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AR059494A1 - Derivados biciclicos de bisamida con actividad pesticida - Google Patents

Derivados biciclicos de bisamida con actividad pesticida

Info

Publication number
AR059494A1
AR059494A1 ARP070100621A ARP070100621A AR059494A1 AR 059494 A1 AR059494 A1 AR 059494A1 AR P070100621 A ARP070100621 A AR P070100621A AR P070100621 A ARP070100621 A AR P070100621A AR 059494 A1 AR059494 A1 AR 059494A1
Authority
AR
Argentina
Prior art keywords
alkyl
haloalkyl
cycloalkyl
alkoxy
thio
Prior art date
Application number
ARP070100621A
Other languages
English (en)
Original Assignee
Syngenta Participations Ag
Syngenta Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Syngenta Participations Ag, Syngenta Ltd filed Critical Syngenta Participations Ag
Publication of AR059494A1 publication Critical patent/AR059494A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/60—1,4-Diazines; Hydrogenated 1,4-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/86—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
    • C07D417/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing three or more hetero rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

Reivindicacion 1: Un compuesto de la formula 1 donde G1, G2, G3 y G4 forman, junto con los dos átomos de carbono a los que G1 y G4 están unidos, un sistema de anillos aromáticos; donde G1 es nitrogeno, azufre, oxígeno, un enlace directo o C-R5a; G2 es nitrogeno, azufre, oxígeno, un enlace directo o C-R5b; G3 es nitrogeno, azufre, oxígeno, un enlace directo o C-R5c; G4 es nitrogeno, azufre, oxígeno, un enlace directo o C-R5d; con la condicion de que a) al menos un sustituyente G represente nitrogeno, azufre u oxígeno, b) no más de 1 sustituyente G pueda formar al mismo tiempo un enlace directo, c) no más de 2 sustituyentes G puedan ser oxigeno o azufre, y d) 2 sustituyentes G como oxigeno y/o azufre se separen por al menos un átomo de carbono, cada uno de R1a, R1b, R5a, R5b, R5c y R5d que pueden ser iguales o diferentes, representa hidrogeno, halogeno, nitro, ciano, hidroxi, CHO, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, cicloalquilo C3-6, haloalquilo C1-6, haloalquenilo C2- 6, haloalquinilo C2-6, halocicloalquilo C3-6, alcoxi C1-4, alcoxi C1-4-alcoxi C1-4-alquilo C1-4, haloalcoxi C1-4, alquil C1-4-tio, haloalquil C1-4-tio, haloalquil C1-4-sulfinilo, haloalquil C1-4-sulfonilo, alquil C1-C4-sulfinilo, alquil C1-4- sulfonilo, alquil C1-4-sulfonil-alquilo C1-4, alquil C1-4- sulfoximino-alquilo C1-4, alquil C1-4-amino, dialquil C2-C-amino, cicloalquil C3-6-amino, alquil C1-6-cicloalquil C3-6-amino, alquil C2-4-carbonilo, alcoxi C2-6-carbonilo, alquil C2-6- aminocarbonilo, dialquil C3-6-aminocarbonilo, alcoxi C2-6-carboniloxi, alquil C2-6-aminocarboniloxi, dialquil C3-6-aminocarboniloxi, alcoxi C1-4-imino-alquilo C1-4, trialquil C3-6-sililo, fenilo, bencilo o fenoxi; o fenilo, bencilo o fenoxi mono-, di- o trisustituido con halogeno, ciano, nitro, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, cicloalquilo C3-6, haloalquilo C1-6, haloalquenilo C2-6, haloalquinilo C2-6, halocicloalquilo C3-6, alcoxi C1-4, haloalcoxi C1-4, alquil C1-4-tio, haloalquil C1-4-tio, alquil C1-4-sulfinilo, alquil C1-4-sulfonilo, alquil C1-4-amino, dialquil C2-4-amino, cicloalquil C3-6-amino, alquil C1-6-cicloalquil C3-6-amino, alquil C2-4-carbonilo, alcoxi C2-6-carbonilo, alquil C2-6-aminocarbonilo, dialquil C3-6-aminocarbonilo, alcoxi C2-6-carboniloxi, alquil C2-6-aminocarboniloxi, dialquil C3-6-aminocarboniloxi o trialquil C3-6-sililo; cada uno de R2 y R3, que pueden ser iguales o diferentes, representa hidrogeno, alquilo C1-6, alquenilo C2-6, alquinilo C2-6 o cicloalquilo C3-8, o alquilo C1-6, alquenilo C2-6, alquinilo C2-6 o cicloalquilo C3-8 sustituido con uno o más sustituyentes seleccionados de halogeno, nitro, ciano, hidroxi, alcoxi C1-4, haloalcoxi C1-4, alquil C1-4-tio, haloalquil C1-4-tio, alquil C1-4-sulfinilo, alquil C1-4-sulfonilo, alquil C1-4-amino, dialquil C2-4-amino, cicloalquil C3-6-amino y alquil C1-6-cicloalquil C3-6-amino; D es 2-piridilo, 3-piridilo o 4-piridilo; o fenilo, 2-piridilo, 3-piridilo o 4-piridilo mono- , di- o trisustituido con alquilo C1-6, cicloalquilo C3-6, haloalquilo C1-6, halogeno, ciano, alcoxi C1-4, haloalcoxi C1-4, alquil C1-4-tio, haloalquil C1-4-tio, alquil C1-4-sulfinilo, alquil C1-4-sulfonilo, haloalquil C1-4-sulfinilo o haloalquil C1- 4-sulfonilo; o D es un grupo de (D1) a (D8) o D es adicionalmente fenilo si Z1 es azufre; R4, R4', R10, R17 y R19 son, de modo independiente entre sí, hidrogeno, alquilo C1-6, cicloalquilo C3-6, haloalquilo C1-6, halogeno, ciano, alcoxi C1-4, haloalcoxi C1-4, alcoxi C2-4-carbonilo, alquil C1-4-tio, haloalquil C1-4-tio, alquil C1-4-sulfinilo, alquil C1-4-sulfonilo, haloalquil C1-4-sulfinilo o haloalquil C1-4-sulfonilo; R5, R6, R8, R11, R12, R15, R16 y R18 son, de modo independiente entre si, alquilo C1-6 o alquilo C1-6 mono-, di- o trisustituido con halogeno, ciano, nitro, hidroxi, alcoxi C1-4, alcoxi C2-4-carbonilo, alquil C1-4-tio, alquil C1-4-sulfinilo, alquil C1-4-sulfonilo, alquil C1-4-amino, dialquil C2-4-amino o cicloalquil C3-6-amino; o son fenilo, 2-piridilo, 3-piridilo, 4-piridilo; o fenilo, 2-piridilo, 3-piridilo o 4-piridilo mono-, di- o trisustituido con alquilo C1-6, cicloalquilo C3-6, haloalquilo C1-6, halogeno, ciano, alcoxi C1-, haloalcoxi C1-4, alquil C1-4- tio, haloalquil C1-4-tio, alquil C1-4-sulfinilo, alquil C1-4-sulfonilo, haloalquil C1-4-sulfinilo o haloalquil C1-4-sulfonilo; R7, R9, R13 y R14 son, de modo independiente entre sí, hidrogeno, alquilo C1-6, haloalquilo C1-6, alquenilo C2-6, haloalquenilo C2-6, alquenilo C3-6 o haloalquenilo C3-6; R20 es hidrogeno, alquilo C1-6, alquenilo C2-6, alquinilo C2-6 o cicloalquilo C3-6; o es alquilo C1-6, alquenilo C2-6, alquinilo C2-6 o cicloalquilo C3-6 sustituido con uno, dos o tres sustituyentes seleccionados del grupo formado por halogeno, ciano, nitro, hidroxi, alquilo C1-4, alcoxi C1-4, haloalcoxi C1-4, alquil C1-4-tio, alquil C1-4-sulfinilo, alquil C1-4-sulfonilo, alquil C1-4-sulfoximino, alcoxi C2-6-carbonilo, alquil C2-6- carbonilo, trialquil C2-6-sililo, bencilo, fenoxi y un sistema de anillos monocíclicos o bicíclicos fusionados de 3 a 10 miembros que puede ser aromático, parcialmente saturado o completamente saturado, donde el sistema de anillos aromáticos de 6 miembros contiene al menos un heteroátomo seleccionado del grupo formado por oxígeno, nitro y azufre; donde es posible que dicho bencilo, fenoxi y sistema de anillos monocíclicos o bicíclicos fusionados de 3 a 10 miembros esté sustituido, a su vez, con uno a tres sustituyentes seleccionados, de modo independiente, del grupo formado por alquilo C1-4, alquenilo C2-4, alquinilo C2-4, cicloalquilo C3-6, haloalquilo C1-4, haloalquenilo C2-4, haloalquinilo C2-4, halocicloalquilo C2-6, halogeno, ciano, nitro, alcoxi C1-4, haloalcoxi C1-4, alquil C1-4-tio, alquil C1-4-sulfinilo, alquil C1-4-sulfonilo, alquil C1-4-sulfoximino, alquil C1-4-amino, dialquil C2-6-amino, cicloalquil C3-6-amino, alquil C1-4-cicloalquil C3-6-amino, alquil C2-4- carbonilo, alcoxi C2-6-carbonilo, alquil C2-6-aminocarbonilo, dialquil C2-8-aminocarbonilo y trialquil C2-6-sililo; donde es posible que dicho sistema de anillos monocíclicos o bicíclicos fusionados de 3 a 10 miembros esté unido de forma espiro con el grupo cicloalquilo C3-6; o R20 es alcoxi C1-4, alquil C1-4-amino, dialquil C2-8-amino, cicloalquil C2-6-amino, alcoxi C2-6-carbonilo o alquil C2-6-carbonilo; o R20 es 3-oxetanilo, 3tietanilo, 1-oxo-3-tietanilo, 1,1-dioxo-3-tietanilo, 1-imino-1- oxo-3-tietanilo, 3-azetidinilo, cada uno opcionalmente sustituido con uno a cinco sustituyentes seleccionados, de modo independiente, de alquilo C1-4, haloalquilo C1-4, halogeno, ciano; cada uno de Z1 y Z2, que pueden ser iguales o diferentes, representa oxígeno o azufre; y sales/isomeros/enantiomeros/tautomeros/N-oxidos de esos compuestos aceptables en agronomía.
ARP070100621A 2006-02-16 2007-02-14 Derivados biciclicos de bisamida con actividad pesticida AR059494A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP06003094 2006-02-16

Publications (1)

Publication Number Publication Date
AR059494A1 true AR059494A1 (es) 2008-04-09

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Country Status (21)

Country Link
US (1) US8658801B2 (es)
EP (1) EP1984354B1 (es)
JP (1) JP2009526798A (es)
KR (1) KR20080093045A (es)
CN (1) CN101426779B (es)
AR (1) AR059494A1 (es)
AT (1) ATE438643T1 (es)
AU (1) AU2007214661B2 (es)
BR (1) BRPI0709555B1 (es)
CA (1) CA2640307A1 (es)
DE (1) DE602007001870D1 (es)
EG (1) EG25368A (es)
ES (1) ES2331437T3 (es)
IL (1) IL192930A0 (es)
MA (1) MA30262B1 (es)
NZ (1) NZ570099A (es)
RU (1) RU2437881C2 (es)
TW (1) TW200808766A (es)
UA (1) UA91406C2 (es)
WO (1) WO2007093402A1 (es)
ZA (1) ZA200806326B (es)

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BRPI0709555A2 (pt) 2011-07-19
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