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AR104596A1 - Compuestos de tioéter como inhibidores de la nitrificación - Google Patents

Compuestos de tioéter como inhibidores de la nitrificación

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Publication number
AR104596A1
AR104596A1 ARP160101362A ARP160101362A AR104596A1 AR 104596 A1 AR104596 A1 AR 104596A1 AR P160101362 A ARP160101362 A AR P160101362A AR P160101362 A ARP160101362 A AR P160101362A AR 104596 A1 AR104596 A1 AR 104596A1
Authority
AR
Argentina
Prior art keywords
alkyl
nrcrd
aryl
hetaryl
haloalkyl
Prior art date
Application number
ARP160101362A
Other languages
English (en)
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of AR104596A1 publication Critical patent/AR104596A1/es

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    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/90Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting the nitrification of ammonium compounds or urea in the soil
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    • C05D9/00Other inorganic fertilisers
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    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
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    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00Sulfones; Sulfoxides
    • C07C317/02Sulfones; Sulfoxides having sulfone or sulfoxide groups bound to acyclic carbon atoms
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    • C07C317/00Sulfones; Sulfoxides
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    • C07C317/00Sulfones; Sulfoxides
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    • C07C317/18Sulfones; Sulfoxides having sulfone or sulfoxide groups and singly-bound oxygen atoms bound to the same carbon skeleton with sulfone or sulfoxide groups bound to acyclic carbon atoms of the carbon skeleton
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    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C321/00Thiols, sulfides, hydropolysulfides or polysulfides
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    • C07C323/00Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/01Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and halogen atoms, or nitro or nitroso groups bound to the same carbon skeleton
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    • C07C323/07Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and halogen atoms, or nitro or nitroso groups bound to the same carbon skeleton having sulfur atoms of thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton containing six-membered aromatic rings
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    • C07C323/23Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton
    • C07C323/46Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having at least one of the nitrogen atoms, not being part of nitro or nitroso groups, further bound to other hetero atoms
    • C07C323/47Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having at least one of the nitrogen atoms, not being part of nitro or nitroso groups, further bound to other hetero atoms to oxygen atoms
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    • C07C323/00Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/23Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton
    • C07C323/46Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having at least one of the nitrogen atoms, not being part of nitro or nitroso groups, further bound to other hetero atoms
    • C07C323/48Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having at least one of the nitrogen atoms, not being part of nitro or nitroso groups, further bound to other hetero atoms to nitrogen atoms
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    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C337/00Derivatives of thiocarbonic acids containing functional groups covered by groups C07C333/00 or C07C335/00 in which at least one nitrogen atom of these functional groups is further bound to another nitrogen atom not being part of a nitro or nitroso group
    • C07C337/06Compounds containing any of the groups, e.g. thiosemicarbazides
    • C07C337/08Compounds containing any of the groups, e.g. thiosemicarbazides the other nitrogen atom being further doubly-bound to a carbon atom, e.g. thiosemicarbazones
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    • C07D221/00Heterocyclic compounds containing six-membered rings having one nitrogen atom as the only ring hetero atom, not provided for by groups C07D211/00 - C07D219/00
    • C07D221/02Heterocyclic compounds containing six-membered rings having one nitrogen atom as the only ring hetero atom, not provided for by groups C07D211/00 - C07D219/00 condensed with carbocyclic rings or ring systems
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    • C07D233/00Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/04Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D233/28Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D233/30Oxygen or sulfur atoms
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    • C07DHETEROCYCLIC COMPOUNDS
    • C07D235/00Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings
    • C07D235/02Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings condensed with carbocyclic rings or ring systems
    • C07D235/04Benzimidazoles; Hydrogenated benzimidazoles
    • C07D235/24Benzimidazoles; Hydrogenated benzimidazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 2
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    • C07DHETEROCYCLIC COMPOUNDS
    • C07D239/00Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
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    • C07D241/00Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings
    • C07D241/02Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings
    • C07D241/10Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D241/14Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • C07D241/38Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings condensed with carbocyclic rings or ring systems with only hydrogen or carbon atoms directly attached to the ring nitrogen atoms
    • C07D241/40Benzopyrazines
    • C07D241/44Benzopyrazines with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to carbon atoms of the hetero ring
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    • C07D249/00Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/02Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D249/081,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • C07D249/101,2,4-Triazoles; Hydrogenated 1,2,4-triazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • C07D277/62Benzothiazoles
    • C07D277/68Benzothiazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 2
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    • C07D285/04Thiadiazoles; Hydrogenated thiadiazoles not condensed with other rings
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    • C07D285/01Five-membered rings
    • C07D285/02Thiadiazoles; Hydrogenated thiadiazoles
    • C07D285/04Thiadiazoles; Hydrogenated thiadiazoles not condensed with other rings
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    • C07D285/1251,3,4-Thiadiazoles; Hydrogenated 1,3,4-thiadiazoles with oxygen, sulfur or nitrogen atoms, directly attached to ring carbon atoms, the nitrogen atoms not forming part of a nitro radical
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    • C07D401/04Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
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    • C07D417/04Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings directly linked by a ring-member-to-ring-member bond
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    • C07D495/02Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
    • C07D495/04Ortho-condensed systems
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    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Soil Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Fertilizers (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Nitrogen- Or Sulfur-Containing Heterocyclic Ring Compounds With Rings Of Six Or More Members (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Thiazole And Isothizaole Compounds (AREA)
  • Other In-Based Heterocyclic Compounds (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)

Abstract

Reivindicación 1: Uso de un compuesto de tioéter caracterizado por la fórmula (1) o un estereoisómero, una sal, un tautómero o un N-óxido de aquel como inhibidor de la nitrificación, en donde R¹ y R² se seleccionan independientemente de H y C₁₋₂-alquilo; y en donde R³ es (i) C(=O)Rᵃ, C(=O)ORᵃ, C(=O)NRᶜRᵈ, C(=N-OH)Rᵃ, C(=N-OH)NRᶜRᵈ, C(=N-Rᵇ)Rᵃ, C(=N-Rᵇ)NRᶜRᵈ, C(=N-Rˣ)Rᵃ o C(=N-Rˣ)NRᶜRᵈ; o (ii) C₁₋₈-alquilo, C₃₋₈-cicloalquilo, C₂₋₈-alquenilo, C₃₋₈-cicloalquenilo o C₂₋₈-alquinilo, en donde los átomos de C de estos grupos pueden ser, en cada caso, no sustituidos o pueden tener 1, 2, 3, 4 ó 5 sustituyentes idénticos o diferentes seleccionados de halógeno, CN, ORᵃ, NO₂, NRᶜRᵈ, NRᵇ(C=O)Rᵃ, C(=O)Rᵃ, C(=O)ORᵃ, C(=O)NRᶜRᵈ, S(O)ₙRᵃ y S(O)ₙNRᶜRᵈ; o (iii) C₆₋₁₄-arilo, C₅₋₁₄-hetarilo, C₆₋₁₄-aril-C₁₋₂-alquilo o C₅₋₁₄-hetaril-C₁₋₂-alquilo, en donde las porciones aromáticas pueden ser, en cada caso, no sustituidas o pueden tener 1, 2, 3, 4 ó 5 sustituyentes idénticos o diferentes seleccionados de halógeno, CN, Rˣ, ORᵃ, SRᵃ, NRᶜRᵈ, NRᵇ(C=O)Rᵃ, NRᵇ(C=O)NRᶜRᵈ, C(=O)Rᵃ, C(=O)ORᵃ, C(=O)NRᶜRᵈ, S(O)ₙRᵃ, S(O)ₙNRᶜRᵈ, C₁₋₄-alquilo, C₁₋₄-haloalquilo, C₂₋₄-alquenilo, C₂₋₄-alquinilo, C₁₋₄-alquilen-ORᵃ, C₁₋₄-alquilen-NRᶜRᵈ, C₆₋₁₀-arilo, C₆₋₁₀-aril-C₁₋₂-alquilo, C₅₋₁₀-hetarilo, C₅₋₁₀-hetaril-C₁₋₂-alquilo, C₅₋₁₀-carbociclilo, C₅₋₁₀-carbociclil-C₁₋₂-alquilo, C₅₋₁₀-heterociclilo y C₅₋₁₀-heterociclil-C₁₋₂-alquilo, en donde las porciones C₆₋₁₀-arilo, C₅₋₁₀-hetarilo, C₅₋₁₀-carbociclilo y C₅₋₁₀-heterociclilo pueden ser, en cada caso, no sustituidas o pueden tener 1, 2, 3, 4 ó 5 sustituyentes idénticos o diferentes seleccionados de halógeno, CN, NO₂, OH, SH, NH₂, C₁₋₄-alquilo, C₁₋₄-alcoxi, C₁₋₄-alquiltio, C₁₋₄-dialquilamino y C₁₋₄ -haloalquilo; o (iv) C₅₋₁₄-carbociclilo, C₅₋₁₄-carbociclil-C₁₋₂-alquilo, C₅₋₁₄-heterociclilo o C₅₋₁₄-heterociclil-C₁₋₂-alquilo, en donde los anillos de heterociclilo pueden tener 1, 2, 3, 4 ó 5 heteroátomos que se seleccionan de O, S y N, de los cuales S y/o N se pueden oxidar opcionalmente, y en donde los anillos carbocíclicos o heterocíclicos pueden ser, en cada caso, no sustituidos o pueden tener 1, 2, 3, 4 ó 5 sustituyentes idénticos o diferentes seleccionados de =O, =S, halógeno, CN, Rˣ, ORᵃ, SRᵃ, NO₂, NRᶜRᵈ, NRᵇ(C=O)Rᵃ, NRᵇ(C=O)NRᶜRᵈ, C(=O)Rᵃ, C(=O)ORᵃ, C(=O)NRᶜRᵈ, S(O)ₙRᵃ, S(O)ₙNRᶜRᵈ, C₁₋₄-alquilo, C₁₋₄-haloalquilo, C₂₋₄-alquenilo, C₂₋₄-alquinilo, C₁₋₄-alquilen-ORᵃ, C₁₋₄-alquilen-NRᶜRᵈ, C₆₋₁₀-arilo, C₆₋₁₀-aril-C₁₋₂-alquilo, C₅₋₁₀-hetarilo, C₅₋₁₀-hetaril-C₁₋₂-alquilo, C₅₋₁₀-carbociclilo, C₅₋₁₀-carbociclil-C₁₋₂-alquilo, C₅₋₁₀-heterociclilo y C₅₋₁₀-heterociclil-C₁₋₂-alquilo, en donde las porciones C₆₋₁₀-arilo, C₅₋₁₀; hetarilo, C₅₋₁₀-carbociclilo y C₅₋₁₀-heterociclilo pueden ser, en cada caso, no sustituidas o pueden tener 1, 2, 3, 4 ó 5 sustituyentes idénticos o diferentes seleccionados de halógeno, CN, NO₂, OH, SH, NH₂, C₁₋₄-alquilo, C₁₋₄-alcoxi, C₁₋₄-alquiltio, C₁₋₄-dialquilamino y C₁₋₄-haloalquilo; o y en donde Rᵃ es H, C₁₋₈-alquilo, C₁₋₈-haloalquilo, C₂₋₈-alquenilo, C₂₋₈-alquinilo; C₅₋₁₀-hetarilo o C₆₋₁₀-arilo, en donde las porciones C₅₋₁₀-hetarilo o C₆₋₁₀-arilo pueden ser, en cada caso, no sustituidas o pueden tener 1, 2, 3, 4 ó 5 sustituyentes idénticos o diferentes seleccionados de halógeno, CN, OH, C₁₋₄-alquilo, C₁₋₄-alcoxi, C₁₋₄-haloalquilo, C₂₋₄-alquenilo, C₂₋₄-alquinilo, C₅₋₆-hetarilo y C₆-arilo, en donde dichas porciones C₅₋₆-hetarilo y C₆-arilo pueden ser no sustituidas o pueden tener 1, 2, 3, 4 ó 5 sustituyentes seleccionados de halógeno, CN, OH, C₁₋₄-alquilo, C₁₋₄-alcoxi, C₁₋₄-haloalquilo, C₂₋₄-alquenilo y C₂₋₄-alquinilo; Rᵇ es H, C₁₋₄-alquilo, C₃₋₈-cicloalquilo, C₂₋₄-alquenilo, C₂₋₈-alquinilo o C₆₋₁₀-arilo; y Rᶜ y Rᵈ se seleccionan, independientemente entre sí, del grupo que consiste en H, C₁₋₄-alquilo, C₁₋₄-haloalquilo, C₃₋₈-cicloalquilo, C₆₋₁₀-arilo y C₅₋₁₀-hetarilo; o Rᶜ y Rᵈ, junto con el, átomo de N al que están unidos, forman un heterociclo saturado o insaturado de 5 a 6 miembros, que puede tener otro heteroátomo que se selecciona de O, S y N como átomo miembro del anillo, de los cuales S y/o N se pueden oxidar opcionalmente, y en donde el anillo heterocíclico puede ser no sustituido o puede tener 1, 2, 3, 4 ó 5 sustituyentes, que se seleccionan independientemente de halógeno, CN, OH, NO₂, C₁₋₄-alquilo, C₁₋₄-haloalquilo, C₁₋₄-alcoxi y C₁₋₄-haloalcoxi; y en donde Rˣ es un resto de fórmula (2) en donde § marca la conexión al átomo al que Rˣ está unido; y en donde V, W, X, Y y Z se seleccionan independientemente de N, CH y CRʸ, en donde Rʸ se selecciona del grupo que consiste en halógeno, CN, NO₂, OH, SH, NH₂, C₁₋₄-alquilo, C₁₋₄-alcoxi, C₁₋₄-alquiltio, C₁₋₄-dialquilamino y C₁₋₄-haloalquilo; y en donde m es 0, 1 ó 2; n es 0, 1 ó 2; y p es 0, 1 ó 2. Reivindicación 6: Una composición para usar en la reducción de la nitrificación caracterizada porque comprende al menos un compuesto de la fórmula (1) como se define en cualquiera de las reivindicaciones 1 a 5 y al menos un portador. Reivindicación 10: Un método para reducir la nitrificación caracterizado porque comprende tratar una planta que crece en el suelo o en sustituyentes del suelo y/o el locus, el suelo o los sustituyentes del suelo en donde la planta crece o debe crecer con al menos un compuesto de la fórmula (1) de acuerdo con las reivindicaciones 1 a 5, o una composición de acuerdo con la reivindicación 6. Reivindicación 12: El método de acuerdo con las reivindicaciones 10 u 11 caracterizado porque la aplicación del compuesto de la fórmula (1) y del fertilizante se lleva a cabo simultáneamente o con un desfase temporal, preferentemente, un intervalo de 1 día, 2 días, 3 días, 1 semana, 2 semanas o 3 semanas. Reivindicación 14: La mezcla agroquímica de acuerdo con la reivindicación 7, el uso de acuerdo con las reivindicaciones 8 ó 9, o el método de acuerdo con cualquiera de las reivindicaciones 11 a 13 caracterizado porque dicho fertilizante es un fertilizante inorgánico sólido o líquido que contiene amonio, tal como un fertilizante NPK, nitrato de amonio, nitrato de amonio y calcio, sulfato nitrato de amonio, sulfato de amonio o fosfato de amonio; un fertilizante orgánico sólido o líquido, tal como estiércol líquido, estiércol semilíquido, estiércol estable, estiércol de biogás y estiércol de paja, humus de lombriz, compost, algas o guano, o un fertilizante que contiene urea, tal como urea, urea formaldehído, solución de urea-nitrato de amonio (UAN), urea-azufre, fertilizantes NPK a base de urea o urea-sulfato de amonio. Reivindicación 16: Un compuesto de tioéter caracterizado por la fórmula (1) o un estereoisómero, una sal, un tautómero o un N-óxido de aquel como inhibidor de la nitrificación, en donde R¹ y R² se seleccionan independientemente de H y C₁₋₂-alquilo; y en donde R³ es (i) C(=N-OH)Rᵃ o C(=N-Rˣ)NRᶜRᵈ; en donde Rᵃ es H o C₁₋₂-alquilo; Rᶜ y Rᵈ se seleccionan, independientemente entre sí, del grupo que consiste en H y C₁₋₂-alquilo; y Rˣ es un resto de la fórmula (2), en donde § marca la conexión al átomo al que Rˣ está unido; y en donde cada uno de V, W, Y y Z representa CH, y X representa CH o CRʸ, en donde Rʸ se selecciona del grupo que consiste en halógeno, CN, C₁₋₂-alquilo y C₁₋₂ alcoxi; y en donde m es 0, 1 ó 2; p es 1 ó 2.
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