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RU2005118361A - METHOD FOR PRODUCING 1- [3-HYDROXY-3- (PYRID-4-IL) PROP-1-IL)] - 1,2-DIHYDRO [60] FULLERENES - Google Patents

METHOD FOR PRODUCING 1- [3-HYDROXY-3- (PYRID-4-IL) PROP-1-IL)] - 1,2-DIHYDRO [60] FULLERENES Download PDF

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RU2005118361A
RU2005118361A RU2005118361/04A RU2005118361A RU2005118361A RU 2005118361 A RU2005118361 A RU 2005118361A RU 2005118361/04 A RU2005118361/04 A RU 2005118361/04A RU 2005118361 A RU2005118361 A RU 2005118361A RU 2005118361 A RU2005118361 A RU 2005118361A
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Russia
Prior art keywords
fullerenes
pyrid
prop
dihydro
hydroxy
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RU2005118361/04A
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Russian (ru)
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RU2294929C2 (en
Inventor
Усеин Меметович Джемилев (RU)
Усеин Меметович Джемилев
Асхат Габдрахманович Ибрагимов (RU)
Асхат Габдрахманович Ибрагимов
Лейла Османовна Хафизова (RU)
Лейла Османовна Хафизова
Алевтина Леонидовна Махаматханова (RU)
Алевтина Леонидовна Махаматханова
Галина Аркадьевна Джемилева (RU)
Галина Аркадьевна Джемилева
Наталь Романовна Поподько (RU)
Наталья Романовна Поподько
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Институт нефтехимии и катализа РАН (RU)
Институт нефтехимии и катализа РАН
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Priority to RU2005118361/04A priority Critical patent/RU2294929C2/en
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Способ получения 1-[3-гидрокси-3-(пирид-4-ил)проп-1-ил]-1,2-дигидро[60]фуллеренов формулы (1)The method of obtaining 1- [3-hydroxy-3- (pyrid-4-yl) prop-1-yl] -1,2-dihydro [60] fullerenes of the formula (1)
Figure 00000001
Figure 00000001
 путем взаимодействия фуллерена С60 с триэтилалюминием (AlEt3) при мольном соотношении С60:AlEt3=1:(25-35) в присутствии катализатора цирконацендихлорида (Cp2ZrCl2), взятого в количестве 15-25 мол.% по отношению к С60, в атмосфере аргона при комнатной температуре 20-21°С и атмосферном давлении в среде толуола в течение 8 ч, отличающийся тем, что к реакционной массе при температуре -15°С добавляют двухкомпонентный катализатор Ni(асас)2+2Рh3Р в ТГФ в количестве 15-25 мол.% по отношению к С60 и 4-пиридинкарбальдегид в эквимольном по отношению к AlEt3 количестве, после чего реакционную массу перемешивают при комнатной температуре в течение 6-10 ч и гидролизуют.by the interaction of fullerene C 60 with triethylaluminum (AlEt 3 ) in a molar ratio of C 60 : AlEt 3 = 1: (25-35) in the presence of a catalyst of zirconacene dichloride (Cp 2 ZrCl 2 ), taken in an amount of 15-25 mol.% relative to C 60 , in an argon atmosphere at room temperature 20-21 ° C and atmospheric pressure in toluene for 8 hours, characterized in that a two-component catalyst Ni (acac) 2 + 2Ph 3 P is added to the reaction mass at a temperature of -15 ° C in THF in an amount of 15-25 mol.% in relation to C 60 and 4-pyridinecarbaldehyde in an amount equimolar to AlEt 3 , after whereby the reaction mass is stirred at room temperature for 6-10 hours and hydrolyzed.
RU2005118361/04A 2005-06-14 2005-06-14 Method for preparing 1-[3-hydroxy-3-(pyrid-4-ylprop-1-yl]-1,2-dihydro[60]fullerenes RU2294929C2 (en)

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RU2005118361/04A RU2294929C2 (en) 2005-06-14 2005-06-14 Method for preparing 1-[3-hydroxy-3-(pyrid-4-ylprop-1-yl]-1,2-dihydro[60]fullerenes

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RU2005118361/04A RU2294929C2 (en) 2005-06-14 2005-06-14 Method for preparing 1-[3-hydroxy-3-(pyrid-4-ylprop-1-yl]-1,2-dihydro[60]fullerenes

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DE4301458A1 (en) * 1993-01-20 1994-07-21 Hoechst Ag Thermally stable fullerene derivatives and processes for their production
RU2238929C1 (en) * 2003-03-24 2004-10-27 ГУ Институт нефтехимии и катализа Академии наук Республики Башкортостан и УНЦ РАН Method for preparing 1-[3'-hydroxy-3'-alkyl-(3',3'-dialkyl)]-n-propyl-2-hydro[60]fullerenes

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