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RU2008105515A - METHOD FOR PRODUCING 9-ETHYL-11-ALKYL-9-ALUMINABicyclo [6.3.01.8] UNDEC-1 (8) -ENES - Google Patents

METHOD FOR PRODUCING 9-ETHYL-11-ALKYL-9-ALUMINABicyclo [6.3.01.8] UNDEC-1 (8) -ENES Download PDF

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RU2008105515A
RU2008105515A RU2008105515/04A RU2008105515A RU2008105515A RU 2008105515 A RU2008105515 A RU 2008105515A RU 2008105515/04 A RU2008105515/04 A RU 2008105515/04A RU 2008105515 A RU2008105515 A RU 2008105515A RU 2008105515 A RU2008105515 A RU 2008105515A
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ene
ethyl
enes
undec
alkyl
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RU2008105515/04A
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RU2373214C1 (en
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Усеин Меметович Джемилев (RU)
Усеин Меметович Джемилев
Владимир Анатольевич Дьяконов (RU)
Владимир Анатольевич Дьяконов
Лилия Фанисовна Галимова (RU)
Лилия Фанисовна Галимова
Асхат Габдрахманович Ибрагимов (RU)
Асхат Габдрахманович Ибрагимов
Галина Аркадьевна Джемилева (RU)
Галина Аркадьевна Джемилева
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ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА Российской академии наук (RU)
ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА Российской Академии Наук
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Abstract

Способ получения 9-этил-11-алкил-9-алюминабициклo[6.3.01,8]ундец-1(8)-енов (1) общей формулы (1), ! ! характеризующийся тем, что эквимольную смесь циклооктина и α-олефина (гекс-1-ен, окт-1-ен, дец-1-ен) подвергают взаимодействию с этилалюминийдихлоридом (EtAlCl2) в присутствии магния (порошок) и катализатора цирконацендихлорида (Ср2ZrCl2) в мольном соотношении циклооктин: α-олефин: EtAlCl2:Mg:Cp2ZrCl2=10:10:(10-14):(10-14):(0.4-0.6) в атмосфере аргона при температуре 20°С и нормальном давлении в тетрагидрофуране в течение 8-12 ч.The method of obtaining 9-ethyl-11-alkyl-9-aluminobicyclo [6.3.01.8] undec-1 (8) -enes (1) of the general formula (1),! ! characterized in that the equimolar mixture of cyclooctin and α-olefin (hex-1-ene, oct-1-ene, dec-1-ene) is reacted with ethyl aluminum dichloride (EtAlCl2) in the presence of magnesium (powder) and a catalyst for zirconacenedichloride (Cp2ZrCl2) in the molar ratio of cyclooctin: α-olefin: EtAlCl2: Mg: Cp2ZrCl2 = 10: 10: (10-14) :( 10-14) :( 0.4-0.6) in an argon atmosphere at a temperature of 20 ° C and normal pressure in tetrahydrofuran for 8-12 hours

Claims (1)

Способ получения 9-этил-11-алкил-9-алюминабициклo[6.3.01,8]ундец-1(8)-енов (1) общей формулы (1),The method of obtaining 9-ethyl-11-alkyl-9-aluminobicyclo [6.3.0 1.8 ] undec-1 (8) -enes (1) of the general formula (1),
Figure 00000001
Figure 00000001
 характеризующийся тем, что эквимольную смесь циклооктина и α-олефина (гекс-1-ен, окт-1-ен, дец-1-ен) подвергают взаимодействию с этилалюминийдихлоридом (EtAlCl2) в присутствии магния (порошок) и катализатора цирконацендихлорида (Ср2ZrCl2) в мольном соотношении циклооктин: α-олефин: EtAlCl2:Mg:Cp2ZrCl2=10:10:(10-14):(10-14):(0.4-0.6) в атмосфере аргона при температуре 20°С и нормальном давлении в тетрагидрофуране в течение 8-12 ч. characterized in that the equimolar mixture of cyclooctin and α-olefin (hex-1-ene, oct-1-ene, dec-1-ene) is reacted with ethyl aluminum dichloride (EtAlCl 2 ) in the presence of magnesium (powder) and a catalyst of zirconacenedichloride (Cp 2 ZrCl 2 ) in a molar ratio of cyclooctin: α-olefin: EtAlCl 2 : Mg: Cp 2 ZrCl 2 = 10: 10: (10-14) :( 10-14) :( 0.4-0.6) in argon atmosphere at a temperature of 20 ° C and normal pressure in tetrahydrofuran for 8-12 hours
RU2008105515/04A 2008-02-12 2008-02-12 Method of producing 9-ethyl-11-alkyl-9-aluminabicyclo[6,3,01,8]undec-1(8)-enes RU2373214C1 (en)

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RU2152393C1 (en) * 1996-01-29 2000-07-10 Институт нефтехимии и катализа с опытным заводом АН РБ Method of synthesis of 1-ethyl-2,3-diphenyl(alkyl)alumacyclo-propenes
RU2275374C2 (en) * 2004-07-05 2006-04-27 ГУ Институт нефтехимии и катализа АН РБ и УНЦ РАН Method for preparing 1,7,8,9-tetraalkyl-10-ethyl-4-oxo-10-aluminatricyclo[5,2,1,02,6]-dec-8-ene-3,5-diones
RU2280037C2 (en) * 2004-10-05 2006-07-20 ГУ Институт нефтехимии и катализа АН РБ и УНЦ РАН METHOD FOR PREPARING 2,6-DIETHYL-5,7-DIPHENYL-1,2,3,3a,4,6,8,8a-OCTAHYDROALUMACYCLOPENTADIENO[3,4-f]-ISOALUMAINDOLE

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