RU2010119024A - Полимеры, функционализированные гетероциклическими нитрильными соединениями - Google Patents
Полимеры, функционализированные гетероциклическими нитрильными соединениями Download PDFInfo
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- RU2010119024A RU2010119024A RU2010119024/04A RU2010119024A RU2010119024A RU 2010119024 A RU2010119024 A RU 2010119024A RU 2010119024/04 A RU2010119024/04 A RU 2010119024/04A RU 2010119024 A RU2010119024 A RU 2010119024A RU 2010119024 A RU2010119024 A RU 2010119024A
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- reactive polymer
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- 229920000642 polymer Polymers 0.000 title claims abstract 7
- -1 NITRILE COMPOUNDS Chemical class 0.000 title claims abstract 5
- 238000000034 method Methods 0.000 claims abstract 10
- 229920013730 reactive polymer Polymers 0.000 claims abstract 10
- 239000003054 catalyst Substances 0.000 claims abstract 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract 4
- 125000000623 heterocyclic group Chemical group 0.000 claims abstract 4
- 239000003999 initiator Substances 0.000 claims abstract 4
- 239000000178 monomer Substances 0.000 claims abstract 4
- 125000000962 organic group Chemical group 0.000 claims abstract 4
- 150000001993 dienes Chemical class 0.000 claims abstract 2
- 229910052747 lanthanoid Inorganic materials 0.000 claims abstract 2
- 150000002602 lanthanoids Chemical group 0.000 claims abstract 2
- 150000002900 organolithium compounds Chemical class 0.000 claims abstract 2
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/22—Incorporating nitrogen atoms into the molecule
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/25—Incorporating silicon atoms into the molecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
- C08C19/42—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
- C08C19/42—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
- C08C19/44—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups of polymers containing metal atoms exclusively at one or both ends of the skeleton
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F136/06—Butadiene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L15/00—Compositions of rubber derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
- C08K3/045—Fullerenes
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Materials Engineering (AREA)
- Tires In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerization Catalysts (AREA)
- Oil, Petroleum & Natural Gas (AREA)
Abstract
1. Способ получения функционализованного полимера, который включает стадии: ! (i) получения реакционноспособного полимера; и ! (ii) проведения реакции между реакционноспособным полимером и гетероциклическим нитрильным соединением. ! 2. Способ по п.1, где упомянутая стадия получения включает: ! (i) введение сопряженного диенового мономера, необязательно мономера, сополимеризуемого с ним, и катализатора или инициатора для получения реакционноспособного полимера, где катализатор представляет собой систему катализатора на основе лантаноида и где инициатор включает литийорганическое соединение. ! 3. Способ по п.1, дополнительно включающий стадию проведения реакции между реакционноспособным полимером и софункционализующим агентом. ! 4. Способ по п.2, дополнительно включающий стадию проведения реакции между реакционноспособным полимером и софункционализующим агентом. ! 5. Способ по пп.1-4, где гетероциклическое нитрильное соединение описывают формулой θ-C≡N или θ-R-C≡N, где θ представляет собой гетероциклическую группу, a R представляет собой двухвалентную органическую группу. ! 6. Функционализованный полимер, описывающийся, по меньшей мере, одной из формул: ! ! где π представляет собой полимерную цепь, θ представляет собой гетероциклическую группу, а R представляет собой двухвалентную органическую группу.
Claims (6)
1. Способ получения функционализованного полимера, который включает стадии:
(i) получения реакционноспособного полимера; и
(ii) проведения реакции между реакционноспособным полимером и гетероциклическим нитрильным соединением.
2. Способ по п.1, где упомянутая стадия получения включает:
(i) введение сопряженного диенового мономера, необязательно мономера, сополимеризуемого с ним, и катализатора или инициатора для получения реакционноспособного полимера, где катализатор представляет собой систему катализатора на основе лантаноида и где инициатор включает литийорганическое соединение.
3. Способ по п.1, дополнительно включающий стадию проведения реакции между реакционноспособным полимером и софункционализующим агентом.
4. Способ по п.2, дополнительно включающий стадию проведения реакции между реакционноспособным полимером и софункционализующим агентом.
5. Способ по пп.1-4, где гетероциклическое нитрильное соединение описывают формулой θ-C≡N или θ-R-C≡N, где θ представляет собой гетероциклическую группу, a R представляет собой двухвалентную органическую группу.
6. Функционализованный полимер, описывающийся, по меньшей мере, одной из формул:
где π представляет собой полимерную цепь, θ представляет собой гетероциклическую группу, а R представляет собой двухвалентную органическую группу.
Applications Claiming Priority (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US99867407P | 2007-10-12 | 2007-10-12 | |
| US60/998.674 | 2007-10-12 | ||
| US99967907P | 2007-10-19 | 2007-10-19 | |
| US60/999,679 | 2007-10-19 | ||
| US1784507P | 2007-12-31 | 2007-12-31 | |
| US61/017,845 | 2007-12-31 | ||
| US12/144,504 | 2008-06-23 | ||
| US12/144,504 US8314189B2 (en) | 2007-10-12 | 2008-06-23 | Polymers functionalized with heterocyclic nitrile compounds |
| PCT/US2008/011725 WO2009051702A1 (en) | 2007-10-12 | 2008-10-14 | Polymers functionalized with heterocyclic nitrile compounds |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2010119024A true RU2010119024A (ru) | 2011-11-20 |
| RU2494114C2 RU2494114C2 (ru) | 2013-09-27 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2010119024/04A RU2494114C2 (ru) | 2007-10-12 | 2008-10-14 | Полимеры, функционализированные гетероциклическими нитрильными соединениями |
Country Status (10)
| Country | Link |
|---|---|
| US (6) | US8314189B2 (ru) |
| EP (2) | EP2203482B1 (ru) |
| JP (3) | JP5475670B2 (ru) |
| KR (1) | KR101548396B1 (ru) |
| CN (2) | CN104945540A (ru) |
| BR (1) | BRPI0818443B1 (ru) |
| ES (1) | ES2563039T3 (ru) |
| RU (1) | RU2494114C2 (ru) |
| WO (2) | WO2009051700A1 (ru) |
| ZA (1) | ZA201002523B (ru) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2671490C2 (ru) * | 2013-10-02 | 2018-11-01 | Бриджстоун Корпорейшн | Полимеры, функционализированные иминными соединениями, содержащими цианогруппу |
Families Citing this family (53)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002038615A1 (en) | 2000-11-10 | 2002-05-16 | Bridgestone Corporation | Functionalized high cis-1,4-polybutadiene prepared using novel functionalizing agents |
| US8324329B2 (en) | 2007-08-07 | 2012-12-04 | Bridgestone Corporation | Process for producing functionalized polymers |
| US8314189B2 (en) | 2007-10-12 | 2012-11-20 | Bridgestone Corporation | Polymers functionalized with heterocyclic nitrile compounds |
| RU2515980C2 (ru) * | 2007-12-31 | 2014-05-20 | Бриджстоун Корпорейшн | Способ получения полидиенов полимеризацией в объеме |
| US8268933B2 (en) * | 2007-12-31 | 2012-09-18 | Bridgestone Corporation | Polymers functionalized with polyimine compounds |
| US7906592B2 (en) * | 2008-07-03 | 2011-03-15 | Bridgestone Corporation | Polymers functionalized with imide compounds containing a protected amino group |
| US8188195B2 (en) * | 2008-12-31 | 2012-05-29 | Bridgestone Corporation | Polymers functionalized with nitroso compounds |
| RU2538253C2 (ru) | 2009-01-23 | 2015-01-10 | Бриджстоун Корпорейшн | Полимеры, функционализированные нитрильными соединениями с защитной аминогруппой |
| WO2010085631A2 (en) | 2009-01-23 | 2010-07-29 | Bridgestone Corporation | Polymers functionalized with polycyano compounds |
| JP5612270B2 (ja) * | 2009-04-27 | 2014-10-22 | 株式会社ブリヂストン | ランフラットタイヤ |
| JP2010275427A (ja) * | 2009-05-28 | 2010-12-09 | Bridgestone Corp | ゴム組成物およびそれを用いた空気入りタイヤ |
| JP5436051B2 (ja) * | 2009-05-29 | 2014-03-05 | 株式会社ブリヂストン | ゴム組成物及びそれを用いたタイヤ |
| US8338544B2 (en) | 2009-12-21 | 2012-12-25 | Bridgestone Corporation | Polymers functionalized with polyoxime compounds and methods for their manufacture |
| BR112012018095B1 (pt) * | 2010-01-22 | 2019-11-05 | Bridgestone Corp | polímeros funcionalizados com compostos de nitrila contendo um grupo amino protegido |
| JP5707049B2 (ja) * | 2010-04-08 | 2015-04-22 | 株式会社ブリヂストン | 空気入りタイヤ |
| US8748531B2 (en) | 2010-12-10 | 2014-06-10 | Bridgestone Corporation | Polymers functionalized with oxime compounds containing an acyl group |
| TWI413648B (zh) * | 2010-12-31 | 2013-11-01 | Chi Mei Corp | 共軛二烯－乙烯基芳香烴共聚物及其製備方法 |
| TWI428357B (zh) * | 2010-12-31 | 2014-03-01 | Chi Mei Corp | 共軛二烯－乙烯基芳香烴共聚物及其製備方法 |
| JP5783797B2 (ja) * | 2011-05-25 | 2015-09-24 | 株式会社ブリヂストン | ゴム組成物の製造方法 |
| US8962766B2 (en) | 2011-09-15 | 2015-02-24 | Bridgestone Corporation | Polymers functionalized with polyhydrazone compounds |
| KR101933751B1 (ko) * | 2011-12-09 | 2018-12-28 | 가부시키가이샤 브리지스톤 | 감소된 저온 유동을 갖는 폴리디엔 및 폴리디엔 공중합체를 생산하는 방법 |
| FR3015979B1 (fr) * | 2014-01-02 | 2016-02-05 | Michelin & Cie | Procede de synthese en continu d'un polyisoprene fonctionnalise. |
| CN106459246B (zh) * | 2014-04-11 | 2020-04-10 | 出光兴产株式会社 | 烯烃系聚合物的制造方法、烯烃聚合用催化剂和烯烃系聚合物 |
| US10030083B2 (en) * | 2014-05-15 | 2018-07-24 | Bridgestone Corporation | Polymers functionalized with protected oxime compounds containing a cyano group |
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| CN107428867B (zh) | 2015-01-28 | 2020-09-22 | 株式会社普利司通 | 老化镧系元素基催化剂体系及其在制备顺式-1,4-聚二烯中的用途 |
| WO2016123370A1 (en) | 2015-01-28 | 2016-08-04 | Bridgestone Corporation | Cis-1,4-polydienes with improved cold flow resistance |
| US9738738B2 (en) | 2015-04-01 | 2017-08-22 | Bridgestone Corporation | Polymers functionalized with activated nitrogen heterocycles containing a pendant functional group |
| US9884928B2 (en) | 2015-04-01 | 2018-02-06 | Bridgestone Corporation | Polymers functionalized with activated nitrogen heterocycles containing a pendant functional group |
| US10370460B1 (en) * | 2015-05-20 | 2019-08-06 | Bridgestone Corporation | Process for producing functionalized polymers |
| JP6769262B2 (ja) * | 2016-01-05 | 2020-10-14 | 宇部興産株式会社 | 変性共役ジエン重合体、ゴム組成物、変性共役ジエン重合体の製造法 |
| US20190185598A1 (en) * | 2016-05-19 | 2019-06-20 | Bridgestone Corporation | Process For Producing Functionalized Polymers |
| WO2018008911A1 (ko) * | 2016-07-04 | 2018-01-11 | 주식회사 엘지화학 | 변성제, 변성 공액디엔계 중합체 및 이를 포함하는 고무 조성물 |
| KR101997596B1 (ko) | 2016-07-04 | 2019-07-08 | 주식회사 엘지화학 | 변성제, 변성 공액디엔계 중합체 및 이를 포함하는 고무 조성물 |
| US10899718B2 (en) | 2016-09-02 | 2021-01-26 | Bridgestone Corporation | Polymers functionalized with N-protected hydantoin compounds |
| JP6869333B2 (ja) | 2016-09-02 | 2021-05-12 | 株式会社ブリヂストン | ポリマーセメントのその場ヒドロシリル化により調製される複数のシラン官能基を有するシス−１，４−ポリジエンの製造 |
| WO2018089635A1 (en) | 2016-11-09 | 2018-05-17 | Bridgestone Corporation | High cis-1,4 block copolymers of polybutadiene and polyisoprene |
| WO2018088919A1 (en) * | 2016-11-10 | 2018-05-17 | Public Joint Stock Company "Sibur Holding" | Method for producing modified polydienes, modified polydienes produced thereby, and rubber mixtures based on the produced modified polydienes |
| JP6769261B2 (ja) * | 2016-11-24 | 2020-10-14 | 宇部興産株式会社 | 変性共役ジエン重合体、ゴム組成物、変性共役ジエン重合体の製造法 |
| CN106632098A (zh) * | 2016-12-17 | 2017-05-10 | 长江大学 | 吩嗪‑1‑羧酸羧基衍生物及含其衍生物的杀菌组合物 |
| US10730985B2 (en) | 2016-12-19 | 2020-08-04 | Bridgestone Corporation | Functionalized polymer, process for preparing and rubber compositions containing the functionalized polymer |
| JP6790888B2 (ja) * | 2017-02-14 | 2020-11-25 | 宇部興産株式会社 | 変性共役ジエン重合体、ゴム組成物、変性共役ジエン重合体の製造法 |
| KR20190038344A (ko) | 2017-09-29 | 2019-04-08 | 주식회사 엘지화학 | 고무 조성물 |
| KR102173756B1 (ko) | 2017-10-18 | 2020-11-04 | 주식회사 엘지화학 | 변성 공액디엔계 중합체의 제조방법 |
| RU2675540C1 (ru) * | 2017-12-12 | 2018-12-19 | Публичное акционерное общество "СИБУР Холдинг" | Способ получения системы для модификации полидиенов, модифицированные полидиены, резиновые смеси на основе модифицированных полидиенов |
| WO2019118688A1 (en) | 2017-12-15 | 2019-06-20 | Bridgestone Corporation | Functionalized polymer, process for preparing and rubber compositions containing the functionalized polymer |
| WO2019133633A1 (en) | 2017-12-30 | 2019-07-04 | Bridgestone Corporation | Composition including multiple terminally functionalized polymers |
| IT201800005841A1 (it) * | 2018-05-30 | 2019-11-30 | Procedimento per la preparazione di copolimeri random butadiene-isoprene ad elevato contenuto di unita’ 1,4-cis | |
| CN112739730B (zh) | 2018-08-27 | 2024-04-16 | 弗劳恩霍夫应用研究促进协会 | 仿生合成橡胶 |
| CN112292410B (zh) * | 2018-12-21 | 2023-09-19 | 株式会社Lg化学 | 改性共轭二烯类聚合物及其制备方法 |
| EP3938412B1 (en) | 2019-03-10 | 2024-04-24 | Bridgestone Corporation | Modified high cis polydiene polymer, related methods and rubber compositions |
| WO2021054785A1 (ko) * | 2019-09-19 | 2021-03-25 | 주식회사 엘지화학 | 변성 공액디엔계 중합체의 제조방법 |
| WO2025145007A1 (en) * | 2023-12-29 | 2025-07-03 | Bridgestone Americas Tire Operations, Llc | Functionalized butadiene polymers in tire compounds and method of making same |
Family Cites Families (104)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US398998A (en) * | 1889-03-05 | Farm-gate | ||
| US3017695A (en) | 1957-01-31 | 1962-01-23 | United Concrete Pipe Corp | Method of sizing bells and spigots of steel-cylinder concrete pipe |
| US3350377A (en) * | 1963-06-03 | 1967-10-31 | Phillips Petroleum Co | Bulk polymerization of conjugated diolefins |
| DE1300240B (de) | 1964-01-22 | 1969-07-31 | Bayer Ag | Verfahren zur Herstellung von Polymerisaten konjugierter Diolefine |
| US3652516A (en) | 1969-02-10 | 1972-03-28 | Phillips Petroleum Co | Polymerization of conjugated dienes or monovinyl aromatic monomers with multifunctional initiators from diisopropenylbenzene |
| US3742057A (en) * | 1970-02-27 | 1973-06-26 | Exxon Research Engineering Co | Chelated sodium compounds |
| US3978103A (en) | 1971-08-17 | 1976-08-31 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler | Sulfur containing organosilicon compounds |
| US3873489A (en) | 1971-08-17 | 1975-03-25 | Degussa | Rubber compositions containing silica and an organosilane |
| BE787691A (fr) | 1971-08-17 | 1973-02-19 | Degussa | Composes organosiliciques contenant du soufre |
| JPS5223380B2 (ru) * | 1973-09-12 | 1977-06-23 | ||
| SU580840A3 (ru) | 1974-02-07 | 1977-11-15 | Дегусса (Фирма) | Способ получени серосодержащих кремнийорганических соединений |
| US3998998A (en) * | 1975-01-13 | 1976-12-21 | Phillips Petroleum Company | Novel copolymers of dicyano-substituted 1,3-dienes |
| US4002594A (en) | 1975-07-08 | 1977-01-11 | Ppg Industries, Inc. | Scorch retardants for rubber reinforced with siliceous pigment and mercapto-type coupling agent |
| SU675871A1 (ru) * | 1977-06-20 | 1992-02-28 | Предприятие П/Я В-8415 | Способ получени модифицированного цис-1,4-полиизопрена |
| JPS5773030A (en) * | 1980-09-20 | 1982-05-07 | Bridgestone Corp | Rubber composition for tire |
| JPS58189203A (ja) | 1982-04-30 | 1983-11-04 | Nippon Zeon Co Ltd | ゴム組成物 |
| JPS5945311A (ja) * | 1982-09-07 | 1984-03-14 | Japan Synthetic Rubber Co Ltd | 改良されたポリブタジエンの製造方法 |
| US4429091A (en) | 1983-03-09 | 1984-01-31 | The Firestone Tire & Rubber Company | Oligomeric oxolanyl alkanes as modifiers for polymerization of dienes using lithium-based initiators |
| EP0150479B1 (en) | 1983-12-26 | 1990-06-13 | Nippon Zeon Co., Ltd. | Process for modifying conjugated diene polymers |
| US4927887A (en) * | 1984-09-21 | 1990-05-22 | Bridgestone/Firestone, Inc. | Modified rubber compositions containing aromatic six-membered heterocyclic nitrogen-containing groups |
| JPH0615598B2 (ja) | 1985-09-17 | 1994-03-02 | 日本合成ゴム株式会社 | 共重合体の製造方法 |
| US4906706A (en) | 1986-09-05 | 1990-03-06 | Japan Synthetic Rubber Co., Ltd. | Modified conjugated diene polymer and process for production thereof |
| US5064910A (en) | 1986-09-05 | 1991-11-12 | Japan Synthetic Rubber Co., Ltd. | Preparation of conjugated diene polymers modified with an organo-tin or germanium halide |
| IT1230756B (it) | 1989-02-17 | 1991-10-29 | Enichem Elastomers | Metodo per la preparazione di polibutadiene a lavorabilita' migliorata. |
| US5268439A (en) | 1991-01-02 | 1993-12-07 | Bridgestone/Firestone, Inc. | Tin containing elastomers and products having reduced hysteresis properties |
| FR2673187B1 (fr) | 1991-02-25 | 1994-07-01 | Michelin & Cie | Composition de caoutchouc et enveloppes de pneumatiques a base de ladite composition. |
| US5227431A (en) | 1991-04-12 | 1993-07-13 | Bridgestone/Firestone, Inc. | Diene polymers and copolymers jumped by partial crosslinking and terminated with a substituted imine |
| US5260123A (en) | 1991-06-28 | 1993-11-09 | Bridgestone Corporation | Block copolymers of polysiloxanes and copolymers of conjugated dienes and aromatic vinyl compounds, and multilayer structures containing same |
| JP3211274B2 (ja) | 1991-08-27 | 2001-09-25 | 旭化成株式会社 | 共役ジエン系重合体の製造方法 |
| JP3230532B2 (ja) | 1991-08-28 | 2001-11-19 | 旭化成株式会社 | 共役ジエン系重合体の製造法 |
| US5153271A (en) * | 1991-11-18 | 1992-10-06 | Bridgestone/Firestone, Inc. | Diene polymers and copolymers terminated by reaction with aromatic nitriles |
| US5329005A (en) | 1992-10-02 | 1994-07-12 | Bridgestone Corporation | Soluble anionic polymerization initiators and preparation thereof |
| US5332810A (en) | 1992-10-02 | 1994-07-26 | Bridgestone Corporation | Solubilized anionic polymerization initiator and preparation thereof |
| US5393721A (en) | 1992-10-16 | 1995-02-28 | Bridgestone Corporation | Anionic polymerization initiators and reduced hysteresis products therefom |
| ES2110557T3 (es) | 1992-10-30 | 1998-02-16 | Bridgestone Corp | Iniciadores de polimerizacion anionica solubles y productos de aquellos. |
| ES2119008T3 (es) | 1993-04-30 | 1998-10-01 | Bridgestone Corp | Iniciadores de polimerizacion anionica y productos de histeresis reducida de los mismos. |
| DE69410470T2 (de) | 1993-07-30 | 1998-09-17 | Nippon Zeon Co | Modifiziertes konjugiertes diencopolymer, verfahren zu dessen herstellung und zusammensetzung daraus |
| US5310798A (en) * | 1993-08-16 | 1994-05-10 | Bridgestone/Firestone, Inc. | Diene polymers and copolymers terminated with compounds having multiple-bonded nitrogen atoms and partially crosslinked with polyfunctional reagents |
| US5491230A (en) | 1993-12-29 | 1996-02-13 | Bridgestone Corporation | Anionic polymerization initiators containing adducts of cyclic secondary amines and conjugated dienes, and products therefrom |
| DE4436059A1 (de) | 1994-10-10 | 1996-04-11 | Bayer Ag | Verfahren zur Herstellung von mittels Nd-Katalysatoren polymerisierten Dienkautschuken mit niedrigem cold-flow und geringem Eigengeruch |
| US5521309A (en) | 1994-12-23 | 1996-05-28 | Bridgestone Corporation | Tertiary-amino allyl-or xylyl-lithium initiators and method of preparing same |
| US5574109A (en) | 1995-02-01 | 1996-11-12 | Bridgestone Corporation | Aminoalkyllithium compounds containing cyclic amines and polymers therefrom |
| US5496940A (en) | 1995-02-01 | 1996-03-05 | Bridgestone Corporation | Alkyllithium compounds containing cyclic amines and their use in polymerization |
| US5674932A (en) | 1995-03-14 | 1997-10-07 | The Goodyear Tire & Rubber Company | Silica reinforced rubber composition and use in tires |
| US5580919A (en) | 1995-03-14 | 1996-12-03 | The Goodyear Tire & Rubber Company | Silica reinforced rubber composition and use in tires |
| JP3555809B2 (ja) | 1995-06-19 | 2004-08-18 | 株式会社ブリヂストン | ラジアルタイヤ |
| AT405285B (de) | 1995-09-07 | 1999-06-25 | Semperit Ag | Kautschukmischung |
| US5583245A (en) | 1996-03-06 | 1996-12-10 | The Goodyear Tire & Rubber Company | Preparation of sulfur-containing organosilicon compounds |
| US5719207A (en) | 1996-03-18 | 1998-02-17 | The Goodyear Tire & Rubber Company | Silica reinforced rubber composition and tire with tread |
| RU2114128C1 (ru) | 1996-04-22 | 1998-06-27 | Открытое акционерное общество "Ефремовский завод синтетического каучука" | Способ получения маслонаполненного цис-1,4-полибутадиена |
| US5696197A (en) | 1996-06-21 | 1997-12-09 | The Goodyear Tire & Rubber Company | Heterogeneous silica carbon black-filled rubber compound |
| JP3606411B2 (ja) | 1996-07-10 | 2005-01-05 | 株式会社ブリヂストン | タイヤ加硫成型用金型およびその製造方法 |
| JP3117645B2 (ja) | 1996-09-03 | 2000-12-18 | 株式会社ブリヂストン | 空気入りラジアルタイヤ |
| US5663396A (en) | 1996-10-31 | 1997-09-02 | The Goodyear Tire & Rubber Company | Preparation of sulfur-containing organosilicon compounds |
| US5786441A (en) | 1996-12-31 | 1998-07-28 | Bridgestone Corporation | Polymers, elastomeric compounds and products thereof, derived from novel amine compounds containing side-chain organolithium moieties |
| US5684172A (en) | 1997-02-11 | 1997-11-04 | The Goodyear Tire & Rubber Company | Process for the preparation of organosilicon polysulfide compounds |
| US5684171A (en) | 1997-02-11 | 1997-11-04 | The Goodyear Tire & Rubber Company | Process for the preparation of organosilicon polysulfide compounds |
| JP4489194B2 (ja) | 1997-03-05 | 2010-06-23 | Ｊｓｒ株式会社 | 共役ジエン系重合体の製造方法 |
| EP0863165B1 (en) | 1997-03-05 | 2003-06-04 | JSR Corporation | Method of producing conjugated diene polymers |
| JP3724125B2 (ja) | 1997-07-15 | 2005-12-07 | Ｊｓｒ株式会社 | 共役ジエン系重合体の製造方法 |
| US6525118B2 (en) | 1997-07-11 | 2003-02-25 | Bridgestone Corporation | Processability of silica-filled rubber stocks with reduced hysteresis |
| US6384117B1 (en) | 1997-07-11 | 2002-05-07 | Bridgestone Corporation | Processability of silica-filled rubber stocks |
| US6221943B1 (en) | 1997-07-11 | 2001-04-24 | Bridgestone Corporation | Processability of silica-filled rubber stocks |
| EP1270581B1 (en) | 1997-08-21 | 2014-02-19 | Momentive Performance Materials Inc. | Blocked mercaptosilane coupling agents for filled rubbers |
| US5971046A (en) | 1997-09-17 | 1999-10-26 | Bridgestone/Firestone, Inc. | Method and apparatus for bonding an active tag to a patch and a tire |
| US6992147B1 (en) | 1999-11-12 | 2006-01-31 | Bridgestone Corporation | Modified polymers prepared with lanthanide-based catalysts |
| US6977281B1 (en) | 1999-11-12 | 2005-12-20 | Bridgestone Corporation | Modified polymers prepared with lanthanide-based catalysts |
| EP1237935B1 (en) | 1999-11-12 | 2007-01-24 | Bridgestone Corporation | Modified polymers prepared with lanthanide-based catalysts |
| DE60026947T2 (de) | 1999-11-12 | 2006-12-14 | Bridgestone Corp. | Modifiziertes Polymer eines konjugierten Diens, Verfahren zur Herstellung und dieses enthaltende Elastomerzusammensetzung |
| FR2802542A1 (fr) | 1999-12-20 | 2001-06-22 | Michelin Soc Tech | Composition de caoutchouc vulcanisable pour la fabrication d'un pneumatique et pneumatique dont la bande de roulement comprend une telle composition |
| US6590017B1 (en) | 2000-05-15 | 2003-07-08 | Bridgestone Corporation | Processability of silica-reinforced rubber containing an amide compound |
| US6608145B1 (en) | 2000-10-13 | 2003-08-19 | Bridgestone Corporation | Silica-reinforced rubber compounded with an organosilane tetrasulfide silica coupling agent at high mixing temperature |
| US7049308B2 (en) * | 2000-10-26 | 2006-05-23 | Duke University | C-nitroso compounds and use thereof |
| WO2002038615A1 (en) | 2000-11-10 | 2002-05-16 | Bridgestone Corporation | Functionalized high cis-1,4-polybutadiene prepared using novel functionalizing agents |
| US6943250B2 (en) * | 2001-03-06 | 2005-09-13 | Fmc Corporation | Protected aminofunctionalized polymerization initiators and methods of making and using same |
| WO2002085952A2 (de) * | 2001-04-23 | 2002-10-31 | Bayer Aktiengesellschaft | Modifizierte polymere mit einem hohen anteil an cis-ständigen doppelbindungen, ein verfahren zu deren herstellung sowie deren verwendung |
| US6579949B1 (en) | 2001-10-30 | 2003-06-17 | Bridgestone Corporation | Preparation of low hysteresis rubber by reacting a lithium polymer with a sulfur containing reagent |
| US6699813B2 (en) | 2001-11-07 | 2004-03-02 | Bridgestone Corporation | Lanthanide-based catalyst composition for the manufacture of polydienes |
| US7723440B2 (en) * | 2002-08-30 | 2010-05-25 | Bridgestone Corporation | Functionalized polymers and improved vulcanizates therefrom |
| WO2004041870A2 (en) | 2002-10-30 | 2004-05-21 | Bridgestone Corporation | The use of sulfur containing initiators for anionic polymerization of monomers |
| JP4596126B2 (ja) * | 2003-05-22 | 2010-12-08 | Ｊｓｒ株式会社 | 変性共役ジエン系重合体の製造方法およびゴム組成物 |
| US7008899B2 (en) | 2003-08-11 | 2006-03-07 | Bridgestone Corporation | Lanthanide-based catalyst composition for producing cis-1,4-polydienes |
| US7094849B2 (en) * | 2003-12-15 | 2006-08-22 | Bridgestone Corporation | Bulk polymerization process for producing polydienes |
| ITMI20040076A1 (it) | 2004-01-22 | 2004-04-22 | Polimeri Europa Spa | Procedimento per la preparazione di polibutadiene a basso grado di ranificazione |
| CN100564407C (zh) | 2004-03-02 | 2009-12-02 | 株式会社普利司通 | 本体聚合方法 |
| RU2260600C1 (ru) * | 2004-04-29 | 2005-09-20 | ОАО "Воронежсинтезкаучук" | Способ получения полимеров |
| CA2581093C (en) * | 2004-09-17 | 2014-11-18 | Angiotech Biomaterials Corporation | Multifunctional compounds for forming crosslinked biomaterials and methods of preparation and use |
| US7335712B2 (en) | 2005-04-21 | 2008-02-26 | Bridgestone Corporation | Process of producing a siloxy-functionalized polymer |
| US20060264590A1 (en) | 2005-05-20 | 2006-11-23 | Bridgestone Corporation | Anionic polymerization initiators and polymers therefrom |
| US7868110B2 (en) | 2005-05-20 | 2011-01-11 | Bridgestone Corporation | Anionic polymerization initiators and polymers therefrom |
| US7879952B2 (en) | 2005-12-28 | 2011-02-01 | Bridgestone Corporation | Functionalized polymers |
| US7671138B2 (en) | 2006-05-26 | 2010-03-02 | Bridgestone Corporation | Polymers functionized with hydrobenzamides |
| US20080051519A1 (en) * | 2006-08-28 | 2008-02-28 | Steven Luo | Polymers functionalized with nitro compounds |
| US7732534B2 (en) | 2006-08-28 | 2010-06-08 | Bridgestone Corporation | Polymers functionalized with nitro compounds |
| US8088868B2 (en) | 2006-12-19 | 2012-01-03 | Bridgestone Corporation | Polymers functionalized with protected oxime compounds |
| US8853352B2 (en) * | 2006-12-20 | 2014-10-07 | Bridgestone Corporation | Functionalized polymer and method for making |
| ZA200711158B (en) * | 2006-12-28 | 2009-03-25 | Bridgestone Corp | A method for producing functionalized cis-1,4-polydienes having high cis-1,4-linkage content and high functionality |
| US8314189B2 (en) * | 2007-10-12 | 2012-11-20 | Bridgestone Corporation | Polymers functionalized with heterocyclic nitrile compounds |
| US8268933B2 (en) * | 2007-12-31 | 2012-09-18 | Bridgestone Corporation | Polymers functionalized with polyimine compounds |
| RU2515980C2 (ru) * | 2007-12-31 | 2014-05-20 | Бриджстоун Корпорейшн | Способ получения полидиенов полимеризацией в объеме |
| US7906592B2 (en) * | 2008-07-03 | 2011-03-15 | Bridgestone Corporation | Polymers functionalized with imide compounds containing a protected amino group |
| US8188195B2 (en) * | 2008-12-31 | 2012-05-29 | Bridgestone Corporation | Polymers functionalized with nitroso compounds |
| US8338544B2 (en) * | 2009-12-21 | 2012-12-25 | Bridgestone Corporation | Polymers functionalized with polyoxime compounds and methods for their manufacture |
| JP6015598B2 (ja) | 2013-08-28 | 2016-10-26 | 信越半導体株式会社 | インゴットの切断方法及びワイヤソー |
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- 2008-10-14 ES ES08839730.2T patent/ES2563039T3/es active Active
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- 2008-10-14 CN CN201510236596.XA patent/CN104945540A/zh active Pending
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2671490C2 (ru) * | 2013-10-02 | 2018-11-01 | Бриджстоун Корпорейшн | Полимеры, функционализированные иминными соединениями, содержащими цианогруппу |
| US11066486B2 (en) | 2013-10-02 | 2021-07-20 | Bridgestone Corporation | Polymers functionalized with imine compounds containing a cyano group |
Also Published As
| Publication number | Publication date |
|---|---|
| US8314189B2 (en) | 2012-11-20 |
| ZA201002523B (en) | 2011-02-23 |
| JP2011500888A (ja) | 2011-01-06 |
| WO2009051700A1 (en) | 2009-04-23 |
| US8362156B2 (en) | 2013-01-29 |
| ES2563039T3 (es) | 2016-03-10 |
| BRPI0818443B1 (pt) | 2019-04-02 |
| US20130066016A1 (en) | 2013-03-14 |
| CN104945540A (zh) | 2015-09-30 |
| US20150267031A1 (en) | 2015-09-24 |
| US10550203B2 (en) | 2020-02-04 |
| KR20100091969A (ko) | 2010-08-19 |
| EP2203482B1 (en) | 2015-11-25 |
| KR101548396B1 (ko) | 2015-08-28 |
| CN101874044A (zh) | 2010-10-27 |
| JP6050857B2 (ja) | 2016-12-21 |
| US20090099325A1 (en) | 2009-04-16 |
| JP5475670B2 (ja) | 2014-04-16 |
| US9469741B2 (en) | 2016-10-18 |
| RU2494114C2 (ru) | 2013-09-27 |
| EP3029074B1 (en) | 2017-08-02 |
| EP2203482A1 (en) | 2010-07-07 |
| EP3029074A1 (en) | 2016-06-08 |
| US9085646B2 (en) | 2015-07-21 |
| US20170015760A1 (en) | 2017-01-19 |
| WO2009051702A1 (en) | 2009-04-23 |
| US20100280217A1 (en) | 2010-11-04 |
| BRPI0818443A2 (pt) | 2017-06-13 |
| JP2015178626A (ja) | 2015-10-08 |
| JP5757037B2 (ja) | 2015-07-29 |
| US20180319905A1 (en) | 2018-11-08 |
| JP2014145077A (ja) | 2014-08-14 |
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