TWI324177B - Process for the treatment of textile fibre materials - Google Patents

Process for the treatment of textile fibre materials Download PDF

Info

Publication number: TWI324177B
Authority: TW; Taiwan
Prior art keywords: group; peroxide; unsubstituted; alkyl; substituted
Prior art date: 2002-02-25

Application number

TW092103773A

Other languages

English (en)

Chinese (zh)

Other versions

TW200303358A (en

Inventor

Jurgen Kaschig

Robert Hochberg

Oliver Becherer

Georges Metzger

Claude Eckhardt

Original Assignee

Ciba Sc Holding Ag

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2002-02-25

Filing date

2003-02-24

Publication date

2010-05-01

2003-02-24 Application filed by Ciba Sc Holding Ag filed Critical Ciba Sc Holding Ag

2003-09-01 Publication of TW200303358A publication Critical patent/TW200303358A/zh

2010-05-01 Application granted granted Critical

2010-05-01 Publication of TWI324177B publication Critical patent/TWI324177B/zh

Links

238000000034 method Methods 0.000 title claims description 27
239000004753 textile Substances 0.000 title claims description 12
239000000835 fiber Substances 0.000 title description 10
239000000463 material Substances 0.000 title description 6
238000011282 treatment Methods 0.000 title description 5
150000001875 compounds Chemical class 0.000 claims description 68
239000003599 detergent Substances 0.000 claims description 56
125000000217 alkyl group Chemical group 0.000 claims description 46
150000002978 peroxides Chemical class 0.000 claims description 39
-1 tetraethyl fluorenyl ethyl diamine Chemical class 0.000 claims description 37
239000000203 mixture Substances 0.000 claims description 34
238000005406 washing Methods 0.000 claims description 31
102000004190 Enzymes Human genes 0.000 claims description 19
108090000790 Enzymes Proteins 0.000 claims description 19
229940088598 enzyme Drugs 0.000 claims description 19
239000012190 activator Substances 0.000 claims description 18
229910052739 hydrogen Inorganic materials 0.000 claims description 18
239000007844 bleaching agent Substances 0.000 claims description 17
239000001257 hydrogen Substances 0.000 claims description 17
229910052757 nitrogen Inorganic materials 0.000 claims description 14
125000004433 nitrogen atom Chemical group N* 0.000 claims description 14
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 13
239000003054 catalyst Substances 0.000 claims description 13
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 13
108091005804 Peptidases Proteins 0.000 claims description 12
NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 claims description 12
239000004365 Protease Substances 0.000 claims description 11
125000004093 cyano group Chemical group *C#N 0.000 claims description 11
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 10
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 10
108010059892 Cellulase Proteins 0.000 claims description 9
229940106157 cellulase Drugs 0.000 claims description 9
102000013142 Amylases Human genes 0.000 claims description 8
108010065511 Amylases Proteins 0.000 claims description 8
102000004882 Lipase Human genes 0.000 claims description 8
108090001060 Lipase Proteins 0.000 claims description 8
239000004367 Lipase Substances 0.000 claims description 8
102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 8
229910052783 alkali metal Inorganic materials 0.000 claims description 8
235000019418 amylase Nutrition 0.000 claims description 8
235000019421 lipase Nutrition 0.000 claims description 8
RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical group C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 claims description 7
239000002736 nonionic surfactant Substances 0.000 claims description 7
235000019419 proteases Nutrition 0.000 claims description 7
239000004382 Amylase Substances 0.000 claims description 6
150000001340 alkali metals Chemical class 0.000 claims description 6
125000003277 amino group Chemical group 0.000 claims description 6
239000003945 anionic surfactant Substances 0.000 claims description 6
239000002657 fibrous material Substances 0.000 claims description 6
125000002757 morpholinyl group Chemical class 0.000 claims description 6
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
229910052784 alkaline earth metal Inorganic materials 0.000 claims description 4
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 4
230000000694 effects Effects 0.000 claims description 4
125000003983 fluorenyl group Chemical class C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 claims description 4
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
150000001335 aliphatic alkanes Chemical class 0.000 claims description 3
150000001342 alkaline earth metals Chemical class 0.000 claims description 3
150000002431 hydrogen Chemical group 0.000 claims description 2
235000017166 Bambusa arundinacea Nutrition 0.000 claims 2
235000017491 Bambusa tulda Nutrition 0.000 claims 2
241001330002 Bambuseae Species 0.000 claims 2
235000015334 Phyllostachys viridis Nutrition 0.000 claims 2
239000011425 bamboo Substances 0.000 claims 2
WQMWKWHHDJJZLF-UHFFFAOYSA-N 1,2,3,4-tetraethyl-5-(2-phenylethenyl)benzene Chemical group C(C)C=1C(=C(C(=C(C1)C=CC1=CC=CC=C1)CC)CC)CC WQMWKWHHDJJZLF-UHFFFAOYSA-N 0.000 claims 1
125000003118 aryl group Chemical group 0.000 claims 1
125000002704 decyl group Chemical class [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
239000007789 gas Substances 0.000 claims 1
125000003588 lysine group Chemical class [H]N([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])(N([H])[H])C(*)=O 0.000 claims 1
150000002923 oximes Chemical class 0.000 claims 1
238000002360 preparation method Methods 0.000 description 34
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 23
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 12
229910052799 carbon Inorganic materials 0.000 description 12
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 12
239000002253 acid Substances 0.000 description 11
239000000843 powder Substances 0.000 description 11
125000004432 carbon atom Chemical group C* 0.000 description 10
239000011541 reaction mixture Substances 0.000 description 10
239000000243 solution Substances 0.000 description 10
239000007864 aqueous solution Substances 0.000 description 9
229920000742 Cotton Polymers 0.000 description 8
239000004744 fabric Substances 0.000 description 8
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
239000000047 product Substances 0.000 description 7
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 6
150000001412 amines Chemical class 0.000 description 6
239000002585 base Substances 0.000 description 6
239000007788 liquid Substances 0.000 description 6
150000003839 salts Chemical class 0.000 description 6
239000011780 sodium chloride Substances 0.000 description 6
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Natural products C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 5
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 5
229910052708 sodium Inorganic materials 0.000 description 5
239000011734 sodium Substances 0.000 description 5
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 4
REJHVSOVQBJEBF-OWOJBTEDSA-N 5-azaniumyl-2-[(e)-2-(4-azaniumyl-2-sulfonatophenyl)ethenyl]benzenesulfonate Chemical compound OS(=O)(=O)C1=CC(N)=CC=C1\C=C\C1=CC=C(N)C=C1S(O)(=O)=O REJHVSOVQBJEBF-OWOJBTEDSA-N 0.000 description 4
REJHVSOVQBJEBF-UHFFFAOYSA-N DSD-acid Natural products OS(=O)(=O)C1=CC(N)=CC=C1C=CC1=CC=C(N)C=C1S(O)(=O)=O REJHVSOVQBJEBF-UHFFFAOYSA-N 0.000 description 4
QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 4
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
102000035195 Peptidases Human genes 0.000 description 4
239000001768 carboxy methyl cellulose Substances 0.000 description 4
229920002678 cellulose Polymers 0.000 description 4
239000001913 cellulose Substances 0.000 description 4
239000003795 chemical substances by application Substances 0.000 description 4
125000000753 cycloalkyl group Chemical group 0.000 description 4
229910052751 metal Inorganic materials 0.000 description 4
239000002184 metal Substances 0.000 description 4
229920000642 polymer Polymers 0.000 description 4
239000002244 precipitate Substances 0.000 description 4
229910052938 sodium sulfate Inorganic materials 0.000 description 4
235000011152 sodium sulphate Nutrition 0.000 description 4
125000001424 substituent group Chemical group 0.000 description 4
210000002268 wool Anatomy 0.000 description 4
239000010457 zeolite Substances 0.000 description 4
125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 3
CNGYZEMWVAWWOB-VAWYXSNFSA-N 5-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-[(e)-2-[4-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound N=1C(NC=2C=C(C(\C=C\C=3C(=CC(NC=4N=C(N=C(NC=5C=CC=CC=5)N=4)N(CCO)CCO)=CC=3)S(O)(=O)=O)=CC=2)S(O)(=O)=O)=NC(N(CCO)CCO)=NC=1NC1=CC=CC=C1 CNGYZEMWVAWWOB-VAWYXSNFSA-N 0.000 description 3
229920002134 Carboxymethyl cellulose Polymers 0.000 description 3
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
229910021536 Zeolite Inorganic materials 0.000 description 3
150000001298 alcohols Chemical class 0.000 description 3
238000004061 bleaching Methods 0.000 description 3
235000010948 carboxy methyl cellulose Nutrition 0.000 description 3
239000008112 carboxymethyl-cellulose Substances 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 3
125000004122 cyclic group Chemical class 0.000 description 3
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
239000006081 fluorescent whitening agent Substances 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
229920005646 polycarboxylate Polymers 0.000 description 3
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
235000017550 sodium carbonate Nutrition 0.000 description 3
229910000029 sodium carbonate Inorganic materials 0.000 description 3
239000007787 solid Substances 0.000 description 3
239000004094 surface-active agent Substances 0.000 description 3
229920002994 synthetic fiber Polymers 0.000 description 3
MIJDSYMOBYNHOT-UHFFFAOYSA-N 2-(ethylamino)ethanol Chemical compound CCNCCO MIJDSYMOBYNHOT-UHFFFAOYSA-N 0.000 description 2
XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical compound CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
108010084185 Cellulases Proteins 0.000 description 2
102000005575 Cellulases Human genes 0.000 description 2
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
239000004952 Polyamide Substances 0.000 description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
DZBUGLKDJFMEHC-UHFFFAOYSA-N acridine Chemical compound C1=CC=CC2=CC3=CC=CC=C3N=C21 DZBUGLKDJFMEHC-UHFFFAOYSA-N 0.000 description 2
125000003342 alkenyl group Chemical group 0.000 description 2
125000003545 alkoxy group Chemical group 0.000 description 2
150000008051 alkyl sulfates Chemical class 0.000 description 2
229940025131 amylases Drugs 0.000 description 2
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
150000007942 carboxylates Chemical class 0.000 description 2
150000001768 cations Chemical class 0.000 description 2
229910052801 chlorine Inorganic materials 0.000 description 2
239000000460 chlorine Substances 0.000 description 2
238000001816 cooling Methods 0.000 description 2
125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 2
235000014113 dietary fatty acids Nutrition 0.000 description 2
239000007884 disintegrant Substances 0.000 description 2
SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 2
239000000975 dye Substances 0.000 description 2
239000000194 fatty acid Substances 0.000 description 2
229930195729 fatty acid Natural products 0.000 description 2
238000009472 formulation Methods 0.000 description 2
235000011187 glycerol Nutrition 0.000 description 2
WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
239000003446 ligand Substances 0.000 description 2
238000011068 loading method Methods 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
239000002304 perfume Substances 0.000 description 2
UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 2
229920002647 polyamide Polymers 0.000 description 2
229920005862 polyol Polymers 0.000 description 2
150000003077 polyols Chemical class 0.000 description 2
229910052700 potassium Inorganic materials 0.000 description 2
239000011591 potassium Substances 0.000 description 2
150000003138 primary alcohols Chemical class 0.000 description 2
229910052707 ruthenium Inorganic materials 0.000 description 2
150000003333 secondary alcohols Chemical class 0.000 description 2
239000000344 soap Substances 0.000 description 2
239000001509 sodium citrate Substances 0.000 description 2
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 2
159000000000 sodium salts Chemical class 0.000 description 2
235000019832 sodium triphosphate Nutrition 0.000 description 2
HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 2
239000000725 suspension Substances 0.000 description 2
239000012209 synthetic fiber Substances 0.000 description 2
239000008399 tap water Substances 0.000 description 2
235000020679 tap water Nutrition 0.000 description 2
125000003396 thiol group Chemical group [H]S* 0.000 description 2
URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 2
DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
JTXMVXSTHSMVQF-UHFFFAOYSA-N 2-acetyloxyethyl acetate Chemical compound CC(=O)OCCOC(C)=O JTXMVXSTHSMVQF-UHFFFAOYSA-N 0.000 description 1
MSWZFWKMSRAUBD-IVMDWMLBSA-N 2-amino-2-deoxy-D-glucopyranose Chemical compound N[C@H]1C(O)O[C@H](CO)[C@@H](O)[C@@H]1O MSWZFWKMSRAUBD-IVMDWMLBSA-N 0.000 description 1
MWEVGBCZECVCRP-UHFFFAOYSA-N 2-decoxybenzenesulfonic acid Chemical compound CCCCCCCCCCOC1=CC=CC=C1S(O)(=O)=O MWEVGBCZECVCRP-UHFFFAOYSA-N 0.000 description 1
RFONJRMUUALMBA-UHFFFAOYSA-N 2-methanidylpropane Chemical compound CC(C)[CH2-] RFONJRMUUALMBA-UHFFFAOYSA-N 0.000 description 1
125000004200 2-methoxyethyl group Chemical group [H]C([H])([H])OC([H])([H])C([H])([H])* 0.000 description 1
YNJSNEKCXVFDKW-UHFFFAOYSA-N 3-(5-amino-1h-indol-3-yl)-2-azaniumylpropanoate Chemical compound C1=C(N)C=C2C(CC(N)C(O)=O)=CNC2=C1 YNJSNEKCXVFDKW-UHFFFAOYSA-N 0.000 description 1
QOXOZONBQWIKDA-UHFFFAOYSA-N 3-hydroxypropyl Chemical compound [CH2]CCO QOXOZONBQWIKDA-UHFFFAOYSA-N 0.000 description 1
MHKLKWCYGIBEQF-UHFFFAOYSA-N 4-(1,3-benzothiazol-2-ylsulfanyl)morpholine Chemical compound C1COCCN1SC1=NC2=CC=CC=C2S1 MHKLKWCYGIBEQF-UHFFFAOYSA-N 0.000 description 1
KVCQTKNUUQOELD-UHFFFAOYSA-N 4-amino-n-[1-(3-chloro-2-fluoroanilino)-6-methylisoquinolin-5-yl]thieno[3,2-d]pyrimidine-7-carboxamide Chemical compound N=1C=CC2=C(NC(=O)C=3C4=NC=NC(N)=C4SC=3)C(C)=CC=C2C=1NC1=CC=CC(Cl)=C1F KVCQTKNUUQOELD-UHFFFAOYSA-N 0.000 description 1
HOSGXJWQVBHGLT-UHFFFAOYSA-N 6-hydroxy-3,4-dihydro-1h-quinolin-2-one Chemical group N1C(=O)CCC2=CC(O)=CC=C21 HOSGXJWQVBHGLT-UHFFFAOYSA-N 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
SPWUCLZUSSSIDU-UHFFFAOYSA-N C(C)OC(=O)C1OC(C=C1)C(=O)OCC Chemical compound C(C)OC(=O)C1OC(C=C1)C(=O)OCC SPWUCLZUSSSIDU-UHFFFAOYSA-N 0.000 description 1
LRNPMFJRWPCSRD-IWQYDBTJSA-N C(C)[C@]1([C@](C(O)(O[C@@H]([C@H]1O)CO)CC)(N(CC)CC)CC)O Chemical compound C(C)[C@]1([C@](C(O)(O[C@@H]([C@H]1O)CO)CC)(N(CC)CC)CC)O LRNPMFJRWPCSRD-IWQYDBTJSA-N 0.000 description 1
244000025254 Cannabis sativa Species 0.000 description 1
241000283707 Capra Species 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical class OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
PHOQVHQSTUBQQK-SQOUGZDYSA-N D-glucono-1,5-lactone Chemical compound OC[C@H]1OC(=O)[C@H](O)[C@@H](O)[C@@H]1O PHOQVHQSTUBQQK-SQOUGZDYSA-N 0.000 description 1
MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 description 1
DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 1
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
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230000007062 hydrolysis Effects 0.000 description 1
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PEYVWSJAZONVQK-UHFFFAOYSA-N hydroperoxy(oxo)borane Chemical compound OOB=O PEYVWSJAZONVQK-UHFFFAOYSA-N 0.000 description 1
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210000004080 milk Anatomy 0.000 description 1
210000000050 mohair Anatomy 0.000 description 1
DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
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MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
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235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
PSBAZVJEUNOIDU-UHFFFAOYSA-L potassium;sodium;diacetate Chemical compound [Na+].[K+].CC([O-])=O.CC([O-])=O PSBAZVJEUNOIDU-UHFFFAOYSA-L 0.000 description 1
239000002243 precursor Substances 0.000 description 1
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
235000013772 propylene glycol Nutrition 0.000 description 1
102000004169 proteins and genes Human genes 0.000 description 1
108090000623 proteins and genes Proteins 0.000 description 1
125000004076 pyridyl group Chemical group 0.000 description 1
125000000719 pyrrolidinyl group Chemical group 0.000 description 1
229940071089 sarcosinate Drugs 0.000 description 1
239000010865 sewage Substances 0.000 description 1
229910021647 smectite Inorganic materials 0.000 description 1
235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
UYLYBEXRJGPQSH-UHFFFAOYSA-N sodium;oxido(dioxo)niobium Chemical compound [Na+].[O-][Nb](=O)=O UYLYBEXRJGPQSH-UHFFFAOYSA-N 0.000 description 1
239000002689 soil Substances 0.000 description 1
239000013042 solid detergent Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
239000008107 starch Substances 0.000 description 1
235000019698 starch Nutrition 0.000 description 1
PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
235000021286 stilbenes Nutrition 0.000 description 1
238000003756 stirring Methods 0.000 description 1
FNWBQFMGIFLWII-UHFFFAOYSA-N strontium aluminate Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Al+3].[Sr+2].[Sr+2] FNWBQFMGIFLWII-UHFFFAOYSA-N 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000005720 sucrose Substances 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
239000000375 suspending agent Substances 0.000 description 1
230000008961 swelling Effects 0.000 description 1
239000003760 tallow Substances 0.000 description 1
DKVBOUDTNWVDEP-NJCHZNEYSA-N teicoplanin aglycone Chemical group N([C@H](C(N[C@@H](C1=CC(O)=CC(O)=C1C=1C(O)=CC=C2C=1)C(O)=O)=O)[C@H](O)C1=CC=C(C(=C1)Cl)OC=1C=C3C=C(C=1O)OC1=CC=C(C=C1Cl)C[C@H](C(=O)N1)NC([C@H](N)C=4C=C(O5)C(O)=CC=4)=O)C(=O)[C@@H]2NC(=O)[C@@H]3NC(=O)[C@@H]1C1=CC5=CC(O)=C1 DKVBOUDTNWVDEP-NJCHZNEYSA-N 0.000 description 1
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UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
235000013311 vegetables Nutrition 0.000 description 1
230000002087 whitening effect Effects 0.000 description 1
125000002256 xylenyl group Chemical group C1(C(C=CC=C1)C)(C)* 0.000 description 1
238000004383 yellowing Methods 0.000 description 1
229910052727 yttrium Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Detergent Compositions (AREA)
Cleaning By Liquid Or Steam (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

TW092103773A 2002-02-25 2003-02-24 Process for the treatment of textile fibre materials TWI324177B (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
EP02405136		2002-02-25
EP02405876		2002-10-11

Publications (2)

Publication Number	Publication Date
TW200303358A TW200303358A (en)	2003-09-01
TWI324177B true TWI324177B (en)	2010-05-01

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ID=27758773

Family Applications (2)

Application Number	Title	Priority Date	Filing Date
TW092103773A TWI324177B (en)	2002-02-25	2003-02-24	Process for the treatment of textile fibre materials
TW092103771A TWI332045B (en)	2002-02-25	2003-02-24	Process for the treatment of textile fibre materials

Family Applications After (1)

Application Number	Title	Priority Date	Filing Date
TW092103771A TWI332045B (en)	2002-02-25	2003-02-24	Process for the treatment of textile fibre materials

Country Status (12)

Country	Link
EP (4)	EP1485460B1 (es)
JP (2)	JP4567975B2 (es)
CN (2)	CN1294247C (es)
AR (3)	AR038582A1 (es)
AT (2)	ATE340242T1 (es)
AU (2)	AU2003208870B2 (es)
BR (3)	BR0306187A (es)
DE (2)	DE60308661T2 (es)
ES (3)	ES2556971T3 (es)
TW (2)	TWI324177B (es)
WO (2)	WO2003070869A1 (es)
ZA (2)	ZA200402941B (es)

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JP4567975B2 (ja) *	2002-02-25	2010-10-27	チバホールディングインコーポレーテッド	繊維材料の処理の方法
US7863236B2 (en) *	2003-03-24	2011-01-04	Ciba Specialty Chemicals Corp.	Detergent compositions
WO2005068597A1 (en) *	2004-01-20	2005-07-28	Ciba Specialty Chemicals Holding Inc.	Triazinylaminostilbene disulphonic acid mixtures
KR20070011437A (ko) *	2004-04-20	2007-01-24	시바 스폐셜티 케미칼스 홀딩 인코포레이티드	세제 배합물 중 양쪽성 형광 증백제
KR101253657B1 (ko) *	2004-08-30	2013-04-10	시바 홀딩 인코포레이티드	셰이딩 방법
EP2024480B1 (en) *	2006-05-23	2010-09-29	Basf Se	A detergent composition for textile fibre materials
CN104801511B (zh) *	2014-01-26	2018-09-18	艺康美国股份有限公司	原位清洗工艺和原位清洗系统
CA2966664C (en)	2014-01-31	2018-11-27	Goldcorp Inc.	Process for separation of at least one metal sulfide from a mixed sulfide ore or concentrate
CN105001671A (zh) *	2015-06-29	2015-10-28	纳爱斯丽水日化有限公司	一种复合型增白剂及含所述增白剂的洗涤剂组合物
CN107857738A (zh) *	2017-11-28	2018-03-30	贺州学院	十六烷基氨基三嗪衍生物的合成与应用

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JPS515308A (ja) *	1974-07-03	1976-01-17	Kao Corp	Hakushokugoseisenzaisoseibutsu
EP0003568B1 (de) *	1978-02-14	1982-06-02	Bayer Ag	Zubereitung optischer Aufheller zum Weisstönen von Papierstreichmassen
US4364845A (en) *	1978-07-17	1982-12-21	Ciba-Geigy Corporation	Concentrated aqueous solutions of sulfo group-containing fluorescent brighteners which are stable on storage
JPS5817199A (ja) *	1981-07-23	1983-02-01	花王株式会社	洗浄剤組成物
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Publication number	Publication date
BR0306184B1 (pt)	2013-08-27
ES2271529T3 (es)	2007-04-16
BRPI0306187B1 (pt)	2021-01-12
AU2003205777B2 (en)	2008-01-31
BR0306187A (pt)	2004-10-19
EP1478724B1 (en)	2006-09-20
BR0306184A (pt)	2004-10-19
EP1715029A3 (en)	2009-04-01
CN1294247C (zh)	2007-01-10
EP1715029A2 (en)	2006-10-25
TW200303386A (en)	2003-09-01
CN1596299A (zh)	2005-03-16
DE60308485D1 (de)	2006-11-02
AR038583A1 (es)	2005-01-19
AR038582A1 (es)	2005-01-19
TWI332045B (en)	2010-10-21
TW200303358A (en)	2003-09-01
ES2271534T3 (es)	2007-04-16
JP2005517801A (ja)	2005-06-16
ATE340242T1 (de)	2006-10-15
ZA200402941B (en)	2005-02-23
JP4567976B2 (ja)	2010-10-27
DE60308661D1 (de)	2006-11-09
ES2556971T3 (es)	2016-01-21
AU2003208870A1 (en)	2003-09-09
EP1485460B1 (en)	2006-09-27
JP4567975B2 (ja)	2010-10-27
EP1724333A1 (en)	2006-11-22
JP2005517800A (ja)	2005-06-16
AR067835A2 (es)	2009-10-28
DE60308661T2 (de)	2007-08-09
WO2003070869A1 (en)	2003-08-28
AU2003208870B2 (en)	2008-05-15
ZA200402942B (en)	2005-02-23
CN1294248C (zh)	2007-01-10
AU2003205777A1 (en)	2003-09-09
WO2003070870A1 (en)	2003-08-28
EP1715029B1 (en)	2015-09-23
EP1485460A1 (en)	2004-12-15
DE60308485T2 (de)	2007-09-06
EP1478724A1 (en)	2004-11-24
ATE340847T1 (de)	2006-10-15
CN1596300A (zh)	2005-03-16

Publication	Publication Date	Title
US7863236B2 (en)	2011-01-04	Detergent compositions
TWI324177B (en)	2010-05-01	Process for the treatment of textile fibre materials
US8080510B2 (en)	2011-12-20	Detergent composition for textile fibre materials
AU2004210104C1 (en)	2009-11-26	Crystalline modifications of triazinylaminostilbenes
BRPI0712671B1 (pt)	2017-08-08	Detergent composition for textile fiber materials, process for the treatment of domestic washing of textile fiber material, and process for the fluorescent blanking of textile materials

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2016-02-01	MM4A	Annulment or lapse of patent due to non-payment of fees