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WO2009001076A1 - Compositions pesticides - Google Patents

Compositions pesticides Download PDF

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Publication number
WO2009001076A1
WO2009001076A1 PCT/GB2008/002170 GB2008002170W WO2009001076A1 WO 2009001076 A1 WO2009001076 A1 WO 2009001076A1 GB 2008002170 W GB2008002170 W GB 2008002170W WO 2009001076 A1 WO2009001076 A1 WO 2009001076A1
Authority
WO
WIPO (PCT)
Prior art keywords
pirimiphos
methyl
composition according
plant essential
essential oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/GB2008/002170
Other languages
English (en)
Inventor
Andrew Bywater
David Barnett
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Syngenta Participations AG
Syngenta Ltd
Original Assignee
Syngenta Participations AG
Syngenta Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Syngenta Participations AG, Syngenta Ltd filed Critical Syngenta Participations AG
Priority to BRPI0813924 priority Critical patent/BRPI0813924A2/pt
Priority to EP08762477A priority patent/EP2170047A1/fr
Priority to CN200880021855.5A priority patent/CN101848642B/zh
Publication of WO2009001076A1 publication Critical patent/WO2009001076A1/fr
Priority to ZA2009/09166A priority patent/ZA200909166B/en
Anticipated expiration legal-status Critical
Priority to AP2010005096A priority patent/AP2010005096A0/en
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N27/00—Biocides, pest repellants or attractants, or plant growth regulators containing hydrocarbons
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/06—Coniferophyta [gymnosperms], e.g. cypress
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08—Magnoliopsida [dicotyledons]
    • A01N65/22—Lamiaceae or Labiatae [Mint family], e.g. thyme, rosemary, skullcap, selfheal, lavender, perilla, pennyroyal, peppermint or spearmint
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/40—Liliopsida [monocotyledons]
    • A01N65/44—Poaceae or Gramineae [Grass family], e.g. bamboo, lemon grass or citronella grass
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

Definitions

  • the field of the invention relates generally to pesticide compositions containing organophosphates and to methods for use thereof. More particularly, the compositions of this invention comprise pyrimidinyl phosphorothioate pesticides microencapsulated with at least one plant essential oil for use in controlling pests.
  • IRS indoor residual spraying
  • IRS must be applied to a very high proportion of households in an area (usually >70%).
  • the community plays a passive role in IRS programs, cooperation with an IRS effort is a key to its success.
  • Community participation for IRS often consists of cooperating with the spray teams by removing food and covering surfaces prior to spraying and refraining from covering the treated surfaces with new paint or plaster.
  • community or individual householder opposition to IRS due to the smell, mess, possible chemical exposure, or sheer bother has become a serious problem in some areas.
  • Pirimiphos-rnethyl is a fast acting pyrimidinyl phosphorothioate insecticide having the chemical structure of (Phosphorothioic acid, O-[2-(diethylamino)-6-methyl-4-pyrimidinyl] O,O-dimethyl ester) employing CAS nomenclature.
  • a liquid product containing 50 weight percent pirimiphos-methyl is being sold under the trademark Actellic ® 50EC by Syngenta for use in grain, grain stores, and for fly control.
  • Pirimiphos-methyl as Actellic also has been demonstrated to be highly effective against pyrethroid resistant mosquitoes. Furthermore, it has also been shown to be effective against some strains of insects with organophosphate resistance.
  • compositions comprising microcapsules that contain pirimiphos-methyl and certain hydrocarbon solvents or plant essential oils have good residual efficacy and reduced odor relative to other pirimiphos-methyl fo ⁇ nulations.
  • inventive compositions are very effective for combating or controlling disease vectors and also are suitable for use in IRS applications.
  • pesticide compositions comprise microcapsules that contain pirimiphos-methyl and (1) at least one plant essential oil selected from citronella, peppermint oil, d-limonene and abies sibirica, (2) at least one single or mixed aromatic hydrocarbon solvent, or mixtures of (1) and (2), wherein the pirimiphos-methyl is present in said composition in a pesticidally effective amount.
  • the present invention also provides a method for controlling pests (such as mosquitoes and other disease vectors).
  • the method for controlling pests comprises applying the compositions of the invention to the target pests, to their locus or to a surface or substrate by brushing, rolling, spraying, spreading or dipping.
  • a surface such as a wall, ceiling or floor surface is contemplated by the method of the invention.
  • it is contemplated to apply such compositions to a substrate such as a fabric material in the form of (or which can be used in the manufacture of) netting, clothing, bedding, curtains and tents.
  • the pesticide composition is a liquid dispersion of such microcapsules and, more particularly, is an aqueous suspension of such microcapsules.
  • aqueous microcapsule suspensions are also referred to as aqueous capsule suspensions (CS).
  • Suitable plant essential oils for use in the pesticidal compositions and pest control methods of the present invention are oils suitable for IRS application, typically of high purity, and, in one embodiment, also are characterized by odor masking properties and solvency for or miscibility with pirimiphos-methyl.
  • Suitable oils are generally composed of one or more plant essential oils such as those selected from citronella, peppermint oil, d-limonene and abies sibirica. These plant essential oil materials are known and used for other uses and can be prepared by a skilled artisan by employing known methods and also are available commercially.
  • Suitable aromatic hydrocarbon solvents include, for example, a single or mixed hydrocarbon solvent comprising one or more members selected from the group consisting of C 8 - Cn aromatic hydrocarbons.
  • Suitable commercially available mixtures include Solvesso 100 or Solvesso 150 (manufactured by Exxon Mobil Co.)
  • microcapsules that are suitable for use in the compositions and methods according to the invention contain a mixture comprising pirimiphos-methyl and (1) at least one plant essential oil selected from citronella, peppermint oil, d-limonene and abies sibirica or (2) at least one aromatic hydrocarbon solvent, which mixture is contained within an encapsulating wall of polymeric material.
  • Such microcapsules are prepared with any suitable technique known in the art.
  • microcapsule wall material and core particles are physically brought together and the wall material flows around the core particle to form the microcapsule.
  • phase separation category microcapsules are formed by emulsifying or dispersing the core material in an immiscible continuous phase in which the wall material is dissolved and caused to physically separate from the continuous phase, such as by coacervation, and deposit around the core particles.
  • interfacial reaction category microcapsules are formed by emulsifying or dispersing the core material in an immiscible continuous phase and then an interfacial polymerization reaction is caused to take place at the surface of the core particles .
  • the concentration of the pirimiphos-methyl present in the microcapsules of the invention can vary from 0.1 to 95% by weight of the microcapsule.
  • the concentration of the plant essential oil present in the microcapsules can vary from 0.1 to 90%. In one embodiment of the invention, the concentration of the pirimiphos-methyl present is about
  • microcapsules 55% by weight of the microcapsule and the concentration of the plant essential oil is between 30- 45% by weight of the microcapsule.
  • concentration of the pirimiphos-methyl present is about 70% by weight of the microcapsule and the concentration of the plant essential oil is between 5-15% by weight of the microcapsule.
  • suitable microcapsules are particles with diameters between 0.1 and 1000 ⁇ m.
  • suitable microcapsule polymeric wall materials are selected from the polyureas, aminoplasts, polyurethanes and polyamides.
  • polyurea microcapsules containing pirimiphos-methyl are prepared as exemplified in U.S. Pat. No. 4,285,720, which involves the use of at least one polyisocyanate such as polymethylene polyphenylisocyanate (PMPPI) and/or tolylene diisocyanate (TDI) as the prepolymer.
  • PMPPI polymethylene polyphenylisocyanate
  • TDI tolylene diisocyanate
  • the wall -forming reaction is initiated by heating the emulsion to an elevated temperature at which point the isocyanate polymers are hydrolyzed at the interface to form amines, which in turn react with unhydrolyzed polymers to form the polyurea microcapsule wall.
  • pirimiphos-methyl containing polyurea microcapsules are prepared which also contain: (i) 5 - 45% by weight, more particularly, 5 - 15% by weight of citronella; (ii) 5 - 45% by weight, more particularly, 5 - 15% by weight of peppermint oil; (Hi) 5 - 45% by weight, more particularly, 5 - 15% by weight of d-limonene; or (iv) 5 - 45% by weight, more particularly, 5 - 15% by weight of abies sibirica.
  • Aqueous capsule suspensions (CS) in accordance with the invention are prepared with a polymerisation stage such that an aqueous dispersion of oil droplets is obtained, in which each oil droplet is encapsulated by a polymeric shell and contains pirimiphos-methyl and a plant essential oil carrier or diluent therefor.
  • the polymeric shell may be produced by either an interfacial polycondensation reaction or by a coacervation procedure.
  • the CS compositions thus obtained may provide for controlled release of pirimiphos-methyl and they may be used for IRS treatment.
  • microcapsules from the directly obtained capsule suspension by: (a) filtration or centrifugation and either to dry or convert them once more into a suspension; or (b) by spray drying the microcapsules using known methods.
  • the microcapsules which have been isolated from the suspension and dried are in the form of, for example, a flowable powder.
  • the microcapsules can also be adsorbed on to a surface (such as a wall, ceiling or floor) or on to a substrate (such as a fabric material including, for example, polyester bed nets).
  • suspensions of microcapsules obtainable in the process of this invention are directly ready for use. However, for transportation and storage they can be stabilised by the addition of further ingredients such as surface-active agents, thickeners, antifoams and antifreeze agents.
  • the liquid compositions described herein can be compounded with, or have mixed therein, other known ingredients such as plasticizers, emulsifiers, surface active agents, stabilizers (including UV light protectants), fillers, antioxidants, fungicides, antimicrobials, antifoaming agents, drying adjuvants, levelling agents, pigments, or other compounding aids.
  • plasticizers emulsifiers
  • stabilizers including UV light protectants
  • Suitable wetting, emulsifying or dispersing agents may be of the cationic, anionic or non-ionic type.
  • Suitable agents of the cationic type include, for example, quaternary ammonium compounds, for example, cetyltrimethyl ammonium bromide.
  • Suitable agents of the anionic type include, for example, soaps, salts of aliphatic monoesters or sulphuric acid, for example, sodium lauryl sulphate, salts of sulphonated aromatic compounds, for example, sodium dodecylbenzene- sulphonate, sodium, calcium or ammonium lignosulphonate, or butylnaphthalene sulphonate, and a mixture of the sodium salts of diisopropyl- and triisopropylnaphthalene sulphonates.
  • Suitable agents of the non-ionic type include, for example, the condensation products of ethylene oxide with fatty alcohols such as oleyl alcohol or cetyl alcohol, or with alkyl phenols such as octyl phenol, nonyl phenol and octyl cresol.
  • Other non-ionic agents are the partial esters derived from long chain fatty acids and hexitol anhydrides, the condensation products of the said partial esters with ethylene oxide, and the lecithins.
  • Additional microencapsulated or non-microencapsulated active ingredients to be applied at a locus separately, sequentially in any order, or simultaneously with the microcapsules of the invention may be employed for enhanced pesticidal effect and for pest resistance management reasons.
  • suitable additional active ingredients include lambda cyhalothrin, ⁇ -cypermethrin, deltametlirin, permetlirin, malathion, fenitrothion, bendiocarb, propoxur, cyfiuthrin, and etofenprox.
  • the pesticide compositions comprise a mixture of (a) microcapsules of pirimiphos-methyl and certain plant essential oils with (b) one or more such additional microencapsulated or non-microencapsulated active ingredients.
  • a pesticide composition comprising microcapsules of pirimiphos- methyl and certain plant essential oils is provided or used with a separate pesticide composition containing the additional active ingredient (e.g., a microencapsulated lambda cyhalothrin such as Icon 10 CS, Icon 2.5 CS or the like).
  • additional active ingredient e.g., a microencapsulated lambda cyhalothrin such as Icon 10 CS, Icon 2.5 CS or the like.
  • these materials can be applied sequentially over a relatively short time period or can be combined with water in a treatment container or tank to form a final treatment composition for simultaneous application. Alternatively, the materials can be applied separately as part of a more long term treatment regime.
  • the pesticidal compositions which are to be used in the form of aqueous suspensions, dispersions or emulsions are generally supplied in the form of a concentrate containing a high proportion of the active ingredient or ingredients, the said concentrate to be diluted with water before use.
  • These concentrates are often required to withstand storage for prolonged periods and after such storage, to be capable of dilution with water to form aqueous preparations which remain homogenous for a sufficient time to enable them to be applied by spreading, brushing or by conventional spray equipment.
  • the concentrates contain from 1 - 85% by weight of the active ingredient (pirimiphos-methyl) or mixture of active ingredients.
  • aqueous preparations When diluted to form aqueous preparations, such dilute preparations may contain varying amounts of the active ingredient or ingredients depending on the purpose for which they are to be used.
  • an aqueous CS spray composition containing between 0.001% to 1% by weight of pirimiphos-methyl microencapsulated along with a suitable plant essential oil is used alone or in admixture with other active ingredients.
  • target pests include insects belonging to the order Diptera (covering mosquitoes, gnats, black flies, tsetse flies and other biting flies), Hemiptera (covering bed bugs) and Siphonaptera (covering fleas).
  • target pests there may also be mentioned, Dictyoptera (covering cockroaches), Coleoptera (covering pests of stored grain), Lepidoptera (covering moths) and Arachnids (covering spiders, mites and ticks).
  • the present invention is particularly suited for controlling flying pests such as mosquitoes including, for example, species of the Anopheles gambiae complex.
  • the method for controlling such pests comprises applying a pesticidally effective amount of the compositions of the invention to the target pests, to their locus, or to a surface or substrate so as to provide effective residual pesticidal activity on the surface or substrate.
  • a pesticidally effective amount of the compositions of the invention to the target pests, to their locus, or to a surface or substrate so as to provide effective residual pesticidal activity on the surface or substrate.
  • Such application may be made by brushing, rolling, spraying, spreading or dipping the pesticidal composition of the invention.
  • an IRS application of a surface such as a wall, ceiling or floor surface is contemplated by the method of the invention so as to provide effective residual pesticidal activity on the surface.
  • it is contemplated to apply such compositions for residual control of pests on a substrate such as a fabric material in the fo ⁇ n of (or which can be used in the manufacture of) netting, clothing, bedding, curtains and tents.
  • Substrates including fabrics or netting to be treated may be made of natural fibres such as cotton, raffia, jute, flax, sisal, hessian, or wool, or synthetic fibres such as polyamide, polyester, polypropylene, polyacrylonitrile or the like.
  • the polyesters are particularly suitable.
  • the present invention provides a method for combating or controlling pests in a dwelling which comprises applying a pesticidally effective amount of a composition comprising a microencapsulated mixture comprising pirimiphos-methyl and (1) at least one plant essential oil thereof selected from citronella, peppermint oil, d-limonene and abies sibirica or (2) at least one aromatic hydrocarbon solvent, wherein the pirimiphos-methyl is present in said composition in a pesticidally effective amount, to a wall, ceiling or floor surface of such dwelling.
  • liquid compositions such as aqueous compositions that comprise suspensions or dispersions of any suitable microcapsule containing a mixture of pirimiphos-methyl and (1) at least one plant essential oil selected from citronella, peppermint oil, d-limonene and abies sibirica, or (2) at least one aromatic hydrocarbon solvent which is effective against the pests to be controlled, particularly against disease vectors such as adult mosquitoes and flies.
  • aqueous compositions that comprise suspensions or dispersions of any suitable microcapsule containing a mixture of pirimiphos-methyl and (1) at least one plant essential oil selected from citronella, peppermint oil, d-limonene and abies sibirica, or (2) at least one aromatic hydrocarbon solvent which is effective against the pests to be controlled, particularly against disease vectors such as adult mosquitoes and flies.
  • Optimum rates of application for a particular composition comprising a microencapsulated mixture of pirimiphos-methyl and at least one plant essential oil, a particular target substrate or locus and a particular set of insect pressure conditions, can be determined easily and without undue experimentation by simple ranging studies carried out in or on target substrates or pests. Determination of such optimum rates in treating target pests will achieve a target loading of the pirimiphos-methyl per square meter of a particular substrate being treated such as in an IRS or bed net application.
  • the pirimiphos-methyl is applied in an amount of from 10 to 2000 mg a.i./m 2 to control such target pests.
  • An aqueous phase is prepared comprising 1.012g of Celvol 205 (88% hydrolysed polyvinylalcohol, ex Celanese Chemicals) dispersed via high shear mixing into 51.93g of deionised water. To this was added 0.51g of Synperonic A7 (C13/15 alcohol ethoxylate, 7 moles ethoxylation, ex Uniqema) whilst mixing. Continuing to mix, the oil phase is slowly added to the emulsion phase and mixing speed adjusted to give a median particle size between 5 ⁇ m and 20 ⁇ m.
  • reaction vessel was then raised to 60 0 C so as to initiate the wall formation reaction, and the temperature maintained, together with low shear mixing, for a period of 3 hours.
  • 0.4g of 35% ammonia solution (ex Aldrich) was then added to quench any unreacted isocyanate and the mixture allowed to stir for a further 30 minutes.
  • the mixture was allowed to cool to room temperature prior to adjustment to pH 7 using 1 M sulphuric acid.
  • surfactants such as Tergitol XD (20% solution) (alkoxylated alcohol) and Agnique NSC 1 INP (Naphthalene Sulfonate Condensate, Na Salt) are suitable alternative surfactants.
  • Examples 2 - 5 [0041] The procedure of example 1 is repeated by replacing Solvesso 100 with equivalent amounts of a plant essential oil selected from citronella, peppermint oil, Abies sibirica and d- limonene.

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Natural Medicines & Medicinal Plants (AREA)
  • Biotechnology (AREA)
  • Microbiology (AREA)
  • Mycology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Catching Or Destruction (AREA)

Abstract

L'invention concerne des compositions pesticides qui comprennent des microcapsules contenant du pirimiphos-méthyle et (1) au moins une huile essentielle végétale, sélectionnée dans le groupe comprenant l'essence de citronnelle, l'huile de menthe poivrée, le d-limonène et Abies sibirica ou (2) au moins un solvant d'hydrocarbure aromatique, le pirimiphos-méthyle étant présent dans la composition en quantité efficace du point de vue de l'action pesticide. L'invention concerne aussi un procédé de lutte antiparasitaire (contre les moustiques et d'autres vecteurs pathogènes), qui comprend l'application des compositions de l'invention sur les parasites ciblés, à l'endroit où ils se trouvent ou sur une surface ou un substrat par brossage, roulage, pulvérisation, dispersion ou immersion. Le procédé de l'invention concerne par exemple l'application en pulvérisation intra-domiciliaire ou 'IRS' (Indoor Residual Spraying) sur une surface telle qu'une surface de paroi, de plafond ou de plancher ou le traitement d'un substrat tel qu'une moustiquaire de lit.
PCT/GB2008/002170 2007-06-25 2008-06-25 Compositions pesticides Ceased WO2009001076A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
BRPI0813924 BRPI0813924A2 (pt) 2007-06-25 2008-06-25 Composições pesticidas
EP08762477A EP2170047A1 (fr) 2007-06-25 2008-06-25 Compositions pesticides
CN200880021855.5A CN101848642B (zh) 2007-06-25 2008-06-25 灭害剂组合物
ZA2009/09166A ZA200909166B (en) 2007-06-25 2009-12-22 Pesticide compositions
AP2010005096A AP2010005096A0 (en) 2007-06-25 2010-01-09 Pesticide compositions

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US94600607P 2007-06-25 2007-06-25
US60/946,006 2007-06-25

Publications (1)

Publication Number Publication Date
WO2009001076A1 true WO2009001076A1 (fr) 2008-12-31

Family

ID=39807792

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2008/002170 Ceased WO2009001076A1 (fr) 2007-06-25 2008-06-25 Compositions pesticides

Country Status (11)

Country Link
EP (1) EP2170047A1 (fr)
CN (1) CN101848642B (fr)
AP (2) AP2890A (fr)
AR (1) AR067166A1 (fr)
BR (1) BRPI0813924A2 (fr)
CL (2) CL2008001885A1 (fr)
JO (1) JO3356B1 (fr)
PE (2) PE20121810A1 (fr)
UY (1) UY31181A1 (fr)
WO (1) WO2009001076A1 (fr)
ZA (1) ZA200909166B (fr)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010101820A1 (fr) * 2009-03-04 2010-09-10 Dow Agrosciences Llc Insecticide microencapsulé à activité résiduelle renforcée
AU2009236007B2 (en) * 2009-11-11 2013-12-19 Creepy Crawly Pest Control Pty Ltd Insecticide Treated Insulation and Surrounds
EP2737799A1 (fr) 2012-11-28 2014-06-04 SC Amia Sport International SRL Biopesticide contenant des huiles essentielles et procédé d'obtention dudit biopesticide
JP2015157780A (ja) * 2014-02-24 2015-09-03 エステー株式会社 防虫剤
WO2016180655A1 (fr) * 2015-05-13 2016-11-17 Sipcam Società Italiana Prodotti Chimici E Per L'agricoltura Milano S.P.A. Formulations ec comprenant des insecticides organophosphatés
WO2016180658A1 (fr) * 2015-05-13 2016-11-17 Sipcam Società Italiana Prodotti Chimici E Per L'agricoltura Milano S.P.A. Formulations ec comprenant des insecticides organophosphatés
CN106818923A (zh) * 2017-01-24 2017-06-13 福建农林大学 一种诱杀橘小实蝇的微胶囊悬浮剂

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102657160A (zh) * 2012-05-10 2012-09-12 湖南化工研究院 杀虫剂甲基嘧啶磷微胶囊悬浮剂及制备方法
CN104068043A (zh) * 2014-06-19 2014-10-01 陈啟文 一种长效杀虫剂
JP6698449B2 (ja) * 2015-09-25 2020-05-27 イノベイティブ・ベクター・コントロール・コンソーティアムＩｎｎｏｖａｔｉｖｅ Ｖｅｃｔｏｒ Ｃｏｎｔｒｏｌ Ｃｏｎｓｏｒｔｉｕｍ 殺虫成分を含有するマルチフィラメント及び繊維製品
HUE049659T2 (hu) * 2016-07-27 2020-10-28 Basf Se Mikrokapszulák anionos C6-C10 ko-diszpergálószerrel alkotott agroformulációja
CN115226715A (zh) * 2022-07-22 2022-10-25 中国人民解放军海军特色医学中心 一种引诱剂组合物在杀虫剂中的应用及杀虫剂

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AP2890A (en) 2014-05-31
JO3356B1 (ar) 2019-03-13
CL2014000320A1 (es) 2014-07-25
CN101848642A (zh) 2010-09-29
EP2170047A1 (fr) 2010-04-07
AP2010005096A0 (en) 2009-12-31
CN101848642B (zh) 2015-04-01
BRPI0813924A2 (pt) 2015-01-06
PE20121810A1 (es) 2013-02-03
AR067166A1 (es) 2009-09-30
CL2008001885A1 (es) 2009-05-22

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