TWI581372B - Nonvolatile memory device and fabricating method thereof - Google Patents
Nonvolatile memory device and fabricating method thereof Download PDFInfo
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- TWI581372B TWI581372B TW102114230A TW102114230A TWI581372B TW I581372 B TWI581372 B TW I581372B TW 102114230 A TW102114230 A TW 102114230A TW 102114230 A TW102114230 A TW 102114230A TW I581372 B TWI581372 B TW I581372B
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- 238000000034 method Methods 0.000 title claims description 32
- 239000003989 dielectric material Substances 0.000 claims description 63
- 239000000758 substrate Substances 0.000 claims description 54
- 230000008569 process Effects 0.000 claims description 22
- 125000006850 spacer group Chemical group 0.000 claims description 16
- MZLGASXMSKOWSE-UHFFFAOYSA-N tantalum nitride Chemical compound [Ta]#N MZLGASXMSKOWSE-UHFFFAOYSA-N 0.000 claims description 16
- 238000005530 etching Methods 0.000 claims description 9
- 238000000059 patterning Methods 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 238000005468 ion implantation Methods 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 238000005303 weighing Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 description 11
- 239000002784 hot electron Substances 0.000 description 8
- 238000002347 injection Methods 0.000 description 7
- 239000007924 injection Substances 0.000 description 7
- 238000007667 floating Methods 0.000 description 6
- 230000015556 catabolic process Effects 0.000 description 5
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 4
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 230000002093 peripheral effect Effects 0.000 description 4
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 4
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 3
- 229910000420 cerium oxide Inorganic materials 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 3
- 229910052732 germanium Inorganic materials 0.000 description 3
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 3
- 230000005641 tunneling Effects 0.000 description 3
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 229910000449 hafnium oxide Inorganic materials 0.000 description 1
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 description 1
- 238000002513 implantation Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- QPJSUIGXIBEQAC-UHFFFAOYSA-N n-(2,4-dichloro-5-propan-2-yloxyphenyl)acetamide Chemical compound CC(C)OC1=CC(NC(C)=O)=C(Cl)C=C1Cl QPJSUIGXIBEQAC-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000001020 plasma etching Methods 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 229920005591 polysilicon Polymers 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 238000002207 thermal evaporation Methods 0.000 description 1
- 238000001039 wet etching Methods 0.000 description 1
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 description 1
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- Non-Volatile Memory (AREA)
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Description
本發明是有關於一種半導體元件及其製作方法,且特別是有關於一種非揮發性記憶體元件及其製作方法。 The present invention relates to a semiconductor device and a method of fabricating the same, and more particularly to a non-volatile memory device and a method of fabricating the same.
由於非揮發性記憶元件具有在斷電狀態下仍具有儲存數據的功能,因此目前已被業界所廣泛使用。非揮發性記憶元件一般可區分為浮置閘結構和矽-氧化矽-氮化矽-氧化矽-矽結構(以下簡稱SONOS結構)。 Since the non-volatile memory element has the function of storing data in the power-off state, it has been widely used in the industry. The non-volatile memory element can be generally classified into a floating gate structure and a yttrium-yttria-yttria-yttria-yttria-ytterbium structure (hereinafter referred to as a SONOS structure).
其中浮置閘結構係應用源極注入(Source-Side Injection,SSI)或穿隧效應(tunneling effect),將熱電子儲存於浮置閘結構內。然而隨著關鍵尺寸逐漸縮小,由於熱電子會沿著選擇閘極通道(select gate channel)產生擊穿(punching through)問題,使得浮置閘結構的應用受到限制。SONOS結構則係應用源極注入將熱電子儲存於氮化矽層之中。由於SONOS結構和浮置閘結構相比,具有較小的關鍵尺寸。因此SONOS結構有逐漸取代浮置閘結構的趨勢。 The floating gate structure uses source-Side Injection (SSI) or tunneling effect to store the hot electrons in the floating gate structure. However, as critical dimensions are gradually reduced, the application of floating gate structures is limited due to the problem of hot electrons punching through along the select gate channel. The SONOS structure uses source implantation to store hot electrons in the tantalum nitride layer. Since the SONOS structure has a smaller critical size than the floating gate structure. Therefore, the SONOS structure has a tendency to gradually replace the floating gate structure.
然而,習知的SONOS非揮發性記憶元件,在提升非揮發型記憶體的寫入/抹除速度,降低電壓操作、增進元件可靠度等問題上,仍存在有相當大的改進空間。 However, the conventional SONOS non-volatile memory element still has considerable room for improvement in improving the writing/erasing speed of non-volatile memory, reducing voltage operation, and improving component reliability.
因此,有需要提供一種先進的非揮發性記憶元件及其製 作方法,解決習知技術所面臨的問題。 Therefore, there is a need to provide an advanced non-volatile memory component and its system. A method to solve the problems faced by conventional technology.
本發明一方面是在提供一種非揮發性記憶元件,包括基材、閘電極、單一電荷捕捉立壁以及源極/汲極區。閘電極位於基材上方,且與基材電性隔離。單一電荷捕捉立壁鄰接閘電極的一個側壁,並與基材和閘電極電性隔離,且與基材夾一個非平角。源極/汲極區位於基材之中,且鄰接閘電極。 One aspect of the invention is to provide a non-volatile memory component comprising a substrate, a gate electrode, a single charge trapping wall, and a source/drain region. The gate electrode is above the substrate and is electrically isolated from the substrate. A single charge trapping wall abuts a sidewall of the gate electrode and is electrically isolated from the substrate and the gate electrode and has a non-flat angle with the substrate. The source/drain regions are located in the substrate and are adjacent to the gate electrode.
在本發明的一實施例之中,單一電荷捕捉立壁位於基材和閘電極之間。 In an embodiment of the invention, a single charge trapping wall is located between the substrate and the gate electrode.
在本發明的一實施例之中,單一電荷捕捉立壁具有L形或I形截面。 In an embodiment of the invention, the single charge trapping wall has an L-shaped or I-shaped cross section.
在本發明的一實施例之中,單一電荷捕捉立壁與基材所夾的非平角實質大於0°小於等於90°。 In an embodiment of the invention, the non-flat angle between the single charge trapping vertical wall and the substrate is substantially greater than 0° and less than or equal to 90°.
在本發明的一實施例之中,非揮發性記憶元件,更包含一第一介電材質層,用來隔離基材和閘電極,以及一第二介電材質層,用來隔離閘電極和單一電荷捕捉立壁。 In an embodiment of the invention, the non-volatile memory device further includes a first dielectric material layer for isolating the substrate and the gate electrode, and a second dielectric material layer for isolating the gate electrode and A single charge captures the vertical wall.
在本發明的一實施例之中,單一電荷捕捉立壁係由氮化矽所構成;第一介電材質層和第二介電材質層,皆為氧化矽層。 In an embodiment of the invention, the single charge trapping vertical wall is made of tantalum nitride; the first dielectric material layer and the second dielectric material layer are both yttria layers.
在本發明的一實施例之中,非揮發性記憶元件更包含一間隙壁(Spacer),位於單一電荷捕捉立壁遠離閘電極的一側壁。 In an embodiment of the invention, the non-volatile memory element further includes a spacer located on a sidewall of the single charge trapping wall away from the gate electrode.
本發明另一方面是在提供一種非揮發性記憶元件,其包含了複數個列前述非揮發性記憶元件,並且排列成複數行和複數列。 Another aspect of the present invention is to provide a non-volatile memory element comprising a plurality of columns of the aforementioned non-volatile memory elements and arranged in a plurality of rows and a plurality of columns.
在本發明的一實施例之中,兩相鄰的非揮發性記憶元件的源極/汲極區,係部分重疊而形成一共用源極/汲極區。 In an embodiment of the invention, the source/drain regions of two adjacent non-volatile memory elements are partially overlapped to form a common source/drain region.
在本發明的一實施例之中,兩相鄰的非揮發性記憶元件 的兩個單一電荷捕捉層,分別位於相對應之閘電極的相反兩側。 In an embodiment of the invention, two adjacent non-volatile memory elements Two single charge trapping layers are located on opposite sides of the corresponding gate electrode.
本發明又一方面是在提供一種非揮發性記憶元件的製作方法,包含下述步驟:首先於基材上形成第一介電材質層和閘電極層。然後,圖案化閘電極層和第一介電材質層,藉以形成一閘極結構。接著,依序形成第二介電材質層以及電荷捕捉層,覆蓋於閘極結構的至少一側壁上。再移除一部分電荷捕捉層以及一部分閘極結構,藉以形成一單一電荷捕捉立壁,鄰接於剩餘的閘極結構的側壁上。後續,於基材之中形成源極/汲極區,鄰接於剩餘的閘極結構。 Yet another aspect of the present invention provides a method of fabricating a non-volatile memory device comprising the steps of first forming a first dielectric material layer and a gate electrode layer on a substrate. Then, the gate electrode layer and the first dielectric material layer are patterned to form a gate structure. Then, a second dielectric material layer and a charge trapping layer are sequentially formed to cover at least one sidewall of the gate structure. A portion of the charge trapping layer and a portion of the gate structure are removed to form a single charge trapping vertical wall adjacent the sidewalls of the remaining gate structures. Subsequently, a source/drain region is formed in the substrate adjacent to the remaining gate structure.
在本發明的一實施例之中,圖案化閘電極層和第一介電材質層的步驟,包含:先蝕刻閘電極層,藉以形成一閘電極;再以閘電極為罩幕,對第一介電材質層進行等向蝕刻,藉以在閘極結構底部形成側蝕缺口(undercut)。 In an embodiment of the invention, the step of patterning the gate electrode layer and the first dielectric material layer comprises: first etching the gate electrode layer to form a gate electrode; and then using the gate electrode as a mask, facing the first The dielectric material layer is isotropically etched to form an undercut at the bottom of the gate structure.
在本發明的一實施例之中,形成第二介電材質層的步驟,並未填滿側蝕缺口;側蝕缺口係由後續形成的電荷捕捉層所填滿。 In an embodiment of the invention, the step of forming the second dielectric material layer does not fill the undercut gap; the side etch gap is filled by the subsequently formed charge trapping layer.
在本發明的一實施例之中,移除一部電荷捕捉層的步驟包括:圖案化電荷捕捉層,藉以形成鄰接於閘極結構第一側壁的第一單一電荷捕捉立壁,以及鄰接於閘極結構第二側壁的第二單一電荷捕捉立壁。 In an embodiment of the invention, the step of removing a charge trap layer includes: patterning the charge trap layer to form a first single charge trapping vertical wall adjacent to the first sidewall of the gate structure, and adjacent to the gate A second single charge of the second sidewall of the structure captures the riser.
在本發明的一實施例之中,移除一部分閘極結構之步驟,包括圖案化閘極結構,藉以將其區分為:包含第一側壁和第一單一電荷捕捉立壁的第一部分閘極結構,以及包含第二側壁和第二單一電荷捕捉立壁的第二部分閘極結構。 In an embodiment of the invention, the step of removing a portion of the gate structure includes patterning the gate structure to distinguish it into a first portion of the gate structure including the first sidewall and the first single charge trapping vertical wall, And a second portion of the gate structure including the second sidewall and the second single charge trapping vertical wall.
在本發明的一實施例之中,非揮發性記憶元件的製作方法,更包括:形成第一間隙壁,鄰接於第一部分閘極結構和第一單一電荷捕捉立壁;以及形成第二間隙壁鄰,鄰接於第二部分閘極結構和第 二單一電荷捕捉立壁。 In an embodiment of the invention, the method for fabricating the non-volatile memory device further includes: forming a first spacer, adjacent to the first portion of the gate structure and the first single charge trapping; and forming the second spacer Adjacent to the second part of the gate structure and Two single charges capture the vertical wall.
在本發明的一實施例之中,形成源極/汲極區的步驟,包括進行至少一離子植入製程,在第一部分閘極結構和第二部分閘極結構之間,形成一共用源極/汲極區。 In an embodiment of the invention, the step of forming a source/drain region includes performing at least one ion implantation process to form a common source between the first portion of the gate structure and the second portion of the gate structure / bungee area.
根據上述實施例,本發明的是提供一種可程式化的非揮發性記憶元件及其製造方法。此可程式化的非揮發性記憶元件,具有一非對稱結構,其包括一個鄰接閘電極之一側壁的單一電荷捕捉立壁。其中,閘電極位於基材上方,且與基材電性隔離。單一電荷捕捉立壁,與基材和閘電極電性隔離,並且與基材夾一非平角。 According to the above embodiments, the present invention provides a programmable non-volatile memory element and a method of fabricating the same. The programmable non-volatile memory element has an asymmetrical structure that includes a single charge trapping wall adjacent one of the sidewalls of the gate electrode. Wherein, the gate electrode is located above the substrate and is electrically isolated from the substrate. A single charge captures the vertical wall, is electrically isolated from the substrate and the gate electrode, and has a non-flat angle with the substrate.
由於,非揮發性記憶元件僅具有一個單一電荷捕捉立壁,在進行非揮發性記憶元件程式化時,無電荷捕捉層的一側,不會有留置電子的現象。在讀取資料時,僅需給予一小偏壓,即可獲得足夠讀取電流。不僅不會影響非揮發性記憶元件的讀取,更可以降低非揮發性記憶元件的漏電流以及崩潰電壓,並改善讀取時的操作電壓和電流消耗過高的問題,也較不會對周邊元件產生干擾,可減少元件的能源消耗。也可減輕源極/汲極摻雜,減少短通道效應及熱載子效應,利於元件的關鍵尺寸的微小化。 Since the non-volatile memory element has only a single charge trapping wall, when the non-volatile memory element is programmed, there is no phenomenon of leaving electrons on the side without the charge trapping layer. When reading data, you only need to give a small bias to get enough read current. It not only does not affect the reading of non-volatile memory components, but also reduces the leakage current and breakdown voltage of non-volatile memory components, and improves the problem of excessive operating voltage and current consumption during reading, and is less likely to be around Component interference can reduce component energy consumption. It also reduces source/drain doping, reduces short-channel effects and hot-carrier effects, and facilitates miniaturization of critical dimensions of components.
100‧‧‧非揮發性記憶元件 100‧‧‧Non-volatile memory components
100’‧‧‧非揮發性記憶元件 100'‧‧‧ Non-volatile memory components
101‧‧‧基材 101‧‧‧Substrate
102‧‧‧第一介電材質層 102‧‧‧First dielectric material layer
103‧‧‧閘極層 103‧‧‧ gate layer
104‧‧‧閘電極 104‧‧‧ gate electrode
105‧‧‧側蝕開口 105‧‧‧Side etching opening
106‧‧‧第二介電材質層 106‧‧‧Second dielectric material layer
106’‧‧‧二氧化矽薄層 106'‧‧‧ Thin layer of cerium oxide
107‧‧‧氮化矽層 107‧‧‧layer of tantalum nitride
108‧‧‧第三介電材質層 108‧‧‧ Third dielectric material layer
109‧‧‧輕汲極摻雜區 109‧‧‧Lightly doped region
110‧‧‧間隙壁 110‧‧‧ spacer
111‧‧‧汲極區 111‧‧‧Bungee Area
112‧‧‧源極區 112‧‧‧ source area
113‧‧‧電荷捕捉立壁 113‧‧‧Charge capture vertical wall
113’‧‧‧電荷捕捉立壁 113’‧‧‧Charge capture vertical wall
114‧‧‧閘極結構 114‧‧‧ gate structure
114a‧‧‧閘極結構的側壁 114a‧‧‧ sidewalls of the gate structure
114b‧‧‧閘極結構的側壁 114b‧‧‧ sidewalls of the gate structure
115‧‧‧非平角 115‧‧‧Non-flat angle
200a‧‧‧非揮發性記憶元件 200a‧‧‧Non-volatile memory components
200b‧‧‧非揮發性記憶元件 200b‧‧‧ non-volatile memory components
204a‧‧‧閘電極 204a‧‧ ‧ gate electrode
204a1‧‧‧閘電極的側壁 204a1‧‧‧ sidewall of the gate electrode
204b‧‧‧閘電極 204b‧‧‧ gate electrode
204b1‧‧‧閘電極的側壁 204b1‧‧‧ sidewall of the gate electrode
209a‧‧‧輕汲極摻區 209a‧‧‧Light 汲 polar zone
209b‧‧‧輕汲極摻區 209b‧‧‧Light 汲 polar zone
210a‧‧‧間隙壁 210a‧‧‧ clearance
210a1‧‧‧二氧化矽層 210a1‧‧ 二2 layer
210a2‧‧‧介電材質層 210a2‧‧‧ dielectric material layer
210b‧‧‧間隙壁 210b‧‧‧ spacer
210b1‧‧‧二氧化矽層 210b1‧‧ 二2 layer
210b2‧‧‧介電材質層 210b2‧‧‧ dielectric material layer
211‧‧‧共用源極/汲極區 211‧‧‧Shared source/bungee area
212a‧‧‧源極區 212a‧‧‧ source area
212b‧‧‧汲極區 212b‧‧‧Bungee Area
213a‧‧‧單一電荷捕捉立壁 213a‧‧‧Single charge capture vertical wall
213b‧‧‧單一電荷捕捉立壁 213b‧‧‧Single charge capture vertical wall
214a‧‧‧第一部分閘極結構 214a‧‧‧The first part of the gate structure
214a1‧‧‧第一部分閘極結構暴露在外的側壁 214a1‧‧‧The first part of the gate structure exposed to the outer side wall
214b‧‧‧第二部分閘極結構 214b‧‧‧Second part gate structure
214b1‧‧‧第二部分閘極結構暴露在外的側壁 214b1‧‧‧The second part of the gate structure exposed to the outer side wall
215a‧‧‧非平角 215a‧‧‧Non-flat angle
215b‧‧‧非平角 215b‧‧‧Non-flat angle
為讓本發明之上述和其他目的、特徵和優點能更明顯易懂,下文特舉數個較佳實施例,並配合所附圖式及比較例,作詳細說明如下:圖1A至1H係根據本發明的一實施例,所繪示之製作非揮發性記憶元件的製程結構剖面示意圖。 The above and other objects, features, and advantages of the present invention will become more apparent and understood. In one embodiment of the invention, a schematic cross-sectional view of a process structure for fabricating a non-volatile memory device is shown.
圖1H’係根據本發明的另一實施例,所繪示之非揮發性記憶元件的結構剖面圖。 1H' is a cross-sectional view showing the structure of a non-volatile memory element according to another embodiment of the present invention.
圖2A至2B係根據本發明的又一實施例,所繪示的製作非揮發性記憶元件的製程結構剖面示意圖。 2A through 2B are cross-sectional views showing a process structure for fabricating a non-volatile memory element, in accordance with still another embodiment of the present invention.
本發明是在提供一種非揮發性記憶元件,解決習知技術操作電壓和電流高、易干擾周邊元件,以及容易引起短通道效應及熱載子效應,導致元件擊穿等問題。為讓本發明之上述和其他目的、特徵和優點能更明顯易懂,下文特舉數個較佳實施例,並配合所附圖式及比較例,作詳細說明如下。 The invention provides a non-volatile memory element, which solves the problems of high operating voltage and current, easy to interfere with peripheral components, and easy to cause short channel effect and hot carrier effect, resulting in component breakdown. The above and other objects, features and advantages of the present invention will become more <
請參照圖1A至1H,圖1A至1H係根據本發明的一實施例所繪示之製作非揮發性記憶元件100的製程結構剖面示意圖。其中製作非揮發性記憶元件100包含下述步驟:首先,在基材101上形成第一介電材質層102及閘極層103(如圖1A所繪示)。在本發明的一些實施例中,基材101包含一P型井的矽基材。第一介電材質層102,係一種形成於矽基材101之P型井區上的二氧化矽層。而閘極層103則係由多晶矽所構成。 1A to 1H are schematic cross-sectional views showing a process structure for fabricating a non-volatile memory device 100 according to an embodiment of the invention. The non-volatile memory device 100 is formed by the following steps: First, a first dielectric material layer 102 and a gate layer 103 are formed on the substrate 101 (as shown in FIG. 1A). In some embodiments of the invention, substrate 101 comprises a p-type well substrate. The first dielectric material layer 102 is a ruthenium dioxide layer formed on the P-type well region of the ruthenium substrate 101. The gate layer 103 is composed of polysilicon.
之後,以第一介電材質層102為蝕刻停止層,圖案化閘極層103,藉以形成閘電極104(如圖1B所繪示)。接著,再藉由等向性蝕刻製程,例如濕式蝕刻製程,移除未被閘電極104所覆蓋的一部分第一介電材質層102,並與閘電極104形成一閘極結構114(如圖1C所繪示)。 Thereafter, the first dielectric material layer 102 is used as an etch stop layer, and the gate layer 103 is patterned to form the gate electrode 104 (as shown in FIG. 1B ). Then, a portion of the first dielectric material layer 102 not covered by the gate electrode 104 is removed by an isotropic etching process, such as a wet etching process, and a gate structure 114 is formed with the gate electrode 104 (as shown in the figure). 1C is shown).
在本發明的一些實施例之中,此一等向性蝕刻製程,係採用包含氫氟酸(HF)的蝕刻劑,來移除材質為二氧化矽的一部分第一介電材質層102。在本實施例之中,蝕刻劑除了會縱向地移除未被閘電極104所覆蓋的一部分第一介電材質層102外,還會橫向地對位於閘電極104下方的一部分第一介電材質層102進行側蝕,進而在閘極 結構114的底部形成複數個側蝕開口105。 In some embodiments of the present invention, the isotropic etching process uses an etchant comprising hydrofluoric acid (HF) to remove a portion of the first dielectric material layer 102 of the material ceria. In this embodiment, in addition to longitudinally removing a portion of the first dielectric material layer 102 not covered by the gate electrode 104, the etchant laterally faces a portion of the first dielectric material under the gate electrode 104. Layer 102 performs side etching, and then at the gate A plurality of undercut openings 105 are formed at the bottom of the structure 114.
然後,再於矽基材101與閘電極104暴露於外的表面上,形成第二介電材質層106(如圖1D所繪示)。在本發明的一些實施例之中,第二介電材質層106,係藉由熱氧化法或沉積製程,所形成的二氧化矽薄層。在本發明的一些實施例之中,第二介電材質層106可完全填滿側蝕開口105。但在本實施例中,第二介電材質層106並未完全填滿側蝕開口105;而該側蝕開口105,係被後續形成於第二介電材質層106上的氮化矽層107所填滿(如圖1E所繪示)。值得注意的是,本發明的其他實施例之中,亦可採用具有捕捉留置電子特性的其他材質層來取代氮化矽層107。 Then, on the exposed surface of the germanium substrate 101 and the gate electrode 104, a second dielectric material layer 106 is formed (as shown in FIG. 1D). In some embodiments of the present invention, the second dielectric material layer 106 is a thin layer of cerium oxide formed by a thermal oxidation process or a deposition process. In some embodiments of the invention, the second dielectric material layer 106 may completely fill the undercut openings 105. However, in this embodiment, the second dielectric material layer 106 does not completely fill the undercut opening 105; and the undercut opening 105 is formed by the tantalum nitride layer 107 subsequently formed on the second dielectric material layer 106. Filled up (as shown in Figure 1E). It should be noted that in other embodiments of the present invention, other material layers having trapping electron retention characteristics may be used instead of the tantalum nitride layer 107.
後續,以矽基材101與閘電極104為蝕刻終止層,進行非等向性蝕刻製程,例如反應離子蝕刻,移除了一部分的氮化矽層107以及第二介電材質層106,並於閘極結構114之側壁114a和114b上,遺留另一部分的氮化矽層107以及第二介電材質層106。而在本實施例之中,位於閘極結構114下方,填充側蝕開口105的另一部分氮化矽層107以及第二介電材質層106也被餘留下來(如圖1F所繪示)。 Subsequently, the germanium substrate 101 and the gate electrode 104 are used as an etch stop layer, and an anisotropic etching process, such as reactive ion etching, removes a portion of the tantalum nitride layer 107 and the second dielectric material layer 106, and On the sidewalls 114a and 114b of the gate structure 114, another portion of the tantalum nitride layer 107 and the second dielectric material layer 106 are left. In the present embodiment, another portion of the tantalum nitride layer 107 and the second dielectric material layer 106 filled under the gate structure 114 are also left behind (as shown in FIG. 1F).
隨後,再以沉積及圖案化製程,在剩餘之氮化矽層107遠離閘極結構114的一側,形成第三介電材質層108,將基材101和氮化矽層107電性隔離(如圖1G所繪示)。在本實施例之中,第三介電材質層108較佳係藉由熱沉積製程以及圖案化製程,所形成的圖案化二氧化矽層。 Then, a third dielectric material layer 108 is formed on the side of the remaining tantalum nitride layer 107 away from the gate structure 114 by a deposition and patterning process to electrically isolate the substrate 101 from the tantalum nitride layer 107 ( As shown in Figure 1G). In the present embodiment, the third dielectric material layer 108 is preferably a patterned cerium oxide layer formed by a thermal deposition process and a patterning process.
後續,以第三介電材質層108、剩餘之第二介電材質層106和氮化矽層107以及閘極結構114為罩幕,進行至少一次的離子摻雜製程,在基材101形成輕汲極摻雜(Light Drain Doping,LDD)區109。並在第三介電材質層108遠離閘極結構114的一側,形成間隙壁110:再以閘極結構114和間隙壁110為罩幕,進行至少以另一離子摻 雜製程,於基材101之中形成汲極區111和源極區112,完成如圖1H所繪示的非揮發性記憶元件100。 Subsequently, the third dielectric material layer 108, the remaining second dielectric material layer 106, the tantalum nitride layer 107, and the gate structure 114 are used as a mask to perform at least one ion doping process to form a light on the substrate 101. Light Drain Doping (LDD) zone 109. And on the side of the third dielectric material layer 108 away from the gate structure 114, the spacer 110 is formed: the gate structure 114 and the spacer 110 are used as a mask to perform at least another ion doping. In the heterogeneous process, the drain region 111 and the source region 112 are formed in the substrate 101 to complete the non-volatile memory device 100 as shown in FIG. 1H.
在本實施例之中(參見圖1H),非揮發性記憶元件100之閘極結構114的兩相對側壁114a和114b上,分別具有蝕刻剩餘的第二介電材質層106和氮化矽層107以及第三介電材質層108所組成的多層結構,可與閘極結構114和矽基材101構成兩個SONOS結構,對稱地形成於閘極結構114的側壁114a和114b之上。 In the present embodiment (see FIG. 1H), the opposite sidewalls 114a and 114b of the gate structure 114 of the non-volatile memory device 100 respectively have a second dielectric material layer 106 and a tantalum nitride layer 107 which are etched away. And the multilayer structure composed of the third dielectric material layer 108 can form two SONOS structures with the gate structure 114 and the germanium substrate 101, and symmetrically formed on the sidewalls 114a and 114b of the gate structure 114.
其中,剩餘的氮化矽層107本身具有捕捉留置電子的特性,且係以立壁的形式,可作為SONOS結構之電荷捕捉層(以下簡稱電荷捕捉立壁113);第三介電材質層108結合一部分剩餘的第一介電材質層102,將基材101的通道和電荷捕捉立壁113二者電性隔離,可做為SONOS結構的穿隧氧化層;剩餘的第二介電材質層106結合另一部分剩餘的第一介電材質層102,將閘電極104和電荷捕捉立壁113二者電性隔離,可做為SONOS結構的阻絕氧化層。 The remaining tantalum nitride layer 107 itself has the property of capturing the indwelling electrons, and is in the form of a vertical wall, and can be used as a charge trapping layer of the SONOS structure (hereinafter referred to as the charge trapping vertical wall 113); the third dielectric material layer 108 is combined with a part. The remaining first dielectric material layer 102 electrically isolates the channel of the substrate 101 from the charge trapping vertical wall 113 and can serve as a tunneling oxide layer of the SONOS structure; the remaining second dielectric material layer 106 is combined with another portion. The remaining first dielectric material layer 102 electrically isolates both the gate electrode 104 and the charge trapping vertical wall 113, and can be used as a resistive oxide layer of the SONOS structure.
在本發明的實施例中,對稱的兩個電荷捕捉立壁113與基材101夾一個非平角115。在本實施例之中,單一電荷捕捉立壁113與基材101所夾的非平角115,可為90°角。但在本發明的其他實施例之中,非平角115也可以是其他角度,例如實質大於0°小於90°的角度。 In an embodiment of the invention, the symmetric two charge trapping walls 113 and the substrate 101 have a non-flat angle 115. In the present embodiment, the non-flat angle 115 between the single charge trapping vertical wall 113 and the substrate 101 may be an angle of 90°. However, in other embodiments of the invention, the non-flat angle 115 may also be other angles, such as an angle substantially greater than 0° and less than 90°.
在本實施例之中,電荷捕捉立壁113,除了縱向的立壁部分,還包含位於閘極結構114下方,用來填充側蝕開口105的橫向延伸部分。因此電荷捕捉立壁113具有一L形截面(如圖1H所繪示)。但在本發明的另一實施例之中,由於側蝕開口105,在尚未形成氮化矽層107之前,已被第二介電材質層106’完全填滿。因此,在非揮發性記憶元件100’中,電荷捕捉立壁113’具有一I形截面(如圖1H’所繪示)。 In the present embodiment, the charge trapping vertical wall 113, in addition to the longitudinal upright wall portion, includes a laterally extending portion under the gate structure 114 for filling the undercut opening 105. Therefore, the charge trapping vertical wall 113 has an L-shaped cross section (as shown in FIG. 1H). However, in another embodiment of the present invention, the second dielectric material layer 106' has been completely filled due to the undercut opening 105 before the tantalum nitride layer 107 has been formed. Therefore, in the non-volatile memory element 100', the charge trapping vertical wall 113' has an I-shaped cross section (as shown in Fig. 1H').
在本發明的一些實施例中,可將前述的複數個非揮發性記憶元件100排列成具有複數行和複數列的非揮發性記憶元件陣列。 In some embodiments of the invention, the aforementioned plurality of non-volatile memory elements 100 may be arranged in a non-volatile memory element array having a plurality of rows and a plurality of columns.
在本實施例之中,當採用通道熱電子注入(Channel Hot Electron Injection,CHE)模式,對非揮發性記憶元件100進行寫入操作時,必須對閘電極104和汲極區111施予正偏壓,在靠近汲極區域112產生大的側向電場,使通道中的電子受到加速而形成熱電子(Hot Electron),越穿隧氧化層,注入SONOS結構的電荷捕捉立壁113。其中,施予閘電極104和汲極區111的正偏壓,較佳分別為7V和5.5V。 In the present embodiment, when the channel hot electron injection (CHE) mode is used to perform the write operation on the non-volatile memory element 100, the gate electrode 104 and the drain region 111 must be positively biased. The pressure generates a large lateral electric field near the drain region 112, so that the electrons in the channel are accelerated to form hot electrons, and the tunneling oxide layer is injected to inject the charge trapping vertical wall 113 of the SONOS structure. The positive bias voltage applied to the gate electrode 104 and the drain region 111 is preferably 7V and 5.5V, respectively.
而當採用通道二次電子注入(Channel Initiated Secondary Electron Injection,CHISEL)模式,對非揮發性記憶元件100進行寫入操作時,必須對閘電極104和源極區112施與正偏壓,並且對基材101施予反向偏壓,使二次碰撞(secondary impact)產生的熱電子,注入SONOS結構的電荷捕捉立壁113。其中,施予閘電極104和源極區112的正偏壓,較佳分別為5V和3V;施予基材101的反向偏壓較佳為-2V。 When the channel initiating Secondary Electron Injection (CHISEL) mode is used to perform the write operation on the non-volatile memory element 100, the gate electrode 104 and the source region 112 must be positively biased, and The substrate 101 is biased in reverse bias so that the hot electrons generated by the secondary impact are injected into the charge trapping wall 113 of the SONOS structure. The positive bias voltage applied to the gate electrode 104 and the source region 112 is preferably 5V and 3V, respectively; and the reverse bias voltage applied to the substrate 101 is preferably -2V.
由於電荷捕捉立壁113本身具有捕捉留置電子的特性。為了避免受到電荷捕捉立壁113因反覆寫入和抹除的動作所造成的讀取干擾(read disturb),因此採用反向讀取(reversed read)的方式,對非揮發性記憶元件100進行讀取操作。在本實施例之中,對非揮發性記憶元件100進行讀取操作,較佳必須對閘電極104和源極區112分別施予2.8V和0.9V的正偏壓。 Since the charge trapping vertical wall 113 itself has the property of capturing indwelling electrons. In order to avoid read disturb caused by the action of repeatedly writing and erasing the charge trapping vertical wall 113, the non-volatile memory element 100 is read by a reverse read method. operating. In the present embodiment, for the read operation of the non-volatile memory device 100, it is preferable to apply a positive bias of 2.8 V and 0.9 V to the gate electrode 104 and the source region 112, respectively.
請參照圖2A至2B,圖2A至2B係根據本發明的另一實施例所繪示的製作非揮發性記憶元件200a和200b的製程結構剖面示意圖。由於製作非揮發性記憶元件200a和200b的步驟,與製作非揮發性記憶元件100的步驟類大致相似,差異僅存在於後段的製程步驟。因此重複的製程步驟不再重複說明,且相同的元件將以相同的符 號代表。 2A to 2B, FIG. 2A to FIG. 2B are schematic cross-sectional views showing a process structure for fabricating non-volatile memory elements 200a and 200b according to another embodiment of the present invention. Since the steps of making the non-volatile memory elements 200a and 200b are substantially similar to the steps of making the non-volatile memory element 100, the difference exists only in the subsequent steps of the process. Therefore, the repeated process steps will not be repeated, and the same components will have the same character. No.
在本實施例之中,製作非揮發性記憶元件200a和200b的步驟,可由前述的圖1F開始。在進行非等向性蝕刻製程之後,以基材101為蝕刻終止層進行蝕刻,藉以將閘極結構114,區分成兩個彼此分離的第一部分閘極結構214a和第二部分閘極結構214b(如圖2A所繪示)。 In the present embodiment, the steps of fabricating the non-volatile memory elements 200a and 200b can be initiated by the aforementioned FIG. 1F. After the anisotropic etching process is performed, the substrate 101 is etched as an etch stop layer, thereby dividing the gate structure 114 into two first partial gate structures 214a and second partial gate structures 214b separated from each other ( As shown in Figure 2A).
其中,第一部分閘極結構214a,包含閘電極204a(一部分剩餘的閘電極104)、一部分第一介電材質層102,以及位於原閘極結構114之側壁114a上的多層結構(包含一部分第二介電材質層106以及電荷捕捉立壁213a);第二部分閘極結構214b,包含閘電極204b、另一部分的第一介電材質層102,以及位於原閘極結構114的側壁114b上的多層結構(包含另一部分的第二介電材質層106以及電荷捕捉立壁213b)。 The first portion of the gate structure 214a includes a gate electrode 204a (a portion of the remaining gate electrode 104), a portion of the first dielectric material layer 102, and a multilayer structure (including a portion of the second portion) on the sidewall 114a of the original gate structure 114. The dielectric material layer 106 and the charge trapping vertical wall 213a); the second partial gate structure 214b includes a gate electrode 204b, another portion of the first dielectric material layer 102, and a multilayer structure on the sidewall 114b of the original gate structure 114. (Including another portion of the second dielectric material layer 106 and the charge trapping vertical wall 213b).
後續,以第一部分閘極結構214a和第二部分閘極結構214b為罩幕,進行離子摻雜製程,分別在基材101之中,形成輕汲極摻區209a和209b;之後,再分別於第一部分閘極結構214a暴露於外的側壁214a1、第二部分閘極結構214b暴露於外的側壁214b1上,以及電荷捕捉立壁213a和213b遠離第一閘電極204a和第二閘電極204b的一側上,形成間隙壁210a和210b。 Subsequently, the first partial gate structure 214a and the second partial gate structure 214b are used as masks to perform an ion doping process to form light-drain-doped regions 209a and 209b in the substrate 101, respectively; The first portion of the gate structure 214a is exposed to the outer sidewall 214a1, the second portion of the gate structure 214b is exposed to the outer sidewall 214b1, and the charge trapping walls 213a and 213b are away from the side of the first gate electrode 204a and the second gate electrode 204b. Upper, the spacers 210a and 210b are formed.
非揮發性記憶元件200a和200b的間隙壁,較佳係由雙層結構所組成。其中,間隙壁210a包含L形的二氧化矽層210a1以及覆蓋在二氧化矽層210a1的介電材質層210a2;間隙壁210b也包含L形的二氧化矽層210b2以及覆蓋在二氧化矽層210b1上的介電材質層210b2。在本發明的一些實施例之中,構成介電層210a2和210b2的材質,可為氮化矽、二氧化矽、氮氧化矽或其他介電材料。 The spacers of the non-volatile memory elements 200a and 200b are preferably composed of a two-layer structure. The spacer 210a includes an L-shaped ceria layer 210a1 and a dielectric material layer 210a2 covering the ceria layer 210a1. The spacer 210b also includes an L-shaped ceria layer 210b2 and a capping layer 210b1. The upper dielectric material layer 210b2. In some embodiments of the present invention, the materials constituting the dielectric layers 210a2 and 210b2 may be tantalum nitride, hafnium oxide, hafnium oxynitride or other dielectric materials.
再以第一部分閘極結構214a、第二部分閘極結構214b 以及間隙壁210和210b為罩幕,對基材101進行至少一次離子摻雜製程,分別在鄰接第一部分閘極結構214a和第二部分閘極結構214b的基材之中,形成共用源極/汲極區211以及源極區212a和汲極區212b。完成如圖2B所繪示兩個相鄰的非揮發性記憶元件200a和200b。 The first partial gate structure 214a and the second partial gate structure 214b And the spacers 210 and 210b are masks, and the substrate 101 is subjected to at least one ion doping process to form a common source/substrate in the substrate adjacent to the first partial gate structure 214a and the second partial gate structure 214b, respectively. The drain region 211 and the source region 212a and the drain region 212b. Two adjacent non-volatile memory elements 200a and 200b are depicted as shown in Figure 2B.
在本發明的一些實施例之中,兩相鄰的非揮發性記憶元件200a和200b分別具有一閘電極204a(或204b)以及包含二氧化矽層210a1(或210b1)、一部分第二介電材質層106和一部分電荷捕捉立壁113的多層結構,可分別與矽基材101構成兩個SONOS結構。 In some embodiments of the present invention, two adjacent non-volatile memory elements 200a and 200b respectively have a gate electrode 204a (or 204b) and a second dielectric material including a ruthenium dioxide layer 210a1 (or 210b1). The multilayer structure of the layer 106 and a portion of the charge trapping vertical wall 113 can form two SONOS structures with the tantalum substrate 101, respectively.
在本發明的實施例之中,非揮發性記憶元件200a和200b的結構相同,但二者彼此互為鏡像;且兩個相鄰非揮發性記憶元件200a和200b都具有一個單一電荷捕捉立壁213a和213b,分別位於相對應之閘電極204a和204b的相反兩側。如圖2B所繪示,非揮發性記憶元件200a的單一電荷捕捉立壁213a,鄰接於第一部分閘極結構214a的左側側壁214a1;非揮發性記憶元件200b的單一電荷捕捉立壁213b鄰接於第二部分閘極結構214b的右側側壁214b1。 In an embodiment of the invention, the non-volatile memory elements 200a and 200b are identical in structure but mirror each other; and both adjacent non-volatile memory elements 200a and 200b have a single charge trapping wall 213a And 213b are respectively located on opposite sides of the corresponding gate electrodes 204a and 204b. As shown in FIG. 2B, the single charge trapping vertical wall 213a of the non-volatile memory element 200a is adjacent to the left side wall 214a1 of the first partial gate structure 214a; the single charge trapping vertical wall 213b of the non-volatile memory element 200b is adjacent to the second portion. The right side wall 214b1 of the gate structure 214b.
另外,非揮發性記憶元件200a和200b的單一電荷捕捉立壁213a和213b,分別與基材101夾一個非平角215a和215b。在本發明的一些實施例之中,此二個非平角215a和215b較佳係等於90°。但在本發明的其他實施例之中,非平角215a和215b也可以是其他角度,例如實質大於0°小於90°的角度。 In addition, the single charge trapping walls 213a and 213b of the non-volatile memory elements 200a and 200b are respectively provided with a non-flat angle 215a and 215b with the substrate 101. In some embodiments of the invention, the two non-flat angles 215a and 215b are preferably equal to 90°. However, in other embodiments of the invention, the non-flat angles 215a and 215b may also be other angles, such as angles substantially greater than 0° and less than 90°.
在本發明的一些實施例中,兩個相鄰的非揮發性記憶元件200a和200b之源極區或汲極區,可部分重疊,而於第一部分閘極結構214a和第二部分閘極結構214b之間,形成一共用源極/汲極區211。 In some embodiments of the invention, the source or drain regions of two adjacent non-volatile memory elements 200a and 200b may partially overlap, and the first portion of the gate structure 214a and the second portion of the gate structure Between 214b, a common source/drain region 211 is formed.
在本發明的一些實施例中,可將前述的複數個非揮發性記憶元件200a和200b排列成具有複數行和複數列的非揮發性記憶元 件陣列。 In some embodiments of the present invention, the aforementioned plurality of non-volatile memory elements 200a and 200b may be arranged in a non-volatile memory element having a plurality of rows and a plurality of columns. Array of parts.
在本實施例中,當採用通道熱電子注入模式,進行元件寫入操作時,以非揮發性記憶元件200b為例,較佳分別對閘電極204a和汲極區212b施予7V和5.5V的正偏壓。當採用通道二次電子注入模式,對非揮發性記憶元件200b進行寫入操作時,較佳分別對閘電極204b和源極區(共用源極/汲極區211)施與5V和3V的正偏壓,並且對基材101施予-2V的反向偏壓。而當採用反向讀取的方式,對進行元件讀取操作時。則僅需對閘電極204a和共用源極/汲極區211分別施予2.8V和0.1至0.3V的正偏壓。 In the present embodiment, when the channel write operation is performed using the channel hot electron injection mode, the non-volatile memory element 200b is exemplified, and the gate electrode 204a and the drain region 212b are preferably applied with 7V and 5.5V, respectively. Positive bias. When the channel secondary electron injection mode is employed, when the non-volatile memory element 200b is subjected to a write operation, it is preferable to apply positive 5V and 3V to the gate electrode 204b and the source region (the common source/drain region 211), respectively. The bias was applied and a reverse bias of -2 V was applied to the substrate 101. When the reverse reading method is used, the component reading operation is performed. Then, only a positive bias of 2.8 V and 0.1 to 0.3 V is applied to the gate electrode 204a and the common source/drain region 211, respectively.
比較非揮發性記憶元件100和200b的操作電壓,可以發現:不論是以通道熱電子注入模式或通道二次電子注入模式,對非揮發性記憶元件100和200b進行讀取操作,二者的操作電壓大致相同。但當採用反向讀取的方式,對進行元件讀取操作時,非揮發性記憶元件200的操作電壓,遠小於非揮發性記憶元件100的操作電壓。 Comparing the operating voltages of the non-volatile memory elements 100 and 200b, it can be found that the read operation of the non-volatile memory elements 100 and 200b, whether in the channel hot electron injection mode or the channel secondary electron injection mode, the operation of the two The voltage is approximately the same. However, when the reverse reading mode is employed, the operating voltage of the non-volatile memory element 200 is much smaller than the operating voltage of the non-volatile memory element 100 when performing a component reading operation.
由於非揮發性記憶元件100具有兩個分別鄰接於源極區112和汲極區111,的對稱電荷捕捉立壁113。加上,電荷捕捉立壁113本身具有捕捉留置電子的特性。因此在進行元件反向讀取程序時,必須增加元件的操作電壓,方可產生足夠空乏區寬度來包覆電荷捕捉層113下方通道,以得到足夠的讀取電流。但此舉將會使得鄰接非讀寫端之源極區112的漏電流增加。故而間接影響或干擾周邊元件的存取,也使得電流消耗變大。另外,為增加讀取電流,源極區112和汲極區111的摻雜濃度也須增加,但容易引起短通道效應及熱載子效應,導致元件擊穿,導致非揮發性記憶元件100的通道長度需加長。 Since the non-volatile memory element 100 has two symmetric charge trapping walls 113 adjacent to the source region 112 and the drain region 111, respectively. In addition, the charge trapping vertical wall 113 itself has the property of capturing indwelling electrons. Therefore, when performing the component reverse reading process, it is necessary to increase the operating voltage of the component to generate a sufficient depletion region width to cover the channel under the charge trapping layer 113 to obtain a sufficient reading current. However, this will increase the leakage current of the source region 112 adjacent to the non-reading end. Therefore, indirectly affecting or interfering with the access of peripheral components also causes current consumption to become large. In addition, in order to increase the read current, the doping concentration of the source region 112 and the drain region 111 must also increase, but it is easy to cause a short channel effect and a hot carrier effect, resulting in component breakdown, resulting in the non-volatile memory device 100. The channel length needs to be lengthened.
相反地,以非揮發性記憶元件200b為例,由於非揮發性記憶元件200b僅具有一鄰接汲極區212b的單一電荷捕捉立壁213b。在讀寫端無電荷捕捉層(共用源極/汲極區211),不會有留置電子 的現象。在讀取資料時,僅需給予一小偏壓,即可獲得足夠讀取電流。可減少鄰接非讀寫端之源極區(共用源極/汲極區211)的漏電流。故不僅不會影響非揮發性記憶元件200b的反向讀取程序,更可以降低非揮發性記憶元件200b的崩潰電壓及讀取時的操作電壓和電流消耗,也較不會對周邊元件產生干擾。可減少非揮發性記憶元件200b的能源消耗,也可減輕並源極/汲極摻雜,減少短通道效應及熱載子效應,有利於非揮發性記憶元件關鍵尺寸的微小化。 Conversely, taking the non-volatile memory element 200b as an example, since the non-volatile memory element 200b has only a single charge trapping vertical wall 213b adjacent to the drain region 212b. There is no charge trapping layer on the read/write side (shared source/drain region 211), there will be no indwelling electrons. The phenomenon. When reading data, you only need to give a small bias to get enough read current. The leakage current of the source region (common source/drain region 211) adjacent to the non-reading terminal can be reduced. Therefore, the reverse reading process of the non-volatile memory element 200b is not affected, and the breakdown voltage of the non-volatile memory element 200b and the operating voltage and current consumption during reading are also reduced, and the peripheral components are not interfered. . The energy consumption of the non-volatile memory element 200b can be reduced, the source/drain doping can be reduced, the short channel effect and the hot carrier effect can be reduced, and the miniaturization of the critical size of the non-volatile memory element is facilitated.
根據上述實施例,本發明的是提供一種可程式化的非揮發性記憶元件及其製造方法。此可程式化的非揮發性記憶元件,具有一非對稱結構,其包括一個鄰接閘電極之一側壁的單一電荷捕捉立壁。其中,閘電極位於基材上方,且與基材電性隔離。單一電荷捕捉立壁,與基材和閘電極電性隔離,並且與基材夾一非平角。 According to the above embodiments, the present invention provides a programmable non-volatile memory element and a method of fabricating the same. The programmable non-volatile memory element has an asymmetrical structure that includes a single charge trapping wall adjacent one of the sidewalls of the gate electrode. Wherein, the gate electrode is located above the substrate and is electrically isolated from the substrate. A single charge captures the vertical wall, is electrically isolated from the substrate and the gate electrode, and has a non-flat angle with the substrate.
由於,非揮發性記憶元件僅有一個單一電荷捕捉立壁,因此在進行非揮發性記憶元件程式化時,無電荷捕捉層的一側,不會有留置電子的現象。在讀取資料時,僅需給予一小偏壓,即可獲得足夠讀取電流。不僅不會影響元件的讀取,更可以降低非揮發性記憶元件的漏電流及崩潰電壓,並改善讀取時的操作電壓和電流消耗過高的問題,也較不會對周邊元件產生干擾,可減少元件的能源消耗。也可減輕源極/汲極摻雜,減少短通道效應及熱載子效應,利於元件的關鍵尺寸的微小化。 Since the non-volatile memory element has only a single charge trapping vertical wall, when the non-volatile memory element is programmed, there is no phenomenon of leaving electrons on the side without the charge trapping layer. When reading data, you only need to give a small bias to get enough read current. It not only does not affect the reading of components, but also reduces the leakage current and breakdown voltage of non-volatile memory components, and improves the problem of excessive operating voltage and current consumption during reading, and does not interfere with peripheral components. It can reduce the energy consumption of components. It also reduces source/drain doping, reduces short-channel effects and hot-carrier effects, and facilitates miniaturization of critical dimensions of components.
雖然本發明已以較佳實施例揭露如上,然其並非用以限定本發明。任何該領域中具有通常知識者,在不脫離本發明之精神和範圍內,當可作些許之更動與潤飾。因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。 While the invention has been described above in the preferred embodiments, it is not intended to limit the invention. Anyone having ordinary knowledge in the field can make some changes and refinements without departing from the spirit and scope of the invention. Therefore, the scope of the invention is defined by the scope of the appended claims.
101‧‧‧基材 101‧‧‧Substrate
106‧‧‧第二介電材質層 106‧‧‧Second dielectric material layer
200a‧‧‧非揮發性記憶元件 200a‧‧‧Non-volatile memory components
200b‧‧‧非揮發性記憶元件 200b‧‧‧ non-volatile memory components
204a‧‧‧閘電極 204a‧‧ ‧ gate electrode
204a1‧‧‧閘電極的側壁 204a1‧‧‧ sidewall of the gate electrode
204b‧‧‧閘電極 204b‧‧‧ gate electrode
204b1‧‧‧閘電極的側壁 204b1‧‧‧ sidewall of the gate electrode
209a‧‧‧輕汲極摻區 209a‧‧‧Light 汲 polar zone
209b‧‧‧輕汲極摻區 209b‧‧‧Light 汲 polar zone
210a‧‧‧間隙壁 210a‧‧‧ clearance
210a1‧‧‧二氧化矽層 210a1‧‧ 二2 layer
210a2‧‧‧介電材質層 210a2‧‧‧ dielectric material layer
210b‧‧‧間隙壁 210b‧‧‧ spacer
210b1‧‧‧二氧化矽層 210b1‧‧ 二2 layer
210b2‧‧‧介電材質層 210b2‧‧‧ dielectric material layer
211‧‧‧共用源極/汲極區 211‧‧‧Shared source/bungee area
212a‧‧‧源極區 212a‧‧‧ source area
212b‧‧‧汲極區 212b‧‧‧Bungee Area
213a‧‧‧單一電荷捕捉立壁 213a‧‧‧Single charge capture vertical wall
213b‧‧‧單一電荷捕捉立壁 213b‧‧‧Single charge capture vertical wall
214a‧‧‧第一部分閘極結構 214a‧‧‧The first part of the gate structure
214a1‧‧‧第一部分閘極結構暴露在外的側壁 214a1‧‧‧The first part of the gate structure exposed to the outer side wall
214b‧‧‧第二部分閘極結構 214b‧‧‧Second part gate structure
214b1‧‧‧第二部分閘極結構暴露在外的側壁 214b1‧‧‧The second part of the gate structure exposed to the outer side wall
215a‧‧‧非平角 215a‧‧‧Non-flat angle
215b‧‧‧非平角 215b‧‧‧Non-flat angle
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