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RU2003108129A - METHOD FOR PRODUCING 1- [1`-HYDROXY-1`-ALKyl (1`, 1`-DIALKYL)] METHYL-2-HYDRO [60] FULLERENES - Google Patents

METHOD FOR PRODUCING 1- [1`-HYDROXY-1`-ALKyl (1`, 1`-DIALKYL)] METHYL-2-HYDRO [60] FULLERENES

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Publication number
RU2003108129A
RU2003108129A RU2003108129/04A RU2003108129A RU2003108129A RU 2003108129 A RU2003108129 A RU 2003108129A RU 2003108129/04 A RU2003108129/04 A RU 2003108129/04A RU 2003108129 A RU2003108129 A RU 2003108129A RU 2003108129 A RU2003108129 A RU 2003108129A
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RU
Russia
Prior art keywords
fullerenes
hydro
dialkyl
hydroxy
alkyl
Prior art date
Application number
RU2003108129/04A
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Russian (ru)
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RU2238263C1 (en
Inventor
Усеин Меметович Джемилев
Асхат Габдрахманович Ибрагимов
Лейла Османовна Хафизова
Алевтина Леонидовна Борисова
Ренат Фаритович Туктаров
Ренат Рафикович Абзалимов
Леонард Мухибович Халилов
Original Assignee
ГУ Институт нефтехимии и катализа Академии наук Республики Башкортостан и УНЦ РАН
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Priority to RU2003108129/04A priority Critical patent/RU2238263C1/en
Priority claimed from RU2003108129/04A external-priority patent/RU2238263C1/en
Application granted granted Critical
Publication of RU2238263C1 publication Critical patent/RU2238263C1/en
Publication of RU2003108129A publication Critical patent/RU2003108129A/en

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Claims (1)

Способ получения 1-[1’-гидрокси-1’-алкил(1’,1’-диалкил)]метил-2-гидро[60]фуллеренов общей формулы (I)The method of obtaining 1- [1’-hydroxy-1’-alkyl (1 ’, 1’-dialkyl)] methyl-2-hydro [60] fullerenes of the general formula (I)
Figure 00000001
,
Figure 00000001
, где R=H, R’=н-С3Н7 where R = H, R '= nC 3 H 7 R=H,R’=н-C5H11;R = H, R '= n-C 5 H 11 ; R=СН3, R’=СН3;R = CH 3 , R '= CH 3 ; R=СН3, R’=C2H5; n=1-3,R = CH 3 , R '= C 2 H 5 ; n = 1-3, отличающийся тем, что фуллерен С60 подвергают взаимодействию с этилалюминийдихлоридом (EtAlCl2) и магнием (Mg) при мольном соотношении C60:EtAlCl2:Mg=1:(25-35):(25-35) в присутствии катализатора титанацендихлорида (Cp2TiCl2), взятого в количестве 15-25 мол.% по отношению к С60, в атмосфере аргона при комнатной температуре (20-21°С) и атмосферном давлении в среде ТГФ-толуол в течение 8 ч с последующим добавлением к реакционной массе при температуре -15°С катализатора хлорида меди (CuCl) в количестве 15-25 мол.% по отношению к С60 и альдегида или кетона (rcor’) в эквимольном по отношению к EtAlCl2 количестве, после чего реакционную массу перемешивают при комнатной температуре в течение 6-10 ч.characterized in that the fullerene C 60 is reacted with ethyl aluminum dichloride (EtAlCl 2 ) and magnesium (Mg) at a molar ratio of C 60 : EtAlCl 2 : Mg = 1: (25-35) :( 25-35) in the presence of a titanium-cenadichloride catalyst (Cp 2 TiCl 2 ), taken in an amount of 15-25 mol.% With respect to C 60 , in an argon atmosphere at room temperature (20-21 ° C) and atmospheric pressure in a THF-toluene environment for 8 hours, followed by addition to the reaction the mass at a temperature of -15 ° C of a catalyst of copper chloride (CuCl) in an amount of 15-25 mol.% in relation to C 60 and aldehyde or ketone (rcor ') in equimolar relative to EtAlCl 2 quantity, after which the reaction mass is stirred at room temperature for 6-10 hours
RU2003108129/04A 2003-03-24 2003-03-24 Method for preparing 1-[1'-hydroxy-1'-alkyl-(1',1'-dialkyl)]-methyl-2-hydro[60]fullerenes RU2238263C1 (en)

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RU2294928C2 (en) * 2005-06-14 2007-03-10 Институт нефтехимии и катализа РАН Method for preparing 1-[1-hydroxy-1-(pyrid-4-yl)methyl]-1,2-dihydro[60]fullerenes
RU2372334C2 (en) * 2006-05-06 2009-11-10 Институт нефтехимии и катализа РАН Method of producing 1-(2-propenyl)-2,5-dimethyl-3,4-fullero[60]pyrrolidine
RU2315038C1 (en) * 2006-05-06 2008-01-20 Институт нефтехимии и катализа РАН Method for preparing 1-(2,7-octadienyl)-2,5-dimethyl-3,4-fullero[60]pyrrolidine
RU2481267C2 (en) * 2011-02-11 2013-05-10 Общество с ограниченной ответственностью "Биогельтек" Method of producing fullerenols
RU2473462C2 (en) * 2011-04-15 2013-01-27 Общество с ограниченной ответственностью "Фуллерон" Method of obtaining mixed fullerenols
CN107954961A (en) * 2017-11-30 2018-04-24 河南师范大学 A kind of synthetic method of [60] fullerene dihydrofuran derivative
RU2730478C1 (en) * 2019-12-04 2020-08-24 Федеральное государственное бюджетное научное учреждение Уфимский федеральный исследовательский центр Российской академии наук Method of producing 1,9-(1',4'-oxathiano)-1,9-dihydro-(c60-ih][5,6]fullerene

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RU2160274C1 (en) * 1999-07-14 2000-12-10 Институт нефтехимии и катализа АН РБ и УНЦ РАН Method of preparing 1-alkoxy-2,3-fullerene [60] alumacyclopropanes
RU2200147C1 (en) * 2001-07-11 2003-03-10 ГУ Институт нефтехимии и катализа АН РБ и УНЦ РАН Method of synthesis of alk-4z-en-1-ols

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