RU2015153202A - Катод, электрохимическая ячейка и ее использование - Google Patents
Катод, электрохимическая ячейка и ее использование Download PDFInfo
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- RU2015153202A RU2015153202A RU2015153202A RU2015153202A RU2015153202A RU 2015153202 A RU2015153202 A RU 2015153202A RU 2015153202 A RU2015153202 A RU 2015153202A RU 2015153202 A RU2015153202 A RU 2015153202A RU 2015153202 A RU2015153202 A RU 2015153202A
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- Prior art keywords
- anode
- consumable
- sacrificial
- powder
- cathode
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 10
- 238000000034 method Methods 0.000 claims 10
- 239000000843 powder Substances 0.000 claims 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 5
- 229910052742 iron Inorganic materials 0.000 claims 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 2
- 239000000356 contaminant Substances 0.000 claims 2
- 238000009297 electrocoagulation Methods 0.000 claims 2
- 229910002804 graphite Inorganic materials 0.000 claims 2
- 239000010439 graphite Substances 0.000 claims 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims 1
- 229910052785 arsenic Inorganic materials 0.000 claims 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims 1
- 229910052804 chromium Inorganic materials 0.000 claims 1
- 239000011651 chromium Substances 0.000 claims 1
- 238000004090 dissolution Methods 0.000 claims 1
- 239000008394 flocculating agent Substances 0.000 claims 1
- 229910001385 heavy metal Inorganic materials 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 229910001220 stainless steel Inorganic materials 0.000 claims 1
- 239000010935 stainless steel Substances 0.000 claims 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/46109—Electrodes
- C02F1/46114—Electrodes in particulate form or with conductive and/or non conductive particles between them
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/463—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrocoagulation
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
- C25B11/03—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form perforated or foraminous
- C25B11/031—Porous electrodes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/042—Electrodes formed of a single material
- C25B11/043—Carbon, e.g. diamond or graphene
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
- C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/46109—Electrodes
- C02F2001/46133—Electrodes characterised by the material
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/46109—Electrodes
- C02F2001/46152—Electrodes characterised by the shape or form
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/46109—Electrodes
- C02F2001/46152—Electrodes characterised by the shape or form
- C02F2001/46157—Perforated or foraminous electrodes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/46109—Electrodes
- C02F2001/46152—Electrodes characterised by the shape or form
- C02F2001/46157—Perforated or foraminous electrodes
- C02F2001/46161—Porous electrodes
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/46109—Electrodes
- C02F2001/46152—Electrodes characterised by the shape or form
- C02F2001/46171—Cylindrical or tubular shaped
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/103—Arsenic compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/12—Halogens or halogen-containing compounds
- C02F2101/14—Fluorine or fluorine-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
- C02F2101/22—Chromium or chromium compounds, e.g. chromates
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/46—Apparatus for electrochemical processes
- C02F2201/461—Electrolysis apparatus
- C02F2201/46105—Details relating to the electrolytic devices
- C02F2201/4612—Controlling or monitoring
- C02F2201/46125—Electrical variables
- C02F2201/4613—Inversing polarity
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Water Supply & Treatment (AREA)
- Environmental & Geological Engineering (AREA)
- Hydrology & Water Resources (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Removal Of Specific Substances (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Claims (21)
1. Расходуемый анод, содержащий расходуемую часть и нерасходуемую электропроводящую часть, отличающийся тем, что расходуемая часть имеет пористость между 20 и 60% по объему, а предпочтительно между 30 и 50% по объему, и содержит железный порошок.
2. Расходуемый анод по п.1, отличающийся тем, что расходуемая часть содержит смесь железного порошка и алюминиевого порошка.
3. Расходуемый анод по п.1 или 2, отличающийся тем, что железный порошок содержит по меньшей мере 90% по массе железа, предпочтительно по меньшей мере 95% по массе железа, а наиболее предпочтительно по меньшей мере 97% по массе железа.
4. Расходуемый анод по любому из пп.2 или 3, отличающийся тем, что массовое соотношение между железным порошком и алюминиевым порошком составляет от 50:50 до 98:2, предпочтительно от 60:40 до 98:2, а наиболее предпочтительно от 70:30 до 95:5.
5. Расходуемый анод по любому из пп.1-4, отличающийся тем, что расходуемая часть состоит из непрессованного порошка или порошков.
6. Расходуемый анод по любому из пп.1-4, отличающийся тем, что расходуемая часть состоит из прессованного порошка или порошков, предпочтительно спрессованных в форме тороида.
7. Расходуемый анод по пп.1-6, отличающийся тем, что нерасходуемая электропроводящая часть анода выполнена из графита или нержавеющей стали.
8. Расходуемый анод по любому из пп.1-7, отличающийся тем, что нерасходуемая электропроводящая часть анода имеет форму пористой корзины или емкости из графита.
9. Расходуемый анод по любому из пп.1-7, отличающийся тем, что нерасходуемая электропроводящая часть анода имеет форму твердотельного стержня или прутка.
10. Расходуемый анод по п.7 или 9, отличающийся тем, что расходуемая часть расходуемого анода представляет собой по меньшей мере один выполненный из прессованного порошка тороид, окружающий нерасходуемую электропроводящую часть и находящийся в тесном электрическом контакте с ней.
11. Электрохимическая ячейка, содержащая расходуемый электрод по любому из пп.1-10.
12. Электрохимическая ячейка по п.11, отличающаяся тем, что анод и катод идентичны по структуре.
13. Способ удаления загрязнителей из воды посредством электрокоагуляции, отличающийся тем, что:
- обеспечивают по меньшей мере одну электрохимическую ячейку по п.11 или 12;
- приводят подлежащую очистке воду в контакт с упомянутой по меньшей мере одной электрохимической ячейкой, подавая разность электрических потенциалов между катодом и анодом.
14. Способ по п.13, отличающийся тем, что процесс останавливают, когда расходуемая часть расходуемого анода по меньшей мере частично израсходована, и необязательно продолжают после замены этой расходуемой части расходуемого анода.
15. Способ по п.13 удаления загрязнителей из воды посредством электрокоагуляции, при этом, когда анод и катод идентичны по структуре, способ дополнительно включает этап переключения полярности, когда расходуемая часть расходуемого анода по меньшей мере частично израсходована.
16. Способ по любому из пп.13-15, при этом до и/или во время процесса регулируют pH до значения, которое препятствует растворению образованных гидроксидных флоккулянтов, предпочтительно до значения между 5 и 8.
17. Способ по любому из пп.13-16, при этом разность потенциалов между анодом и катодом достаточна, чтобы давать плотность тока между 15 и 300 А/м2.
18. Способ по любому из пп.13-17, при этом вода содержит тяжелые металлы, такие как хром или мышьяк.
19. Способ по любому из пп.13-18, при этом вода содержит фторид.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP13167470.7 | 2013-05-13 | ||
| EP13167470 | 2013-05-13 | ||
| PCT/EP2014/059548 WO2014184106A1 (en) | 2013-05-13 | 2014-05-09 | Cathode, electrochemical cell and its use |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2015153202A true RU2015153202A (ru) | 2017-06-20 |
| RU2688166C2 RU2688166C2 (ru) | 2019-05-20 |
Family
ID=48468137
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2015153202A RU2688166C2 (ru) | 2013-05-13 | 2014-05-09 | Катод, электрохимическая ячейка и ее использование |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US10676378B2 (ru) |
| EP (1) | EP2997179B1 (ru) |
| JP (1) | JP6621735B2 (ru) |
| KR (1) | KR102357207B1 (ru) |
| CN (2) | CN110078176A (ru) |
| AU (1) | AU2014267490B2 (ru) |
| BR (1) | BR112015027865B1 (ru) |
| CA (1) | CA2909741A1 (ru) |
| ES (1) | ES2691308T3 (ru) |
| MX (1) | MX376423B (ru) |
| RU (1) | RU2688166C2 (ru) |
| TW (1) | TWI654145B (ru) |
| WO (1) | WO2014184106A1 (ru) |
| ZA (1) | ZA201508099B (ru) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FI126678B (fi) | 2015-09-17 | 2017-03-31 | Elwater Ltd Oy | Laite veden puhdistamiseksi ja sen käyttö |
| EP3293152A1 (en) | 2016-09-09 | 2018-03-14 | Höganäs AB (publ) | Device and process for electrocoagulation |
| US20180141836A1 (en) * | 2016-11-16 | 2018-05-24 | Bo Hu | Electrochemical removal of sulfide species and phosphorus species |
| JP6791733B2 (ja) * | 2016-11-22 | 2020-11-25 | 住友電気工業株式会社 | 窒化鉄粒子及び窒化鉄粒子の製造方法 |
| FI127277B (fi) | 2017-01-20 | 2018-02-28 | Martti Klemola | Menetelmä veden puhdistamiseksi, menetelmällä valmistettu tuote ja sen käyttö |
| TWI640556B (zh) * | 2017-09-13 | 2018-11-11 | 日商住友化學股份有限公司 | 用於製造偏光膜的方法與系統 |
| CN107935130B (zh) * | 2017-12-16 | 2023-12-15 | 傲自然成都生物科技有限公司 | 一种用于净化饮用水的电化学系统以及净化方法 |
| FI128052B (en) * | 2018-04-16 | 2019-08-30 | Lappeenrannan Teknillinen Yliopisto | A power converter for a bioelectrochemical system |
| JP7114054B2 (ja) * | 2018-05-01 | 2022-08-08 | 国立大学法人 名古屋工業大学 | 水電解用電解液、それを用いた水電解装置及び水電解方法 |
| US11161759B2 (en) * | 2018-10-15 | 2021-11-02 | Qatar University | Electrocoagulation cell design |
| CN109626521A (zh) * | 2019-01-25 | 2019-04-16 | 新乡市蓝海环境科技有限公司 | 高频脉冲电化学处理含氟废水方法及其装置 |
| CA3140014A1 (en) | 2019-06-12 | 2020-12-17 | Carlos Borras | Removal of materials from water |
| US12351492B2 (en) | 2019-06-12 | 2025-07-08 | Nuquatic, Llc | Removal of materials from water |
| FI128821B (fi) * | 2019-10-14 | 2020-12-31 | Elwater Ltd | Laite veden puhdistamiseksi |
| DE102019217944A1 (de) * | 2019-11-21 | 2021-05-27 | Robert Bosch Gmbh | Zyklon-Elektrolysezelle und Verfahren zur Reduktion von Chromat(VI)-Ionen |
| KR102254586B1 (ko) * | 2020-11-02 | 2021-05-20 | 길현영 | 분말전극 고정장치 |
| US11401181B1 (en) | 2021-03-02 | 2022-08-02 | Phosphorus Free Water Solutions, Llc | Galvanic process for treating aqueous compositions |
| EP4265571A1 (en) * | 2022-04-18 | 2023-10-25 | Inserpyme Global, S.A. | Electrochemical device and method for wastewater treatment |
| CN115961332B (zh) * | 2023-01-16 | 2024-12-20 | 浙江瑞成新材料股份有限公司 | 一种多孔铝粉及其制备方法 |
| US12122691B1 (en) | 2023-04-05 | 2024-10-22 | Nuquatic, Llc | Removal of fluoroalkyl compounds from water using galvanic cell |
| US12240772B2 (en) | 2023-04-05 | 2025-03-04 | Nuquatic, Llc | Treatment of aqueous composition with metal component |
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| US3523891A (en) | 1969-02-19 | 1970-08-11 | Purity Control Inc | Electrolytic sewage treatment system and process |
| US3846300A (en) * | 1971-01-11 | 1974-11-05 | Inoue Japax Res | Water purification |
| JPS5117235B2 (ru) | 1971-08-13 | 1976-06-01 | ||
| JPS5149356B2 (ru) | 1971-12-02 | 1976-12-25 | ||
| US3926754A (en) * | 1972-02-11 | 1975-12-16 | Andco Inc | Electrochemical contaminant removal from aqueous media |
| JPS5439668B2 (ru) | 1972-05-24 | 1979-11-29 | ||
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-
2014
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- 2014-05-09 JP JP2016513305A patent/JP6621735B2/ja not_active Expired - Fee Related
- 2014-05-09 RU RU2015153202A patent/RU2688166C2/ru active
- 2014-05-09 CN CN201480026614.5A patent/CN105229202B/zh active Active
- 2014-05-09 MX MX2015015679A patent/MX376423B/es active IP Right Grant
- 2014-05-09 KR KR1020157035110A patent/KR102357207B1/ko active Active
- 2014-05-09 EP EP14722239.2A patent/EP2997179B1/en not_active Not-in-force
- 2014-05-09 ES ES14722239.2T patent/ES2691308T3/es active Active
- 2014-05-09 CA CA2909741A patent/CA2909741A1/en active Pending
- 2014-05-09 BR BR112015027865-5A patent/BR112015027865B1/pt not_active IP Right Cessation
- 2014-05-09 AU AU2014267490A patent/AU2014267490B2/en not_active Ceased
- 2014-05-09 US US14/889,055 patent/US10676378B2/en not_active Expired - Fee Related
- 2014-05-09 WO PCT/EP2014/059548 patent/WO2014184106A1/en not_active Ceased
- 2014-05-12 TW TW103116783A patent/TWI654145B/zh not_active IP Right Cessation
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2015
- 2015-11-02 ZA ZA2015/08099A patent/ZA201508099B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AU2014267490B2 (en) | 2018-10-18 |
| EP2997179A1 (en) | 2016-03-23 |
| RU2688166C2 (ru) | 2019-05-20 |
| AU2014267490A1 (en) | 2015-11-12 |
| MX2015015679A (es) | 2016-03-15 |
| ZA201508099B (en) | 2018-05-30 |
| CN105229202B (zh) | 2019-03-15 |
| KR102357207B1 (ko) | 2022-01-27 |
| US20160075572A1 (en) | 2016-03-17 |
| WO2014184106A1 (en) | 2014-11-20 |
| TW201507978A (zh) | 2015-03-01 |
| US10676378B2 (en) | 2020-06-09 |
| BR112015027865B1 (pt) | 2021-10-13 |
| TWI654145B (zh) | 2019-03-21 |
| CA2909741A1 (en) | 2014-11-20 |
| ES2691308T3 (es) | 2018-11-26 |
| JP6621735B2 (ja) | 2019-12-18 |
| CN110078176A (zh) | 2019-08-02 |
| EP2997179B1 (en) | 2018-07-18 |
| JP2016524037A (ja) | 2016-08-12 |
| MX376423B (es) | 2025-03-07 |
| KR20160008590A (ko) | 2016-01-22 |
| CN105229202A (zh) | 2016-01-06 |
| BR112015027865A2 (pt) | 2017-07-25 |
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