AR058946A1 - Metodo para la reduccion directa de oxidos de hierro a hierro metlico utilizando gas de coquerias o similares - Google Patents
Metodo para la reduccion directa de oxidos de hierro a hierro metlico utilizando gas de coquerias o similaresInfo
- Publication number
- AR058946A1 AR058946A1 ARP070100072A AR058946A1 AR 058946 A1 AR058946 A1 AR 058946A1 AR P070100072 A ARP070100072 A AR P070100072A AR 058946 A1 AR058946 A1 AR 058946A1
- Authority
- AR
- Argentina
- Prior art keywords
- reduction
- zone
- gas
- gas stream
- reactor
- Prior art date
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title abstract 8
- 229910052742 iron Inorganic materials 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 title abstract 2
- 235000013980 iron oxide Nutrition 0.000 title abstract 2
- 239000007789 gas Substances 0.000 abstract 16
- 239000000571 coke Substances 0.000 abstract 4
- 239000002245 particle Substances 0.000 abstract 4
- 238000001816 cooling Methods 0.000 abstract 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 230000002745 absorbent Effects 0.000 abstract 1
- 239000002250 absorbent Substances 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 230000001143 conditioned effect Effects 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B5/00—General methods of reducing to metals
- C22B5/02—Dry methods smelting of sulfides or formation of mattes
- C22B5/12—Dry methods smelting of sulfides or formation of mattes by gases
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/0073—Selection or treatment of the reducing gases
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/02—Making spongy iron or liquid steel, by direct processes in shaft furnaces
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/02—Making spongy iron or liquid steel, by direct processes in shaft furnaces
- C21B13/029—Introducing coolant gas in the shaft furnaces
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
- C21B2100/20—Increasing the gas reduction potential of recycled exhaust gases
- C21B2100/22—Increasing the gas reduction potential of recycled exhaust gases by reforming
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
- C21B2100/60—Process control or energy utilisation in the manufacture of iron or steel
- C21B2100/64—Controlling the physical properties of the gas, e.g. pressure or temperature
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/10—Reduction of greenhouse gas [GHG] emissions
- Y02P10/122—Reduction of greenhouse gas [GHG] emissions by capturing or storing CO2
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/10—Reduction of greenhouse gas [GHG] emissions
- Y02P10/134—Reduction of greenhouse gas [GHG] emissions by avoiding CO2, e.g. using hydrogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/10—Reduction of greenhouse gas [GHG] emissions
- Y02P10/143—Reduction of greenhouse gas [GHG] emissions of methane [CH4]
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Manufacture Of Iron (AREA)
- Industrial Gases (AREA)
Abstract
Un proceso para la reduccion de partículas de mineral de hierro en un reactor de reduccion de lecho movil que comprende una zona de reduccion superior y una zona inferior de descarga, en el cual el gas de horno de coque forma preferentemente la totalidad de la reposicion de gas reductor que circula a través de dicha zona de reduccion y reacciona en la misma es alimentada en primer lugar a dicha zona de descarga (enfriamiento) y luego se retira del reactor dicho gas de horno de coque, acondicionado por el DRI en la zona inferior y se lo alimenta al gas reductor reciclado para inyectarlo a la zona de reduccion del reactor. Se eliminan los hidrocarburos pesados y otros componentes del gas de horno de coque que, de lo contrario, pueden causar obstruccion, corrosion o depositos en la planta de reduccion directa del gas de horno de coque mediante la accion catalítica y/o absorbente del DRI presente en dicha zona inferior, antes de ser transferida por medios exteriores a la zona de reduccion del reactor de reduccion. Reivindicacion 1: Un método para la produccion de hierro de reduccion directa (DRI) por medio de la reduccion de partículas que contienen oxidos de hierro a hierro metálico (DRI) en un reactor de reduccion que comprende una zona de reduccion y una zona inferior de enfriamiento y/o descarga, mediante el contacto de dichas partículas con una corriente de gas a alta temperatura que comprende hidrogeno y monoxido de carbono en dicha zona de reduccion, y donde las partículas reducidas descienden a través de dicha zona inferior, donde dicho método se caracteriza por la mejora que comprende: hacer circular de una primera corriente de gas a través de dicha zona inferior, extraer una porcion de dicha primera corriente de gas de dicha zona inferior como una segunda corriente de gas, alimentar una tercera corriente de gas conteniendo metano a dicha zona inferior de dicho reactor de manera que fluya hacia dicha zona inferior y por lo menos una parte de dicha tercera corriente de gas forme parte de la primera corriente de gas; y transferir externamente por lo menos una primera porcion de dicha segunda corriente de gas de nuevo a dicha zona de reduccion, donde la velocidad de flujo de dicha tercera corriente de gas es mayor que la velocidad de flujo de dicha porcion transferida de dicha segunda corriente de gas y donde la diferencia de dichas velocidades de flujo es de entre aproximadamente 50 metros cubicos normales y aproximadamente 300 metros cubicos normales por tonelada métrica de DRI producido en dicho reactor de reduccion.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US75768806P | 2006-01-06 | 2006-01-06 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR058946A1 true AR058946A1 (es) | 2008-03-05 |
Family
ID=38250603
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP070100072 AR058946A1 (es) | 2006-01-06 | 2007-01-08 | Metodo para la reduccion directa de oxidos de hierro a hierro metlico utilizando gas de coquerias o similares |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US8377168B2 (es) |
| EP (1) | EP1984530B1 (es) |
| CN (1) | CN1995402B (es) |
| AR (1) | AR058946A1 (es) |
| BR (1) | BRPI0706367B1 (es) |
| MX (1) | MX2008008812A (es) |
| RU (1) | RU2439165C2 (es) |
| UA (1) | UA91109C2 (es) |
| WO (1) | WO2007096784A2 (es) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7938882B2 (en) * | 2007-04-02 | 2011-05-10 | Midrex Technologies, Inc. | Method and system for the supply of hot direct reduced iron for multiple uses |
| KR101710560B1 (ko) * | 2009-07-31 | 2017-02-27 | 에이치와이엘 테크놀로지즈, 에스.에이. 데 씨.브이. | 제한된 co2 방출로 직접 환원 철을 제조하기 위한 방법 |
| US8496730B2 (en) * | 2010-05-14 | 2013-07-30 | Midrex Technologies, Inc. | System and method for reducing iron oxide to metallic iron using coke oven gas and oxygen steelmaking furnace gas |
| US9028585B2 (en) | 2010-05-14 | 2015-05-12 | Midrex Technologies, Inc. | System and method for reducing iron oxide to metallic iron using coke oven gas and oxygen steelmaking furnace gas |
| US9127326B2 (en) | 2010-05-14 | 2015-09-08 | Midrex Technologies, Inc. | System and method for reducing iron oxide to metallic iron using natural gas |
| US8690986B2 (en) | 2010-09-03 | 2014-04-08 | Forest Vue Research, Llc | Method for simultaneously producing iron, coke, and power |
| WO2012030413A2 (en) * | 2010-09-03 | 2012-03-08 | Forest Vue Research Llc | Method for simultaneously producing iron, coke, and power |
| AT510955B1 (de) * | 2011-05-30 | 2012-08-15 | Siemens Vai Metals Tech Gmbh | Reduktion von metalloxiden unter verwendung eines sowohl kohlenwasserstoff als auch wasserstoff enthaltenden gasstromes |
| CN102338766A (zh) * | 2011-08-02 | 2012-02-01 | 湘潭大学 | 一种用于双酚a检测的电化学传感器 |
| EP2744922B1 (en) * | 2011-08-20 | 2020-07-01 | HYL Technologies, S.A. de C.V. | Process for producing direct reduced iron (dri) utilizing gases derived from coal |
| CN102311821A (zh) * | 2011-08-20 | 2012-01-11 | 太原理工大学 | 一种焦炉气磁化赤铁矿生产天然气的方法 |
| KR20140108309A (ko) * | 2011-12-21 | 2014-09-05 | 에이치와이엘 테크놀로지즈, 에스.에이. 데 씨.브이. | 코크스로 가스를 이용하여 직접환원철(dri)을 생성하기 위한 방법 및 장치 |
| CN102605132A (zh) * | 2012-01-13 | 2012-07-25 | 中冶赛迪工程技术股份有限公司 | 一种利用焦炉煤气生产直接还原铁的方法 |
| JP2014227588A (ja) * | 2013-05-24 | 2014-12-08 | 新日鉄住金エンジニアリング株式会社 | 直接還元鉄の製造装置、及び直接還元鉄の製造方法 |
| UA117374C2 (uk) * | 2013-07-31 | 2018-07-25 | Мідрекс Текнолоджиз, Інк. | Відновлення оксиду заліза до металевого заліза із застосуванням коксового газу та газу зі сталеплавильної печі з подачею кисню |
| KR20160048766A (ko) * | 2013-07-31 | 2016-05-04 | 미드렉스 테크놀리지스, 인코오포레이티드 | 천연가스를 이용하여 산화철을 금속철로 환원하는 시스템 및 그 방법 |
| WO2016011122A1 (en) * | 2014-07-15 | 2016-01-21 | Midrex Technologies, Inc. | Methods and systems for producing direct reduced iron and steel mill fuel gas |
| WO2016118474A1 (en) * | 2015-01-20 | 2016-07-28 | Midrex Technologies, Inc. | Methods and systems for producing high carbon content metallic iron using coke over gas |
| WO2016199291A1 (ja) * | 2015-06-12 | 2016-12-15 | 株式会社神戸製鋼所 | 還元鉄の製造方法 |
| EP3255157A1 (de) * | 2016-06-09 | 2017-12-13 | Primetals Technologies Austria GmbH | Verfahren zur direktreduktion mit trockener ventgasentstaubung |
| US11021766B2 (en) | 2016-11-03 | 2021-06-01 | Midrex Technologies, Inc. | Direct reduction with coal gasification and coke oven gas |
| EP3453773A1 (de) * | 2017-09-06 | 2019-03-13 | Primetals Technologies Austria GmbH | Reduktionsgasgewinnung aus gesättigtem topgas |
| JP6917266B2 (ja) * | 2017-10-04 | 2021-08-11 | 三菱重工エンジニアリング株式会社 | ガス燃焼処理装置及び燃焼処理方法、ガス燃焼処理装置を備えたガス精製システム |
| EP3581663A1 (de) | 2018-06-12 | 2019-12-18 | Primetals Technologies Austria GmbH | Herstellung von karburiertem eisenschwamm mittels wasserstoffbasierter direktreduktion |
| CN109433277A (zh) * | 2018-11-25 | 2019-03-08 | 中海油天津化工研究设计院有限公司 | 一种可连续操作的催化剂还原装置 |
| IT201900002081A1 (it) * | 2019-02-13 | 2020-08-13 | Danieli Off Mecc | Impianto di riduzione diretta e relativo processo |
| DE102021112208A1 (de) * | 2021-05-11 | 2022-11-17 | Thyssenkrupp Steel Europe Ag | Verfahren zur Direktreduktion von Eisenerz |
| CN113883851B (zh) * | 2021-08-31 | 2022-09-13 | 内蒙古万众炜业科技环保股份公司 | 一种兰炭节能生产用干燥装置及其工艺 |
| TWI861574B (zh) * | 2021-10-14 | 2024-11-11 | 日商日本製鐵股份有限公司 | 還原鐵之製造方法 |
| CN116832723A (zh) * | 2023-04-11 | 2023-10-03 | 湖南科技大学 | 一种太阳能高倍聚光供热的Fe3O4还原铁粉燃料生产系统 |
| WO2025058716A1 (en) | 2023-09-12 | 2025-03-20 | Ternium Mexico S.A. De C.V. | Process for producing clean steel with low nitrogen content using an electric arc furnace and a degassing system |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4049440A (en) * | 1975-05-19 | 1977-09-20 | Midrex Corporation | Method for producing metallic iron pellets |
| US4054444A (en) * | 1975-09-22 | 1977-10-18 | Midrex Corporation | Method for controlling the carbon content of directly reduced iron |
| US4224057A (en) * | 1979-08-20 | 1980-09-23 | Hylsa, S.A. | Method for carburizing sponge iron |
| US4253867A (en) * | 1979-10-15 | 1981-03-03 | Hylsa, S.A. | Method of using a methane-containing gas for reducing iron ore |
| US4270739A (en) * | 1979-10-22 | 1981-06-02 | Midrex Corporation | Apparatus for direct reduction of iron using high sulfur gas |
| US4351513A (en) * | 1981-01-29 | 1982-09-28 | Midrex Corporation | Direct reduction of iron using coke oven gas |
| MX156697A (es) * | 1982-05-12 | 1988-09-27 | Hylsa Sa | Metodo mejorado para la reduccion directa de minerales de hierro |
| US5110350A (en) * | 1983-05-16 | 1992-05-05 | Hylsa S.A. De C.V. | Method of reducing iron ore |
| CA2090906A1 (en) * | 1992-03-05 | 1993-09-06 | Corporacion Venezolana De Guayana (Cvg) | Method for improving quality of reforming gas used in the direct reduction of metal oxides |
| CN1102215A (zh) * | 1993-10-29 | 1995-05-03 | 鞍山钢铁学院 | 生产直接还原铁的方法 |
| US6039916A (en) * | 1996-09-25 | 2000-03-21 | Hylsa S.A. De C.V. | Apparatus for producing direct reduced iron with a controlled amount of carbon |
| CN1093883C (zh) * | 1997-10-10 | 2002-11-06 | 伊尔萨有限公司 | 控制直接还原铁渗碳的方法和设备 |
| US6033456A (en) * | 1998-02-06 | 2000-03-07 | Texaco Inc. | Integration of partial oxidation process and direct reduction reaction process |
| US6027545A (en) * | 1998-02-20 | 2000-02-22 | Hylsa, S.A. De C.V. | Method and apparatus for producing direct reduced iron with improved reducing gas utilization |
| US20050151307A1 (en) * | 2003-09-30 | 2005-07-14 | Ricardo Viramontes-Brown | Method and apparatus for producing molten iron |
-
2006
- 2006-04-07 CN CN2006100820379A patent/CN1995402B/zh active Active
-
2007
- 2007-01-05 RU RU2008132328A patent/RU2439165C2/ru active
- 2007-01-05 EP EP07734876.1A patent/EP1984530B1/en active Active
- 2007-01-05 US US12/160,180 patent/US8377168B2/en active Active
- 2007-01-05 UA UAA200810025A patent/UA91109C2/ru unknown
- 2007-01-05 MX MX2008008812A patent/MX2008008812A/es active IP Right Grant
- 2007-01-05 BR BRPI0706367-9B1A patent/BRPI0706367B1/pt active IP Right Grant
- 2007-01-05 WO PCT/IB2007/001681 patent/WO2007096784A2/en not_active Ceased
- 2007-01-08 AR ARP070100072 patent/AR058946A1/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0706367B1 (pt) | 2014-07-08 |
| UA91109C2 (ru) | 2010-06-25 |
| EP1984530A2 (en) | 2008-10-29 |
| MX2008008812A (es) | 2008-11-18 |
| EP1984530B1 (en) | 2019-07-17 |
| US20090211401A1 (en) | 2009-08-27 |
| US8377168B2 (en) | 2013-02-19 |
| EP1984530A4 (en) | 2017-04-26 |
| CN1995402A (zh) | 2007-07-11 |
| WO2007096784A3 (en) | 2009-04-23 |
| WO2007096784A2 (en) | 2007-08-30 |
| RU2008132328A (ru) | 2010-02-20 |
| BRPI0706367A2 (pt) | 2011-03-22 |
| CN1995402B (zh) | 2011-11-16 |
| RU2439165C2 (ru) | 2012-01-10 |
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| Date | Code | Title | Description |
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| FG | Grant, registration |