UA88346C2 - Liquid-phase process for oxidative desulfuration - Google Patents
Liquid-phase process for oxidative desulfurationInfo
- Publication number
- UA88346C2 UA88346C2 UAA200708611A UAA200708611A UA88346C2 UA 88346 C2 UA88346 C2 UA 88346C2 UA A200708611 A UAA200708611 A UA A200708611A UA A200708611 A UAA200708611 A UA A200708611A UA 88346 C2 UA88346 C2 UA 88346C2
- Authority
- UA
- Ukraine
- Prior art keywords
- desulfuration
- oxidative
- liquid
- phase process
- oxidation
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- 238000006477 desulfuration reaction Methods 0.000 title 1
- 239000007791 liquid phase Substances 0.000 title 1
- 230000001590 oxidative effect Effects 0.000 title 1
- 230000003647 oxidation Effects 0.000 abstract 3
- 238000007254 oxidation reaction Methods 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 2
- 239000000446 fuel Substances 0.000 abstract 2
- 229910052717 sulfur Inorganic materials 0.000 abstract 2
- 239000011593 sulfur Substances 0.000 abstract 2
- 229910052719 titanium Inorganic materials 0.000 abstract 2
- 239000010936 titanium Substances 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 abstract 1
- 150000003457 sulfones Chemical class 0.000 abstract 1
- 150000003462 sulfoxides Chemical class 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
- C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
- B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Treating Waste Gases (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
Процес зменшення вмісту сірки в дистилятній сировині для виготовлення на нафтоочисному заводі моторного палива або змішуваних компонентів для виготовлення моторного палива, який здійснюють шляхом приведення в контакт сировини з кисневмісним газом у зоні окислювання та адсорбції в умовах окислювання при наявності каталізатора окислювання, що містить титановмісний композиційний матеріал, у результаті чого сірковмісні речовини перетворюються на сульфони та/або сульфоксиди, які адсорбуються на титановмісному композиційному матеріалі.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US64003904P | 2004-12-29 | 2004-12-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| UA88346C2 true UA88346C2 (en) | 2009-10-12 |
Family
ID=36282805
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| UAA200708611A UA88346C2 (en) | 2004-12-29 | 2005-12-22 | Liquid-phase process for oxidative desulfuration |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US20080308463A1 (uk) |
| EP (1) | EP1841838A1 (uk) |
| JP (1) | JP2008525624A (uk) |
| KR (1) | KR20070091297A (uk) |
| CN (1) | CN101094908B (uk) |
| AU (1) | AU2005322059B2 (uk) |
| BR (1) | BRPI0519500A2 (uk) |
| CA (1) | CA2589399A1 (uk) |
| EA (1) | EA011964B1 (uk) |
| MX (1) | MX2007007802A (uk) |
| NO (1) | NO20073938L (uk) |
| NZ (1) | NZ555486A (uk) |
| UA (1) | UA88346C2 (uk) |
| WO (1) | WO2006071793A1 (uk) |
| ZA (1) | ZA200704539B (uk) |
Families Citing this family (61)
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| US7824655B2 (en) * | 2006-01-25 | 2010-11-02 | Air Products And Chemicals, Inc. | Regeneration of complex metal oxides for the production of hydrogen |
| JP2008106172A (ja) * | 2006-10-26 | 2008-05-08 | Idemitsu Kosan Co Ltd | 脱硫装置、その方法、燃料電池用燃料ガスの製造装置、および、燃料電池システム |
| CN101274260A (zh) * | 2006-12-29 | 2008-10-01 | 亚申科技研发中心(上海)有限公司 | 一种催化加氢处理不洁原料的研究方法 |
| PL2150557T3 (pl) | 2007-05-03 | 2016-12-30 | Produkt zawierający monomer i polimery tytanyli i sposoby ich wytwarzania | |
| JP2009079155A (ja) * | 2007-09-26 | 2009-04-16 | Toshiba Fuel Cell Power Systems Corp | 液体燃料脱硫装置及び液体燃料脱硫システム |
| US8894843B2 (en) | 2008-03-26 | 2014-11-25 | Auterra, Inc. | Methods for upgrading of contaminated hydrocarbon streams |
| US8197671B2 (en) * | 2008-03-26 | 2012-06-12 | Auterra, Inc. | Methods for upgrading of contaminated hydrocarbon streams |
| US8298404B2 (en) | 2010-09-22 | 2012-10-30 | Auterra, Inc. | Reaction system and products therefrom |
| US9206359B2 (en) | 2008-03-26 | 2015-12-08 | Auterra, Inc. | Methods for upgrading of contaminated hydrocarbon streams |
| US9061273B2 (en) | 2008-03-26 | 2015-06-23 | Auterra, Inc. | Sulfoxidation catalysts and methods and systems of using same |
| US8764973B2 (en) | 2008-03-26 | 2014-07-01 | Auterra, Inc. | Methods for upgrading of contaminated hydrocarbon streams |
| US8241490B2 (en) * | 2008-03-26 | 2012-08-14 | Auterra, Inc. | Methods for upgrading of contaminated hydrocarbon streams |
| BRPI0821570A2 (pt) * | 2008-03-26 | 2015-09-08 | Auterra Inc | catalisadores de sulfoxidação e métodos e sistemas para utilizar os mesmos |
| US8562821B2 (en) * | 2008-12-15 | 2013-10-22 | Council of Scientific & Industrial Research Center for High Technology | Process for the removal of sulfones from oxidized hydrocarbon fuels |
| US20100264067A1 (en) * | 2009-04-16 | 2010-10-21 | General Electric Company | Method for removing impurities from hydrocarbon oils |
| US20100294698A1 (en) * | 2009-05-20 | 2010-11-25 | Chevron U.S.A., Inc. | Deep desulfurization process |
| CN101921613A (zh) * | 2009-06-17 | 2010-12-22 | 中国科学院大连化学物理研究所 | 一种超低硫柴油的制备方法 |
| US9296960B2 (en) | 2010-03-15 | 2016-03-29 | Saudi Arabian Oil Company | Targeted desulfurization process and apparatus integrating oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds |
| WO2011116059A1 (en) | 2010-03-16 | 2011-09-22 | Saudi Arabian Oil Company | System and process for integrated oxidative desulfurization, desalting and deasphalting of hydrocarbon feedstocks |
| US8658027B2 (en) | 2010-03-29 | 2014-02-25 | Saudi Arabian Oil Company | Integrated hydrotreating and oxidative desulfurization process |
| US8888994B2 (en) * | 2010-04-22 | 2014-11-18 | The United States Of America As Represented By The Administrator Of The U.S. Environmental Protection Agency | Method for deep desulphurization of hydrocarbon fuels |
| US9598647B2 (en) | 2010-09-07 | 2017-03-21 | Saudi Arabian Oil Company | Process for oxidative desulfurization and sulfone disposal using solvent deasphalting |
| US9574144B2 (en) | 2010-09-07 | 2017-02-21 | Saudi Arabian Oil Company | Process for oxidative desulfurization and denitrogenation using a fluid catalytic cracking (FCC) unit |
| US10035960B2 (en) | 2010-09-07 | 2018-07-31 | Saudi Arabian Oil Company | Process for oxidative desulfurization and sulfone management by gasification |
| US10081770B2 (en) | 2010-09-07 | 2018-09-25 | Saudi Arabian Oil Company | Process for oxidative desulfurization and sulfone disposal using solvent deasphalting |
| US9574142B2 (en) | 2010-09-07 | 2017-02-21 | Saudi Arabian Oil Company | Process for oxidative desulfurization and sulfone management by gasification |
| US9574143B2 (en) | 2010-09-07 | 2017-02-21 | Saudi Arabian Oil Company | Desulfurization and sulfone removal using a coker |
| US10093871B2 (en) | 2010-09-07 | 2018-10-09 | Saudi Arabian Oil Company | Desulfurization and sulfone removal using a coker |
| US10093870B2 (en) | 2010-09-07 | 2018-10-09 | Saudi Arabian Oil Company | Desulfurization and sulfone removal using a coker |
| US10087377B2 (en) | 2010-09-07 | 2018-10-02 | Saudi Arabian Oil Company | Oxidative desulfurization of oil fractions and sulfone management using an FCC |
| US10093872B2 (en) | 2010-09-07 | 2018-10-09 | Saudi Arabian Oil Company | Oxidative desulfurization of oil fractions and sulfone management using an FCC |
| US9828557B2 (en) | 2010-09-22 | 2017-11-28 | Auterra, Inc. | Reaction system, methods and products therefrom |
| US8790508B2 (en) | 2010-09-29 | 2014-07-29 | Saudi Arabian Oil Company | Integrated deasphalting and oxidative removal of heteroatom hydrocarbon compounds from liquid hydrocarbon feedstocks |
| US8741127B2 (en) | 2010-12-14 | 2014-06-03 | Saudi Arabian Oil Company | Integrated desulfurization and denitrification process including mild hydrotreating and oxidation of aromatic-rich hydrotreated products |
| US8741128B2 (en) | 2010-12-15 | 2014-06-03 | Saudi Arabian Oil Company | Integrated desulfurization and denitrification process including mild hydrotreating of aromatic-lean fraction and oxidation of aromatic-rich fraction |
| EP2651860B1 (en) | 2010-12-15 | 2018-09-05 | Saudi Arabian Oil Company | Desulfurization of hydrocarbon feed using gaseous oxidant |
| US20130015104A1 (en) | 2011-07-12 | 2013-01-17 | Adnan Al-Hajji | Process for sulfone conversion by super electron donors |
| KR101955704B1 (ko) | 2011-07-29 | 2019-03-07 | 사우디 아라비안 오일 컴퍼니 | 이성화 및 수소화처리 통합 공정 |
| KR20140064801A (ko) | 2011-07-29 | 2014-05-28 | 사우디 아라비안 오일 컴퍼니 | 유동접촉분해 공정에서 산화적 탈황 |
| KR101973703B1 (ko) | 2011-07-29 | 2019-04-29 | 사우디 아라비안 오일 컴퍼니 | 방향족 추출 탄화수소 스트림의 수소화처리 |
| JP6018198B2 (ja) | 2011-07-29 | 2016-11-02 | サウジ アラビアン オイル カンパニー | 芳香族分離を伴う統合型水素化および異性化処理プロセス |
| KR102024349B1 (ko) | 2011-07-31 | 2019-09-23 | 사우디 아라비안 오일 컴퍼니 | 통합 설폰 분해로 산화적 탈황하는 방법 |
| JP6215826B2 (ja) | 2011-07-31 | 2017-10-18 | サウジ アラビアン オイル カンパニー | アスファルトおよび脱硫オイルを生産する統合プロセス |
| BR112014009803B1 (pt) | 2011-10-24 | 2021-07-06 | Aditya Birla Nuvo Limited | processo para produzir um negro de fumo modificado na superfície |
| KR101362939B1 (ko) * | 2011-12-22 | 2014-02-14 | 에스케이이노베이션 주식회사 | 메탄올을 극성용매로하는 2단계 흡착을 이용한 황산화물 분리공정 |
| US8906227B2 (en) | 2012-02-02 | 2014-12-09 | Suadi Arabian Oil Company | Mild hydrodesulfurization integrating gas phase catalytic oxidation to produce fuels having an ultra-low level of organosulfur compounds |
| HUE045169T2 (hu) | 2012-03-30 | 2019-12-30 | Aditya Birla Science And Tech Company Limited | Eljárás csökkentett kén-tartalmú korom por elõállítására |
| CN102925198A (zh) * | 2012-09-28 | 2013-02-13 | 石河子大学 | 改性催化剂用于催化氧化脱除dbt的方法 |
| WO2014052951A1 (en) | 2012-09-28 | 2014-04-03 | Saudi Arabian Oil Company | Process for reducing the sulfur content from oxidized sulfur-containing hydrocarbons |
| JP6144352B2 (ja) | 2012-11-09 | 2017-06-07 | サウジ アラビアン オイル カンパニー | 酸化的脱硫方法および気体状酸化剤を高めた供給物を用いたシステム |
| US8920635B2 (en) | 2013-01-14 | 2014-12-30 | Saudi Arabian Oil Company | Targeted desulfurization process and apparatus integrating gas phase oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds |
| JP6142785B2 (ja) * | 2013-11-27 | 2017-06-07 | 株式会社豊田中央研究所 | 燃料中の硫黄化合物の脱硫方法及び脱硫装置 |
| US9365780B2 (en) * | 2014-02-19 | 2016-06-14 | King Abdulaziz City For Science And Technology | Cold process for removal of sulfur in straight run diesel by ozone and tert-butyl hydroperoxide |
| KR20170034908A (ko) | 2014-07-25 | 2017-03-29 | 사우디 아라비안 오일 컴퍼니 | 아스팔트, 석유 그린 코크스, 및 액체 및 기체 코킹 유닛 생성물을 제조하기 위한 통합된 공정 |
| WO2016154529A1 (en) | 2015-03-26 | 2016-09-29 | Auterra, Inc. | Adsorbents and methods of use |
| US10450516B2 (en) | 2016-03-08 | 2019-10-22 | Auterra, Inc. | Catalytic caustic desulfonylation |
| WO2022076426A1 (en) | 2020-10-08 | 2022-04-14 | Conocophillips Company | Elemental sulfur dissolution and solvation |
| US11572514B2 (en) | 2020-10-08 | 2023-02-07 | Conocophillips Company | Elemental sulfur dissolution and solvation |
| EP4334027A4 (en) | 2021-05-06 | 2025-04-16 | King Abdullah University Of Science And Technology | REACTOR CONFIGURATION FOR ULTRASONIC-INDUCED CAVITATION WITH OPTIMAL BUBBLE DISTRIBUTION |
| KR20240004922A (ko) | 2021-05-06 | 2024-01-11 | 킹 압둘라 유니버시티 오브 사이언스 앤드 테크놀로지 | 초음파로 유도된 공동현상에 의해 향상된 산화적 탈황을 위한 시스템 |
| KR20240004920A (ko) | 2021-05-06 | 2024-01-11 | 킹 압둘라 유니버시티 오브 사이언스 앤드 테크놀로지 | 초음파로 유도된 공동현상을 사용하여 중유 탈황을 위한 방법 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6251289B1 (en) * | 1999-06-03 | 2001-06-26 | Grt, Inc. | Treatment of contaminated liquids with oxidizing gases and liquids |
| US6368495B1 (en) * | 1999-06-07 | 2002-04-09 | Uop Llc | Removal of sulfur-containing compounds from liquid hydrocarbon streams |
| ES2179753B1 (es) * | 2000-10-11 | 2005-02-16 | Universidad Politecnica De Valencia | Proceso y catalizadores para la eliminacion de compuestos de azufre de la fraccion gasolina. |
| FR2818990B1 (fr) * | 2000-12-28 | 2004-09-24 | Total Raffinage Distribution | Procede et dispositif de desulfuration d'hydrocarbures charges en derives thiopheniques |
| US20020148754A1 (en) * | 2001-02-08 | 2002-10-17 | Gong William H. | Integrated preparation of blending components for refinery transportation fuels |
| ES2183710B1 (es) * | 2001-04-12 | 2004-01-16 | Univ Valencia Politecnica | Proceso y catalizadores para la eliminacion de compuestos de azufre de la fraccion diesel. |
| AU2002359461A1 (en) * | 2001-12-13 | 2003-06-30 | Lehigh University | Oxidative desulfurization of sulfur-containing hydrocarbons |
| JP2004168663A (ja) * | 2002-11-15 | 2004-06-17 | Osaka Industrial Promotion Organization | 硫黄化合物の酸化方法および脱硫油の製造方法 |
| EP1581601B1 (en) * | 2002-12-17 | 2008-08-13 | Shell Internationale Researchmaatschappij B.V. | Process for the catalytic selective oxidation of sulphur compounds |
| CN1202209C (zh) * | 2003-01-17 | 2005-05-18 | 石油大学(北京) | 一种石油油品脱硫方法 |
-
2005
- 2005-12-22 EP EP05855415A patent/EP1841838A1/en not_active Withdrawn
- 2005-12-22 JP JP2007549514A patent/JP2008525624A/ja active Pending
- 2005-12-22 EA EA200701421A patent/EA011964B1/ru not_active IP Right Cessation
- 2005-12-22 US US11/722,138 patent/US20080308463A1/en not_active Abandoned
- 2005-12-22 WO PCT/US2005/046849 patent/WO2006071793A1/en not_active Ceased
- 2005-12-22 CN CN2005800453208A patent/CN101094908B/zh not_active Expired - Fee Related
- 2005-12-22 NZ NZ555486A patent/NZ555486A/en not_active IP Right Cessation
- 2005-12-22 UA UAA200708611A patent/UA88346C2/ru unknown
- 2005-12-22 KR KR1020077013929A patent/KR20070091297A/ko not_active Withdrawn
- 2005-12-22 AU AU2005322059A patent/AU2005322059B2/en not_active Ceased
- 2005-12-22 BR BRPI0519500-4A patent/BRPI0519500A2/pt not_active IP Right Cessation
- 2005-12-22 MX MX2007007802A patent/MX2007007802A/es unknown
- 2005-12-22 CA CA002589399A patent/CA2589399A1/en not_active Abandoned
-
2007
- 2007-05-31 ZA ZA200704539A patent/ZA200704539B/xx unknown
- 2007-07-27 NO NO20073938A patent/NO20073938L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| EA200701421A1 (ru) | 2007-12-28 |
| AU2005322059B2 (en) | 2011-03-10 |
| ZA200704539B (en) | 2008-09-25 |
| CA2589399A1 (en) | 2006-07-06 |
| AU2005322059A1 (en) | 2006-07-06 |
| NO20073938L (no) | 2007-10-01 |
| CN101094908A (zh) | 2007-12-26 |
| WO2006071793A1 (en) | 2006-07-06 |
| KR20070091297A (ko) | 2007-09-10 |
| MX2007007802A (es) | 2007-07-25 |
| EP1841838A1 (en) | 2007-10-10 |
| US20080308463A1 (en) | 2008-12-18 |
| JP2008525624A (ja) | 2008-07-17 |
| EA011964B1 (ru) | 2009-06-30 |
| CN101094908B (zh) | 2010-11-17 |
| NZ555486A (en) | 2010-03-26 |
| BRPI0519500A2 (pt) | 2009-02-03 |
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