ES2119008T3 - Iniciadores de polimerizacion anionica y productos de histeresis reducida de los mismos. - Google Patents
Iniciadores de polimerizacion anionica y productos de histeresis reducida de los mismos.Info
- Publication number
- ES2119008T3 ES2119008T3 ES94106485T ES94106485T ES2119008T3 ES 2119008 T3 ES2119008 T3 ES 2119008T3 ES 94106485 T ES94106485 T ES 94106485T ES 94106485 T ES94106485 T ES 94106485T ES 2119008 T3 ES2119008 T3 ES 2119008T3
- Authority
- ES
- Spain
- Prior art keywords
- products
- anionic polymerization
- initiators
- aldimines
- lithium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000010539 anionic addition polymerization reaction Methods 0.000 title abstract 2
- 239000003999 initiator Substances 0.000 title abstract 2
- 229920000642 polymer Polymers 0.000 abstract 4
- -1 LITHIUM ALDIMINES Chemical class 0.000 abstract 2
- 150000004705 aldimines Chemical class 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 229910052744 lithium Inorganic materials 0.000 abstract 2
- 239000000047 product Substances 0.000 abstract 2
- 230000009920 chelation Effects 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerization Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
LA PRESENTE INVENCION SE REFIERE A LA POLIMERIZACION ANIONICA QUE UTILIZA ALDIMINAS DE LITIO MEZCLADAS CON UN COMPUESTO ALEATORIZADOR METALICO ALCALINO ORGANICO Y, OPCIONALMENTE, UN REACTIVO DE QUELACION. LAS ALDIMINAS DE LITIO TIENEN LA FORMULA GENERAL (A)LI, DONDE A SE DERIVA DE UNA ALDIMINA SUSTITUIDA. LA INVENCION TAMBIEN SE REFIERE A POLIMEROS Y OTROS PRODUCTOS UTILIZANDO UN INICIADOR, Y METODOS DE LOS MISMOS. ADEMAS, LA INVENCION CONTEMPLA UN POLIMERO, UNA COMPOSICION POLIMERICA Y PRODUCTOS DE LOS MISMOS, QUE INCLUYEN UN GRUPO FUNCIONAL PROCEDENTE DEL PRODUCTO DE REACCION DE UNA ALDIMINA SUSTITUIDA Y DE UN COMPUESTO ORGANOLITIO. LOS POLIMEROS RESULTANTES PUEDEN MODIFICARSE CON UN AGENTE DE TERMINO, CONEXION O ENLACE, QUE PUEDEN PROPORCIONAR EL POLIMERO CON UNA FUNCIONALIDAD MULTIPLE.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US5628193A | 1993-04-30 | 1993-04-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2119008T3 true ES2119008T3 (es) | 1998-10-01 |
Family
ID=22003383
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES94106485T Expired - Lifetime ES2119008T3 (es) | 1993-04-30 | 1994-04-26 | Iniciadores de polimerizacion anionica y productos de histeresis reducida de los mismos. |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US5698646A (es) |
| EP (1) | EP0622381B1 (es) |
| JP (1) | JPH072916A (es) |
| DE (1) | DE69411984T2 (es) |
| ES (1) | ES2119008T3 (es) |
Families Citing this family (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4945868A (en) * | 1989-06-21 | 1990-08-07 | General Motors Corporation | Two cycle exhaust recycling |
| JP3319639B2 (ja) * | 1992-12-24 | 2002-09-03 | 株式会社ブリヂストン | 共役ジエン系重合体の製造方法、スチレン−ブタジエン系重合体及びそのゴム組成物 |
| FR2804120A1 (fr) * | 2000-01-24 | 2001-07-27 | Michelin Soc Tech | Composition de caoutchouc pour pneumatique comportant une charge blanche renforcante et un systeme de couplage (charge blanche/elstomere) |
| US7671139B1 (en) | 2004-06-18 | 2010-03-02 | Bridgestone Corporation | Functionalized polymers and tires made therefrom |
| CN101040007A (zh) * | 2004-10-02 | 2007-09-19 | 费尔斯通聚合物有限责任公司 | 聚合物及其在沥青组合物和沥青混凝土中的用途 |
| US7875671B2 (en) | 2006-08-03 | 2011-01-25 | Bridgestone Corporation | Process for preparing filler-dispersed polymeric compositions |
| WO2008045372A2 (en) * | 2006-10-06 | 2008-04-17 | Bridgestone Corporation | Branched polymers and methods for their synthesis and use |
| ZA200711159B (en) | 2006-12-28 | 2009-03-25 | Bridgestone Corp | Amine-containing alkoxysilyl-functionalized polymers |
| MX2009011323A (es) | 2007-04-20 | 2010-01-18 | Heritage Res Group | Composiciones de asfalto modificadas con polimero. |
| US7829624B2 (en) | 2007-06-29 | 2010-11-09 | Bridgestone Corporation | One-pot synthesis of nanoparticles and liquid polymer for rubber applications |
| US8314189B2 (en) | 2007-10-12 | 2012-11-20 | Bridgestone Corporation | Polymers functionalized with heterocyclic nitrile compounds |
| US20090326176A1 (en) * | 2007-12-28 | 2009-12-31 | Yuan-Yong Yan | Novel multifunctional initiators for anionic polymerization and polymers therefrom |
| US9732178B1 (en) | 2008-07-24 | 2017-08-15 | Bridgestone Corporation | Block copolymers including high vinyl segments |
| FR2940294B1 (fr) | 2008-12-23 | 2011-02-18 | Michelin Soc Tech | Nouveau systeme d'amorcage pour polymerisation anionique de dienes conjugues, procede de preparation d'elastomeres dieniques. |
| CN102482382B (zh) | 2009-06-30 | 2013-11-27 | 株式会社普利司通 | 羟芳基官能化聚合物 |
| US8338544B2 (en) | 2009-12-21 | 2012-12-25 | Bridgestone Corporation | Polymers functionalized with polyoxime compounds and methods for their manufacture |
| RU2557060C2 (ru) | 2009-12-22 | 2015-07-20 | Бриджстоун Корпорейшн | Улучшенная композиция модификатора уровня содержания винила и способы использования такой композиции |
| BR112012018095B1 (pt) | 2010-01-22 | 2019-11-05 | Bridgestone Corp | polímeros funcionalizados com compostos de nitrila contendo um grupo amino protegido |
| US8748531B2 (en) | 2010-12-10 | 2014-06-10 | Bridgestone Corporation | Polymers functionalized with oxime compounds containing an acyl group |
| US8962745B2 (en) | 2010-12-27 | 2015-02-24 | Bridgestone Corporation | Functionalized polymers and vulcanizates with reduced hysteretic loss |
| EP2495267B1 (en) | 2011-03-04 | 2016-10-12 | Trinseo Europe GmbH | High styrene high vinyl styrene-butadiene rubber and methods for preparation thereof |
| EP2495266A1 (en) | 2011-03-04 | 2012-09-05 | Styron Deutschland GmbH | High styrene high vinyl styrene-butadiene rubber and methods for preparation thereof |
| JP5956556B2 (ja) | 2011-03-29 | 2016-07-27 | 株式会社ブリヂストン | シリル化アミノ基を含有するカルボン酸またはチオカルボン酸エステルで官能化されたポリマー |
| ES2545332T3 (es) * | 2011-06-22 | 2015-09-10 | Trinseo Europe Gmbh | Caucho de estireno-butadieno de alto contenido en estireno, alto contenido en vinilo, con distribución de pesos moleculares estrecha y métodos para la preparación de los mismos |
| PL2537871T3 (pl) | 2011-06-22 | 2019-03-29 | Trinseo Europe Gmbh | Kauczuk styrenowo-butadienowy o dużej zawartości styrenu i o dużej zawartości winylu o wąskim rozkładzie masy cząsteczkowej i sposoby jego otrzymywania |
| US8993683B2 (en) | 2011-08-31 | 2015-03-31 | Bridgestone Corporation | Polymers functionalized with lactones or thiolactones containing a protected amino group |
| EP2780177B1 (en) | 2011-11-18 | 2016-03-23 | Bridgestone Corporation | Method for producing polydienes and polydiene copolymers with reduced cold flow |
| KR101933751B1 (ko) | 2011-12-09 | 2018-12-28 | 가부시키가이샤 브리지스톤 | 감소된 저온 유동을 갖는 폴리디엔 및 폴리디엔 공중합체를 생산하는 방법 |
| CN109553720A (zh) | 2012-05-01 | 2019-04-02 | 株式会社普利司通 | 具有有机膦官能的聚二烯和二烯共聚物 |
| US9469706B2 (en) | 2012-06-08 | 2016-10-18 | Bridgestone Corporation | Polymers functionalized with unsaturated heterocycles containing a protected amino group |
| US9663637B2 (en) | 2012-12-31 | 2017-05-30 | Bridgestone Corporation | Polymers functionalized with unsaturated heterocycles containing an azolinyl group |
| US9127092B2 (en) | 2012-12-31 | 2015-09-08 | Bridgestone Corporation | Method for producing polydienes and polydiene copolymers with reduced cold flow |
| WO2014107447A1 (en) | 2013-01-02 | 2014-07-10 | Bridgestone Corporation | Functionalized polymers |
| WO2014149931A1 (en) | 2013-03-15 | 2014-09-25 | Bridgestone Corporation | Polymers functionalized with heterocyclic imines |
| EP3052531B1 (en) | 2013-10-02 | 2024-07-24 | Bridgestone Corporation | Polymers functionalized with imine compounds containing a cyano group |
| JP2017501289A (ja) | 2013-12-12 | 2017-01-12 | ファイアストン ポリマーズ エルエルシー | 官能化ポリマーを含むポリマー組成物の製造方法 |
| US10030083B2 (en) | 2014-05-15 | 2018-07-24 | Bridgestone Corporation | Polymers functionalized with protected oxime compounds containing a cyano group |
| EP3204429B1 (en) | 2014-10-07 | 2018-09-05 | Bridgestone Corporation | Method for producing polydienes and polydiene copolymers with reduced cold flow |
| US10077323B2 (en) | 2015-07-24 | 2018-09-18 | Bridgestone Corporation | Polymers functionalized with imine compounds containing a protected thiol group |
| US10519266B2 (en) | 2015-09-23 | 2019-12-31 | Bridgestone Corporation | Polydienes and diene copolymers using 1,1-bis(hydrocarbylthio)hydrocarbyl-1-ene compounds |
| KR102019841B1 (ko) * | 2015-12-22 | 2019-09-10 | 주식회사 엘지화학 | 변성 공액 디엔계 중합체의 제조방법 및 이에 의해 제조된 변성 공액 디엔계 중합체 |
| KR102234506B1 (ko) * | 2015-12-22 | 2021-03-31 | 주식회사 엘지화학 | 이민 유도체 화합물 및 이의 제조방법 |
| US12054573B2 (en) | 2020-02-05 | 2024-08-06 | Bridgestone Corporation | Functionalized polymers having thermoresponsive behavior |
Family Cites Families (56)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2849432A (en) * | 1956-02-06 | 1958-08-26 | Firestone Tire & Rubber Co | Polymerization of diolefines |
| US3317918A (en) * | 1956-08-21 | 1967-05-02 | Firestone Tire & Rubber Co | Butadiene polymers prepared with a lithium based catalyst characterized by having at least 29 percent of the butadiene as cis-1, 4 |
| US3178398A (en) * | 1960-10-24 | 1965-04-13 | Phillips Petroleum Co | Production and curing of polymers containing terminally reactive nitrogen |
| US3109871A (en) * | 1960-12-27 | 1963-11-05 | Phillips Petroleum Co | Production and curing of polyfunctional terminally reactive polymers |
| US3177190A (en) * | 1961-06-14 | 1965-04-06 | Phillips Petroleum Co | Preparing and curing compositions of terminally reactive polymers |
| US3290414A (en) * | 1963-05-20 | 1966-12-06 | Shell Oil Co | Block copolymers of alpha c1-4 alkyl styrene and ethylene |
| US3294768A (en) * | 1963-11-14 | 1966-12-27 | Phillips Petroleum Co | Preparation of conjugated diene polymers |
| DE1300240B (de) * | 1964-01-22 | 1969-07-31 | Bayer Ag | Verfahren zur Herstellung von Polymerisaten konjugierter Diolefine |
| US3439049A (en) * | 1964-05-11 | 1969-04-15 | Phillips Petroleum Co | Organolithium polymerization initiator |
| US3393182A (en) * | 1965-02-23 | 1968-07-16 | Phillips Petroleum Co | Prevention of cold flow in polymers of conjugated dienes |
| US3862077A (en) * | 1971-02-22 | 1975-01-21 | Cpc International Inc | Stable latexes of a chemically joined, phase separated thermoplastic graft copolymer and method for preparing the same |
| US4085265A (en) * | 1972-08-25 | 1978-04-18 | Nippon Oil Company, Limited | Process for isomerization of lower polymers of butadiene |
| JPS5633410B2 (es) * | 1972-11-15 | 1981-08-04 | ||
| DE2355941A1 (de) * | 1973-11-09 | 1975-05-15 | Bayer Ag | Polymerisation und copolymerisation von dienen |
| US4026865A (en) * | 1974-07-01 | 1977-05-31 | Phillips Petroleum Company | Preparation of organometal terminated polymers |
| DD138070A1 (de) * | 1974-09-20 | 1979-10-10 | Peter Knoth | Verfahren zur polymerisation von konjugierten dienen zu"lebenden"polymeren |
| US4015061A (en) * | 1975-02-14 | 1977-03-29 | The Firestone Tire & Rubber Company | Protected amino-functional initiators and amino-terminated polymers and their production |
| US4316001A (en) * | 1976-05-26 | 1982-02-16 | Societe Nationale Des Poudres Et Explosifs | Anionic polymerization of heterocyclic monomers with alkali metal amide hydroxylated compound initiator |
| JPS5465788A (en) * | 1977-11-07 | 1979-05-26 | Denki Kagaku Kogyo Kk | Preparation of copolymer |
| US4247418A (en) * | 1979-10-18 | 1981-01-27 | The Firestone Tire & Rubber Company | Polymerization catalyst and process for polymerizing dienes therewith |
| JPS5773030A (en) * | 1980-09-20 | 1982-05-07 | Bridgestone Corp | Rubber composition for tire |
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| US4414372A (en) * | 1982-06-17 | 1983-11-08 | E. I. Du Pont De Nemours & Co. | Process for preparing living polymers |
| US4476240A (en) * | 1982-07-01 | 1984-10-09 | The Firestone Tire & Rubber Company | Catalyst system containing an anionic initiator based on lithium and phosphine oxide modifier |
| JPS59140240A (ja) * | 1983-01-31 | 1984-08-11 | Japan Synthetic Rubber Co Ltd | ゴム組成物 |
| JPS59164308A (ja) * | 1983-03-09 | 1984-09-17 | Asahi Chem Ind Co Ltd | ポリエチレンの製造方法 |
| US4429091A (en) * | 1983-03-09 | 1984-01-31 | The Firestone Tire & Rubber Company | Oligomeric oxolanyl alkanes as modifiers for polymerization of dienes using lithium-based initiators |
| CH654585A5 (de) * | 1983-03-24 | 1986-02-28 | Schweizerische Viscose | Zusammensetzung und verfahren zur praeadhaerisierung von synthetischen faeden. |
| CA1217122A (en) * | 1983-06-01 | 1987-01-27 | John Timar | Pneumatic tire inner liner having puncture sealing characteristics |
| FR2567135B1 (fr) * | 1984-07-03 | 1989-01-13 | Asahi Chemical Ind | Polymere ou copolymere de butadiene et procede de preparation |
| US4616069A (en) * | 1984-10-26 | 1986-10-07 | Nippon Zeon Co., Ltd. | Process for making diene polymer rubbers |
| JPS61103901A (ja) * | 1984-10-26 | 1986-05-22 | Nippon Zeon Co Ltd | ジエン系共重合体ゴムの製造方法 |
| JPS61225202A (ja) * | 1985-03-29 | 1986-10-07 | Nippon Zeon Co Ltd | ゴムの変性方法 |
| IT1186743B (it) * | 1985-07-01 | 1987-12-16 | Eniricerche Spa | Metodo per la terminazione di polimeri ottenuti per polimerizzazione anionica di monomeri dienici e/o vinilaromatici e composti adatti allo scopo |
| IT1206738B (it) * | 1985-07-01 | 1989-05-03 | Eniricerche Spa | Metodo per la terminazione di polimeri viventi ottenuti per polimerizzazione anionica di monomeri dienici e/o vinilaromatici e composti adatti allo scopo. |
| IT1186746B (it) * | 1985-07-01 | 1987-12-16 | Eniricerche Spa | Metodo per la terminazione di polimeri viventi e composti adatti allo scopo |
| EP0245505B2 (en) * | 1985-10-11 | 1996-08-14 | Asahi Kasei Kogyo Kabushiki Kaisha | Terminal-modified block copolymer and composition containing said copolymer |
| US4835209A (en) * | 1986-01-10 | 1989-05-30 | Asahi Kasei Kogyo Kabushiki Kaisha | Rubber for tire treads and compositions thereof |
| US4647634A (en) * | 1986-03-10 | 1987-03-03 | The Goodyear Tire & Rubber Company | Randomizers for use in solution polymerizations |
| DE3611421A1 (de) * | 1986-04-05 | 1987-10-08 | Basf Ag | Polymerisate mit aminogruppen, deren herstellung und verwendung |
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| US4843120A (en) * | 1986-09-29 | 1989-06-27 | The Goodyear Tire & Rubber Company | Rubber composition |
| DE3639569A1 (de) * | 1986-11-20 | 1988-06-01 | Basf Ag | Am kettenende funktionalisierte polymere und verfahren zu ihrer herstellung |
| US4845165A (en) * | 1987-03-13 | 1989-07-04 | The Goodyear Tire & Rubber Company | Anionic diene polymerization process with branching |
| CA1303264C (en) * | 1987-05-11 | 1992-06-09 | Hiroyoshi Takao | Modified diene polymer rubbers |
| JPH0778151B2 (ja) * | 1987-07-17 | 1995-08-23 | 日本合成ゴム株式会社 | ゴム組成物 |
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| US4935471A (en) * | 1987-10-15 | 1990-06-19 | The Goodyear Tire & Rubber Company | Capped polydienes |
| CA1322750C (en) * | 1987-12-17 | 1993-10-05 | Mitsui Toatsu Chemicals, Inc. | Preparation process of unsaturated carboxylic acid amide |
| US5149457A (en) * | 1989-06-30 | 1992-09-22 | Cyprus Foote Mineral Company | Stable mixed lithium amide reagent compositions |
| FR2660738B1 (fr) * | 1990-04-05 | 1994-10-28 | Cma | Installation permettant de realiser la refrigeration (ou rechauffement) rapide de produits emballes, notamment de bouteilles. |
| US5153159A (en) * | 1990-04-09 | 1992-10-06 | Bridgestone/Firestone, Inc. | Elastomers and products having reduced hysteresis |
| US5066729A (en) * | 1990-04-09 | 1991-11-19 | Bridgestone/Firestone, Inc. | Diene polymers and copolymers terminated by reaction with n-alkyl and n-aryl imines |
| US5292790A (en) * | 1991-07-31 | 1994-03-08 | Bridgestone Corporation | Conjugated diene series rubber compositions |
-
1994
- 1994-04-26 ES ES94106485T patent/ES2119008T3/es not_active Expired - Lifetime
- 1994-04-26 DE DE69411984T patent/DE69411984T2/de not_active Expired - Lifetime
- 1994-04-26 EP EP94106485A patent/EP0622381B1/en not_active Expired - Lifetime
- 1994-04-28 JP JP6111931A patent/JPH072916A/ja active Pending
-
1995
- 1995-06-06 US US08/467,370 patent/US5698646A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0622381B1 (en) | 1998-07-29 |
| JPH072916A (ja) | 1995-01-06 |
| US5698646A (en) | 1997-12-16 |
| DE69411984D1 (de) | 1998-09-03 |
| EP0622381A1 (en) | 1994-11-02 |
| DE69411984T2 (de) | 1998-12-10 |
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| FG2A | Definitive protection |
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