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RU2008106330A - METHOD FOR PRODUCING TRICYCLO [4.2.1.02,5] NONAN-3-SPIRO (3'-Ethyl-3'-ALUMINACYCLOPENTANE) - Google Patents

METHOD FOR PRODUCING TRICYCLO [4.2.1.02,5] NONAN-3-SPIRO (3'-Ethyl-3'-ALUMINACYCLOPENTANE) Download PDF

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Publication number
RU2008106330A
RU2008106330A RU2008106330/04A RU2008106330A RU2008106330A RU 2008106330 A RU2008106330 A RU 2008106330A RU 2008106330/04 A RU2008106330/04 A RU 2008106330/04A RU 2008106330 A RU2008106330 A RU 2008106330A RU 2008106330 A RU2008106330 A RU 2008106330A
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Russia
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tricyclo
aluminacyclopentane
spiro
ethyl
nonane
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RU2008106330/04A
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Russian (ru)
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RU2381230C2 (en
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Усеин Меметович Джемилев (RU)
Усеин Меметович Джемилев
Владимир Анатольевич Дьяконов (RU)
Владимир Анатольевич Дьяконов
Ольга Александровна Трапезникова (RU)
Ольга Александровна Трапезникова
Асхат Габдрахманович Ибрагимов (RU)
Асхат Габдрахманович Ибрагимов
Леонард Мухибович Халилов (RU)
Леонард Мухибович Халилов
Татьяна Викторовна Тюмкина (RU)
Татьяна Викторовна Тюмкина
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ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА Российской академии наук (RU)
ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА Российской Академии Наук
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Priority to RU2008106330/04A priority Critical patent/RU2381230C2/en
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Abstract

Способ получения тpициклo[4.2.1.02,5]нoнaн-3-cпиpo(3'-этил-3'-алюминациклопентана) общей формулы (1) ! ! характеризующийся тем, что 3-метилентрицикло[4.2.1.02,5]нонан подвергают взаимодействию с триэтилалюминием (Еt3Аl) в присутствии катализатора цирконацендихлорида (Cp2ZrCl2) в мольном соотношении 3-метилен-тpициклo[4.2.1.02,5]нoнaн:Et3Al:Cp2ZrCl2=10:(10-14):(0.4-0.6) в атмосфере аргона при температуре 20°С и нормальном давлении в гексане в течение 8-12 ч.The method of producing tricyclo [4.2.1.02,5] nonane-3-spiro (3'-ethyl-3'-aluminacyclopentane) of the general formula (1)! ! characterized in that 3-methylene tricyclo [4.2.1.02.5] nonane is reacted with triethylaluminium (Et3Al) in the presence of a zirconacenedichloride catalyst (Cp2ZrCl2) in a molar ratio of 3-methylene-tricyclo [4.2.1.02.5] nonane: Et3Al: Cp2ZrCl 10: (10-14) :( 0.4-0.6) in an argon atmosphere at a temperature of 20 ° C and normal pressure in hexane for 8-12 hours.

Claims (1)

Способ получения тpициклo[4.2.1.02,5]нoнaн-3-cпиpo(3'-этил-3'-алюминациклопентана) общей формулы (1)The method of obtaining tricyclo [4.2.1.0 2,5 ] nonan-3-spiro (3'-ethyl-3'-aluminacyclopentane) of the general formula (1)
Figure 00000001
Figure 00000001
 характеризующийся тем, что 3-метилентрицикло[4.2.1.02,5]нонан подвергают взаимодействию с триэтилалюминием (Еt3Аl) в присутствии катализатора цирконацендихлорида (Cp2ZrCl2) в мольном соотношении 3-метилен-тpициклo[4.2.1.02,5]нoнaн:Et3Al:Cp2ZrCl2=10:(10-14):(0.4-0.6) в атмосфере аргона при температуре 20°С и нормальном давлении в гексане в течение 8-12 ч. characterized in that 3-methylene tricyclo [4.2.1.0 2,5 ] nonane is reacted with triethylaluminium (Et 3 Al) in the presence of a zirconacenedichloride catalyst (Cp 2 ZrCl 2 ) in a molar ratio of 3-methylene-tricyclo [4.2.1.0 2,5 ] nonane: Et 3 Al: Cp 2 ZrCl 2 = 10: (10-14) :( 0.4-0.6) in an argon atmosphere at a temperature of 20 ° С and normal pressure in hexane for 8-12 h.
RU2008106330/04A 2008-02-18 2008-02-18 Method of producing tricyclo[4.2.1.02,5]nonane-3-spiro (3'-ethyl-3'-aluminacyclopentane) RU2381230C2 (en)

Priority Applications (1)

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RU2008106330/04A RU2381230C2 (en) 2008-02-18 2008-02-18 Method of producing tricyclo[4.2.1.02,5]nonane-3-spiro (3'-ethyl-3'-aluminacyclopentane)

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RU2008106330/04A RU2381230C2 (en) 2008-02-18 2008-02-18 Method of producing tricyclo[4.2.1.02,5]nonane-3-spiro (3'-ethyl-3'-aluminacyclopentane)

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RU2381230C2 RU2381230C2 (en) 2010-02-10

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RU2584686C1 (en) * 2014-11-21 2016-05-20 Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук Method for combined synthesis of 2,6,8,11-tetraethyl-4-phenyl-1,7-dithia-4-aza-2,6,8,11-tetraaluminacycloundecane and 2,4,7,9,12-pentaethyl-5-phenyl-18-dithia-5-aza-2,4,7,9,12-pentaaluminacyclododecane
RU2594560C2 (en) * 2014-11-21 2016-08-20 Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук Method for producing 2,6,8,11-tetraethyl-4-aryl-1,7-dithia-4-aza-2,6,8,11-tetraaluminacikloundecanes

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DE3817090A1 (en) * 1988-05-19 1989-11-30 Merck Patent Gmbh CYCLIC METAL ORGANIC COMPOUNDS
RU2160269C1 (en) * 1999-03-15 2000-12-10 Институт нефтехимии и катализа Академии наук Республики Башкортостан и УНЦ РАН Method of combined preparation of 1-ethyl -2,3-diackyl (phenyl)alumacyclopropenes, 1-ethyl-2,3-dialkyl (phenyl)alumacyclopent-2-enes and 1-ethyl-2,3,4,5-tetraalylalumacyclopentadienes
RU2295532C1 (en) * 2005-08-12 2007-03-20 Открытое акционерное общество "Нижнекамскнефтехим" Method for preparing aluminum alkyls
RU2295530C1 (en) * 2005-10-17 2007-03-20 Институт нефтехимии и катализа РАН Method for preparing 11-chloro-1,8,9,10-tetraalkyl-11-aluminatricyclo[6.2.1.02,7]undec-9-ene-3,6-diones
RU2313531C1 (en) * 2006-05-06 2007-12-27 Институт нефтехимии и катализа РАН Method for preparing 1-ethyl-3,4-di-(7-octenyl)-aluminacyclopentane

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