2016013210A (es) 2017-05-25
MX386276B MX386276B (es) 2025-03-04

Family

ID=54288246

Family Applications (2)

Application Number Title Priority Date Filing Date
MX2016013210A MX386276B (es) 2014-04-10 2014-12-12 Deshidratacion de un alcohol de azucar con combinacion mixta de catalizadores de acido.
MX2016013208A MX2016013208A (es) 2014-04-10 2015-04-10 Proceso para el aislamiento de 1,2,5,6-hexanotetrol a partir de mezclas de reaccion de hidrogenolisis de sorbitol utilizando cromatografia de lecho movil simulado.

Family Applications After (1)

Application Number Title Priority Date Filing Date
MX2016013208A MX2016013208A (es) 2014-04-10 2015-04-10 Proceso para el aislamiento de 1,2,5,6-hexanotetrol a partir de mezclas de reaccion de hidrogenolisis de sorbitol utilizando cromatografia de lecho movil simulado.

Country Status (12)

Country Link
US (3) US9856195B2 (es)
EP (3) EP3129363B1 (es)
JP (3) JP6275278B2 (es)
KR (3) KR102107274B1 (es)
CN (3) CN106458946B (es)
AU (3) AU2014390000B2 (es)
BR (2) BR112016023472B1 (es)
CA (3) CA2945088C (es)
MX (2) MX386276B (es)
RU (1) RU2016141812A (es)
SG (1) SG11201608423YA (es)
WO (3) WO2015156846A1 (es)

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Also Published As

Publication number Publication date
US20170029350A1 (en) 2017-02-02
MX2016013208A (es) 2017-05-19
EP3129363A1 (en) 2017-02-15
CA2945144A1 (en) 2015-10-15
BR112016023472A2 (es) 2017-08-15
MX386276B (es) 2025-03-04
JP2017515803A (ja) 2017-06-15
SG11201608423YA (en) 2016-11-29
CN106414384A (zh) 2017-02-15
EP3129342A4 (en) 2017-11-29
EP3129342A1 (en) 2017-02-15
CN106458946B (zh) 2021-10-22
AU2015243402B2 (en) 2018-08-16
AU2015243213A1 (en) 2016-11-03
CN106458946A (zh) 2017-02-22
EP3129343A1 (en) 2017-02-15
EP3129363A4 (en) 2017-11-29
BR112016023472B1 (pt) 2021-10-13
AU2015243402A1 (en) 2016-10-27
AU2014390000B2 (en) 2018-08-16
WO2015157671A1 (en) 2015-10-15
EP3129343A4 (en) 2017-12-20
WO2015157617A1 (en) 2015-10-15
BR112016023499A2 (pt) 2017-08-15
US20170029434A1 (en) 2017-02-02
KR20160147777A (ko) 2016-12-23
KR20160143712A (ko) 2016-12-14
JP2017513840A (ja) 2017-06-01
CN106414384B (zh) 2019-06-21
RU2016141812A (ru) 2018-05-11
CN106458806A (zh) 2017-02-22
CA2945327A1 (en) 2015-10-15
WO2015156846A1 (en) 2015-10-15
US20170066702A1 (en) 2017-03-09
JP2017515801A (ja) 2017-06-15
CA2945088C (en) 2020-06-30
US9856195B2 (en) 2018-01-02
KR102107274B1 (ko) 2020-05-06
AU2014390000A1 (en) 2016-10-27
KR20160146780A (ko) 2016-12-21
CA2945088A1 (en) 2015-10-15
JP6275278B2 (ja) 2018-02-07
US9732020B2 (en) 2017-08-15
EP3129363B1 (en) 2020-01-22

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