UA88346C2 - Liquid-phase process for oxidative desulfuration - Google Patents
Liquid-phase process for oxidative desulfurationInfo
- Publication number
- UA88346C2 UA88346C2 UAA200708611A UAA200708611A UA88346C2 UA 88346 C2 UA88346 C2 UA 88346C2 UA A200708611 A UAA200708611 A UA A200708611A UA A200708611 A UAA200708611 A UA A200708611A UA 88346 C2 UA88346 C2 UA 88346C2
- Authority
- UA
- Ukraine
- Prior art keywords
- desulfuration
- oxidative
- liquid
- phase process
- oxidation
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- 238000006477 desulfuration reaction Methods 0.000 title 1
- 239000007791 liquid phase Substances 0.000 title 1
- 230000001590 oxidative effect Effects 0.000 title 1
- 230000003647 oxidation Effects 0.000 abstract 3
- 238000007254 oxidation reaction Methods 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 2
- 239000000446 fuel Substances 0.000 abstract 2
- 229910052717 sulfur Inorganic materials 0.000 abstract 2
- 239000011593 sulfur Substances 0.000 abstract 2
- 229910052719 titanium Inorganic materials 0.000 abstract 2
- 239000010936 titanium Substances 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 abstract 1
- 150000003457 sulfones Chemical class 0.000 abstract 1
- 150000003462 sulfoxides Chemical class 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
- C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
- B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Treating Waste Gases (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
Disclosed is a process which reduces the sulfur and/or nitrogen content of a distillate feedstock to produce a refinery transportation fuel or blending components for refinery transportation fuel, by contacting the feedstock with an oxygen-containing gas in an 5 oxidation/adsorption zone at oxidation conditions in the presence of an oxidation catalyst comprising a titanium-containing composition whereby the sulfur species are converted to sulfones and/or sulfoxides which are adsorbed onto the titanium-containing composition.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US64003904P | 2004-12-29 | 2004-12-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| UA88346C2 true UA88346C2 (en) | 2009-10-12 |
Family
ID=36282805
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| UAA200708611A UA88346C2 (en) | 2004-12-29 | 2005-12-22 | Liquid-phase process for oxidative desulfuration |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US20080308463A1 (en) |
| EP (1) | EP1841838A1 (en) |
| JP (1) | JP2008525624A (en) |
| KR (1) | KR20070091297A (en) |
| CN (1) | CN101094908B (en) |
| AU (1) | AU2005322059B2 (en) |
| BR (1) | BRPI0519500A2 (en) |
| CA (1) | CA2589399A1 (en) |
| EA (1) | EA011964B1 (en) |
| MX (1) | MX2007007802A (en) |
| NO (1) | NO20073938L (en) |
| NZ (1) | NZ555486A (en) |
| UA (1) | UA88346C2 (en) |
| WO (1) | WO2006071793A1 (en) |
| ZA (1) | ZA200704539B (en) |
Families Citing this family (61)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7824655B2 (en) * | 2006-01-25 | 2010-11-02 | Air Products And Chemicals, Inc. | Regeneration of complex metal oxides for the production of hydrogen |
| JP2008106172A (en) * | 2006-10-26 | 2008-05-08 | Idemitsu Kosan Co Ltd | Desulfurization apparatus, method thereof, fuel gas fuel gas production apparatus, and fuel cell system |
| CN101274260A (en) * | 2006-12-29 | 2008-10-01 | 亚申科技研发中心(上海)有限公司 | Catalytic hydrotreating nasty raw material investigation method |
| PL2150557T3 (en) | 2007-05-03 | 2016-12-30 | Product containing monomer and polymers of titanyls and methods for making same | |
| JP2009079155A (en) * | 2007-09-26 | 2009-04-16 | Toshiba Fuel Cell Power Systems Corp | Liquid fuel desulfurization apparatus and liquid fuel desulfurization system |
| US8894843B2 (en) | 2008-03-26 | 2014-11-25 | Auterra, Inc. | Methods for upgrading of contaminated hydrocarbon streams |
| US8197671B2 (en) * | 2008-03-26 | 2012-06-12 | Auterra, Inc. | Methods for upgrading of contaminated hydrocarbon streams |
| US8298404B2 (en) | 2010-09-22 | 2012-10-30 | Auterra, Inc. | Reaction system and products therefrom |
| US9206359B2 (en) | 2008-03-26 | 2015-12-08 | Auterra, Inc. | Methods for upgrading of contaminated hydrocarbon streams |
| US9061273B2 (en) | 2008-03-26 | 2015-06-23 | Auterra, Inc. | Sulfoxidation catalysts and methods and systems of using same |
| US8764973B2 (en) | 2008-03-26 | 2014-07-01 | Auterra, Inc. | Methods for upgrading of contaminated hydrocarbon streams |
| US8241490B2 (en) * | 2008-03-26 | 2012-08-14 | Auterra, Inc. | Methods for upgrading of contaminated hydrocarbon streams |
| BRPI0821570A2 (en) * | 2008-03-26 | 2015-09-08 | Auterra Inc | sulfoxidation catalysts and methods and systems for using them |
| US8562821B2 (en) * | 2008-12-15 | 2013-10-22 | Council of Scientific & Industrial Research Center for High Technology | Process for the removal of sulfones from oxidized hydrocarbon fuels |
| US20100264067A1 (en) * | 2009-04-16 | 2010-10-21 | General Electric Company | Method for removing impurities from hydrocarbon oils |
| US20100294698A1 (en) * | 2009-05-20 | 2010-11-25 | Chevron U.S.A., Inc. | Deep desulfurization process |
| CN101921613A (en) * | 2009-06-17 | 2010-12-22 | 中国科学院大连化学物理研究所 | A kind of preparation method of ultra-low sulfur diesel oil |
| US9296960B2 (en) | 2010-03-15 | 2016-03-29 | Saudi Arabian Oil Company | Targeted desulfurization process and apparatus integrating oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds |
| WO2011116059A1 (en) | 2010-03-16 | 2011-09-22 | Saudi Arabian Oil Company | System and process for integrated oxidative desulfurization, desalting and deasphalting of hydrocarbon feedstocks |
| US8658027B2 (en) | 2010-03-29 | 2014-02-25 | Saudi Arabian Oil Company | Integrated hydrotreating and oxidative desulfurization process |
| US8888994B2 (en) * | 2010-04-22 | 2014-11-18 | The United States Of America As Represented By The Administrator Of The U.S. Environmental Protection Agency | Method for deep desulphurization of hydrocarbon fuels |
| US9598647B2 (en) | 2010-09-07 | 2017-03-21 | Saudi Arabian Oil Company | Process for oxidative desulfurization and sulfone disposal using solvent deasphalting |
| US9574144B2 (en) | 2010-09-07 | 2017-02-21 | Saudi Arabian Oil Company | Process for oxidative desulfurization and denitrogenation using a fluid catalytic cracking (FCC) unit |
| US10035960B2 (en) | 2010-09-07 | 2018-07-31 | Saudi Arabian Oil Company | Process for oxidative desulfurization and sulfone management by gasification |
| US10081770B2 (en) | 2010-09-07 | 2018-09-25 | Saudi Arabian Oil Company | Process for oxidative desulfurization and sulfone disposal using solvent deasphalting |
| US9574142B2 (en) | 2010-09-07 | 2017-02-21 | Saudi Arabian Oil Company | Process for oxidative desulfurization and sulfone management by gasification |
| US9574143B2 (en) | 2010-09-07 | 2017-02-21 | Saudi Arabian Oil Company | Desulfurization and sulfone removal using a coker |
| US10093871B2 (en) | 2010-09-07 | 2018-10-09 | Saudi Arabian Oil Company | Desulfurization and sulfone removal using a coker |
| US10093870B2 (en) | 2010-09-07 | 2018-10-09 | Saudi Arabian Oil Company | Desulfurization and sulfone removal using a coker |
| US10087377B2 (en) | 2010-09-07 | 2018-10-02 | Saudi Arabian Oil Company | Oxidative desulfurization of oil fractions and sulfone management using an FCC |
| US10093872B2 (en) | 2010-09-07 | 2018-10-09 | Saudi Arabian Oil Company | Oxidative desulfurization of oil fractions and sulfone management using an FCC |
| US9828557B2 (en) | 2010-09-22 | 2017-11-28 | Auterra, Inc. | Reaction system, methods and products therefrom |
| US8790508B2 (en) | 2010-09-29 | 2014-07-29 | Saudi Arabian Oil Company | Integrated deasphalting and oxidative removal of heteroatom hydrocarbon compounds from liquid hydrocarbon feedstocks |
| US8741127B2 (en) | 2010-12-14 | 2014-06-03 | Saudi Arabian Oil Company | Integrated desulfurization and denitrification process including mild hydrotreating and oxidation of aromatic-rich hydrotreated products |
| US8741128B2 (en) | 2010-12-15 | 2014-06-03 | Saudi Arabian Oil Company | Integrated desulfurization and denitrification process including mild hydrotreating of aromatic-lean fraction and oxidation of aromatic-rich fraction |
| EP2651860B1 (en) | 2010-12-15 | 2018-09-05 | Saudi Arabian Oil Company | Desulfurization of hydrocarbon feed using gaseous oxidant |
| US20130015104A1 (en) | 2011-07-12 | 2013-01-17 | Adnan Al-Hajji | Process for sulfone conversion by super electron donors |
| KR101955704B1 (en) | 2011-07-29 | 2019-03-07 | 사우디 아라비안 오일 컴퍼니 | Integrated Isomerization and Hydrotreating Process |
| KR20140064801A (en) | 2011-07-29 | 2014-05-28 | 사우디 아라비안 오일 컴퍼니 | Oxidative desulfurization in fluid catalytic cracking process |
| KR101973703B1 (en) | 2011-07-29 | 2019-04-29 | 사우디 아라비안 오일 컴퍼니 | Hydrotreating of Aromatic-Extracted Hydrocarbon Streams |
| JP6018198B2 (en) | 2011-07-29 | 2016-11-02 | サウジ アラビアン オイル カンパニー | Integrated hydroprocessing and isomerization process with aromatic separation |
| KR102024349B1 (en) | 2011-07-31 | 2019-09-23 | 사우디 아라비안 오일 컴퍼니 | Process for Oxidative Desulfurization with Integrated Sulfone Decomposition |
| JP6215826B2 (en) | 2011-07-31 | 2017-10-18 | サウジ アラビアン オイル カンパニー | Integrated process to produce asphalt and desulfurized oil |
| BR112014009803B1 (en) | 2011-10-24 | 2021-07-06 | Aditya Birla Nuvo Limited | process to produce a surface-modified carbon black |
| KR101362939B1 (en) * | 2011-12-22 | 2014-02-14 | 에스케이이노베이션 주식회사 | Sulfone separation process using methanol solvent and 2-step adsorption |
| US8906227B2 (en) | 2012-02-02 | 2014-12-09 | Suadi Arabian Oil Company | Mild hydrodesulfurization integrating gas phase catalytic oxidation to produce fuels having an ultra-low level of organosulfur compounds |
| HUE045169T2 (en) | 2012-03-30 | 2019-12-30 | Aditya Birla Science And Tech Company Limited | A process for obtaining carbon black powder with reduced sulfur content |
| CN102925198A (en) * | 2012-09-28 | 2013-02-13 | 石河子大学 | Method of applying modified catalyst to catalytic oxidation DBT (dibenzothiophene) removal |
| WO2014052951A1 (en) | 2012-09-28 | 2014-04-03 | Saudi Arabian Oil Company | Process for reducing the sulfur content from oxidized sulfur-containing hydrocarbons |
| JP6144352B2 (en) | 2012-11-09 | 2017-06-07 | サウジ アラビアン オイル カンパニー | Oxidative desulfurization process and system using gaseous oxidant enriched feed |
| US8920635B2 (en) | 2013-01-14 | 2014-12-30 | Saudi Arabian Oil Company | Targeted desulfurization process and apparatus integrating gas phase oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds |
| JP6142785B2 (en) * | 2013-11-27 | 2017-06-07 | 株式会社豊田中央研究所 | Method and apparatus for desulfurization of sulfur compounds in fuel |
| US9365780B2 (en) * | 2014-02-19 | 2016-06-14 | King Abdulaziz City For Science And Technology | Cold process for removal of sulfur in straight run diesel by ozone and tert-butyl hydroperoxide |
| KR20170034908A (en) | 2014-07-25 | 2017-03-29 | 사우디 아라비안 오일 컴퍼니 | Integrated process to produce asphalt, petroleum green coke, and liquid and gas coking unit products |
| WO2016154529A1 (en) | 2015-03-26 | 2016-09-29 | Auterra, Inc. | Adsorbents and methods of use |
| US10450516B2 (en) | 2016-03-08 | 2019-10-22 | Auterra, Inc. | Catalytic caustic desulfonylation |
| WO2022076426A1 (en) | 2020-10-08 | 2022-04-14 | Conocophillips Company | Elemental sulfur dissolution and solvation |
| US11572514B2 (en) | 2020-10-08 | 2023-02-07 | Conocophillips Company | Elemental sulfur dissolution and solvation |
| EP4334027A4 (en) | 2021-05-06 | 2025-04-16 | King Abdullah University Of Science And Technology | Reactor configuration for ultrasonically induced cavitation with optimal bubbles distribution |
| KR20240004922A (en) | 2021-05-06 | 2024-01-11 | 킹 압둘라 유니버시티 오브 사이언스 앤드 테크놀로지 | System for enhanced oxidative desulfurization by ultrasonically induced cavitation |
| KR20240004920A (en) | 2021-05-06 | 2024-01-11 | 킹 압둘라 유니버시티 오브 사이언스 앤드 테크놀로지 | Method for heavy oil desulfurization using ultrasonically induced cavitation |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6251289B1 (en) * | 1999-06-03 | 2001-06-26 | Grt, Inc. | Treatment of contaminated liquids with oxidizing gases and liquids |
| US6368495B1 (en) * | 1999-06-07 | 2002-04-09 | Uop Llc | Removal of sulfur-containing compounds from liquid hydrocarbon streams |
| ES2179753B1 (en) * | 2000-10-11 | 2005-02-16 | Universidad Politecnica De Valencia | PROCESS AND CATALYSTS FOR THE ELIMINATION OF SULFUR COMPOUNDS FROM THE GASOLINE FRACTION. |
| FR2818990B1 (en) * | 2000-12-28 | 2004-09-24 | Total Raffinage Distribution | PROCESS AND DEVICE FOR DESULFURIZING HYDROCARBONS FILLED WITH THIOPHENIC DERIVATIVES |
| US20020148754A1 (en) * | 2001-02-08 | 2002-10-17 | Gong William H. | Integrated preparation of blending components for refinery transportation fuels |
| ES2183710B1 (en) * | 2001-04-12 | 2004-01-16 | Univ Valencia Politecnica | PROCESS AND CATALYSTS FOR THE ELIMINATION OF Sulfur Compounds from the FRACTION DIESEL. |
| AU2002359461A1 (en) * | 2001-12-13 | 2003-06-30 | Lehigh University | Oxidative desulfurization of sulfur-containing hydrocarbons |
| JP2004168663A (en) * | 2002-11-15 | 2004-06-17 | Osaka Industrial Promotion Organization | Method for oxidizing sulfur compounds and method for producing desulfurized oil |
| EP1581601B1 (en) * | 2002-12-17 | 2008-08-13 | Shell Internationale Researchmaatschappij B.V. | Process for the catalytic selective oxidation of sulphur compounds |
| CN1202209C (en) * | 2003-01-17 | 2005-05-18 | 石油大学(北京) | Desulfurizing method for petroleum product |
-
2005
- 2005-12-22 EP EP05855415A patent/EP1841838A1/en not_active Withdrawn
- 2005-12-22 JP JP2007549514A patent/JP2008525624A/en active Pending
- 2005-12-22 EA EA200701421A patent/EA011964B1/en not_active IP Right Cessation
- 2005-12-22 US US11/722,138 patent/US20080308463A1/en not_active Abandoned
- 2005-12-22 WO PCT/US2005/046849 patent/WO2006071793A1/en not_active Ceased
- 2005-12-22 CN CN2005800453208A patent/CN101094908B/en not_active Expired - Fee Related
- 2005-12-22 NZ NZ555486A patent/NZ555486A/en not_active IP Right Cessation
- 2005-12-22 UA UAA200708611A patent/UA88346C2/en unknown
- 2005-12-22 KR KR1020077013929A patent/KR20070091297A/en not_active Withdrawn
- 2005-12-22 AU AU2005322059A patent/AU2005322059B2/en not_active Ceased
- 2005-12-22 BR BRPI0519500-4A patent/BRPI0519500A2/en not_active IP Right Cessation
- 2005-12-22 MX MX2007007802A patent/MX2007007802A/en unknown
- 2005-12-22 CA CA002589399A patent/CA2589399A1/en not_active Abandoned
-
2007
- 2007-05-31 ZA ZA200704539A patent/ZA200704539B/en unknown
- 2007-07-27 NO NO20073938A patent/NO20073938L/en not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| EA200701421A1 (en) | 2007-12-28 |
| AU2005322059B2 (en) | 2011-03-10 |
| ZA200704539B (en) | 2008-09-25 |
| CA2589399A1 (en) | 2006-07-06 |
| AU2005322059A1 (en) | 2006-07-06 |
| NO20073938L (en) | 2007-10-01 |
| CN101094908A (en) | 2007-12-26 |
| WO2006071793A1 (en) | 2006-07-06 |
| KR20070091297A (en) | 2007-09-10 |
| MX2007007802A (en) | 2007-07-25 |
| EP1841838A1 (en) | 2007-10-10 |
| US20080308463A1 (en) | 2008-12-18 |
| JP2008525624A (en) | 2008-07-17 |
| EA011964B1 (en) | 2009-06-30 |
| CN101094908B (en) | 2010-11-17 |
| NZ555486A (en) | 2010-03-26 |
| BRPI0519500A2 (en) | 2009-02-03 |
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