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RU2008105276A - METHOD FOR PRODUCING 11-ETHYL-11-ALUMINETETRACYCLO [11.2.1.02,12.04,11] HEXADETS-3 (10) -ENA - Google Patents

METHOD FOR PRODUCING 11-ETHYL-11-ALUMINETETRACYCLO [11.2.1.02,12.04,11] HEXADETS-3 (10) -ENA Download PDF

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RU2008105276A
RU2008105276A RU2008105276/04A RU2008105276A RU2008105276A RU 2008105276 A RU2008105276 A RU 2008105276A RU 2008105276/04 A RU2008105276/04 A RU 2008105276/04A RU 2008105276 A RU2008105276 A RU 2008105276A RU 2008105276 A RU2008105276 A RU 2008105276A
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Russia
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ethyl
cyclooctin
norbornene
dichloride
hexadets
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RU2008105276/04A
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Russian (ru)
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RU2375366C2 (en
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Усеин Меметович Джемилев (RU)
Усеин Меметович Джемилев
Владимир Анатольевич Дьяконов (RU)
Владимир Анатольевич Дьяконов
Лилия Фанисовна Галимова (RU)
Лилия Фанисовна Галимова
Асхат Габдрахманович Ибрагимов (RU)
Асхат Габдрахманович Ибрагимов
Галина Аркадьевна Джемилева (RU)
Галина Аркадьевна Джемилева
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ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА Российской академии наук (RU)
ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА Российской Академии Наук
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Abstract

Способ получения 11-этил-11-алюминатетрацикло[11.2.1.02,12.04.11]-гексадец-3(10)-ена (1) общей формулы (1), ! ! характеризующийся тем, что эквимольную смесь циклооктина и норборнена подвергают взаимодействию с этилалюминийдихлоридом (EtAlCl2) в присутствии порошка магния и катализатора цирконацендихлорида (Cp2ZrCl2) в мольном соотношении циклооктин:норборнен:EtAlCl2:Mg:Cp2ZrCl2=10:10:(10-14):(10-14):(0.4-0.6) в атмосфере аргона при температуре 20°С и нормальном давлении в тетрагидрофуране в течение 8-12 ч.A method of obtaining 11-ethyl-11-aluminate tetracyclo [11.2.1.02,12.04.11] -hexadec-3 (10) -ene (1) of the general formula (1),! ! characterized in that the equimolar mixture of cyclooctin and norbornene is reacted with ethyl aluminum dichloride (EtAlCl2) in the presence of magnesium powder and a catalyst of zirconocenti dichloride (Cp2ZrCl2) in a molar ratio cyclooctin: norbornene: EtAlCl2: Mg: Cp2ZrCl: 10 = 10-14) :( 0.4-0.6) in an argon atmosphere at a temperature of 20 ° C and normal pressure in tetrahydrofuran for 8-12 hours

Claims (1)

Способ получения 11-этил-11-алюминатетрацикло[11.2.1.02,12.04.11]-гексадец-3(10)-ена (1) общей формулы (1),A process for preparing 11-ethyl-11-alyuminatetratsiklo [11.2.1.0 2,12 .0 4.11] -geksadets-3 (10) -ene (1) of the general formula (1),
Figure 00000001
Figure 00000001
 характеризующийся тем, что эквимольную смесь циклооктина и норборнена подвергают взаимодействию с этилалюминийдихлоридом (EtAlCl2) в присутствии порошка магния и катализатора цирконацендихлорида (Cp2ZrCl2) в мольном соотношении циклооктин:норборнен:EtAlCl2:Mg:Cp2ZrCl2=10:10:(10-14):(10-14):(0.4-0.6) в атмосфере аргона при температуре 20°С и нормальном давлении в тетрагидрофуране в течение 8-12 ч. characterized in that the equimolar mixture of cyclooctin and norbornene is reacted with ethyl aluminum dichloride (EtAlCl 2 ) in the presence of magnesium powder and a catalyst of zirconocenti dichloride (Cp 2 ZrCl 2 ) in a molar ratio cyclooctin: norbornene: EtAlCl 2 : Mg: Cp 2 ZrCl 2 = : (10-14) :( 10-14) :( 0.4-0.6) in an argon atmosphere at a temperature of 20 ° C and normal pressure in tetrahydrofuran for 8-12 hours.
RU2008105276/04A 2008-02-12 2008-02-12 Method of producing 11-ethyl-11-aluminatetracyclo[11.2.1.02,12.04,11]hexadec-3( 10 )-ene RU2375366C2 (en)

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RU2008105276/04A RU2375366C2 (en) 2008-02-12 2008-02-12 Method of producing 11-ethyl-11-aluminatetracyclo[11.2.1.02,12.04,11]hexadec-3( 10 )-ene

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RU2008105276/04A RU2375366C2 (en) 2008-02-12 2008-02-12 Method of producing 11-ethyl-11-aluminatetracyclo[11.2.1.02,12.04,11]hexadec-3( 10 )-ene

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DE3817090A1 (en) * 1988-05-19 1989-11-30 Merck Patent Gmbh CYCLIC METAL ORGANIC COMPOUNDS
RU2160269C1 (en) * 1999-03-15 2000-12-10 Институт нефтехимии и катализа Академии наук Республики Башкортостан и УНЦ РАН Method of combined preparation of 1-ethyl -2,3-diackyl (phenyl)alumacyclopropenes, 1-ethyl-2,3-dialkyl (phenyl)alumacyclopent-2-enes and 1-ethyl-2,3,4,5-tetraalylalumacyclopentadienes
RU2295532C1 (en) * 2005-08-12 2007-03-20 Открытое акционерное общество "Нижнекамскнефтехим" Method for preparing aluminum alkyls
RU2295530C1 (en) * 2005-10-17 2007-03-20 Институт нефтехимии и катализа РАН Method for preparing 11-chloro-1,8,9,10-tetraalkyl-11-aluminatricyclo[6.2.1.02,7]undec-9-ene-3,6-diones
RU2313531C1 (en) * 2006-05-06 2007-12-27 Институт нефтехимии и катализа РАН Method for preparing 1-ethyl-3,4-di-(7-octenyl)-aluminacyclopentane

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