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RU2005118353A - METHOD FOR PRODUCING 1- [1-HYDROXY-1- (PYRID-4-IL) METHYL] -1,2-DIHYDRO [60] FULLERENES - Google Patents

METHOD FOR PRODUCING 1- [1-HYDROXY-1- (PYRID-4-IL) METHYL] -1,2-DIHYDRO [60] FULLERENES Download PDF

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Publication number
RU2005118353A
RU2005118353A RU2005118353/04A RU2005118353A RU2005118353A RU 2005118353 A RU2005118353 A RU 2005118353A RU 2005118353/04 A RU2005118353/04 A RU 2005118353/04A RU 2005118353 A RU2005118353 A RU 2005118353A RU 2005118353 A RU2005118353 A RU 2005118353A
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Russia
Prior art keywords
fullerenes
pyrid
dihydro
hydroxy
methyl
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RU2005118353/04A
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Russian (ru)
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RU2294928C2 (en
Inventor
Усеин Меметович Джемилев (RU)
Усеин Меметович Джемилев
Асхат Габдрахманович Ибрагимов (RU)
Асхат Габдрахманович Ибрагимов
Лейла Османовна Хафизова (RU)
Лейла Османовна Хафизова
Алевтина Леонидовна Махаматханова (RU)
Алевтина Леонидовна Махаматханова
Галина Аркадьевна Джмилева (RU)
Галина Аркадьевна Джмилева
Светлана Маратовна Мурадымова (RU)
Светлана Маратовна Мурадымова
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Институт нефтехимии и катализа РАН (RU)
Институт нефтехимии и катализа РАН
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Priority to RU2005118353/04A priority Critical patent/RU2294928C2/en
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Claims (1)

Способ получения 1-[1-гидрокси-1-(пирид-4-ил)метил]-1,2-дигидро[60]фуллеренов общей формулы (1)The method of obtaining 1- [1-hydroxy-1- (pyrid-4-yl) methyl] -1,2-dihydro [60] fullerenes of the General formula (1)
Figure 00000001
Figure 00000001
 путем взаимодействия фуллерена С60 с этилалюминийдихлоридом (EtAlCl2) и магнием (Mg) при мольном соотношении C60:EtAlCl2:Mg=1:(25-35):(25-35) в присутствии катализатора титанацендихлорида (Cp2TiCl2), взятого в количестве 15-25 мол.% по отношению к С60, в атмосфере аргона при комнатной температуре 20-21°С и атмосферном давлении в среде ТГФ-толуол в течение 8 ч, отличающийся тем, что к реакционной массе при температуре -15°С добавляют катализатор Ni(асас)2+2Рh3Р в количестве 15-25 мол.% по отношению к С60 и 4-пиридинкарбальдегид в эквимольном по отношению к EtAlCl2 количестве, после чего реакционную массу перемешивают при комнатной температуре в течение 6-10 ч и гидролизуют.by the interaction of fullerene C 60 with ethyl aluminum dichloride (EtAlCl 2 ) and magnesium (Mg) at a molar ratio of C 60 : EtAlCl 2 : Mg = 1: (25-35) :( 25-35) in the presence of a titanacenedichloride catalyst (Cp 2 TiCl 2 ) taken in an amount of 15-25 mol.% with respect to C 60 in an argon atmosphere at room temperature of 20-21 ° C and atmospheric pressure in a THF-toluene medium for 8 hours, characterized in that the reaction mass at a temperature of At 15 ° C, a Ni (acac) 2 + 2Ph 3 P catalyst was added in an amount of 15-25 mol% with respect to C 60 and 4-pyridinecarbaldehyde in an amount equimolar with respect to EtAlCl 2 , after which the reaction mass is stirred at room temperature for 6-10 hours and hydrolyzed.
RU2005118353/04A 2005-06-14 2005-06-14 Method for preparing 1-[1-hydroxy-1-(pyrid-4-yl)methyl]-1,2-dihydro[60]fullerenes RU2294928C2 (en)

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RU2005118353/04A RU2294928C2 (en) 2005-06-14 2005-06-14 Method for preparing 1-[1-hydroxy-1-(pyrid-4-yl)methyl]-1,2-dihydro[60]fullerenes

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RU2005118353/04A RU2294928C2 (en) 2005-06-14 2005-06-14 Method for preparing 1-[1-hydroxy-1-(pyrid-4-yl)methyl]-1,2-dihydro[60]fullerenes

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DE4301458A1 (en) * 1993-01-20 1994-07-21 Hoechst Ag Thermally stable fullerene derivatives and processes for their production
RU2238263C1 (en) * 2003-03-24 2004-10-20 ГУ Институт нефтехимии и катализа Академии наук Республики Башкортостан и УНЦ РАН Method for preparing 1-[1'-hydroxy-1'-alkyl-(1',1'-dialkyl)]-methyl-2-hydro[60]fullerenes

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