AR069489A1 - Derivados de 3-(bencilsulfinil)-5,5-dimetil-4,5-dihidroisoxazol y derivados de 5,5-dimetil-3-[(1h-pirazol-4-ilmetil)sulfinil]-4,5-dihidroisoxazol quirales, proce-dimientos para su preparacion asi como su uso como herbicidas y como re-guladores del crecimiento de las plantas - Google Patents
Derivados de 3-(bencilsulfinil)-5,5-dimetil-4,5-dihidroisoxazol y derivados de 5,5-dimetil-3-[(1h-pirazol-4-ilmetil)sulfinil]-4,5-dihidroisoxazol quirales, proce-dimientos para su preparacion asi como su uso como herbicidas y como re-guladores del crecimiento de las plantasInfo
- Publication number
- AR069489A1 AR069489A1 ARP080105200A AR069489A1 AR 069489 A1 AR069489 A1 AR 069489A1 AR P080105200 A ARP080105200 A AR P080105200A AR 069489 A1 AR069489 A1 AR 069489A1
- Authority
- AR
- Argentina
- Prior art keywords
- alkyl
- haloalkyl
- cycloalkyl
- cycloalkenyl
- alkoxy
- Prior art date
Links
- 239000004009 herbicide Substances 0.000 title abstract 3
- 238000002360 preparation method Methods 0.000 title abstract 2
- 230000012010 growth Effects 0.000 title 1
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 abstract 9
- 125000000217 alkyl group Chemical group 0.000 abstract 8
- 125000005196 alkyl carbonyloxy group Chemical group 0.000 abstract 7
- 125000000392 cycloalkenyl group Chemical group 0.000 abstract 4
- 125000004916 (C1-C6) alkylcarbonyl group Chemical group 0.000 abstract 3
- 125000004739 (C1-C6) alkylsulfonyl group Chemical group 0.000 abstract 3
- 125000000171 (C1-C6) haloalkyl group Chemical group 0.000 abstract 3
- 125000003545 alkoxy group Chemical group 0.000 abstract 3
- -1 cyano, nitro, amino Chemical group 0.000 abstract 3
- 125000004438 haloalkoxy group Chemical group 0.000 abstract 3
- 125000003161 (C1-C6) alkylene group Chemical group 0.000 abstract 2
- 125000004741 (C1-C6) haloalkylsulfonyl group Chemical group 0.000 abstract 2
- 125000006636 (C3-C8) cycloalkylcarbonyl group Chemical group 0.000 abstract 2
- 239000003905 agrochemical Substances 0.000 abstract 2
- 125000005090 alkenylcarbonyl group Chemical group 0.000 abstract 2
- 125000004453 alkoxycarbonyl group Chemical group 0.000 abstract 2
- 125000005201 cycloalkylcarbonyloxy group Chemical group 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 125000005843 halogen group Chemical group 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 2
- 125000001424 substituent group Chemical group 0.000 abstract 2
- 125000000101 thioether group Chemical group 0.000 abstract 2
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 abstract 1
- 125000004454 (C1-C6) alkoxycarbonyl group Chemical group 0.000 abstract 1
- 125000004738 (C1-C6) alkyl sulfinyl group Chemical group 0.000 abstract 1
- 125000004890 (C1-C6) alkylamino group Chemical group 0.000 abstract 1
- 125000006700 (C1-C6) alkylthio group Chemical group 0.000 abstract 1
- 125000006619 (C1-C6) dialkylamino group Chemical group 0.000 abstract 1
- 125000004737 (C1-C6) haloalkoxy group Chemical group 0.000 abstract 1
- 125000004749 (C1-C6) haloalkylsulfinyl group Chemical group 0.000 abstract 1
- 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 abstract 1
- 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 abstract 1
- 125000006621 (C3-C8) cycloalkyl-(C1-C6) alkyl group Chemical group 0.000 abstract 1
- 125000005947 C1-C6 alkylsulfonyloxy group Chemical group 0.000 abstract 1
- 125000006577 C1-C6 hydroxyalkyl group Chemical group 0.000 abstract 1
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 abstract 1
- 125000003320 C2-C6 alkenyloxy group Chemical group 0.000 abstract 1
- 125000003601 C2-C6 alkynyl group Chemical group 0.000 abstract 1
- 125000005915 C6-C14 aryl group Chemical group 0.000 abstract 1
- 125000005974 C6-C14 arylcarbonyl group Chemical group 0.000 abstract 1
- 125000005914 C6-C14 aryloxy group Chemical group 0.000 abstract 1
- 241000196324 Embryophyta Species 0.000 abstract 1
- 125000005092 alkenyloxycarbonyl group Chemical group 0.000 abstract 1
- 125000005108 alkenylthio group Chemical group 0.000 abstract 1
- 125000005194 alkoxycarbonyloxy group Chemical group 0.000 abstract 1
- 125000004691 alkyl thio carbonyl group Chemical group 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 125000005087 alkynylcarbonyl group Chemical group 0.000 abstract 1
- 125000005225 alkynyloxycarbonyl group Chemical group 0.000 abstract 1
- 125000005109 alkynylthio group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 125000005161 aryl oxy carbonyl group Chemical group 0.000 abstract 1
- 125000005135 aryl sulfinyl group Chemical group 0.000 abstract 1
- 125000004391 aryl sulfonyl group Chemical group 0.000 abstract 1
- 125000005110 aryl thio group Chemical group 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000004122 cyclic group Chemical group 0.000 abstract 1
- 125000004465 cycloalkenyloxy group Chemical group 0.000 abstract 1
- 125000000000 cycloalkoxy group Chemical group 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 125000005366 cycloalkylthio group Chemical group 0.000 abstract 1
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 abstract 1
- 125000005280 halo alkyl sulfonyloxy group Chemical group 0.000 abstract 1
- 125000000262 haloalkenyl group Chemical group 0.000 abstract 1
- 125000005291 haloalkenyloxy group Chemical group 0.000 abstract 1
- 125000006788 haloalkenyloxycarbonyl group Chemical group 0.000 abstract 1
- 125000004993 haloalkoxycarbonyl group Chemical group 0.000 abstract 1
- 125000006797 haloalkoxycarbonyloxy group Chemical group 0.000 abstract 1
- 125000001188 haloalkyl group Chemical group 0.000 abstract 1
- 125000004692 haloalkylcarbonyl group Chemical group 0.000 abstract 1
- 125000005203 haloalkylcarbonyloxy group Chemical group 0.000 abstract 1
- 125000004995 haloalkylthio group Chemical group 0.000 abstract 1
- 125000004693 haloalkylthiocarbonyl group Chemical group 0.000 abstract 1
- 125000000232 haloalkynyl group Chemical group 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 230000002363 herbicidal effect Effects 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 150000002829 nitrogen Chemical class 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 1
- 239000005648 plant growth regulator Substances 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 244000045561 useful plants Species 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D261/00—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings
- C07D261/02—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings
- C07D261/04—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
- C07D413/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D413/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing three or more hetero rings
Landscapes
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Plural Heterocyclic Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Procedimientos para su preparacion, así como su uso como herbicidas y reguladores del crecimiento de las plantas, en especial como herbicidas para combatir en forma selectiva malezas en cultivos de plantas utiles y composiciones herbicidas. Reivindicacion 1: Compuestos opticamente activos de la formula general (1), sus sales de tolerancia agroquímica o sus derivados de nitrogeno cuaternarios de tolerancia agroquímica donde Y es el grupo de formulas (2) y los distintos sustituyentes R1 a R8, en cada caso de manera independiente entre si, se seleccionaron del grupo que se compone de: hidrogeno, halogeno, hidroxi, ciano, nitro, amino, C(O)OH, formilo, alquilo C1-6,haloalquilo C1-6, alquilcarbonilo C1-6,haloalquilcarbonilo C1-6,alquilcarboniloxi C1-6, haloalquilcarboniloxi C1-6, alquilcarbonilo C1-6-alquilo C1-4, haloalquilcarbonilo C1-6-alquilo C1-4, alquilcarbonilo C1-6-haloalquilo C1-4-haloalquilcarbonilo C1-6-haloalquilo C1-4, alcoxi C1-6,haloalcoxi C1-6, alcoxicarbonilo C1-6, haloalcoxicarbonilo C1-6, alcoxicarbonilo C1-6-alquilo C1-6, haloalcoxicarbonilo C1-6-alquilo C1-6, alcoxicarbonilo C1-6-haloalquilo C1-6, haloalcoxicarbonilo C1-6-haloalquilo C1-6, alquenilo C2-6, haloalquenilo C2-6, alquenilcarbonilo C2-6, haloalquenilcarbonilo C2-6, alqueniloxi C2-6, haloalqueniloxi C2-6, alqueniloxicarbonilo C2-6, haloalqueniloxicarbonilo C2-6, alquinilo C2-6, haloalquinilo C2-6, alquinilcarbonilo C2-6, haloalquinilcarbonilo C2-6, alquiniloxi C2-6, haloalquiniloxi C2-6, alquiniloxicarbonilo C2-6, haloalquiniloxicarbonilo C2-6, alquiltiocarbonilo C1-6,haloalquiltiocarbonilo C1-6, alquiltiocarboniloxi C1-6, haloalquiltiocarboniloxi C1-6, alquiltio C1-6-alcoxi C1-6, alquiltio C1-6-alquilcarbonilo C1-6, alquiltio C1-6-alquilcarboniloxi C1-6, arilo C6-14, ariloxi C6-14, arilcarbonilo C6-14, ariloxicarbonilo C6-14, aril-C6-14-alquilo C1-6, ariloxi C6-14-alquilo C1-6, aril-C6-14-alcoxi C1-6, aril-C6-14-alquilcarbonilo C1-6, aril-C6-14-alquilcarboniloxi C1-6, aril-C6-14-alcoxicarbonilo C1-6, aril-C6-14-alcoxicarboniloxi C1-6, alquilsulfonilo C1-6, alquiltio C1-6, alquilsulfinilo C1-6, haloalquilsulfonilo C1-6, haloalquiltio C1-6, haloalquilsulfinilo C1-6, alquilsulfonilo C1-6-alquilo C1-6, alquiltio C1-6-alquilo C1-6, alquilsulfinilo C1-6-alquilo C1-6, haloalquilsulfonilo C1-6-alquilo C1-6, haloalquiltio C1-6-alquilo C1-6, haloalquilsulfinilo C1-6-alquilo C1-6, alquilsulfonilo C1-6-haloalquilo C1-6, alquiltio C1-6-haloalquilo C1-6, alquilsulfinilo C1-6-haloalquilo C1-6, haloalquilsulfonilo C1-6-haloalquilo C1-6, haloalquiltio C1-6-haloalquilo C1-6,haloalquilsulfinilo C1-6-haloalquilo C1-6, alquilsulfoniloxi C1-6, haloalquilsulfoniloxi C1-6, arilsulfonilo C4-14, ariltio C6-14, arilsulfinilo C6-14, mono-(alquil-C1-6)-amino, mono-(haloalquil--C1-6)-amino, di- (alquil-C1-6)-amino, di-(haloalquil-C1-6)-amino, (alquil-C1-6-haloalquil-C1-6)-amino, N-(alcanoil-C1-6)-amino, N-(haloalcanoil-C1-6)-amino, aminocarbonil-C1-6)-alquilo, mono-alquilaminocarbonil-C1-6-C1-6-alquilo, mono-(alquil-C1-6)-aminocarbonilo, di-alquilaminocarbonil-C1-6-alquilo C1-6-, alcoxi C1-6-alquilo C1-6, alcoxi C1-6- alcoxi C1-6, alcoxicarbonilo C1-6-alcoxi C1-6, cicloalquilo C3-8, cicloalcoxi C3-8, cicloalquil-C3-8-alquilo C1-6, cicloalquil-C3-8-haloalquilo C1-6, cicloalquil-C3-8-alcoxi C1-6, cicloalquil-C3-8-haloalcoxi C1-6, cicloalquilcarbonilo C3-8, cicloalcoxicarbonilo C3-8, cicloalquil-C3-8-alquilcarbonilo C1-6, cicloalquil-C3-8-haloaquilcarbonilo C1-6, cicloalquil-C3-8-alcoxicarbonilo C1-6, cicloalquil-C3-8-haloalcoxicarbonilo C1-6, cicloalquilcarboniloxi C3-8, cicloalcoxicarboniloxi C3-8, cicloalquil-C3-8-alquilcarboniloxi C1-6, cicloalquil-C3-8-haloalquilcarboniloxi C1-6, cicloalquil-C3-8-alcoxicarboniloxi C1-6, cicloalquil-C3-8-haloalcoxicarboniloxi C1-6, cicloalquenilo C3-8, cicloalqueniloxi C3-8, cicloalquenil-C3-8-alquilo C1-6, cicloalquenil-C3-8-haloalquilo C1-6, cicloalquenil-C3-8-alcoxi C1-6, cicloalquenil-C3-8-haloalcoxi C1-6, cicloalquenilcarbonilo C3-8, cicloalqueniloxicarbonilo C3-8, cicloalquenil-C3-8-alquilcarbonilo C1-6, cicloalquenil-C3-8-haloalquilcarbonilo C1-6, cicloalquenil-C3-8-alcoxicarbonilo C1-6, cicloalquenil-C3-8-haloalcoxicarbonilo C1-6, cicloalquenilcarboniloxi C3-8, cicloalqueniloxicarboniloxi C3-8, cicloalquenil-C3-8-alquilcarboniloxi C1-6, cicloalquenil-C3-8-haloalquilcarboniloxi C1-6, cicloalquenil-C3-8-alcoxicarboniloxi C1-6, cicloalquenil-C3-8-haloalcoxicarboniloxi C1-6; cicloalquiltio C3-8, alqueniltio C3-8, cicloalqueniltio C3-8, alquiniltio C3-8, hidroxi-alquilo C1-6, hidroxi-alcoxi C1-6 ciano-alcoxi C1-6, ciano-alquilo C1-6,-3-oxetaniloxi-, pirimidinil-2-ilo y 4,6-dimetoxipirimidinil-2-ilo -C(O)NR9R10 donde R9 y R10 de manera independiente entre sí significan hidrogeno, alquilo C1-6, cicloalquilo C3-6, haloalquilo C1-6, o donde R9 y R10 forman juntos un grupo alquileno C1-6, que puede contener un átomo de oxígeno o un átomo de sulfuro o uno o dos grupos amino o alquilamino C1-6, donde los restos mencionados en su caso pueden estar enlazados en forma cíclica entre sí, con la condicion que se encuentren en posicion-orto y/o dos sustituyentes en posicion orto forman juntos un grupo alquileno C1-6, que puede contener uno o varios átomos de oxígeno y/o sulfuro, donde el grupo alquileno C1-6 puede estar mono- o polisustituido con halogeno y los respectivos sustituyentes halogeno pueden ser iguales o diferentes; donde los restos cicloalquilo o arilo pueden estar mono- o polisustituidos de manera independiente entre sí.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP07023152A EP2065373A1 (de) | 2007-11-30 | 2007-11-30 | Chirale 3-(Benzylsulfinyl)-5,5-dimethyl-4,5-dihydroisoxazol-Derivate und 5,5-Dimethyl-3-[(1H-pyrazol-4-ylmethyl) sulfinyl]-4,5-dihydroisoxazol-Derivate, Verfahren zu deren Herstellung sowie deren Verwendung als Herbizide und Pflanzenwachstumsregulatoren |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR069489A1 true AR069489A1 (es) | 2010-01-27 |
Family
ID=39247238
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP080105200 AR069489A1 (es) | 2007-11-30 | 2008-11-28 | Derivados de 3-(bencilsulfinil)-5,5-dimetil-4,5-dihidroisoxazol y derivados de 5,5-dimetil-3-[(1h-pirazol-4-ilmetil)sulfinil]-4,5-dihidroisoxazol quirales, proce-dimientos para su preparacion asi como su uso como herbicidas y como re-guladores del crecimiento de las plantas |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US8420570B2 (es) |
| EP (2) | EP2065373A1 (es) |
| AR (1) | AR069489A1 (es) |
| AU (1) | AU2008329187B2 (es) |
| BR (1) | BRPI0819702A2 (es) |
| CA (1) | CA2707133C (es) |
| WO (1) | WO2009068171A2 (es) |
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| US9121022B2 (en) | 2010-03-08 | 2015-09-01 | Monsanto Technology Llc | Method for controlling herbicide-resistant plants |
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| MX350775B (es) | 2011-09-13 | 2017-09-15 | Monsanto Technology Llc | Métodos y composiciones para el control de malezas. |
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| CN116803993A (zh) * | 2019-10-23 | 2023-09-26 | 青岛清原化合物有限公司 | 一种含手性硫氧化物的芳基甲酰胺类化合物或其盐、制备方法、除草组合物和应用 |
| CN113620941B (zh) * | 2020-05-07 | 2023-07-14 | 宁夏苏融达化工有限公司 | 环丙基-吡唑衍生物及其在农业中的应用 |
| CN113754648B (zh) * | 2020-06-02 | 2023-02-17 | 山东润博生物科技有限公司 | 一种砜吡草唑及其中间体的制备方法 |
| CN114075149A (zh) * | 2020-08-20 | 2022-02-22 | 宁夏苏融达化工有限公司 | 含二氟苯基的杂环化合物及其应用 |
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-
2007
- 2007-11-30 EP EP07023152A patent/EP2065373A1/de not_active Withdrawn
-
2008
- 2008-11-08 WO PCT/EP2008/009438 patent/WO2009068171A2/de not_active Ceased
- 2008-11-08 CA CA2707133A patent/CA2707133C/en not_active Expired - Fee Related
- 2008-11-08 AU AU2008329187A patent/AU2008329187B2/en not_active Ceased
- 2008-11-08 BR BRPI0819702-4A2A patent/BRPI0819702A2/pt not_active Application Discontinuation
- 2008-11-08 EP EP08854816.9A patent/EP2227457B1/de not_active Not-in-force
- 2008-11-08 US US12/744,042 patent/US8420570B2/en not_active Expired - Fee Related
- 2008-11-28 AR ARP080105200 patent/AR069489A1/es unknown
-
2013
- 2013-03-15 US US13/842,245 patent/US8895471B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| AU2008329187A1 (en) | 2009-06-04 |
| US8420570B2 (en) | 2013-04-16 |
| WO2009068171A2 (de) | 2009-06-04 |
| AU2008329187B2 (en) | 2014-08-14 |
| EP2227457A2 (de) | 2010-09-15 |
| US20130316904A1 (en) | 2013-11-28 |
| US20100255988A1 (en) | 2010-10-07 |
| WO2009068171A3 (de) | 2009-09-03 |
| CA2707133C (en) | 2016-06-14 |
| US8895471B2 (en) | 2014-11-25 |
| BRPI0819702A2 (pt) | 2014-10-07 |
| EP2065373A1 (de) | 2009-06-03 |
| EP2227457B1 (de) | 2016-05-04 |
| CA2707133A1 (en) | 2009-06-04 |
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