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ES8706480A1 - Un procedimiento para minimizar la descomposicion de un ligando de diorganofosfito libre en una reaccion de hidroformilacion. - Google Patents

Un procedimiento para minimizar la descomposicion de un ligando de diorganofosfito libre en una reaccion de hidroformilacion.

Info

Publication number
ES8706480A1
ES8706480A1 ES554326A ES554326A ES8706480A1 ES 8706480 A1 ES8706480 A1 ES 8706480A1 ES 554326 A ES554326 A ES 554326A ES 554326 A ES554326 A ES 554326A ES 8706480 A1 ES8706480 A1 ES 8706480A1
Authority
ES
Spain
Prior art keywords
transition metal
metal complex
catalyzed reactions
complex catalyzed
diorganophosphite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES554326A
Other languages
English (en)
Other versions
ES554326A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of ES8706480A1 publication Critical patent/ES8706480A1/es
Publication of ES554326A0 publication Critical patent/ES554326A0/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C07F15/008—Rhodium compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65744—Esters of oxyacids of phosphorus condensed with carbocyclic or heterocyclic rings or ring systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6578—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and sulfur atoms with or without oxygen atoms, as ring hetero atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
    • B01J2531/0266—Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biochemistry (AREA)
  • Molecular Biology (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Steroid Compounds (AREA)
  • Saccharide Compounds (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Materials For Medical Uses (AREA)

Abstract

PROCEDIMIENTO PARA MINIMIZAR LA DESCOMPOSICION DE UN LIGADO DE DIORGANOFOSFITO EN UNA REACCION DE HIDROFORMILACION. COMPRENDE: A) SEPARAR UNA PORCION DEL MEDIO DE REACCION DE HIDROFORMILACION DE LA ZONA DE REACCION DE HIDROFOMILACION; B) TRATAR LA PORCION SEPARADA CON UNA RESINA CAMBIADORA DE ANION BASICA; Y C) DEVOLVER EL MEDIO DE REACCION A LA ZONA DE REACCION DE HIDROFORMILACION. LA HIDROFORMILACION CONSISTE EN UN PROCESO CONTINUO CON RECIRCULACION DE LIQUIDO QUE CONTIENE CATALIZADOR, LA RESINA CAMBIADORA ES UNA AMINA TERCIARIA-POLIESTIRENO RETICULADA TIPO DEL GEL Y EL CATALIZADOR ESTA FORMADO POR MONOXIDO DE CARBONO Y LIGANDO DE DIORGANOFOSFITO LIBRE. SE UTILIZA EN LA PRODUCCION DE ALDEHIDOS.
ES554326A 1984-02-17 1986-04-24 Un procedimiento para minimizar la descomposicion de un ligando de diorganofosfito libre en una reaccion de hidroformilacion. Expired ES8706480A1 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US58135284A 1984-02-17 1984-02-17
US06/685,025 US4599206A (en) 1984-02-17 1984-12-28 Transition metal complex catalyzed reactions

Publications (2)

Publication Number Publication Date
ES8706480A1 true ES8706480A1 (es) 1987-07-01
ES554326A0 ES554326A0 (es) 1987-07-01

Family

ID=27078299

Family Applications (3)

Application Number Title Priority Date Filing Date
ES540439A Expired ES8609185A1 (es) 1984-02-17 1985-02-15 Un procedimiento para hidroformulacion para producir adheridos.
ES549717A Expired ES8701140A1 (es) 1984-02-17 1985-12-09 Un procedimiento de carbonilacion
ES554326A Expired ES8706480A1 (es) 1984-02-17 1986-04-24 Un procedimiento para minimizar la descomposicion de un ligando de diorganofosfito libre en una reaccion de hidroformilacion.

Family Applications Before (2)

Application Number Title Priority Date Filing Date
ES540439A Expired ES8609185A1 (es) 1984-02-17 1985-02-15 Un procedimiento para hidroformulacion para producir adheridos.
ES549717A Expired ES8701140A1 (es) 1984-02-17 1985-12-09 Un procedimiento de carbonilacion

Country Status (21)

Country Link
US (1) US4599206A (es)
EP (1) EP0155508B1 (es)
JP (1) JPH0645633B2 (es)
KR (1) KR920010519B1 (es)
AT (1) ATE83230T1 (es)
AU (2) AU579144B2 (es)
BR (1) BR8505278A (es)
CA (1) CA1262915A1 (es)
CS (1) CS271311B2 (es)
DE (1) DE3586878T2 (es)
DK (1) DK473485A (es)
ES (3) ES8609185A1 (es)
FI (1) FI88709C (es)
HU (1) HU202176B (es)
MX (1) MX164254B (es)
NO (1) NO165915C (es)
PL (2) PL151491B1 (es)
RO (1) RO92321B (es)
SG (1) SG32193G (es)
WO (1) WO1985003702A1 (es)
YU (1) YU44255B (es)

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