TWI445165B - Non-volatile memory, manufacturing method thereof and operating method of memory cell - Google Patents
Non-volatile memory, manufacturing method thereof and operating method of memory cell Download PDFInfo
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- 238000004519 manufacturing process Methods 0.000 title claims description 24
- 238000011017 operating method Methods 0.000 title 1
- 239000004020 conductor Substances 0.000 claims description 137
- 238000000034 method Methods 0.000 claims description 76
- 239000000758 substrate Substances 0.000 claims description 61
- 125000006850 spacer group Chemical group 0.000 claims description 32
- 239000000463 material Substances 0.000 claims description 28
- 239000011810 insulating material Substances 0.000 claims description 18
- 239000002784 hot electron Substances 0.000 claims description 12
- 238000002347 injection Methods 0.000 claims description 12
- 239000007924 injection Substances 0.000 claims description 12
- 238000000059 patterning Methods 0.000 claims description 9
- 238000005530 etching Methods 0.000 claims description 6
- 238000005468 ion implantation Methods 0.000 claims description 6
- 150000004767 nitrides Chemical class 0.000 claims description 4
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 2
- 230000000873 masking effect Effects 0.000 claims 1
- 230000000694 effects Effects 0.000 description 16
- 238000010586 diagram Methods 0.000 description 6
- 230000005684 electric field Effects 0.000 description 4
- 229910052732 germanium Inorganic materials 0.000 description 4
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 4
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 4
- 229920005591 polysilicon Polymers 0.000 description 4
- 238000009413 insulation Methods 0.000 description 3
- 230000006870 function Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 230000005641 tunneling Effects 0.000 description 1
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Description
本發明是有關於一種非揮發性記憶體(non-volatile memory)及其製造方法與記憶胞的操作方法,且特別是有關於一種可以避免第二位元效應(second bit effect)的非揮發性記憶體及其製造方法與記憶胞的操作方法。The present invention relates to a non-volatile memory, a method for fabricating the same, and a method for operating a memory cell, and more particularly to a non-volatile method capable of avoiding a second bit effect. Memory and its manufacturing method and method of operating memory cells.
非揮發性記憶體由於具有存入之資料在斷電後也不會消失之優點,因此許多電器產品中必須具備此類記憶體,以維持電器產品開機時的正常操作。特別是,快閃記憶體(flash memory)由於具有可多次進行資料之存入、讀取、抹除等操作,所以已成為個人電腦和電子設備所廣泛採用的一種記憶體元件。Non-volatile memory has the advantage that it does not disappear after power-off, so many electrical products must have such memory to maintain the normal operation of the electrical products when they are turned on. In particular, flash memory has become a memory component widely used in personal computers and electronic devices because it has operations such as storing, reading, and erasing data.
電荷捕捉快閃記憶體(charge-traped flash memory)為目前常見的一種快閃記憶體。在電荷捕捉快閃記憶體中,利用由氧化物層-氮化物層-氧化物層所構成的電荷捕捉結構(即熟知的ONO層)可儲存二位元的資料。一般來說,二位元的資料可分別儲存於電荷捕捉結構中的氮化物層的左側(即左位元)或右側(即右位元)Charge-trapped flash memory is a commonly used flash memory. In a charge trapping flash memory, a two-bit data can be stored using a charge trapping structure (i.e., a well-known ONO layer) composed of an oxide layer-nitride layer-oxide layer. In general, the two-bit data can be stored separately on the left side (ie, the left bit) or the right side (ie, the right bit) of the nitride layer in the charge trapping structure.
然而,在電荷捕捉快閃記憶體中存在著第二位元效應,即當對左位元進行讀取操作時,會受到右位元的影響,或當對右位元進行讀取操作時,會受到左位元的影響。此外,隨著記憶體尺寸逐漸縮小,第二位元效應更為顯著,因而影響了記憶體的操作裕度(operation window)與元件效能。However, there is a second bit effect in the charge trapping flash memory, that is, when the left bit is read, it is affected by the right bit, or when the right bit is read, Will be affected by the left bit. In addition, as the size of the memory shrinks, the second bit effect is more significant, thus affecting the operation window and component performance of the memory.
本發明的實施例提供一種非揮發性記憶體,其可以避免在操作時產生第二位元效應。Embodiments of the present invention provide a non-volatile memory that avoids the generation of a second bit effect during operation.
本發明的實施例另提供一種非揮發性記憶體的製作方法,其可製造具有較大操作裕度的非揮發性記憶體。Embodiments of the present invention further provide a method of fabricating a non-volatile memory that can produce a non-volatile memory having a large operational margin.
本發明的實施例又提供一種記憶胞的操作方法,其可以有效地提高元件效能。Embodiments of the present invention further provide a method of operating a memory cell that can effectively improve component performance.
本發明的實施例提出一種非揮發性記憶體,其包括基底、多個條狀的第一摻雜區、多個條狀的第二摻雜區、電荷捕捉結構、多個條狀的第一閘極、多個條狀的第二閘極以及閘間絕緣層。第一摻雜區配置於基底中,並沿第一方向延伸。第二摻雜區配置於基底中,並沿第一方向延伸,且第二摻雜區與第一摻雜區交替排列。電荷捕捉結構配置於基底上。第一閘極配置於電荷捕捉結構上,並沿第一方向延伸,且每一個第一閘極位於這些第一摻雜區的其中一者上。第二閘極配置於電荷捕捉結構上,並沿第二方向延伸,且位於第二摻雜區上,其中第二方向與第一方向交錯。閘間絕緣層配置於第一閘極與第二閘極之間。相鄰的第一摻雜區與第二摻雜區以及位於相鄰的第一摻雜區與第二摻雜區之間的第一閘極、第二閘極與電荷捕捉結構定義出記憶胞。Embodiments of the present invention provide a non-volatile memory including a substrate, a plurality of strip-shaped first doped regions, a plurality of strip-shaped second doped regions, a charge trapping structure, and a plurality of strip-shaped first a gate, a plurality of strip-shaped second gates, and an inter-gate insulating layer. The first doped region is disposed in the substrate and extends in the first direction. The second doped region is disposed in the substrate and extends in the first direction, and the second doped region is alternately arranged with the first doped region. The charge trapping structure is disposed on the substrate. The first gate is disposed on the charge trapping structure and extends in the first direction, and each of the first gates is located on one of the first doped regions. The second gate is disposed on the charge trapping structure and extends in the second direction and is located on the second doped region, wherein the second direction is staggered with the first direction. The gate insulating layer is disposed between the first gate and the second gate. The first first doped region and the second doped region and the first gate, the second gate and the charge trapping structure between the adjacent first doped region and the second doped region define a memory cell .
依照本發明實施例所述之非揮發性記憶體,上述之第一閘極的寬度例如大於第一摻雜區的寬度。According to the non-volatile memory of the embodiment of the invention, the width of the first gate is greater than the width of the first doped region, for example.
依照本發明實施例所述之非揮發性記憶體,上述之基底中例如具有多個溝渠,每一個第一摻雜區位於這些溝渠的其中一者下方,每一個第一閘極位於這些溝渠的其中一者的底部,且在第二方向上,這些第二閘極填入這些溝渠。In a non-volatile memory according to an embodiment of the invention, the substrate has, for example, a plurality of trenches, each of the first doped regions being located below one of the trenches, each of the first gates being located in the trenches The bottom of one of them, and in the second direction, these second gates fill the trenches.
依照本發明實施例所述之非揮發性記憶體,上述之電荷捕捉結構例如是由底氧化物層、電荷捕捉層與頂氧化物層所構成的複合結構。According to the non-volatile memory of the embodiment of the invention, the charge trapping structure is, for example, a composite structure composed of a bottom oxide layer, a charge trap layer and a top oxide layer.
依照本發明實施例所述之非揮發性記憶體,上述之電荷捕捉層的材料例如為氮化物或高介電常數材料。According to the non-volatile memory of the embodiment of the invention, the material of the charge trapping layer is, for example, a nitride or a high dielectric constant material.
依照本發明實施例所述之非揮發性記憶體,上述之高介電常數材料例如為HfO2 、TiO2 、ZrO2 、Ta2 O5 或A12 O3 。According to the non-volatile memory of the embodiment of the invention, the high dielectric constant material is, for example, HfO 2 , TiO 2 , ZrO 2 , Ta 2 O 5 or A 1 2 O 3 .
本發明的實施例另提出一種非揮發性記憶體的製造方法,此方法是先提供基底。然後,於基底上形成電荷捕捉結構。接著,於電荷捕捉結構上形成多個條狀的第一絕緣層,且這些第一絕緣層沿第一方向延伸。而後,於每一個第一絕緣層的側壁上形成導體間隙壁,且導體間隙壁沿第一方向延伸。繼之,以這些第一絕緣層與這些導體間隙壁為罩幕,進行離子植入製程,以於基底中形成多個條狀的摻雜區,且這些摻雜區沿第一方向延伸。隨後,於電荷捕捉結構上形成第一導體層,此第一導體層覆蓋導體間隙壁且暴露出第一絕緣層。接下來,於第一導體層上與第一絕緣層上形成第二絕緣層,此第二絕緣層在第一方向上暴露出部分第一導體層。然後,於第二絕緣層與第一導體層上形成第二導體層。之後,將第二導體層與第二絕緣層所暴露出的第一導體層圖案化,以在第二方向上形成多個條狀的第三導體層,其中第二方向與第一方向交錯。Embodiments of the present invention further provide a method of fabricating a non-volatile memory by first providing a substrate. Then, a charge trapping structure is formed on the substrate. Next, a plurality of strip-shaped first insulating layers are formed on the charge trapping structure, and the first insulating layers extend in the first direction. Then, conductor spacers are formed on the sidewalls of each of the first insulating layers, and the conductor spacers extend in the first direction. Then, the first insulating layer and the conductor spacers are used as masks to perform an ion implantation process to form a plurality of strip-shaped doped regions in the substrate, and the doped regions extend in the first direction. Subsequently, a first conductor layer is formed on the charge trapping structure, the first conductor layer covering the conductor spacers and exposing the first insulating layer. Next, a second insulating layer is formed on the first conductor layer and the first insulating layer, the second insulating layer exposing a portion of the first conductor layer in the first direction. Then, a second conductor layer is formed on the second insulating layer and the first conductor layer. Thereafter, the second conductor layer and the first conductor layer exposed by the second insulating layer are patterned to form a plurality of strip-shaped third conductor layers in the second direction, wherein the second direction is staggered with the first direction.
依照本發明實施例所述之非揮發性記憶體的製造方法,上述之每一個第一絕緣層與導體間隙壁具有一個總寬度,每一個第一絕緣層的寬度例如大於此總寬度的四分之一且小於此總寬度的二分之一。According to the manufacturing method of the non-volatile memory of the embodiment of the present invention, each of the first insulating layer and the conductor spacer has a total width, and the width of each of the first insulating layers is, for example, greater than four points of the total width. One and less than one-half of this total width.
依照本發明實施例所述之非揮發性記憶體的製造方法,上述之第一導體層的形成方法例如是先於電荷捕捉結構上形成導體材料層,並覆蓋第一絕緣層與導體間隙壁。之後,進行平坦化製程,移除部分導體材料層,直到暴露出第一絕緣層。According to a method of manufacturing a non-volatile memory according to an embodiment of the invention, the first conductor layer is formed by, for example, forming a conductor material layer on the charge trapping structure and covering the first insulating layer and the conductor spacer. Thereafter, a planarization process is performed to remove a portion of the layer of conductor material until the first insulating layer is exposed.
依照本發明實施例所述之非揮發性記憶體的製造方法,上述之第二絕緣層的形成方法例如是先於第一導體層與第一絕緣層上形成絕緣材料層。之後,進行圖案化製程,在第一方向上移除部分絕緣材料層。According to a method of manufacturing a non-volatile memory according to an embodiment of the invention, the method for forming the second insulating layer is, for example, forming an insulating material layer on the first conductor layer and the first insulating layer. Thereafter, a patterning process is performed to remove a portion of the insulating material layer in the first direction.
本發明的實施例再提出一種非揮發性記憶體的製造方法,此方法是先提供基底。然後,於基底中形成多個溝渠,且這些溝渠沿第一方向延伸。接著,於基底上形成電荷捕捉結構。而後,於這些溝渠之間以及這些溝渠底部的基底中形成多個摻雜區,且這些摻雜區沿第一方向延伸。繼之,於這些溝渠底部形成第一導體層,且第一導體層沿第一方向延伸。隨後,於第一導體層上形成絕緣層。之後,在第二方向上,於電荷捕捉結構上形成多個條狀的第二導體層,且這些第二導體層填入這些溝渠,其中第二方向與第一方向交錯。Embodiments of the present invention further provide a method of fabricating a non-volatile memory by first providing a substrate. Then, a plurality of trenches are formed in the substrate, and the trenches extend in the first direction. Next, a charge trapping structure is formed on the substrate. A plurality of doped regions are then formed in the trenches and in the substrate at the bottom of the trenches, and the doped regions extend in the first direction. Then, a first conductor layer is formed at the bottom of the trenches, and the first conductor layer extends in the first direction. Subsequently, an insulating layer is formed on the first conductor layer. Thereafter, in the second direction, a plurality of strip-shaped second conductor layers are formed on the charge trapping structure, and the second conductor layers fill the trenches, wherein the second direction is staggered with the first direction.
依照本發明實施例所述之非揮發性記憶體的製造方法,上述之第一導體層的形成方法例如是先於電荷捕捉結構上形成導體材料層,並填滿這些溝渠。之後,進行蝕刻製程,移除部分導體材料層,且保留位於溝渠底部的部分導體材料層。According to the method for fabricating a non-volatile memory according to an embodiment of the invention, the first conductor layer is formed by, for example, forming a layer of a conductor material on the charge trapping structure and filling the trenches. Thereafter, an etching process is performed to remove a portion of the conductor material layer and retain a portion of the conductor material layer at the bottom of the trench.
依照本發明實施例所述之非揮發性記憶體的製造方法,上述之絕緣層的形成方法例如是先於電荷捕捉結構上形成絕緣材料層,並填滿這些溝渠。之後,進行蝕刻製程,移除部分絕緣材料層,且保留位於第一導體層上的部分導體材料層。According to the method for fabricating a non-volatile memory according to an embodiment of the invention, the method for forming the insulating layer is, for example, forming a layer of insulating material on the charge trapping structure and filling the trenches. Thereafter, an etching process is performed to remove a portion of the insulating material layer and retain a portion of the conductive material layer on the first conductor layer.
依照本發明實施例所述之非揮發性記憶體的製造方法,上述之第二導體層的形成方法例如是先於電荷捕捉結構上形成導體材料層,並填滿這些溝渠。之後,進行圖案化製程,在第二方向上移除部分導體材料層。According to the method for fabricating a non-volatile memory according to an embodiment of the invention, the second conductor layer is formed by, for example, forming a layer of a conductor material on the charge trapping structure and filling the trenches. Thereafter, a patterning process is performed to remove a portion of the layer of conductor material in the second direction.
本發明的實施例又提出一種記憶胞的操作方法,此方法是提供如上所述的記憶胞,當進行程式化操作時,於第一閘極施加第一電壓;於第二閘極施加第二電壓;於第一摻雜區施加第三電壓;於第二摻雜區施加第四電壓;於基底施加第五電壓。Embodiments of the present invention further provide a method of operating a memory cell, the method of providing a memory cell as described above, applying a first voltage to a first gate when performing a program operation, and applying a second voltage to a second gate a voltage; applying a third voltage to the first doped region; applying a fourth voltage to the second doped region; applying a fifth voltage to the substrate.
依照本發明實施例所述之記憶胞的操作方法,當程式化操作例如由通道熱電子(channel hot electrons,CHE)注入執行時,第一電壓與第二電壓實質上相同,其中第一電壓介於9伏特至13伏特之間;第二電壓介於9伏特至13伏特之間;第三電壓與該第四電壓其中之一為0伏特,且第三電壓與該第四電壓其中另一介於3.5伏特至5.5伏特之間;第五電壓為0伏特。According to the method for operating a memory cell according to an embodiment of the present invention, when the program operation is performed by, for example, channel hot electrons (CHE) injection, the first voltage is substantially the same as the second voltage, wherein the first voltage is Between 9 volts and 13 volts; the second voltage is between 9 volts and 13 volts; one of the third voltage and the fourth voltage is 0 volts, and the third voltage and the fourth voltage are the other Between 3.5 volts and 5.5 volts; the fifth voltage is 0 volts.
依照本發明實施例所述之記憶胞的操作方法,當程式化操作例如由增強型通道熱電子注入執行時,第一電壓與第二電壓其中之一介於9伏特至13伏特之間,且第一電壓與第二電壓其中另一介於1.5伏特至3伏特之間;第三電壓與第四電壓其中之一為0伏特,且第三電壓與第四電壓其中另一介於3.5伏特至5.5伏特之間;第五電壓為0伏特。According to the method of operating a memory cell according to an embodiment of the invention, when the staging operation is performed, for example, by enhanced channel hot electron injection, one of the first voltage and the second voltage is between 9 volts and 13 volts, and One of the voltage and the second voltage is between 1.5 volts and 3 volts; one of the third voltage and the fourth voltage is 0 volts, and the third voltage and the fourth voltage are the other ones between 3.5 volts and 5.5 volts The fifth voltage is 0 volts.
依照本發明實施例所述之記憶胞的操作方法,在進行程式化操作之後,還可以進行抹除操作,且當進行抹除操作時,於第一閘極施加第六電壓;於第二閘極施加第七電壓;於第一摻雜區施加第八電壓;於第二摻雜區施加第九電壓;於基底施加第十電壓。According to the operation method of the memory cell according to the embodiment of the present invention, after the stylization operation, the erase operation may be performed, and when the erase operation is performed, the sixth voltage is applied to the first gate; A seventh voltage is applied to the pole; an eighth voltage is applied to the first doped region; a ninth voltage is applied to the second doped region; and a tenth voltage is applied to the substrate.
依照本發明實施例所述之記憶胞的操作方法,當抹除操作例如由能帶對能帶熱電洞(band-to-band hot hole,BBHH)執行時,第六電壓與第七電壓其中之一為0伏特、浮置(floating)或介於-11伏特至-15伏特之間,且第六電壓與第七電壓其中另一介於-11伏特至-15伏特之間;第八電壓與第九電壓其中之一為0伏特或浮置,且第八電壓與第九電壓其中另一介於4伏特至5伏特之間;第十電壓為0伏特。According to the method of operating a memory cell according to an embodiment of the invention, when the erasing operation is performed, for example, by a band-to-band hot hole (BBHH), the sixth voltage and the seventh voltage are One is 0 volts, floating or between -11 volts and -15 volts, and the sixth voltage and the seventh voltage are between -11 volts and -15 volts; the eighth voltage and the first One of the nine voltages is 0 volts or floating, and the eighth voltage and the ninth voltage are between 4 volts and 5 volts; the tenth voltage is 0 volts.
依照本發明實施例所述之記憶胞的操作方法,在進行程式化操作之後,還可以進行讀取操作,且當進行讀取操作時,於第一閘極施加第十一電壓;於第二閘極施加第十二電壓;於第一摻雜區施加第十三電壓;於第二摻雜區施加第十四電壓;於基底施加一第十五電壓。According to the operation method of the memory cell according to the embodiment of the present invention, after the stylization operation, a read operation may be performed, and when the read operation is performed, the eleventh voltage is applied to the first gate; The gate applies a twelfth voltage; a thirteenth voltage is applied to the first doped region; a fourteenth voltage is applied to the second doped region; and a fifteenth voltage is applied to the substrate.
依照本發明實施例所述之記憶胞的操作方法,上述之第十一電壓與第十二電壓其中之一介於5伏特至9.5伏特之間,且第十一電壓與第十二電壓其中另一介於0伏特至6伏特之間;第十三電壓與第十四電壓其中之一介於0.7伏特至1.6伏特之間,且第十三電壓與第十四電壓其中另一為0伏特;第十五電壓為0伏特。According to the method for operating a memory cell according to an embodiment of the invention, one of the eleventh voltage and the twelfth voltage is between 5 volts and 9.5 volts, and the eleventh voltage and the twelfth voltage are Between 0 volts and 6 volts; one of the thirteenth voltage and the fourteenth voltage is between 0.7 volts and 1.6 volts, and the thirteenth voltage and the fourteenth voltage voltage of the other is 0 volts; The voltage is 0 volts.
本發明的實施例又提出一種非揮發性記憶體的製造方法,其是先提供基底。然後,於基底中形成多個條狀的第一摻雜區與多個條狀的第二摻雜區。第一摻雜區與第二摻雜區沿第一方向延伸,且第一摻雜區與第二摻雜區交替排列。接著,於基底上形成電荷捕捉結構。而後,於電荷捕捉結構上形成多個條狀的第一閘極。第一閘極沿第一方向延伸,且每一個第一閘極位於這些第一摻雜區的其中一者上。繼之,於電荷捕捉結構上形成多個條狀的第二閘極。第二閘極沿第二方向延伸,且位於第二摻雜區上,其中第二方向與第一方向交錯。之後,於第一閘極與第二閘極之間形成閘間絕緣層。Embodiments of the present invention further provide a method of fabricating a non-volatile memory that provides a substrate first. Then, a plurality of strip-shaped first doped regions and a plurality of strip-shaped second doped regions are formed in the substrate. The first doped region and the second doped region extend in the first direction, and the first doped region and the second doped region are alternately arranged. Next, a charge trapping structure is formed on the substrate. Then, a plurality of strip-shaped first gates are formed on the charge trapping structure. The first gate extends in the first direction, and each of the first gates is located on one of the first doped regions. Then, a plurality of strip-shaped second gates are formed on the charge trapping structure. The second gate extends in the second direction and is located on the second doped region, wherein the second direction is staggered with the first direction. Thereafter, an inter-gate insulating layer is formed between the first gate and the second gate.
依照本發明實施例所述之非揮發性記憶體的製造方法,上述之第一閘極、第二閘極與閘間絕緣層的形成方法例如是先於電荷捕捉結構上形成多個條狀的第一絕緣層,且這些第一絕緣層沿第一方向延伸。然後,於每一個第一絕緣層的側壁上形成導體間隙壁,且這些導體間隙壁沿第一方向延伸。接著,於電荷捕捉結構上形成第一導體層,此第一導體層覆蓋導體間隙壁且暴露出第一絕緣層。而後,於第一導體層上與第一絕緣層上形成第二絕緣層,此第二絕緣層在第一方向上暴露出部分第一導體層,隨後,於第二絕緣層與第一導體層上形成第二導體層。之後,將第二導體層與第二絕緣層所暴露出的第一導體層圖案化,以在第二方向上形成多個條狀的第三導體層,其中第三導體層以及位於其下方的第一導體層構成第二閘極。According to the method for manufacturing a non-volatile memory according to the embodiment of the present invention, the method for forming the first gate, the second gate, and the inter-gate insulating layer is formed by, for example, forming a plurality of strips on the charge trapping structure. a first insulating layer, and the first insulating layers extend in the first direction. Then, conductor spacers are formed on the sidewalls of each of the first insulating layers, and the conductor spacers extend in the first direction. Next, a first conductor layer is formed on the charge trapping structure, the first conductor layer covering the conductor spacers and exposing the first insulating layer. And forming a second insulating layer on the first conductive layer and the first insulating layer, the second insulating layer exposing a portion of the first conductive layer in the first direction, and then, in the second insulating layer and the first conductive layer A second conductor layer is formed thereon. Thereafter, the second conductor layer and the first conductor layer exposed by the second insulating layer are patterned to form a plurality of strip-shaped third conductor layers in the second direction, wherein the third conductor layer and the underlying layer The first conductor layer constitutes a second gate.
依照本發明實施例所述之非揮發性記憶體的製造方法,上述之第一摻雜區與第二摻雜區的形成方法例如是以第一絕緣層與導體間隙壁為罩幕,進行離子植入製程。According to the method for fabricating a non-volatile memory according to the embodiment of the present invention, the method for forming the first doped region and the second doped region is performed by, for example, using a first insulating layer and a conductor spacer as a mask to perform ion Implantation process.
基於上述,本發明實施例的非揮發性記憶體具有交錯配置的多條第一閘極與多條第二閘極,使得每一個記憶胞具有二個閘極,因此在進行程式化操作時,可藉由對二個閘極施加適當的電壓來進行通道熱電子注入或增強型通道熱電子注入以增加程式化效率,進而提高元件效能。此外,在進行讀取操作時,可藉由對位於非讀取側的閘極施加高電壓來抑制第二位元效應,以增加操作裕度。另外,進行讀取操作時,由於已對位於非讀取側的閘極施加高電壓來抑制第二位元效應,因此不需對位於非讀取側的閘極下方的摻雜區施加高電壓來抑制第二位元效應,因而可以減輕讀取干擾(read disturb)的問題。Based on the above, the non-volatile memory of the embodiment of the present invention has a plurality of first gates and a plurality of second gates arranged in a staggered manner, so that each memory cell has two gates, so when performing a program operation, Channel hot electron injection or enhanced channel hot electron injection can be performed by applying appropriate voltages to the two gates to increase stylized efficiency and thereby improve component performance. Further, when a read operation is performed, the second bit effect can be suppressed by applying a high voltage to the gate located on the non-read side to increase the operation margin. In addition, when the read operation is performed, since the second bit effect is suppressed by applying a high voltage to the gate on the non-read side, it is not necessary to apply a high voltage to the doped region under the gate on the non-read side. To suppress the second bit effect, the problem of read disturb can be alleviated.
需要瞭解的是,上述一般的說明以及下述詳細的說明為示範性的,其並非用以限定本發明。The above general description and the following detailed description are exemplary and are not intended to limit the invention.
為讓本發明之上述特徵和優點能更明顯易懂,下文特舉實施例,並配合所附圖式作詳細說明如下。The above described features and advantages of the present invention will be more apparent from the following description.
第一實施例First embodiment
圖1A為依照本發明一實施例所繪示的非揮發性記憶體之上視示意圖。圖1B為沿圖1A中的I-I’剖面所繪示的記憶胞之剖面示意圖。請同時參照圖1A與圖1B,非揮發性記憶體10包括基底100、多個條狀的第一摻雜區102、多個條狀的第二摻雜區104、電荷捕捉結構106、多個條狀的第一閘極108、多個條狀的第二閘極110以及閘間絕緣層112。基底100例如為矽基底或絕緣層上有矽(silicon on insulator,SOI)基底。第一摻雜區102與第二摻雜區104配置於基底100中,並沿第一方向Y延伸。第一摻雜區102與第二摻雜區104交替排列。第一摻雜區102與第二摻雜區104分別作為源極與汲極。或者,第一摻雜區102與第二摻雜區104也可以分別作為汲極與源極。電荷捕捉結構106配置於基底100上。電荷捕捉結構106例如是由底氧化物層、電荷捕捉層與頂氧化物層所構成的複合結構,其中底氧化物層作為穿隧介電層,頂氧化物層作為電荷阻擋層。電荷捕捉層的材料例如為氮化物或高介電常數材料(例如HfO2 、TiO2 、ZrO2 、Ta2 O5 或Al2 O3 )。底氧化物層的厚度例如介於40至50之間。電荷捕捉層的厚度例如介於60至100之間。頂氧化物層的厚度例如介於70至110之間。FIG. 1A is a top view of a non-volatile memory according to an embodiment of the invention. 1B is a schematic cross-sectional view of the memory cell taken along line II' of FIG. 1A. Referring to FIG. 1A and FIG. 1B simultaneously, the non-volatile memory 10 includes a substrate 100, a plurality of strip-shaped first doped regions 102, a plurality of strip-shaped second doped regions 104, a charge trapping structure 106, and a plurality of A strip-shaped first gate 108, a plurality of strip-shaped second gates 110, and an inter-gate insulating layer 112. The substrate 100 is, for example, a germanium substrate or a silicon on insulator (SOI) substrate. The first doping region 102 and the second doping region 104 are disposed in the substrate 100 and extend along the first direction Y. The first doping region 102 and the second doping region 104 are alternately arranged. The first doping region 102 and the second doping region 104 serve as a source and a drain, respectively. Alternatively, the first doping region 102 and the second doping region 104 may also serve as a drain and a source, respectively. The charge trapping structure 106 is disposed on the substrate 100. The charge trapping structure 106 is, for example, a composite structure composed of a bottom oxide layer, a charge trapping layer, and a top oxide layer, wherein the bottom oxide layer functions as a tunneling dielectric layer and the top oxide layer functions as a charge blocking layer. The material of the charge trap layer is, for example, a nitride or a high dielectric constant material (for example, HfO 2 , TiO 2 , ZrO 2 , Ta 2 O 5 or Al 2 O 3 ). The thickness of the bottom oxide layer is, for example, 40 To 50 between. The thickness of the charge trap layer is, for example, 60 To 100 between. The thickness of the top oxide layer is, for example, 70 To 110 between.
第一閘極108配置於電荷捕捉結構106上,並沿第一方向Y延伸,且每一個第一閘極108位於一個第一摻雜區102上。第一閘極108的寬度例如大於第一摻雜區102的寬度。第二閘極110配置於電荷捕捉結構106上,並沿第二方向X延伸,且位於第二摻雜區104上。第一方向Y與第二方向X交錯。在本實施例中,第一方向Y與第二方向X垂直。第一閘極108與第二閘極110的材料例如為多晶矽。閘間絕緣層112配置於第一閘極108與第二閘極110之間。閘間絕緣層112例如是由位於第一閘極108頂面上的閘間絕緣層112a與位於第一閘極108側壁上的閘間絕緣層112b所構成。The first gate 108 is disposed on the charge trapping structure 106 and extends along the first direction Y, and each of the first gates 108 is located on a first doping region 102. The width of the first gate 108 is, for example, greater than the width of the first doped region 102. The second gate 110 is disposed on the charge trapping structure 106 and extends along the second direction X and is located on the second doping region 104. The first direction Y is interlaced with the second direction X. In the present embodiment, the first direction Y is perpendicular to the second direction X. The material of the first gate 108 and the second gate 110 is, for example, polysilicon. The inter-gate insulating layer 112 is disposed between the first gate 108 and the second gate 110. The inter-gate insulating layer 112 is composed of, for example, an inter-gate insulating layer 112a on the top surface of the first gate 108 and an inter-gate insulating layer 112b on the sidewall of the first gate 108.
在本實施例中,相鄰的第一摻雜區102與第二摻雜區104以及位於相鄰的第一摻雜區102與第二摻雜區104之間的第一閘極108、第二閘極110與電荷捕捉結構106定義出記憶胞10a,即圖1A中方塊B所圍繞的區域。在記憶胞10a中,部分的第一閘極108位於第一掺雜區102上方,且部分的第二閘極110位於第二掺雜區104上方。此外,第二閘極110除了位於電荷捕捉結構106上之外,還覆蓋第一閘極108的頂部。第一閘極108與第二閘極110藉由閘間絕緣層112a與閘間絕緣層112b而彼此分離。In this embodiment, the adjacent first doping region 102 and the second doping region 104 and the first gate 108 between the adjacent first doping region 102 and the second doping region 104, The two gates 110 and the charge trapping structure 106 define a memory cell 10a, that is, a region surrounded by block B in FIG. 1A. In the memory cell 10a, a portion of the first gate 108 is above the first doped region 102 and a portion of the second gate 110 is above the second doped region 104. In addition, the second gate 110 covers the top of the first gate 108 in addition to the charge trapping structure 106. The first gate 108 and the second gate 110 are separated from each other by the inter-gate insulating layer 112a and the inter-gate insulating layer 112b.
以下將由圖1A中的I-I’剖面說明非揮發性記憶體10的製造方法。Hereinafter, a method of manufacturing the non-volatile memory 10 will be described by the cross section I-I' in Fig. 1A.
圖2A至圖2D為沿圖1A中的I-I’剖面所繪示的非揮發性記憶體之製造流程剖面圖。在圖2A至圖2D中,與圖1A、圖1B相同的元件將以相同的標號表示,於此不另行說明。首先,請參照圖2A,提供基底100。然後,於基底100上形成電荷捕捉結構106。接著,於電荷捕捉結構106上形成條狀的第一絕緣層200。第一絕緣層200沿圖1A中的第一方向Y延伸。第一絕緣層200即為圖1B中的閘間絕緣層112a。第一絕緣層200的形成方法例如是先於電荷捕捉結構106上形成一層絕緣材料層,然後再進行圖案化製程。2A to 2D are cross-sectional views showing the manufacturing process of the non-volatile memory taken along the line I-I' in Fig. 1A. In FIGS. 2A to 2D, the same elements as those in FIGS. 1A and 1B will be denoted by the same reference numerals and will not be described herein. First, referring to FIG. 2A, a substrate 100 is provided. Then, a charge trapping structure 106 is formed on the substrate 100. Next, a strip-shaped first insulating layer 200 is formed on the charge trapping structure 106. The first insulating layer 200 extends along the first direction Y in FIG. 1A. The first insulating layer 200 is the inter-gate insulating layer 112a in FIG. 1B. The first insulating layer 200 is formed by, for example, forming a layer of insulating material on the charge trapping structure 106 and then performing a patterning process.
然後,請參照圖2B,於第一絕緣層200的側壁上形成導體間隙壁202。導體間隙壁202沿圖1A中的第一方向Y延伸。導體間隙壁202的材料例如為多晶矽。在本實施例中,第一絕緣層200與其側壁上的導體間隙壁202具有總寬度W1,而第一絕緣層200的寬度W2大於總寬度W1的四分之一且小於總寬度W1的二分之一。之後,以第一絕緣層200與導體間隙壁202為罩幕,進行離子植入製程,以於基底100中形成條狀的第一摻雜區102與條狀的第二摻雜區104。第一摻雜區102與第二摻雜區104沿圖1A中的第一方向Y延伸。Then, referring to FIG. 2B, a conductor spacer 202 is formed on the sidewall of the first insulating layer 200. The conductor spacer 202 extends in a first direction Y in FIG. 1A. The material of the conductor spacer 202 is, for example, polysilicon. In the present embodiment, the first insulating layer 200 has a total width W1 with the conductor spacers 202 on the sidewalls thereof, and the width W2 of the first insulating layer 200 is greater than a quarter of the total width W1 and less than the total width W1. one. Thereafter, an ion implantation process is performed with the first insulating layer 200 and the conductor spacers 202 as masks to form strip-shaped first doping regions 102 and strip-shaped second doping regions 104 in the substrate 100. The first doped region 102 and the second doped region 104 extend along a first direction Y in FIG. 1A.
接著,請參照圖2C,於電荷捕捉結構106上形成第一導體層204。第一導體層204覆蓋導體間隙壁202且暴露出第一絕緣層200。第一導體層204的材料例如為多晶矽。第一導體層204的形成方法例如是先於電荷捕捉結構106上形成導體材料層,並覆蓋第一絕緣層200與導體間隙壁202。之後,進行平坦化製程,移除部分導體材料層,直到暴露出第一絕緣層200。Next, referring to FIG. 2C, a first conductor layer 204 is formed on the charge trapping structure 106. The first conductor layer 204 covers the conductor spacers 202 and exposes the first insulating layer 200. The material of the first conductor layer 204 is, for example, polysilicon. The first conductor layer 204 is formed by, for example, forming a conductor material layer on the charge trapping structure 106 and covering the first insulating layer 200 and the conductor spacers 202. Thereafter, a planarization process is performed to remove a portion of the conductor material layer until the first insulating layer 200 is exposed.
之後,請參照圖2D,於第一導體層204上與第一絕緣層200上形成第二絕緣層206。第二絕緣層206在圖1A中的第一方向Y上暴露出部分第一導體層204。第二絕緣層206即為圖1B中的閘間絕緣層112b。第二絕緣層206的形成方法例如是先於第一導體層204與第一絕緣層200上形成絕緣材料層。之後,進行圖案化製程,在第一方向Y上移除部分絕緣材料層。然後,於第二絕緣層206與第一導體層204上形成第二導體層208。第二導體層208的材料例如為多晶矽。之後,將第二導體層208以及被第二絕緣層206所暴露出的第一導體層204圖案化,以在圖1A中的第二方向X上形成條狀的第三導體層(由經圖案化的第二導體層208及其下方的第一導體層204構成),且相鄰的兩條第三導體層之間暴露出電荷捕捉結構106。Thereafter, referring to FIG. 2D, a second insulating layer 206 is formed on the first conductor layer 204 and the first insulating layer 200. The second insulating layer 206 exposes a portion of the first conductor layer 204 in the first direction Y in FIG. 1A. The second insulating layer 206 is the inter-gate insulating layer 112b in FIG. 1B. The second insulating layer 206 is formed by, for example, forming an insulating material layer on the first conductive layer 204 and the first insulating layer 200. Thereafter, a patterning process is performed to remove a portion of the insulating material layer in the first direction Y. Then, a second conductor layer 208 is formed on the second insulating layer 206 and the first conductor layer 204. The material of the second conductor layer 208 is, for example, polycrystalline germanium. Thereafter, the second conductor layer 208 and the first conductor layer 204 exposed by the second insulating layer 206 are patterned to form a strip-shaped third conductor layer (by the pattern in the second direction X in FIG. 1A) The second conductor layer 208 and the first conductor layer 204 below it are formed, and the charge trapping structure 106 is exposed between the adjacent two third conductor layers.
在本實施例中,被第一絕緣層200與第二絕緣層206覆蓋的導體間隙壁202與第一導體層204(即圖2D中位於第一絕緣層200右側的導體間隙壁202與第一導體層204)構成圖1A與圖1B中的第一閘極108。此外,經圖案化的第二導體層208及其下方的第一導體層204(即圖2D中位於第一絕緣層200左側的第一導體層204與第二導體層208)構成圖1A與圖1B中的第二閘極110。In the present embodiment, the conductor spacer 202 and the first conductor layer 204 covered by the first insulating layer 200 and the second insulating layer 206 (ie, the conductor spacer 202 on the right side of the first insulating layer 200 in FIG. 2D and the first The conductor layer 204) constitutes the first gate 108 in FIGS. 1A and 1B. In addition, the patterned second conductor layer 208 and the first conductor layer 204 below it (ie, the first conductor layer 204 and the second conductor layer 208 on the left side of the first insulating layer 200 in FIG. 2D) constitute FIG. 1A and FIG. The second gate 110 in 1B.
第二實施例Second embodiment
圖3A為依照本發明另一實施例所繪示的非揮發性記憶體之上視示意圖。圖3B為沿圖3A中的II-II’剖面所繪示的記憶胞之剖面示意圖。請同時參照圖3A與圖3B,非揮發性記憶體30包括基底300、多個條狀的第一摻雜區302、多個條狀的第二摻雜區304、電荷捕捉結構306、多個條狀的第一閘極308、多個條狀的第二閘極310以及閘間絕緣層312。基底300例如為矽基底或絕緣層上有矽基底。基底300中具有多個沿第一方向Y延伸的溝渠301。第一摻雜區302與第二摻雜區304配置於基底300中,並沿第一方向Y延伸。每一個第一摻雜區302位於一個溝渠301的下方。第二摻雜區304與溝渠301交替排列。第一摻雜區302與第二摻雜區304分別作為源極與汲極。或者,第一摻雜區302與第二摻雜區304也可以分別作為汲極與源極。電荷捕捉結構306共形地(conformally)配置於基底300上。電荷捕捉結構306與第一實施例中的電荷捕捉結構106相同,於此不另行說明。FIG. 3A is a top view of a non-volatile memory according to another embodiment of the invention. Fig. 3B is a schematic cross-sectional view of the memory cell taken along the line II-II' in Fig. 3A. Referring to FIG. 3A and FIG. 3B simultaneously, the non-volatile memory 30 includes a substrate 300, a plurality of strip-shaped first doped regions 302, a plurality of strip-shaped second doped regions 304, a charge trapping structure 306, and a plurality of A strip-shaped first gate 308, a plurality of strip-shaped second gates 310, and an inter-gate insulating layer 312. The substrate 300 is, for example, a germanium substrate or a germanium substrate with an insulating substrate. The substrate 300 has a plurality of trenches 301 extending in a first direction Y. The first doping region 302 and the second doping region 304 are disposed in the substrate 300 and extend along the first direction Y. Each of the first doping regions 302 is located below a trench 301. The second doped region 304 is alternately arranged with the trench 301. The first doping region 302 and the second doping region 304 serve as a source and a drain, respectively. Alternatively, the first doping region 302 and the second doping region 304 may also serve as a drain and a source, respectively. The charge trapping structure 306 is conformally disposed on the substrate 300. The charge trapping structure 306 is the same as the charge trapping structure 106 of the first embodiment and will not be described herein.
每一個第一閘極308位於一個溝渠301的底部,且配置於電荷捕捉結構306上,並沿第一方向Y延伸。第二閘極310配置於電荷捕捉結構306上,並沿第二方向X延伸,且位於第二摻雜區304上。第一方向Y與第二方向X交錯。在本實施例中,第一方向Y與第二方向X垂直。此外,在第二方向X上,第二閘極310填入溝渠301。第一閘極308與第二閘極310的材料例如為多晶矽。閘間絕緣層312配置於溝渠301中,且位於第一閘極308與第二閘極310之間,用以隔離第一閘極308與第二閘極310。Each of the first gates 308 is located at the bottom of one of the trenches 301 and is disposed on the charge trapping structure 306 and extends in the first direction Y. The second gate 310 is disposed on the charge trapping structure 306 and extends along the second direction X and is located on the second doping region 304. The first direction Y is interlaced with the second direction X. In the present embodiment, the first direction Y is perpendicular to the second direction X. Further, in the second direction X, the second gate 310 is filled in the trench 301. The material of the first gate 308 and the second gate 310 is, for example, polysilicon. The inter-gate insulating layer 312 is disposed in the trench 301 and between the first gate 308 and the second gate 310 for isolating the first gate 308 and the second gate 310.
在本實施例中,相鄰的第一摻雜區302與第二摻雜區304以及位於相鄰的第一摻雜區302與第二摻雜區304之間的第一閘極308、第二閘極310與電荷捕捉結構306定義出記憶胞30a,即圖3B中虛線所圍繞的區域。In this embodiment, the adjacent first doping region 302 and the second doping region 304 and the first gate 308 between the adjacent first doping region 302 and the second doping region 304, The two gates 310 and the charge trapping structure 306 define a memory cell 30a, that is, a region surrounded by a broken line in FIG. 3B.
以下將由圖3A中的II-II’剖面說明非揮發性記憶體30的製造方法。Hereinafter, a method of manufacturing the non-volatile memory 30 will be described by a cross section II-II' in Fig. 3A.
圖4A至圖4C為沿圖3A中的II-II’剖面所繪示的非揮發性記憶體之製造流程剖面圖。在圖4A至圖4D中,與圖3A、圖3B相同的元件將以相同的標號表示,於此不另行說明。首先,請參照圖4A,提供基底300。然後,於基底300中形成多個沿第一方向Y延伸的溝渠301。接著,於基底300上共形地形成電荷捕捉結構306。4A to 4C are cross-sectional views showing the manufacturing process of the non-volatile memory taken along the line II-II' in Fig. 3A. In FIGS. 4A to 4D, the same elements as those in FIGS. 3A and 3B will be denoted by the same reference numerals and will not be described herein. First, referring to FIG. 4A, a substrate 300 is provided. Then, a plurality of trenches 301 extending in the first direction Y are formed in the substrate 300. Next, a charge trapping structure 306 is conformally formed on the substrate 300.
然後,請參照圖4B,進行離子植入製程,以於溝渠301底部的基底300中形成沿第一方向Y延伸的第一摻雜區302,以及於溝渠301之間的基底300中形成沿第一方向Y延伸的第二摻雜區304。接著,於溝渠301底部形成沿第一方向Y延伸的第一導體層400。第一導體層400的形成方法例如是先於電荷捕捉結構306上形成導體材料層,並填滿溝渠301。然後,進行蝕刻製程,移除溝渠301之外的導體材料層以及溝渠301中的部分導體材料層,保留位於溝渠301底部的導體材料層。第一導體層400即為圖3A與圖3B中的第一閘極308。而後,於第一導體層400上形成絕緣層402。絕緣層402的形成方法例如是先於電荷捕捉結構306上形成絕緣材料層,並填滿溝渠301。然後,進行蝕刻製程,移除溝渠301之外的絕緣材料層以及溝渠301中的部分絕緣材料層,保留位於第一導體層400上的絕緣材料層。絕緣層402即為圖3A與圖3B中的閘間絕緣層312。Then, referring to FIG. 4B, an ion implantation process is performed to form a first doping region 302 extending in the first direction Y in the substrate 300 at the bottom of the trench 301, and a formation along the substrate 300 between the trenches 301. A second doped region 304 extending in a direction Y. Next, a first conductor layer 400 extending in the first direction Y is formed at the bottom of the trench 301. The first conductor layer 400 is formed by, for example, forming a layer of a conductor material on the charge trapping structure 306 and filling the trench 301. Then, an etching process is performed to remove the conductive material layer outside the trench 301 and a portion of the conductive material layer in the trench 301, leaving the conductive material layer at the bottom of the trench 301. The first conductor layer 400 is the first gate 308 in FIGS. 3A and 3B. Then, an insulating layer 402 is formed on the first conductor layer 400. The insulating layer 402 is formed by, for example, forming a layer of insulating material on the charge trapping structure 306 and filling the trench 301. Then, an etching process is performed to remove the insulating material layer outside the trench 301 and a portion of the insulating material layer in the trench 301, leaving the insulating material layer on the first conductive layer 400. The insulating layer 402 is the inter-gate insulating layer 312 in FIGS. 3A and 3B.
之後,請參照圖4C,在第二方向X上,於電荷捕捉結構306上形成多個條狀的第二導體層404,且第二導體層404填入溝渠301。第二導體層404的形成方法例如是先於電荷捕捉結構306上形成導體材料層,並填滿溝渠301。然後,進行圖案化製程,在第二方向X上,移除溝渠301之外以及溝渠301中的部分導體材料層,以形成條狀的第二導體層404。第二導體層404即為圖3A與圖3B中的第二閘極310。Thereafter, referring to FIG. 4C, in the second direction X, a plurality of strip-shaped second conductor layers 404 are formed on the charge trapping structure 306, and the second conductor layer 404 is filled in the trenches 301. The second conductor layer 404 is formed by, for example, forming a layer of a conductor material on the charge trapping structure 306 and filling the trench 301. Then, a patterning process is performed in which a portion of the conductor material layer outside the trench 301 and in the trench 301 is removed to form a strip-shaped second conductor layer 404. The second conductor layer 404 is the second gate 310 in FIGS. 3A and 3B.
以下將以圖1B中的記憶胞10a為例來說明本發明實施例的記憶胞的操作方法。The operation method of the memory cell of the embodiment of the present invention will be described below by taking the memory cell 10a of FIG. 1B as an example.
圖5A為依照本發明一實施例所繪示的記憶胞之程式化操作示意圖。請參照圖5A,當對記憶胞10a進行程式化操作時,於第一閘極108施加電壓V1 ;於第二閘極110施加電壓V2 ;於第一摻雜區102施加電壓V3 ;於第二摻雜區104施加電壓V4 ;於基底100施加電壓V5 。FIG. 5A is a schematic diagram of a stylized operation of a memory cell according to an embodiment of the invention. Referring to FIG. 5A, when the memory cell 10a is programmed, a voltage V 1 is applied to the first gate 108; a voltage V 2 is applied to the second gate 110; and a voltage V 3 is applied to the first doping region 102; A voltage V 4 is applied to the second doped region 104; a voltage V 5 is applied to the substrate 100.
詳細地說,欲使用通道熱電子注入來對記憶胞10a的右位元R執行程式化操作(即將電子存入第一閘極108下方的電荷捕捉結構106中)時,電壓V1 、V2 為實質上相同的相對高電壓,且例如介於9伏特至13伏特之間,以使第一掺雜區102與第二摻雜區104之間的通道為相對強地開啟(strongly turn-on);電壓V3 例如介於3.5伏特至5.5伏特之間;電壓V4 例如為0伏特;電壓V5 例如為0伏特。因此,電子可以被橫向電場(lateral electric field)加速,以注入第一閘極108下方的電荷捕捉結構106中。同樣地,欲使用通道熱電子注入來對記憶胞10a的左位元L執行程式化操作(即將電子存入第二閘極110下方的電荷捕捉結構106中)時,電壓V1 、V2 為實質上相同的相對高電壓,且例如介於9伏特至13伏特之間,以使第一掺雜區102與第二摻雜區104之間的通道為相對強地開啟;電壓V3 例如為0伏特;電壓V4 例如介於3.5伏特至5.5伏特之間;電壓V5 例如為0伏特。因此,電子可以被橫向電場加速,以注入第二閘極110下方的電荷捕捉結構106中。In detail, when channel hot electron injection is used to perform a programmatic operation on the right bit R of the memory cell 10a (ie, electrons are stored in the charge trapping structure 106 below the first gate 108), the voltages V 1 , V 2 Is substantially the same relatively high voltage, and for example between 9 volts and 13 volts, such that the channel between the first doped region 102 and the second doped region 104 is relatively strongly turned on (strongly turn-on The voltage V 3 is, for example, between 3.5 volts and 5.5 volts; the voltage V 4 is, for example, 0 volts; and the voltage V 5 is, for example, 0 volts. Thus, electrons can be accelerated by a lateral electric field to be injected into the charge trapping structure 106 below the first gate 108. Similarly, when using channel hot electron injection to be left bit L to perform operations on the programmable memory cell 10a (the second gate is about 110 electrons into the charge trapping structure 106 below), the voltage V 1, V 2 is substantially the same relatively high voltage, for example between 9 and 13 volts to V, so that the passage between the second doped region 102 and the first doped region 104 is relatively strongly on; for example, the voltage V 3 0 volts; voltage V 4 is, for example, between 3.5 volts and 5.5 volts; voltage V 5 is, for example, 0 volts. Thus, electrons can be accelerated by the lateral electric field to be injected into the charge trapping structure 106 below the second gate 110.
此外,欲使用增強型通道熱電子注入來對記憶胞10a的右位元R執行程式化操作時,電壓V1 例如介於9伏特至13伏特之間,以使第一閘極108下方的通道為相對強地開啟;電壓V2 例如介於1.5伏特至3伏特之間,以使第二閘極110下方的通道為相對弱地開啟(weakly turn-on);電壓V3 例如介於3.5伏特至5.5伏特之間;電壓V4 例如為0伏特;電壓V5 例如為0伏特。藉由對第一閘極108施加相對高的電壓可以得到較高的垂直電場(vertical electric field),且藉由對第二閘極110施加相對低的電壓可以得到較高的橫向電場,因此可以使程式化操作更有效率。同樣地,欲使用增強型通道熱電子注入來對記憶胞10a的左位元L執行程式化操作時,電壓V1 例如介於1.5伏特至3伏特之間,以使第一閘極108下方的通道為相對弱地開啟;電壓V2 例如介於9伏特至13伏特之間,以使第二閘極110下方的通道為相對強地開啟;電壓V3 例如為0伏特;電壓V4 例如介於3.5伏特至5.5伏特之間;電壓V5 例如為0伏特。藉由對第一閘極108施加相對低的電壓可以得到較高的橫向電場,且藉由對第二閘極110施加相對高的電壓可以得到較高的垂直電場,因此可以使程式化操作更有效率。Further, to be enhanced using channel hot electron injection for the memory cell 10a stylized operation is performed, voltage V 1 is for example between 9 volts to 13 volts right bit R, so that the electrode 108 below the first gate passage To be relatively strong; the voltage V 2 is, for example, between 1.5 volts and 3 volts such that the channel below the second gate 110 is weakly turn-on; the voltage V 3 is, for example, 3.5 volts Between 5.5 volts; voltage V 4 is, for example, 0 volts; voltage V 5 is, for example, 0 volts. A higher vertical electric field can be obtained by applying a relatively high voltage to the first gate 108, and a relatively high voltage can be obtained by applying a relatively low voltage to the second gate 110, so that Make stylized operations more efficient. Similarly, to be enhanced using channel hot electron injection on the left bit memory cell L stylized operation is performed, for example, voltage V 1 is interposed between 10a 1.5 volts to 3 volts, so that under the first gate 108 The channel is relatively weakly open; the voltage V 2 is, for example, between 9 volts and 13 volts such that the channel below the second gate 110 is relatively strongly turned on; the voltage V 3 is, for example, 0 volts; the voltage V 4 is, for example, between 3.5 volts to 5.5 volts; the voltage V 5 is, for example 0 volts. A relatively high electric field can be obtained by applying a relatively low voltage to the first gate 108, and a relatively high voltage can be applied by applying a relatively high voltage to the second gate 110, thereby enabling a more stylized operation. Efficient.
在進行上述的程式化操作之後,還可以進一步地對記憶胞10a中所儲存的資料進行抹除操作。After the above-described stylization operation, the data stored in the memory cell 10a can be further erased.
圖5B為依照本發明一實施例所繪示的記憶胞之抹除操作示意圖。請參照圖5B,當對已程式化的記憶胞10a進行抹除操作時,於第一閘極108施加電壓V6 ;於第二閘極110施加電壓V7 ;於第一摻雜區102施加電壓V8 ;於第二摻雜區104施加電壓V9 ;於基底100施加電壓V10 。FIG. 5B is a schematic diagram of an erase operation of a memory cell according to an embodiment of the invention. Referring to FIG. 5B, when the programmed memory cell 10a is erased, a voltage V 6 is applied to the first gate 108; a voltage V 7 is applied to the second gate 110; and the first doping region 102 is applied. Voltage V 8 ; voltage V 9 is applied to second doped region 104; voltage V 10 is applied to substrate 100.
詳細地說,欲使用能帶對能帶熱電洞來對已程式化的記憶胞10a的右位元R進行抹除操作時,電壓V6 例如介於-11伏特至-15伏特之間;電壓V7 例如為0伏特、浮置或介於-11伏特至-15伏特之間;電壓V8 例如介於4伏特至5伏特之間;電壓V9 例如為0伏特或浮置;電壓V10 例如為0伏特。因此,電洞被注入第一閘極108下方的電荷捕捉結構106中而與電子結合,以將記憶胞10a的右位元R中所儲存的資料抹除。同樣地,欲使用能帶對能帶熱電洞來對已程式化的記憶胞10a的左位元L進行抹除操作時,電壓V6 例如為0伏特、浮置或介於-11伏特至-15伏特之間;電壓V7 例如介於-11伏特至-15伏特之間;電壓V8 例如為0伏特或浮置;電壓V9 例如介於4伏特至5伏特之間;電壓V10 例如為0伏特。因此,電洞被注入第二閘極110下方的電荷捕捉結構106中而與電子結合,以將記憶胞10a的左位元L中所儲存的資料抹除。In detail, when an energy band can be used to erase the right bit R of the programmed memory cell 10a, the voltage V 6 is, for example, between -11 volts and -15 volts; V 7 is, for example, 0 volts, floating or between -11 volts and -15 volts; voltage V 8 is, for example, between 4 volts and 5 volts; voltage V 9 is, for example, 0 volts or floating; voltage V 10 For example, it is 0 volts. Therefore, a hole is injected into the charge trapping structure 106 under the first gate 108 to be combined with electrons to erase the data stored in the right bit R of the memory cell 10a. Similarly, to use a band-to-band thermal hole to erase the left bit L of the programmed memory cell 10a, the voltage V 6 is, for example, 0 volts, floating or between -11 volts to - Between 15 volts; voltage V 7 is, for example, between -11 volts and -15 volts; voltage V 8 is, for example, 0 volts or floating; voltage V 9 is, for example, between 4 volts and 5 volts; voltage V 10 is for example It is 0 volts. Therefore, a hole is injected into the charge trapping structure 106 under the second gate 110 to be combined with electrons to erase the data stored in the left bit L of the memory cell 10a.
在進行上述的程式化操作之後,也可以進一步地對記憶胞10a中所儲存的資料進行讀取操作。After the above-described stylization operation, the data stored in the memory cell 10a can be further read.
圖5C為依照本發明一實施例所繪示的記憶胞之讀取操作示意圖。請參照圖5C,當對已程式化的記憶胞10a進行讀取操作時,於第一閘極108施加電壓V11 ;於第二閘極110施加電壓V12 ;於第一摻雜區102施加電壓V13 ;於第二摻雜區104施加電壓V14 ;於基底100施加電壓V15 。FIG. 5C is a schematic diagram of a read operation of a memory cell according to an embodiment of the invention. Referring to Figure 5C, when the memory cell for read operation has been stylized 10a, a voltage V 11 is applied to the first gate 108; the applied voltage V 12 to the second gate 110; 102 applied to the first doped region Voltage V 13 ; voltage V 14 is applied to second doped region 104; voltage V 15 is applied to substrate 100.
當對記憶胞10a的右位元R進行讀取操作時,電壓V11 例如介於0伏特至6伏特之間;電壓V12 例如介於5伏特至9.5伏特之間;電壓V13 例如為0伏特;電壓V14 例如介於0.7伏特至1.6伏特之間;電壓V15 例如為0伏特。由於在讀取儲存於右位元R中的資料時,左位元L處的第二閘極110被施加了相對高的電壓,因此抑制了第二位元效應,進而增加了操作裕度。此外,在對記憶胞10a的右位元R進行讀取操作時,由於已對位於非讀取側的第二閘極110施加高電壓來抑制第二位元效應,因此不需如同先前技術一般對第二摻雜區104施加高電壓來抑制第二位元效應,因而可以減輕讀取干擾的問題。同樣地,當對記憶胞10a的左位元L進行讀取操作時,電壓V11 例如介於5伏特至9.5伏特之間;電壓V12 例如介於0伏特至6伏特之間;電壓V13 例如介於0.7伏特至1.6伏特之間;電壓V14 例如為0伏特;電壓V15 例如為0伏特。由於在讀取儲存於左位元L中的資料時,右位元R處的第一閘極108被施加了相對高的電壓,因此抑制了第二位元效應,進而增加了操作裕度。此外,在對記憶胞10a的左位元L進行讀取操作時,由於已對位於非讀取側的第一閘極108施加高電壓來抑制第二位元效應,因此不需如同先前技術一般對第一摻雜區102施加高電壓來抑制第二位元效應,因而可以減輕讀取干擾的問題。When a read operation is performed on the right bit R of the memory cell 10a, the voltage V 11 is, for example, between 0 volts and 6 volts; the voltage V 12 is, for example, between 5 volts and 9.5 volts; and the voltage V 13 is, for example, 0. Volt; voltage V 14 is, for example, between 0.7 volts and 1.6 volts; voltage V 15 is, for example, 0 volts. Since the second gate 110 at the left bit L is applied with a relatively high voltage when reading the data stored in the right bit R, the second bit effect is suppressed, thereby increasing the operation margin. Further, when the read operation is performed on the right bit R of the memory cell 10a, since the second bit effect is suppressed by applying a high voltage to the second gate 110 on the non-read side, it is not required to be as in the prior art. Applying a high voltage to the second doping region 104 suppresses the second bit effect, thereby alleviating the problem of read disturb. Similarly, when a read operation is performed on the left bit L of the memory cell 10a, the voltage V 11 is, for example, between 5 volts and 9.5 volts; the voltage V 12 is, for example, between 0 volts and 6 volts; the voltage V 13 For example, between 0.7 volts and 1.6 volts; voltage V 14 is, for example, 0 volts; voltage V 15 is, for example, 0 volts. Since the first gate 108 at the right bit R is applied with a relatively high voltage when reading the data stored in the left bit L, the second bit effect is suppressed, thereby increasing the operation margin. Further, when the read operation is performed on the left bit L of the memory cell 10a, since the high voltage is applied to the first gate 108 on the non-read side to suppress the second bit effect, it is not necessary to be as in the prior art. Applying a high voltage to the first doping region 102 suppresses the second bit effect, thereby alleviating the problem of read disturb.
特別一提的是,上述對記憶胞10a的操作方法同樣可以應用於操作記憶胞30a。本領域技術人員依據上述對記憶胞10a的程式化、抹除、讀取操作應可達成對記憶胞30a的程式化、抹除、讀取操作,因此本說明書於此不另行說明。In particular, the above-described method of operating the memory cell 10a can also be applied to the memory cell 30a. Those skilled in the art can achieve stylized, erased, and read operations on the memory cell 30a in accordance with the above-described stylization, erasing, and reading operations on the memory cell 10a. Therefore, the present specification will not be described herein.
綜上所述,本發明實施例的非揮發性記憶體具有交錯配置的多條第一閘極與多條第二閘極,使得每一個記憶胞具有二個閘極,因此在進行程式化操作時,可藉由對記憶胞的第一閘極與第二閘極施加適當的電壓來進行通道熱電子注入或增強型通道熱電子注入,以增加程式化效率,進而提高元件效能。In summary, the non-volatile memory of the embodiment of the present invention has a plurality of first gates and a plurality of second gates arranged in a staggered manner, so that each memory cell has two gates, and thus is programmed. Channel hot electron injection or enhanced channel hot electron injection can be performed by applying an appropriate voltage to the first gate and the second gate of the memory cell to increase the stylization efficiency and thereby improve the component performance.
此外,在對記憶胞進行讀取操作時,可藉由對位於非讀取側的閘極施加高電壓來抑制第二位元效應,以增加操作裕度。Further, when a read operation is performed on the memory cell, the second bit effect can be suppressed by applying a high voltage to the gate on the non-read side to increase the operation margin.
另外,在對記憶胞進行讀取操作時,由於已對位於非讀取側的閘極施加高電壓來抑制第二位元效應,因此不需如同先前技術一般對位於非讀取側的閘極下方的摻雜區施加高電壓來抑制第二位元效應,使得讀取干擾可以被有效地減輕。In addition, when a read operation is performed on the memory cell, since the second bit effect is suppressed by applying a high voltage to the gate on the non-read side, it is not necessary to have the gate on the non-read side as in the prior art. The lower doped region applies a high voltage to suppress the second bit effect, so that read disturb can be effectively alleviated.
雖然本發明已以實施例揭露如上,然其並非用以限定本發明,任何所屬技術領域中具有通常知識者,在不脫離本發明之精神和範圍內,當可作些許之更動與潤飾,故本發明之保護範圍當視後附之申請專利範圍所界定者為準。Although the present invention has been disclosed in the above embodiments, it is not intended to limit the invention, and any one of ordinary skill in the art can make some modifications and refinements without departing from the spirit and scope of the invention. The scope of the invention is defined by the scope of the appended claims.
10、30...非揮發性記憶體10, 30. . . Non-volatile memory
10a、30a...記憶胞10a, 30a. . . Memory cell
100、300...基底100, 300. . . Base
102、302...第一摻雜區102, 302. . . First doped region
104、304...第二摻雜區104, 304. . . Second doped region
106、306...電荷捕捉結構106, 306. . . Charge trapping structure
108、308...第一閘極108, 308. . . First gate
110、310...第二閘極110, 310. . . Second gate
112、112a、112b、312...閘間絕緣層112, 112a, 112b, 312. . . Inter-gate insulation
200...第一絕緣層200. . . First insulating layer
202...導體間隙壁202. . . Conductor spacer
204、400...第一導體層204, 400. . . First conductor layer
206...第二絕緣層206. . . Second insulating layer
208、404...第二導體層208, 404. . . Second conductor layer
301...溝渠301. . . ditch
402...絕緣層402. . . Insulation
B...方塊B. . . Square
L...左位元L. . . Left bit
R...右位元R. . . Right bit
V1 ~V15 ...電壓V 1 ~ V 15 . . . Voltage
W1...總寬度W1. . . Total width
W2...寬度W2. . . width
X...第二方向X. . . Second direction
Y...第一方向Y. . . First direction
圖1A為依照本發明一實施例所繪示的非揮發性記憶體之上視示意圖。FIG. 1A is a top view of a non-volatile memory according to an embodiment of the invention.
圖1B為沿圖1A中的I-I’剖面所繪示的記憶胞之剖面示意圖。Fig. 1B is a schematic cross-sectional view of the memory cell taken along the line I-I' in Fig. 1A.
圖2A至圖2D為沿圖1A中的I-I’剖面所繪示的非揮發性記憶體之製造流程剖面圖。2A to 2D are cross-sectional views showing the manufacturing process of the non-volatile memory taken along the line I-I' in Fig. 1A.
圖3A為依照本發明另一實施例所繪示的非揮發性記憶體之上視示意圖。FIG. 3A is a top view of a non-volatile memory according to another embodiment of the invention.
圖3B為沿圖3A中的II-II’剖面所繪示的記憶胞之剖面示意圖。Fig. 3B is a schematic cross-sectional view of the memory cell taken along the line II-II' in Fig. 3A.
圖4A至圖4C為沿圖3A中的II-II’剖面所繪示的非揮發性記憶體之製造流程剖面圖。4A to 4C are cross-sectional views showing the manufacturing process of the non-volatile memory taken along the line II-II' in Fig. 3A.
圖5A為依照本發明一實施例所繪示的記憶胞之程式化操作示意圖。FIG. 5A is a schematic diagram of a stylized operation of a memory cell according to an embodiment of the invention.
圖5B為依照本發明一實施例所繪示的記憶胞之抹除操作示意圖。FIG. 5B is a schematic diagram of an erase operation of a memory cell according to an embodiment of the invention.
圖5C為依照本發明一實施例所繪示的記憶胞之讀取操作示意圖。FIG. 5C is a schematic diagram of a read operation of a memory cell according to an embodiment of the invention.
10a...記憶胞10a. . . Memory cell
100...基底100. . . Base
102...第一摻雜區102. . . First doped region
104...第二摻雜區104. . . Second doped region
106...電荷捕捉結構106. . . Charge trapping structure
108...第一閘極108. . . First gate
110...第二閘極110. . . Second gate
112、112a、112b...閘間絕緣層112, 112a, 112b. . . Inter-gate insulation
Claims (27)
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