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RU2008143882A - METHOD FOR PRODUCING EXO-PENTACYCLO [5.4.0.02,9.03,6.08,10] UNDEKAN-4-SPIRO-1 '- (3'-Ethyl-3'-ALUMIN) CYCLOPENTANE - Google Patents

METHOD FOR PRODUCING EXO-PENTACYCLO [5.4.0.02,9.03,6.08,10] UNDEKAN-4-SPIRO-1 '- (3'-Ethyl-3'-ALUMIN) CYCLOPENTANE Download PDF

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RU2008143882A
RU2008143882A RU2008143882/04A RU2008143882A RU2008143882A RU 2008143882 A RU2008143882 A RU 2008143882A RU 2008143882/04 A RU2008143882/04 A RU 2008143882/04A RU 2008143882 A RU2008143882 A RU 2008143882A RU 2008143882 A RU2008143882 A RU 2008143882A
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Russia
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pentacyclo
exo
cyclopentane
spiro
ethyl
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RU2008143882/04A
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Russian (ru)
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RU2404187C2 (en
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Усеин Меметович Джемилев (RU)
Усеин Меметович Джемилев
Владимир Анатольевич Дьяконов (RU)
Владимир Анатольевич Дьяконов
Ольга Александровна Трапезникова (RU)
Ольга Александровна Трапезникова
Асхат Габдрахманович Ибрагимов (RU)
Асхат Габдрахманович Ибрагимов
Галина Аркадьевна Джемилева (RU)
Галина Аркадьевна Джемилева
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Учреждение Российской академии наук ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА РАН (RU)
Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран
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Priority to RU2008143882/04A priority Critical patent/RU2404187C2/en
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Abstract

Способ получения экзо-пентацикло[5.4.0.02,9.03,6.08,10]ундекан-4-спиро-1′-(3′-этил-3′-алюмина)-циклопентана общей формулы (1) ! ! характеризующийся тем, что 4-метилен-экзо-пентациклo[5.4.0.02,9.03,6.08,10]yндекан подвергают взаимодействию с триэтилалюминием (Et3Аl) в присутствии катализатора цирконацендихлорида (Cp2ZrCl2) в мольном соотношении 4-метилен-экзо-пентациклo[5.4.0.02,9.03,6.08,10]yндекан:Et3Al:Cp2ZrC2=10:(10-14):(0,6-1,0) в атмосфере аргона при нормальном давлении в гексане в течение 5-7 ч. The method of producing exo-pentacyclo [5.4.0.02,9.03,6.08,10] undecane-4-spiro-1 ′ - (3′-ethyl-3′-aluminine) -cyclopentane of the general formula (1)! ! characterized in that 4-methylene-exo-pentacyclo [5.4.0.02,9.03,6.08,10] undecane is reacted with triethylaluminium (Et3Al) in the presence of a catalyst of zirconacenedichloride (Cp2ZrCl2) in a molar ratio of 4-methylene-exo-pentacyclo [5.4. 0.02.9.03.6.08.10] undecane: Et3Al: Cp2ZrC2 = 10: (10-14) :( 0.6-1.0) in an argon atmosphere at normal pressure in hexane for 5-7 hours.

Claims (1)

Способ получения экзо-пентацикло[5.4.0.02,9.03,6.08,10]ундекан-4-спиро-1′-(3′-этил-3′-алюмина)-циклопентана общей формулы (1)The method of producing exo-pentacyclo [5.4.0.0 2.9 .0 3.6 .0 8.10 ] undecane-4-spiro-1 ′ - (3′-ethyl-3′-aluminine) -cyclopentane of the general formula (1)
Figure 00000001
Figure 00000001
 характеризующийся тем, что 4-метилен-экзо-пентациклo[5.4.0.02,9.03,6.08,10]yндекан подвергают взаимодействию с триэтилалюминием (Et3Аl) в присутствии катализатора цирконацендихлорида (Cp2ZrCl2) в мольном соотношении 4-метилен-экзо-пентациклo[5.4.0.02,9.03,6.08,10]yндекан:Et3Al:Cp2ZrC2=10:(10-14):(0,6-1,0) в атмосфере аргона при нормальном давлении в гексане в течение 5-7 ч. characterized in that 4-methylene-exo-pentacyclo [5.4.0.0 2.9 .0 3.6 .0 8.10 ] undecane is reacted with triethylaluminum (Et 3 Al) in the presence of a catalyst of zirconacene dichloride (Cp 2 ZrCl 2 ) in molar ratio of 4-methylene-exo-pentacyclo [5.4.0.0 2.9 .0 3.6 .0 8.10 ] undecane: Et 3 Al: Cp 2 ZrC 2 = 10: (10-14) :( 0.6 -1.0) in an argon atmosphere at normal pressure in hexane for 5-7 hours
RU2008143882/04A 2008-11-05 2008-11-05 exo-PENTACYCLO[5.4.0.02,9.03,6.08,10]UNDECANE-4-SPIRO-1'-(3'-ETHYL-3'-ALUMINIUM)CYCLOPENTANE SYNTHESIS METHOD RU2404187C2 (en)

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RU2008143882/04A RU2404187C2 (en) 2008-11-05 2008-11-05 exo-PENTACYCLO[5.4.0.02,9.03,6.08,10]UNDECANE-4-SPIRO-1'-(3'-ETHYL-3'-ALUMINIUM)CYCLOPENTANE SYNTHESIS METHOD

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RU2008143882/04A RU2404187C2 (en) 2008-11-05 2008-11-05 exo-PENTACYCLO[5.4.0.02,9.03,6.08,10]UNDECANE-4-SPIRO-1'-(3'-ETHYL-3'-ALUMINIUM)CYCLOPENTANE SYNTHESIS METHOD

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RU2275374C2 (en) * 2004-07-05 2006-04-27 ГУ Институт нефтехимии и катализа АН РБ и УНЦ РАН Method for preparing 1,7,8,9-tetraalkyl-10-ethyl-4-oxo-10-aluminatricyclo[5,2,1,02,6]-dec-8-ene-3,5-diones
RU2342393C2 (en) * 2007-01-30 2008-12-27 Институт нефтехимии и катализа РАН METHOD OF OBTAINING 1-ETHYL-1,2,3,3a,4,5,6,7,8,9-DECAHYDROCYCLONONE[b]ALUMINACYCLOPENTANE

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