[go: up one dir, main page]

RU2003108128A - METHOD FOR PRODUCING 1- [3'-HYDROXY-3'ALKYL (3 ', 3'-DIALKYL)] - N-PROPYL-2-HYDRO [60] FULLERENES - Google Patents

METHOD FOR PRODUCING 1- [3'-HYDROXY-3'ALKYL (3 ', 3'-DIALKYL)] - N-PROPYL-2-HYDRO [60] FULLERENES

Info

Publication number
RU2003108128A
RU2003108128A RU2003108128/04A RU2003108128A RU2003108128A RU 2003108128 A RU2003108128 A RU 2003108128A RU 2003108128/04 A RU2003108128/04 A RU 2003108128/04A RU 2003108128 A RU2003108128 A RU 2003108128A RU 2003108128 A RU2003108128 A RU 2003108128A
Authority
RU
Russia
Prior art keywords
fullerenes
hydro
dialkyl
propyl
hydroxy
Prior art date
Application number
RU2003108128/04A
Other languages
Russian (ru)
Other versions
RU2238929C1 (en
Inventor
Усеин Меметович Джемилев
Асхат Габдрахманович Ибрагимов
Лейла Османовна Хафизова
Алевтина Леонидовна Борисова
Ренат Фаритович Туктаров
Ренат Рафикович Абзалимов
Леонард Мухибович Халилов
Original Assignee
ГУ Институт нефтехимии и катализа Академии наук Республики Башкортостан и УНЦ РАН
Filing date
Publication date
Application filed by ГУ Институт нефтехимии и катализа Академии наук Республики Башкортостан и УНЦ РАН filed Critical ГУ Институт нефтехимии и катализа Академии наук Республики Башкортостан и УНЦ РАН
Priority to RU2003108128/04A priority Critical patent/RU2238929C1/en
Priority claimed from RU2003108128/04A external-priority patent/RU2238929C1/en
Publication of RU2003108128A publication Critical patent/RU2003108128A/en
Application granted granted Critical
Publication of RU2238929C1 publication Critical patent/RU2238929C1/en

Links

Claims (1)

Способ получения 1-[3’-гидрокси-3’-алкил(3’,3’-диалкил).]-н-пропил-2-гидро[60]фуллеренов общей формулы (1)The method of obtaining 1- [3’-hydroxy-3’-alkyl (3 ’, 3’-dialkyl).] - n-propyl-2-hydro [60] fullerenes of the general formula (1)
Figure 00000001
Figure 00000001
 где R=H, R’=н-C3H7; R=H,R’=н-C5H11; R=CH3, R’=CH3; R=CH3, R’=C2H5;where R = H, R '= n-C 3 H 7 ; R = H, R '= n-C 5 H 11 ; R = CH 3 , R '= CH 3 ; R = CH 3 , R '= C 2 H 5 ; n=1-3n = 1-3 отличающийся тем, что фуллерен C60 подвергают взаимодействию с триэтилалюминием (AlEt3) при мольном соотношении С60:AlEt3=1:(25-35) в присутствии катализатора цирконацендихлорида (Cp2ZrCl2), взятого в количестве 15-25 мол.% по отношению к С60, в атмосфере аргона при комнатной температуре 20-21°С и атмосферном давлении в среде толуола в течение 8 ч с последующим добавлением к реакционной массе при температуре -15°С катализатора хлорида меди (CuCl) в количестве 15-25 мол.% по отношению к С60 и альдегида или кетона (RCOR’) в эквимольном по отношению к AlEt3 количестве, после чего реакционную массу перемешивают при комнатной температуре в течение 6-10 ч.characterized in that the fullerene C 60 is reacted with triethylaluminum (AlEt 3 ) in a molar ratio of C 60 : AlEt 3 = 1: (25-35) in the presence of a catalyst of zirconacenedichloride (Cp 2 ZrCl 2 ), taken in an amount of 15-25 mol. % with respect to C 60 , in an argon atmosphere at room temperature of 20-21 ° C and atmospheric pressure in toluene for 8 hours, followed by the addition of a catalyst of copper chloride (CuCl) to the reaction mass at a temperature of -15 ° C in an amount of 15- 25 mol.% In relation to C 60 and aldehyde or ketone (RCOR ') in an amount equimolar to AlEt 3 , after which the reaction mass is stirred at room temperature for 6-10 hours
RU2003108128/04A 2003-03-24 2003-03-24 Method for preparing 1-[3'-hydroxy-3'-alkyl-(3',3'-dialkyl)]-n-propyl-2-hydro[60]fullerenes RU2238929C1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2003108128/04A RU2238929C1 (en) 2003-03-24 2003-03-24 Method for preparing 1-[3'-hydroxy-3'-alkyl-(3',3'-dialkyl)]-n-propyl-2-hydro[60]fullerenes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2003108128/04A RU2238929C1 (en) 2003-03-24 2003-03-24 Method for preparing 1-[3'-hydroxy-3'-alkyl-(3',3'-dialkyl)]-n-propyl-2-hydro[60]fullerenes

Publications (2)

Publication Number Publication Date
RU2003108128A true RU2003108128A (en) 2004-10-10
RU2238929C1 RU2238929C1 (en) 2004-10-27

Family

ID=33537762

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2003108128/04A RU2238929C1 (en) 2003-03-24 2003-03-24 Method for preparing 1-[3'-hydroxy-3'-alkyl-(3',3'-dialkyl)]-n-propyl-2-hydro[60]fullerenes

Country Status (1)

Country Link
RU (1) RU2238929C1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2290367C1 (en) * 2005-06-14 2006-12-27 Институт нефтехимии и катализа РАН Method of preparing 1-[3-hydroxy-3-arylprop-1-yl]-1,2-dihydro[60]fullerenes
RU2294929C2 (en) * 2005-06-14 2007-03-10 Институт нефтехимии и катализа РАН Method for preparing 1-[3-hydroxy-3-(pyrid-4-ylprop-1-yl]-1,2-dihydro[60]fullerenes
RU2290401C1 (en) * 2005-06-14 2006-12-27 Институт нефтехимии и катализа РАН Method for preparing 1-[3-hydroxy-4-(fur-2-yl)prop-1-yl]-1,2-dihydro[60]fullerenes

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2160274C1 (en) * 1999-07-14 2000-12-10 Институт нефтехимии и катализа АН РБ и УНЦ РАН Method of preparing 1-alkoxy-2,3-fullerene [60] alumacyclopropanes
RU2200147C1 (en) * 2001-07-11 2003-03-10 ГУ Институт нефтехимии и катализа АН РБ и УНЦ РАН Method of synthesis of alk-4z-en-1-ols

Similar Documents

Publication Publication Date Title
RU2003108128A (en) METHOD FOR PRODUCING 1- [3'-HYDROXY-3'ALKYL (3 ', 3'-DIALKYL)] - N-PROPYL-2-HYDRO [60] FULLERENES
RU2003108129A (en) METHOD FOR PRODUCING 1- [1`-HYDROXY-1`-ALKyl (1`, 1`-DIALKYL)] METHYL-2-HYDRO [60] FULLERENES
RU2003108127A (en) METHOD FOR PRODUCING 2,3-FULLERENO [60] CYCLOPENTANOLES
RU2003110602A (en) METHOD FOR PRODUCING 1- (3`, 3`-DIALCOXIPROP-1`-IL) -2-HYDRO [60] FULLERENES
EP1471056A4 (en) METHOD FOR PRODUCING A CONDENSED IMIDAZOLE COMPOUND, REFORMAT CYREAGEN IN STABLE FORM AND METHOD FOR THE PRODUCTION THEREOF
RU2003110601A (en) METHOD FOR PRODUCING 1- (DIALCOXYMETHYL) -2-HYDRO [60] FULLERENES
RU2002116385A (en) The method of obtaining 1-methyl-3-alkylcyclopentan-1-tins
RU2220969C2 (en) Method for preparing 1-ethyl-3-alkyl(phenyl)-6,7- -fullereno[60]cyclohepta-2-ox-1-alanes
RU2220971C2 (en) Method for preparing 1-ethyl-3-alkyl-4-alkylidenecyclohepta-2-oxalanes
RU2001118659A (en) The method of obtaining 3- (n-propyl) alk-3-en-2-ones
RU2002107665A (en) The method of obtaining 3-thia-exo-tricyclo [5.2.1.0.2,6] decane
RU2005118361A (en) METHOD FOR PRODUCING 1- [3-HYDROXY-3- (PYRID-4-IL) PROP-1-IL)] - 1,2-DIHYDRO [60] FULLERENES
RU2133727C1 (en) Method of synthesis of ethyl-containing c60-fullerenes
RU2004134792A (en) METHOD FOR PRODUCING 3-H-ALKYL-1-HYDROXYCYCLOPENTANE-N-ALKylCARBOXYLATES
RU2002101447A (en) The method of obtaining 1-ethyl-3-alkyl-4-alkylidenecyclohepta-2-oxalanes
RU97115431A (en) METHOD FOR PRODUCING 1- (ALCOXY) -2 (2'-PHENYLETHYLENE) -3-PHENYLALUMACYCLOPROPANES
RU2238930C1 (en) Method for preparing 1-(3',3'-dialkoxyprop-1'-yl)-2-hydro[60]fullerenes
RU2002103992A (en) The method of obtaining 1-ethyl-2-aza-3-methyl-4-alkylidenealuminocyclohept-2-enes
RU2152394C1 (en) Method of synthesis of 1-(e-alkenyl)-1,1-diethylalanes
RU2220972C2 (en) Method for preparing 1-ethyl-1-alumina-2-oxa-3-phenyl[(furan-2'-yl)]-4- alkylidenecycloheptans
RU2002103987A (en) The method of obtaining 1-ethyl-3-methyl-3-phenyl- (alkyl-, cyclopropyl -) - 4-alkylidenecyclohepta-2-oxalanes
RU2220970C2 (en) Method for preparing 1-ethyl-3-alkyl(phenyl)-4,5-fullereno[60]cyclohepta-2- ox-1-alanes
RU2206570C1 (en) Method for preparing 1-ethyl-3,3-dialkyl-6,7-fullereno[60]cyclohepta-2-ox-1-alanes
RU2002100654A (en) The method of obtaining 1-ethyl-3-alkyl (phenyl) -6,7-fullereno [60] cyclohepta-2-ox-1-alans
RU2002103982A (en) The method of obtaining 1-ethyl-3-phenyl [(furan-2'-yl)] - 4-alkylidenecyclohepta-2-oxalanes