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MX2008008812A - Metodo para la reduccion directa de oxidos de hierro a hierro metalico utilizando gas de coquerias o similares. - Google Patents

Metodo para la reduccion directa de oxidos de hierro a hierro metalico utilizando gas de coquerias o similares.

Info

Publication number
MX2008008812A
MX2008008812A MX2008008812A MX2008008812A MX2008008812A MX 2008008812 A MX2008008812 A MX 2008008812A MX 2008008812 A MX2008008812 A MX 2008008812A MX 2008008812 A MX2008008812 A MX 2008008812A MX 2008008812 A MX2008008812 A MX 2008008812A
Authority
MX
Mexico
Prior art keywords
zone
coke oven
reduction
oven gas
reactor
Prior art date
Application number
MX2008008812A
Other languages
English (en)
Inventor
Eugenio Zendejas Martinez
Pablo Enrique Duarte Escareno
Original Assignee
Hyl Technologies Sa De Cv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hyl Technologies Sa De Cv filed Critical Hyl Technologies Sa De Cv
Publication of MX2008008812A publication Critical patent/MX2008008812A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B5/00—General methods of reducing to metals
    • C22B5/02—Dry methods smelting of sulfides or formation of mattes
    • C22B5/12—Dry methods smelting of sulfides or formation of mattes by gases
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B13/00—Making spongy iron or liquid steel, by direct processes
    • C21B13/0073—Selection or treatment of the reducing gases
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B13/00—Making spongy iron or liquid steel, by direct processes
    • C21B13/02—Making spongy iron or liquid steel, by direct processes in shaft furnaces
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B13/00—Making spongy iron or liquid steel, by direct processes
    • C21B13/02—Making spongy iron or liquid steel, by direct processes in shaft furnaces
    • C21B13/029—Introducing coolant gas in the shaft furnaces
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/20—Increasing the gas reduction potential of recycled exhaust gases
    • C21B2100/22—Increasing the gas reduction potential of recycled exhaust gases by reforming
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/60—Process control or energy utilisation in the manufacture of iron or steel
    • C21B2100/64—Controlling the physical properties of the gas, e.g. pressure or temperature
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/10—Reduction of greenhouse gas [GHG] emissions
    • Y02P10/122—Reduction of greenhouse gas [GHG] emissions by capturing or storing CO2
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/10—Reduction of greenhouse gas [GHG] emissions
    • Y02P10/134—Reduction of greenhouse gas [GHG] emissions by avoiding CO2, e.g. using hydrogen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/10—Reduction of greenhouse gas [GHG] emissions
    • Y02P10/143—Reduction of greenhouse gas [GHG] emissions of methane [CH4]

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Manufacture Of Iron (AREA)
  • Industrial Gases (AREA)

Abstract

Un proceso para la reducción de partículas de mineral de hierro en un reactor de reducción de lecho móvil que comprende una zona superior de reducción y una zona inferior de descarga, donde un gas de proceso contenido metano, por ejemplo gas de coquerías, forma preferentemente la totalidad del repuesto de gas reductor que reacciona y que circula a través de dicha zona de reducción y es alimentado en primer lugar a dicha zona de descarga (y opcionalmente de enfriamiento) y luego dicho gas de coquería, acondicionado por el HRD en la zona inferior, se extrae del reactor y se transfiere externamente al gas reductor reciclado para inyectarlo a la zona de reducción del reactor. Se eliminan del gas de horno de coquerías los hidrocarburos pesados y otros componentes del gas de horno de coquería que, de lo contrario, pueden causar obstrucción, corrosión o depósitos en la planta de reducción directa, mediante la acción catalítica y/o adsorbente del HRD presente en dicha zona inferior, antes de ser transferido externamente a la zona de reducción del reactor de reducción. La diferencia en el flujo volumétrico del gas de proceso conteniendo metano y el flujo volumétrico del gas transferido externamente está en el rango de aproximadamente 100 y aproximadamente 200 metros cúbicos normales (MCN) por tonelada de HRD producida.
MX2008008812A 2006-01-06 2007-01-05 Metodo para la reduccion directa de oxidos de hierro a hierro metalico utilizando gas de coquerias o similares. MX2008008812A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US75768806P 2006-01-06 2006-01-06
PCT/IB2007/001681 WO2007096784A2 (en) 2006-01-06 2007-01-05 Method and apparatus for the direct reduction of iron oxides to metallic iron

Publications (1)

Publication Number Publication Date
MX2008008812A true MX2008008812A (es) 2008-11-18

Family

ID=38250603

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2008008812A MX2008008812A (es) 2006-01-06 2007-01-05 Metodo para la reduccion directa de oxidos de hierro a hierro metalico utilizando gas de coquerias o similares.

Country Status (9)

Country Link
US (1) US8377168B2 (es)
EP (1) EP1984530B1 (es)
CN (1) CN1995402B (es)
AR (1) AR058946A1 (es)
BR (1) BRPI0706367B1 (es)
MX (1) MX2008008812A (es)
RU (1) RU2439165C2 (es)
UA (1) UA91109C2 (es)
WO (1) WO2007096784A2 (es)

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US7938882B2 (en) * 2007-04-02 2011-05-10 Midrex Technologies, Inc. Method and system for the supply of hot direct reduced iron for multiple uses
KR101710560B1 (ko) * 2009-07-31 2017-02-27 에이치와이엘 테크놀로지즈, 에스.에이. 데 씨.브이. 제한된 ｃｏ2 방출로 직접 환원 철을 제조하기 위한 방법
US8496730B2 (en) * 2010-05-14 2013-07-30 Midrex Technologies, Inc. System and method for reducing iron oxide to metallic iron using coke oven gas and oxygen steelmaking furnace gas
US9028585B2 (en) 2010-05-14 2015-05-12 Midrex Technologies, Inc. System and method for reducing iron oxide to metallic iron using coke oven gas and oxygen steelmaking furnace gas
US9127326B2 (en) 2010-05-14 2015-09-08 Midrex Technologies, Inc. System and method for reducing iron oxide to metallic iron using natural gas
US8690986B2 (en) 2010-09-03 2014-04-08 Forest Vue Research, Llc Method for simultaneously producing iron, coke, and power
WO2012030413A2 (en) * 2010-09-03 2012-03-08 Forest Vue Research Llc Method for simultaneously producing iron, coke, and power
AT510955B1 (de) * 2011-05-30 2012-08-15 Siemens Vai Metals Tech Gmbh Reduktion von metalloxiden unter verwendung eines sowohl kohlenwasserstoff als auch wasserstoff enthaltenden gasstromes
CN102338766A (zh) * 2011-08-02 2012-02-01 湘潭大学 一种用于双酚a检测的电化学传感器
EP2744922B1 (en) * 2011-08-20 2020-07-01 HYL Technologies, S.A. de C.V. Process for producing direct reduced iron (dri) utilizing gases derived from coal
CN102311821A (zh) * 2011-08-20 2012-01-11 太原理工大学 一种焦炉气磁化赤铁矿生产天然气的方法
KR20140108309A (ko) * 2011-12-21 2014-09-05 에이치와이엘 테크놀로지즈, 에스.에이. 데 씨.브이. 코크스로 가스를 이용하여 직접환원철(ｄｒｉ)을 생성하기 위한 방법 및 장치
CN102605132A (zh) * 2012-01-13 2012-07-25 中冶赛迪工程技术股份有限公司 一种利用焦炉煤气生产直接还原铁的方法
JP2014227588A (ja) * 2013-05-24 2014-12-08 新日鉄住金エンジニアリング株式会社 直接還元鉄の製造装置、及び直接還元鉄の製造方法
UA117374C2 (uk) * 2013-07-31 2018-07-25 Мідрекс Текнолоджиз, Інк. Відновлення оксиду заліза до металевого заліза із застосуванням коксового газу та газу зі сталеплавильної печі з подачею кисню
KR20160048766A (ko) * 2013-07-31 2016-05-04 미드렉스 테크놀리지스, 인코오포레이티드 천연가스를 이용하여 산화철을 금속철로 환원하는 시스템 및 그 방법
WO2016011122A1 (en) * 2014-07-15 2016-01-21 Midrex Technologies, Inc. Methods and systems for producing direct reduced iron and steel mill fuel gas
WO2016118474A1 (en) * 2015-01-20 2016-07-28 Midrex Technologies, Inc. Methods and systems for producing high carbon content metallic iron using coke over gas
WO2016199291A1 (ja) * 2015-06-12 2016-12-15 株式会社神戸製鋼所 還元鉄の製造方法
EP3255157A1 (de) * 2016-06-09 2017-12-13 Primetals Technologies Austria GmbH Verfahren zur direktreduktion mit trockener ventgasentstaubung
US11021766B2 (en) 2016-11-03 2021-06-01 Midrex Technologies, Inc. Direct reduction with coal gasification and coke oven gas
EP3453773A1 (de) * 2017-09-06 2019-03-13 Primetals Technologies Austria GmbH Reduktionsgasgewinnung aus gesättigtem topgas
JP6917266B2 (ja) * 2017-10-04 2021-08-11 三菱重工エンジニアリング株式会社 ガス燃焼処理装置及び燃焼処理方法、ガス燃焼処理装置を備えたガス精製システム
EP3581663A1 (de) 2018-06-12 2019-12-18 Primetals Technologies Austria GmbH Herstellung von karburiertem eisenschwamm mittels wasserstoffbasierter direktreduktion
CN109433277A (zh) * 2018-11-25 2019-03-08 中海油天津化工研究设计院有限公司 一种可连续操作的催化剂还原装置
IT201900002081A1 (it) * 2019-02-13 2020-08-13 Danieli Off Mecc Impianto di riduzione diretta e relativo processo
DE102021112208A1 (de) * 2021-05-11 2022-11-17 Thyssenkrupp Steel Europe Ag Verfahren zur Direktreduktion von Eisenerz
CN113883851B (zh) * 2021-08-31 2022-09-13 内蒙古万众炜业科技环保股份公司 一种兰炭节能生产用干燥装置及其工艺
TWI861574B (zh) * 2021-10-14 2024-11-11 日商日本製鐵股份有限公司 還原鐵之製造方法
CN116832723A (zh) * 2023-04-11 2023-10-03 湖南科技大学 一种太阳能高倍聚光供热的Fe3O4还原铁粉燃料生产系统
WO2025058716A1 (en) 2023-09-12 2025-03-20 Ternium Mexico S.A. De C.V. Process for producing clean steel with low nitrogen content using an electric arc furnace and a degassing system

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US4224057A (en) * 1979-08-20 1980-09-23 Hylsa, S.A. Method for carburizing sponge iron
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Also Published As

Publication number Publication date
BRPI0706367B1 (pt) 2014-07-08
UA91109C2 (ru) 2010-06-25
EP1984530A2 (en) 2008-10-29
EP1984530B1 (en) 2019-07-17
US20090211401A1 (en) 2009-08-27
US8377168B2 (en) 2013-02-19
AR058946A1 (es) 2008-03-05
EP1984530A4 (en) 2017-04-26
CN1995402A (zh) 2007-07-11
WO2007096784A3 (en) 2009-04-23
WO2007096784A2 (en) 2007-08-30
RU2008132328A (ru) 2010-02-20
BRPI0706367A2 (pt) 2011-03-22
CN1995402B (zh) 2011-11-16
RU2439165C2 (ru) 2012-01-10

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