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WO1994000548A1 - Compositions contenant un peracide organique et un compose d'ammonium quaternaire - Google Patents

Compositions contenant un peracide organique et un compose d'ammonium quaternaire Download PDF

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Publication number
WO1994000548A1
WO1994000548A1 PCT/GB1993/001276 GB9301276W WO9400548A1 WO 1994000548 A1 WO1994000548 A1 WO 1994000548A1 GB 9301276 W GB9301276 W GB 9301276W WO 9400548 A1 WO9400548 A1 WO 9400548A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
qac
ammonium
solution
sanitising
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/GB1993/001276
Other languages
English (en)
Inventor
Christopher Thomas Wright
Paul Brougham
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LHS UK Ltd
Original Assignee
Laporte ESD Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Laporte ESD Ltd filed Critical Laporte ESD Ltd
Publication of WO1994000548A1 publication Critical patent/WO1994000548A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group; Thio analogues thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3947—Liquid compositions

Definitions

  • This invention is concerned with compositions comprising organic peroxygenated acids and quaternary ammonium compounds (QAC's). More particularly, though not exclusively, this invention concerns solutions comprising peracetic acid and biocidal QAC's suitable for use in or as cleaning, sanitising and sterilising compositions.
  • QAC's quaternary ammonium compounds
  • PAA peracetic acid
  • QAC certain QAC's have biocidal activity and this fact has been exploited in the past by incorporating the compounds individually into, for example, cleaning, sanitising and sterilising compositions used in hospitals and dairies.
  • PAA based compositions are most effective at acidic pH's, whereas the QAC based compositions are most effective at alkaline pH's.
  • WO 88/00795 discloses an antiseptic composition comprising PAA, alkyldimethylbenzyl ammonium chloride and an essential oil.
  • compositions suitable for use in or as a cleaning, sanitising or sterilising composition characterised in that the composition comprises an organic peroxyacid, and a quaternary ammonium compound having a non-halogen or non-halogenated anion.
  • the QAC is a non- halogenated QAC, where both the anion and cation of the QAC comprise groups other than halogen or halogenated groups.
  • compositions of the present invention are stable over relatively long periods of time (at least one month) and both peroxyacid and non-biocidal QAC compositions and peroxyacid and biocidal QAC compositions may demonstrate synergistic improvements in effectiveness against microbials. Furthermore, the peroxyacid and biocidal QAC compositions may be effective over a broader pH range than prior art compositions comprising the components alone.
  • the weight ratio of peroxyacid:QAC in the composition is preferably from about 20:1 to about 1:30, more preferably from about 10:1 to about 1:10, and most preferably from about 10:1 to about 1:3.
  • the peroxyacids useful in the composition of the present invention are preferably organic peroxycarboxylic acids, more preferably C 2 -C 10 aliphatic peroxyacids, e.g. PAA and pernonanoicacid.
  • the peracid may be unsubstituted or substituted.
  • the most preferred peroxyacid is PAA.
  • the QAC's useful in the present invention must contain non-halogen or non-halogenated counter ions and are preferably biocidal.
  • suitable QAC's include alkyl poly(oxyalkyl)ammonium propionates such as N,N- didecyl-N-methyl-poly(oxyethyl)ammoniumpropionates, alkyl or alkylaryl ammonium methosulphates such as alkyltrimethyl ammonium methosulphates or alkyldimethylbenzylammoniummethosulphate, dialkylammonium methosulphates, alkyldimethylbenzylammoniumsaccharinates, quaternary ammonium ethosulphates, quaternary ammonium hydroxides, polypropoxyquaternary ammonium acetates and polypropoxyquaternary ammonium phosphates.
  • the alkyl groups are Cj-C 30 , more preferably C 10 -C 20 , and most preferably C 12 -C ⁇ 6 , alkyl groups.
  • the oxyalkyl groups are preferably ox ⁇ (C 1 -C 6 )alkyl groups.
  • compositions of the present invention are preferably in the form of a solution.
  • the preferred solvents include water and appropriate organic polar solvents such as methanol or ethanol. Water is the most preferred solvent.
  • the solutions are preferably acidic, e.g. having a pH of from 1 to 7, for enhanced storage stability.
  • nonionic surfactant it is preferred to add to the composition a nonionic surfactant, at an amount of 1-20 wt.% of the composition, preferably 8-12 wt.%.
  • Any nonionic surfactant compatible with the PAA/QAC system may be used, preferably alcohol ethoxylates such as members of the ETHYLAN series from Harcross Chemicals or the SYNPERONIC series from ICI.
  • the nonionic surfactants provide detergency and act as wetting agents.
  • the compositions of the present invention may be supplied in a dilute solution form which is ready for immediate use or in a concentrate solution form which is diluted to the appropriate concentration before use.
  • the amount of peracid in the composition is from about 0.0001% to about 20%, more preferably from about 0.001% to about 5%, and most preferably from about 0.001% to about 2%, by weight of the composition.
  • the amount of QAC in such a typical composition is preferably from about 0.0001% to about 50%, more preferably from about 0.001% to 20%, and most preferably from about 0.005% to about 10%, by weight of the composition.
  • compositions of the present invention may find use in a number of applications where cleaning, sanitising or sterilising solutions are required.
  • solutions based on the compositions are in or as a sterilising solution which may be used by doctors or dentists to sterilise their instruments.
  • the solutions of the present invention offer the advantage that sterilisation of surgical instruments and the like may be effected in a one step process, rather than a two step process as currently practised with prior art sterilisation systems.
  • compositions may also be used in dairies, food processing plants, animal houses, dairy farms and breweries, where the rapid, broad spectrum activity of the compositions together with their ability to wet and penetrate give significant advantages over traditional sanitisers and disinfectants.
  • the solutions have proved particularly effective in meat cleansing, especially cleansing of chicken carcasses.
  • a composition comprising 5 wt.% PAA and 1% wt.% QAA was preferred for this use.
  • the solutions may also be used in paper mills, where a disinfectant is required to prevent microbial growth in the papermaking processes.
  • a disinfectant is required to prevent microbial growth in the papermaking processes.
  • Figure 1 is a graph which compares the effect as a microbicide of a composition of the present invention against a PAA solution and a QAC solution over a broad pH range. -.
  • aqueous PAA solution comprising 13.6% by wt PAA and 11.4% by wt H 2 0 2 , hereafter component K
  • component L hexadecyltrimethyl ammonium chloride
  • Example 13 comprising 50ppm PAA and lOOppm CATIGENE ST30 (alkyltrimethyl ammonium y methosulphate)
  • Example 14 comprising 50ppm PAA
  • Example 15 comprising lOOppm CATIGENE ST30
  • the LRF logarithmic reduction factor
  • compositions comprising nonionic surfactants.
  • the compositions comprised:
  • PAA 10 Wt.% BARDAP 26 10 wt.% nonionic surfactant.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Agronomy & Crop Science (AREA)
  • Inorganic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Une composition pouvant être utilisée comme composition de nettoyage, d'assainissement ou de stérilisation, ou dans une telle composition, est caractérisée par le fait qu'elle comprend un peracide organique, tel qu'un acide peracétique, ainsi qu'un composé d'ammonium quaternaire contenant un anion non halogène ou non halogéné.
PCT/GB1993/001276 1992-06-19 1993-06-16 Compositions contenant un peracide organique et un compose d'ammonium quaternaire Ceased WO1994000548A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB929213059A GB9213059D0 (en) 1992-06-19 1992-06-19 Compositions
GB9213059.0 1992-06-19

Publications (1)

Publication Number Publication Date
WO1994000548A1 true WO1994000548A1 (fr) 1994-01-06

Family

ID=10717401

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB1993/001276 Ceased WO1994000548A1 (fr) 1992-06-19 1993-06-16 Compositions contenant un peracide organique et un compose d'ammonium quaternaire

Country Status (2)

Country Link
GB (1) GB9213059D0 (fr)
WO (1) WO1994000548A1 (fr)

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5731275A (en) * 1994-04-05 1998-03-24 Universite De Montreal Synergistic detergent and disinfectant combinations for decontaminating biofilm-coated surfaces
FR2759380A1 (fr) * 1997-02-13 1998-08-14 Anios Lab Sarl Composition detergente et/ou desinfectante
FR2761080A1 (fr) * 1997-03-21 1998-09-25 Quadrimex Composition a base de peracides pour le nettoyage, la desinfection et la decontamination de surfaces souillees par des agents toxiques
WO2001030452A1 (fr) * 1999-10-29 2001-05-03 Atofina Composition et procede pour la destruction de polluants organophosphores et/ou organosoufres
US6262013B1 (en) 1999-01-14 2001-07-17 Ecolab Inc. Sanitizing laundry sour
WO2001070030A3 (fr) * 2000-03-22 2002-01-31 Ecolab Inc Compositions d'acide peroxycarboxylique et procedes d'utilisations contre des spores microbiennes
US6436445B1 (en) 1999-03-26 2002-08-20 Ecolab Inc. Antimicrobial and antiviral compositions containing an oxidizing species
US6534075B1 (en) 1999-03-26 2003-03-18 Ecolab Inc. Antimicrobial and antiviral compositions and treatments for food surfaces
US6762160B2 (en) 1998-11-06 2004-07-13 Universite De Montreal Composition for removing biofilms comprising a detergent and a salt forming acid
US6855328B2 (en) 2002-03-28 2005-02-15 Ecolab Inc. Antimicrobial and antiviral compositions containing an oxidizing species
US6908628B2 (en) * 2001-06-15 2005-06-21 Oftrai, S.L. Disinfectant and antiseptic composition
WO2010109166A1 (fr) * 2009-03-25 2010-09-30 Reckitt Benckiser N.V. Composition
EP2407529A1 (fr) * 2010-07-12 2012-01-18 Solvay SA Composition de peroxygène
WO2016040230A1 (fr) * 2014-09-09 2016-03-17 Lonza, Inc. Composition désinfectante contenant des composés d'ammonium quaternaire
US9382503B2 (en) 2011-03-09 2016-07-05 Reckitt Benckiser Vanish B.V. Carpet cleaning composition

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2126255A1 (fr) * 1971-02-22 1972-10-06 Procter & Gamble
US4045358A (en) * 1973-06-04 1977-08-30 Colgate Palmolive Company Softener and bleaching composition
EP0086423A2 (fr) * 1982-02-15 1983-08-24 Henkel Kommanditgesellschaft auf Aktien Moyen et procédé pour le posttraitement du linge lavé
EP0184099A2 (fr) * 1984-12-03 1986-06-11 Henkel Kommanditgesellschaft auf Aktien Moyen et procédé pour le post-traitement du linge lavé
WO1988000795A1 (fr) * 1986-07-25 1988-02-11 Garcin Francoise Composition antiseptique incorporant des huiles essentielles
EP0340754A2 (fr) * 1988-05-04 1989-11-08 AUSIMONT S.p.A. Monopersulfates d'acides amino-(poly)percarboxyliques
EP0443640A2 (fr) * 1990-01-23 1991-08-28 Unilever N.V. Procédé de blanchiment et utilisation de composés d'ammonium quaternaires dans des compositions de blanchiment

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2126255A1 (fr) * 1971-02-22 1972-10-06 Procter & Gamble
US4045358A (en) * 1973-06-04 1977-08-30 Colgate Palmolive Company Softener and bleaching composition
EP0086423A2 (fr) * 1982-02-15 1983-08-24 Henkel Kommanditgesellschaft auf Aktien Moyen et procédé pour le posttraitement du linge lavé
EP0184099A2 (fr) * 1984-12-03 1986-06-11 Henkel Kommanditgesellschaft auf Aktien Moyen et procédé pour le post-traitement du linge lavé
WO1988000795A1 (fr) * 1986-07-25 1988-02-11 Garcin Francoise Composition antiseptique incorporant des huiles essentielles
EP0340754A2 (fr) * 1988-05-04 1989-11-08 AUSIMONT S.p.A. Monopersulfates d'acides amino-(poly)percarboxyliques
EP0443640A2 (fr) * 1990-01-23 1991-08-28 Unilever N.V. Procédé de blanchiment et utilisation de composés d'ammonium quaternaires dans des compositions de blanchiment

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Section Ch, Week 8925, Derwent Publications Ltd., London, GB; Class D25, AN 89-184199 [25] *

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5759970A (en) * 1994-04-05 1998-06-02 Universite De Montreal Synergistic detergent and disinfectant combinations for decontaminating biofilm- coated surfaces
US5731275A (en) * 1994-04-05 1998-03-24 Universite De Montreal Synergistic detergent and disinfectant combinations for decontaminating biofilm-coated surfaces
US5942480A (en) * 1994-12-30 1999-08-24 Universite De Montreal Synergistic detergent and disinfectant combinations for decontamination biofilm-coated surfaces
FR2759380A1 (fr) * 1997-02-13 1998-08-14 Anios Lab Sarl Composition detergente et/ou desinfectante
EP0860117A1 (fr) * 1997-02-13 1998-08-26 LABORATOIRES ANIOS, Société Anonyme Composition détergente et/ou désinfectante
FR2761080A1 (fr) * 1997-03-21 1998-09-25 Quadrimex Composition a base de peracides pour le nettoyage, la desinfection et la decontamination de surfaces souillees par des agents toxiques
US6762160B2 (en) 1998-11-06 2004-07-13 Universite De Montreal Composition for removing biofilms comprising a detergent and a salt forming acid
US6262013B1 (en) 1999-01-14 2001-07-17 Ecolab Inc. Sanitizing laundry sour
US6436445B1 (en) 1999-03-26 2002-08-20 Ecolab Inc. Antimicrobial and antiviral compositions containing an oxidizing species
US6534075B1 (en) 1999-03-26 2003-03-18 Ecolab Inc. Antimicrobial and antiviral compositions and treatments for food surfaces
FR2800291A1 (fr) * 1999-10-29 2001-05-04 Atofina Composition et procede pour la destruction de polluants organophosphores et/ou organosoufres
WO2001030452A1 (fr) * 1999-10-29 2001-05-03 Atofina Composition et procede pour la destruction de polluants organophosphores et/ou organosoufres
WO2001070030A3 (fr) * 2000-03-22 2002-01-31 Ecolab Inc Compositions d'acide peroxycarboxylique et procedes d'utilisations contre des spores microbiennes
US6627657B1 (en) 2000-03-22 2003-09-30 Ecolab Inc. Peroxycarboxylic acid compositions and methods of use against microbial spores
US6908628B2 (en) * 2001-06-15 2005-06-21 Oftrai, S.L. Disinfectant and antiseptic composition
US6855328B2 (en) 2002-03-28 2005-02-15 Ecolab Inc. Antimicrobial and antiviral compositions containing an oxidizing species
WO2010109166A1 (fr) * 2009-03-25 2010-09-30 Reckitt Benckiser N.V. Composition
EP2407529A1 (fr) * 2010-07-12 2012-01-18 Solvay SA Composition de peroxygène
WO2012007377A2 (fr) 2010-07-12 2012-01-19 Solvay Sa Composition de peroxygène
WO2012007377A3 (fr) * 2010-07-12 2012-03-22 Solvay Sa Composition de peroxygène
US9382503B2 (en) 2011-03-09 2016-07-05 Reckitt Benckiser Vanish B.V. Carpet cleaning composition
WO2016040230A1 (fr) * 2014-09-09 2016-03-17 Lonza, Inc. Composition désinfectante contenant des composés d'ammonium quaternaire
US10285400B2 (en) 2014-09-09 2019-05-14 Lonza Inc. Disinfectant composition containing quaternary ammonium compounds

Also Published As

Publication number Publication date
GB9213059D0 (en) 1992-08-05

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