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AR059035A1 - Insecticidas derivados de antranilamida - Google Patents

Insecticidas derivados de antranilamida

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Publication number
AR059035A1
AR059035A1 ARP070100150A ARP070100150A AR059035A1 AR 059035 A1 AR059035 A1 AR 059035A1 AR P070100150 A ARP070100150 A AR P070100150A AR P070100150 A ARP070100150 A AR P070100150A AR 059035 A1 AR059035 A1 AR 059035A1
Authority
AR
Argentina
Prior art keywords
alkyl
haloalkyl
alkoxy
cycloalkyl
haloalkoxy
Prior art date
Application number
ARP070100150A
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English (en)
Original Assignee
Syngenta Participations Ag
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Filing date
Publication date
Application filed by Syngenta Participations Ag filed Critical Syngenta Participations Ag
Publication of AR059035A1 publication Critical patent/AR059035A1/es

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D223/00—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom
    • C07D223/02—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings
    • C07D223/06—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D223/12—Nitrogen atoms not forming part of a nitro radical
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D331/00—Heterocyclic compounds containing rings of less than five members, having one sulfur atom as the only ring hetero atom
    • C07D331/04—Four-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
    • C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
    • C07D403/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
    • C07D403/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
    • C07D405/12—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/14—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
    • C07D409/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
    • C07F9/65681—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms the ring phosphorus atom being part of a (thio)phosphinic acid or ester thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Environmental Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Biochemistry (AREA)
  • Molecular Biology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

Reivindicacion 1: Un compuesto de formula (1), donde D es fenilo, 2-piridilo, 3-piridilo o 4-piridilo; o fenilo, 2-piridilo, 3-piridilo o 4-piridilo mono-, di- o trisubstituido con alquilo C1-6, cicloalquilo C3-6, haloalquilo C1-6, halogeno, ciano, alcoxi C1-4, haloalcoxi C1-4, alquiltio C1-4, haloalquiltio C1-4, alquilsulfinilo C1-4, alquilsulfonilo C1-4, haloalquilsulfinilo C1-4 o haloalquilsulfonilo C1-4; o D es un radical seleccionado del grupo de formulas (2); R4, R4', R10, R17 y R19 independientemente entre sí, son hidrogeno, alquilo C1-6, cicloalquilo C3-6, haloalquilo C1-6, halogeno, ciano, alcoxi C1-4, haloalcoxi C1-4, alcoxicarbonilo C2-4, alquiltio C1-4, haloalquiltio C1-4, alquilsulfinilo C1-4, alquilsulfonilo C1-4, haloalquilsulfinilo C1-4 o haloalquilsulfonilo C1-4; R5, R6, R8, R11, R12, R15. R16 y R18 independientemente entre sí, son alquilo C1-6, o alquilo C1-6 mono-, di- o trisubstituido con halogeno, ciano, nitro, hidroxi, alcoxi C1-4, alcoxicarbonilo C2- 4, alquiltio C1-4, alquilsulfinilo C1-4, alquilsulfonilo C1-4, alquilamino C1-4, dialquilamino C2-4 o cicloalquilamino C3-6; o son fenilo, 2-piridilo, 3-piridilo, 4-piridilo; o son fenilo, 2-piridilo, 3-piridilo o 4-piridilo mono-, di- o trisubstituido con alquilo C1-6, cicloalquilo C3-6, haloalquilo C1-6, halogeno, ciano, alcoxi C1-4, haloalcoxi C1-4, alquiltio C1-4, haloalquiltio C1-4, alquilsulfinilo C1-4, alquilsulfonilo C1-4, haloalquilsulfinilo C1-4 o haloalquilsulfonilo C1-4; R7, R9, R13 y R14 independientemente entre sí, son hidrogeno, alquilo C1-6, haloalquilo C1-6, alquenilo C2-6, haloalquenilo C2-6, alquenilo C3-6 o haloalquenilo ; cada R1 es independientemente halogeno, nitro, ciano, hidroxi, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, cicloalquilo C3-6, haloalquilo C1-6, haloalquenilo C2-6, haloalquinilo C2-6, halocicloalquilo C3-6, alcoxi C1-4, haloalcoxi C1-4, alquiltio C1-4, haloalquiltio C1-4, haloalquilsulfinilo C1-4, haloalquilsulfonilo C1-4, alquilsulfinilo C1-4, alquilsulfonilo C1-4, alquilamino C1-4, dialquilamino C2-4, cicloalquilamino C3-6, alquil C1-6-cicloalquilamino C3-6, alquilcarbonilo C2-4, alcoxicarbonilo C2-6, alquilaminocarbonilo C2-6, dialquilaminocarbonilo C3-6, alcoxicarboniloxi C2-6, dialquilaminocarboniloxi C2-6 o trialquilsililo C3-6, fenilo, bencilo o fenoxi, o fenilo, bencilo o fenoxi mono-, di- o trisubstituido con halogeno, ciano, nitro, halogeno, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, cicloalquilo C3-6, haloalquilo C1-6, haloalquenilo C2-6, haloalquinilo C2-6, halocicloalquilo C3-6, alcoxi C1-4, haloalcoxi C1-4, alquiltio C1-4, haloalquiltio C1-4, alquilsulfinilo C1-4, alquilsulfonilo C1-4, alquilamino C1-4, dialquilamino C2-4, cicloalquilamino C3-6, alquil C1-6-cicloalquilamino C3-6, alquilcarbonilo C2-4, alcoxicarbonilo C2-6, alquilaminocarbonilo C2-6, dialquilaminocarbonilo C3-6, alcoxicarboniloxi C2-6, alquilaminocarboniloxi C2-6, dialquilaminocarboniloxi C3-6 o trialquilsililo C3-6; n es 0, 1, 2 o 3; cada uno de R2 y R3, los cuales pueden ser iguales o diferentes, representa hidrogeno, alquilo C1-6, alquenilo C2-6, alquinilo C2-6 o cicloalquilo C3-8; o alquilo C1-6, alquenilo C2-6, alquinilo C2-6 o cicloalquilo C3-8 substituido con uno o más substituyentes seleccionados entre halogeno nitro, ciano, hidroxi, alcoxi C1-4, haloalcoxi C1-4, alquiltio C1-4, haloalquiltio C1-4, alquilsulfinilo C1-4, alquilsulfonilo C1-4, alquilamino C1-4, dialquilamino C2-4, cicloalquilamino C3-6 y alquil C1-6-cicloalquilamino C3-6; cada uno de E1 y E2, los cuales pueden ser iguales o diferentes, representa oxígeno o azufre; A es oxígeno, azufre, SO, SO2, S(O)p=N-R, C=N-OR36, N-R0, C=O o P(X)t-R33; R33 es hidrogeno, alquilo C1-6, alquenilo C2-6, alquinilo , haloalquilo C1-6, alcoxi C1-6, hidroxi, cicloalquilo C3-6, cicloalquil C3-6-alquilo C1-6, bencilo o fenilo; donde fenilo y bencilo por su parte pueden ser mono- di- o trisubstituidos con alquilo C1-6, haloalquilo C1-6, halogeno, ciano o nitro; o R33 es O-Na+, O-Li+ o O-K+; R36 es hidrogeno, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, haloalquilo C1-6, haloalquenilo C2-6, haloalquinilo C2-6, alcoxi C1-6-alquilo C1-6, haloalcoxi C1- 6-alquilo C1-6 o bencilo; X es oxígeno o azufre; p es 0 o 1 ; t es 0 o 1; cada uno de R34 y R35, los cuales pueden ser iguales o diferentes, representa hidrogeno, COOH, halogeno, nitro, ciano, hidroxi, alquilo C1-6, haloalquilo C1-6, alquenilo C2-6, alquinilo C2-6, haloalquenilo C2-6, haloalquinilo C2-6, alquiltio C1-6, alquilsulfinilo C1-6, alquilsulfonilo C1-6, haloalquiltio C1-6, haloalquilsulfinilo C1-6, haloalquilsulfonilo C1-6, alcoxicarbonilo C1-6, alquilcarbonilo C1-6, alquilaminocarbonilo C3-6, dialquilaminocarbonilo C3-6, alcoxi C1-6-alquilo C1-6, haloalcoxi C1-6-alquilo C1-6, alcoxi C1-6, haloalcoxi C1-6, alquilamino C1-6, dialquilamino C2-6, trialquilsililo C3-8, bencilo o fenilo; donde fenilo y bencilo por su parte pueden ser mono- di- o trisubstituido con alquilo C1-6, haloalquilo C1-6, alcoxi C1-6, haloalcoxi C1-6, halogeno, ciano, hidroxilo o nitro; m es 0, 1, 2, 3 o 4; R es hidrogeno, alquilo C1-6, haloalquilo C1-6, cicloalquilo C3-6, halocicloalquilo C3-6, alquiltio C1-6, haloalquiltio C1-6, alcoxi C1-6-alquilo C1-6 o haloalcoxi C1-6-alquilo C1-6; o R es alquilo C1-6, haloalquilo C1-6, cicloalquilo C3-6, halocicloalquilo C3-6, alquiltio C1-6, haloalquiltio C1-6, alcoxi C1-6- alquilo C1-6 o haloalcoxi C1-6-alquilo C1-6 substituido con alquilo C1-6, haloalquilo C1-6, cicloalquilo C3-6, halocicloalquilo C3-6, alcoxi C1-6, o haloalcoxi C1-6; o R es ciano, nitro, -C(O)R26, -C(O)OR27, -CONR28R29, -SO2R30 o -P(O)(OR31)(OR32); R0 es hidrogeno, alquilo C1-6, haloalquilo C1-6, cicloalquilo C3-6, halocicloalquilo C3-6, alquiltio C1-6, haloalquiltio C1-6, alcoxi C1-6-alquilo C1-6 o haloalcoxi C1-6-alquilo C1-6; o R0 es alquilo C1-6, haloalquilo C1-6, cicloalquilo C3-6, halocicloalquilo C3-6, alquiltio C1-6, haloalquiltio C1-6, alcoxi C1-6-alquilo C1-6 o haloalcoxi C1-6-alquilo C1-6 substituido con alquilo C1-6, haloalquilo C1-6, cicloalquilo C3-6, halocicloalquilo C3-6, alcoxi C1-6, o haloalcoxi C1-6; o R0 es ciano, nitro, -C(O)R026, -C(O)OR027, -CONR028R029, -SO2R030 o -P(O)(OR031)(OR032); o R0 es fenilo o bencilo, o fenilo o bencilo mono-, di- o trisubstituido con substituyentes seleccionados entre alquilo C1-6, cicloalquilo C3-6, haloalquilo C1-6, halogeno, ciano, alcoxi C1-4, haloalcoxi C1-4, alquiltio C1-4, haloalquiltio C1-4, alquilsulfinilo C1-4, alquilsulfonilo C1-4, haloalquilsulfinilo C1-4 y haloalquilsulfonilo C1-4; cada uno de R26 y R026. los cuales pueden ser iguales o diferentes, representa hidrogeno, alquilo C1-6, haloalquilo C1-6, cicloalquilo C3-6, halocicloalquilo C3-6, alquiltio C1-6, haloalquiltio C1-6, alcoxicarbonilo C1-6, alquilcarbonilo C1-6 o alcoxi C1-6-alquilo C1-6; o alquilo C1-6, haloalquilo C1-6, cicloalquilo C3-6, halocicloalquilo C3-6, alquiltio C1-6, haloalquiltio C1-6, alcoxicarbonilo C1-6, alquilcarbonilo C1-6 o alcoxi C1-6-alquilo C1-6 substituido con alquilo C1-6, haloalquilo C1-6, cicloalquilo C3-6, halocicloalquilo C3-6, alcoxi C1-6, o haloalcoxi C1-6; cada uno de R27, R28, R29, R30, R31, R32, R027, R028, R029, R030, R031 y R032 los cuales pueden ser iguales o diferentes, representa alquilo C1-6, haloalquilo C1-6, cicloalquilo C3-6 o halocicloalquilo C3-6; o alquilo C1-6, haloalquilo C1-6, cicloalquilo C3-6 o halocicloalquilo C3-6 substituido con alquilo C1-6, haloalquilo C1-6, cicloalquilo C3-6, halocicloalquilo C3-6, alcoxi C1-6 o haloalcoxi C1-6; con la condicion de que E1 o E2 sea azufre si A es oxígeno, azufre o N-R0, donde R0 es hidrogeno, alquilo C1-3, haloalquilo C1-3, alquilcarbonilo C2-4, haloalquilcarbonilo C2-4, alcoxicarbonilo C2-4 o alquilsulfonilo C1-3; y las sales, isomeros, diasteromeros, enantiomeros, tautomeros, N-oxidos aceptables para agronomía de esos compuestos.
ARP070100150A 2006-01-16 2007-01-12 Insecticidas derivados de antranilamida AR059035A1 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP06000826 2006-01-16
EP06002803 2006-02-13

Publications (1)

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AR059035A1 true AR059035A1 (es) 2008-03-12

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Country Status (14)

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US (2) US8084474B2 (es)
EP (2) EP1976385A2 (es)
JP (1) JP5215190B2 (es)
KR (1) KR101342875B1 (es)
AR (1) AR059035A1 (es)
AU (1) AU2007204417B2 (es)
BR (1) BRPI0707882A2 (es)
CA (1) CA2635827C (es)
ES (1) ES2430419T3 (es)
IL (2) IL192470A (es)
NZ (1) NZ569504A (es)
TW (1) TWI389898B (es)
UY (1) UY30090A1 (es)
WO (1) WO2007080131A2 (es)

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