TW201815909A - 低光澤之聚醯亞胺膜及其製造方法 - Google Patents
低光澤之聚醯亞胺膜及其製造方法 Download PDFInfo
- Publication number
- TW201815909A TW201815909A TW105133667A TW105133667A TW201815909A TW 201815909 A TW201815909 A TW 201815909A TW 105133667 A TW105133667 A TW 105133667A TW 105133667 A TW105133667 A TW 105133667A TW 201815909 A TW201815909 A TW 201815909A
- Authority
- TW
- Taiwan
- Prior art keywords
- polyimide
- black
- gloss
- polyimide film
- low
- Prior art date
Links
- 229920001721 polyimide Polymers 0.000 title claims abstract description 75
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 16
- 239000004642 Polyimide Substances 0.000 claims abstract description 31
- 238000000034 method Methods 0.000 claims abstract description 24
- 239000002904 solvent Substances 0.000 claims abstract description 17
- 239000000178 monomer Substances 0.000 claims abstract description 14
- GTDPSWPPOUPBNX-UHFFFAOYSA-N ac1mqpva Chemical compound CC12C(=O)OC(=O)C1(C)C1(C)C2(C)C(=O)OC1=O GTDPSWPPOUPBNX-UHFFFAOYSA-N 0.000 claims abstract description 10
- 150000004985 diamines Chemical class 0.000 claims abstract description 9
- 239000002253 acid Substances 0.000 claims abstract description 4
- 238000004049 embossing Methods 0.000 claims description 25
- 239000002243 precursor Substances 0.000 claims description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- 239000006224 matting agent Substances 0.000 claims description 9
- 229920002098 polyfluorene Polymers 0.000 claims description 7
- 150000003949 imides Chemical class 0.000 claims description 6
- HLBLWEWZXPIGSM-UHFFFAOYSA-N 4-Aminophenyl ether Chemical compound C1=CC(N)=CC=C1OC1=CC=C(N)C=C1 HLBLWEWZXPIGSM-UHFFFAOYSA-N 0.000 claims description 5
- NVKGJHAQGWCWDI-UHFFFAOYSA-N 4-[4-amino-2-(trifluoromethyl)phenyl]-3-(trifluoromethyl)aniline Chemical compound FC(F)(F)C1=CC(N)=CC=C1C1=CC=C(N)C=C1C(F)(F)F NVKGJHAQGWCWDI-UHFFFAOYSA-N 0.000 claims description 4
- VLDPXPPHXDGHEW-UHFFFAOYSA-N 1-chloro-2-dichlorophosphoryloxybenzene Chemical compound ClC1=CC=CC=C1OP(Cl)(Cl)=O VLDPXPPHXDGHEW-UHFFFAOYSA-N 0.000 claims description 3
- FWLHAQYOFMQTHQ-UHFFFAOYSA-N 2-N-[8-[[8-(4-aminoanilino)-10-phenylphenazin-10-ium-2-yl]amino]-10-phenylphenazin-10-ium-2-yl]-8-N,10-diphenylphenazin-10-ium-2,8-diamine hydroxy-oxido-dioxochromium Chemical compound O[Cr]([O-])(=O)=O.O[Cr]([O-])(=O)=O.O[Cr]([O-])(=O)=O.Nc1ccc(Nc2ccc3nc4ccc(Nc5ccc6nc7ccc(Nc8ccc9nc%10ccc(Nc%11ccccc%11)cc%10[n+](-c%10ccccc%10)c9c8)cc7[n+](-c7ccccc7)c6c5)cc4[n+](-c4ccccc4)c3c2)cc1 FWLHAQYOFMQTHQ-UHFFFAOYSA-N 0.000 claims description 3
- MQAHXEQUBNDFGI-UHFFFAOYSA-N 5-[4-[2-[4-[(1,3-dioxo-2-benzofuran-5-yl)oxy]phenyl]propan-2-yl]phenoxy]-2-benzofuran-1,3-dione Chemical compound C1=C2C(=O)OC(=O)C2=CC(OC2=CC=C(C=C2)C(C)(C=2C=CC(OC=3C=C4C(=O)OC(=O)C4=CC=3)=CC=2)C)=C1 MQAHXEQUBNDFGI-UHFFFAOYSA-N 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 239000006230 acetylene black Substances 0.000 claims description 3
- 210000000988 bone and bone Anatomy 0.000 claims description 3
- WKDNYTOXBCRNPV-UHFFFAOYSA-N bpda Chemical compound C1=C2C(=O)OC(=O)C2=CC(C=2C=C3C(=O)OC(C3=CC=2)=O)=C1 WKDNYTOXBCRNPV-UHFFFAOYSA-N 0.000 claims description 3
- 239000006229 carbon black Substances 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- UCNNJGDEJXIUCC-UHFFFAOYSA-L hydroxy(oxo)iron;iron Chemical compound [Fe].O[Fe]=O.O[Fe]=O UCNNJGDEJXIUCC-UHFFFAOYSA-L 0.000 claims description 3
- 150000002466 imines Chemical class 0.000 claims description 3
- 239000006233 lamp black Substances 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 229920000767 polyaniline Polymers 0.000 claims description 3
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 claims 4
- 239000004952 Polyamide Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 229920002647 polyamide Polymers 0.000 abstract 1
- -1 3-aminophenoxy Chemical group 0.000 description 6
- 238000010586 diagram Methods 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- QGKMIGUHVLGJBR-UHFFFAOYSA-M (4z)-1-(3-methylbutyl)-4-[[1-(3-methylbutyl)quinolin-1-ium-4-yl]methylidene]quinoline;iodide Chemical compound [I-].C12=CC=CC=C2N(CCC(C)C)C=CC1=CC1=CC=[N+](CCC(C)C)C2=CC=CC=C12 QGKMIGUHVLGJBR-UHFFFAOYSA-M 0.000 description 2
- UMGYJGHIMRFYSP-UHFFFAOYSA-N 2-(4-aminophenyl)-1,3-benzoxazol-5-amine Chemical compound C1=CC(N)=CC=C1C1=NC2=CC(N)=CC=C2O1 UMGYJGHIMRFYSP-UHFFFAOYSA-N 0.000 description 2
- QYIMZXITLDTULQ-UHFFFAOYSA-N 4-(4-amino-2-methylphenyl)-3-methylaniline Chemical group CC1=CC(N)=CC=C1C1=CC=C(N)C=C1C QYIMZXITLDTULQ-UHFFFAOYSA-N 0.000 description 2
- WUPRYUDHUFLKFL-UHFFFAOYSA-N 4-[3-(4-aminophenoxy)phenoxy]aniline Chemical compound C1=CC(N)=CC=C1OC1=CC=CC(OC=2C=CC(N)=CC=2)=C1 WUPRYUDHUFLKFL-UHFFFAOYSA-N 0.000 description 2
- JCRRFJIVUPSNTA-UHFFFAOYSA-N 4-[4-(4-aminophenoxy)phenoxy]aniline Chemical compound C1=CC(N)=CC=C1OC(C=C1)=CC=C1OC1=CC=C(N)C=C1 JCRRFJIVUPSNTA-UHFFFAOYSA-N 0.000 description 2
- VQVIHDPBMFABCQ-UHFFFAOYSA-N 5-(1,3-dioxo-2-benzofuran-5-carbonyl)-2-benzofuran-1,3-dione Chemical compound C1=C2C(=O)OC(=O)C2=CC(C(C=2C=C3C(=O)OC(=O)C3=CC=2)=O)=C1 VQVIHDPBMFABCQ-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 229920005575 poly(amic acid) Polymers 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- ZUTDUGMNROUBOX-UHFFFAOYSA-N 1,2,3,4,5-pentachloro-6-(3,5-dichlorophenyl)benzene Chemical compound ClC1=CC(Cl)=CC(C=2C(=C(Cl)C(Cl)=C(Cl)C=2Cl)Cl)=C1 ZUTDUGMNROUBOX-UHFFFAOYSA-N 0.000 description 1
- IBKFNGCWUPNUHY-UHFFFAOYSA-N 2-(4-aminophenyl)-1,3-benzoxazol-6-amine Chemical compound C1=CC(N)=CC=C1C1=NC2=CC=C(N)C=C2O1 IBKFNGCWUPNUHY-UHFFFAOYSA-N 0.000 description 1
- DKKYOQYISDAQER-UHFFFAOYSA-N 3-[3-(3-aminophenoxy)phenoxy]aniline Chemical compound NC1=CC=CC(OC=2C=C(OC=3C=C(N)C=CC=3)C=CC=2)=C1 DKKYOQYISDAQER-UHFFFAOYSA-N 0.000 description 1
- XUSNPFGLKGCWGN-UHFFFAOYSA-N 3-[4-(3-aminopropyl)piperazin-1-yl]propan-1-amine Chemical compound NCCCN1CCN(CCCN)CC1 XUSNPFGLKGCWGN-UHFFFAOYSA-N 0.000 description 1
- KHYXYOGWAIYVBD-UHFFFAOYSA-N 4-(4-propylphenoxy)aniline Chemical compound C1=CC(CCC)=CC=C1OC1=CC=C(N)C=C1 KHYXYOGWAIYVBD-UHFFFAOYSA-N 0.000 description 1
- KZSXRDLXTFEHJM-UHFFFAOYSA-N 5-(trifluoromethyl)benzene-1,3-diamine Chemical compound NC1=CC(N)=CC(C(F)(F)F)=C1 KZSXRDLXTFEHJM-UHFFFAOYSA-N 0.000 description 1
- QHHKLPCQTTWFSS-UHFFFAOYSA-N 5-[2-(1,3-dioxo-2-benzofuran-5-yl)-1,1,1,3,3,3-hexafluoropropan-2-yl]-2-benzofuran-1,3-dione Chemical compound C1=C2C(=O)OC(=O)C2=CC(C(C=2C=C3C(=O)OC(=O)C3=CC=2)(C(F)(F)F)C(F)(F)F)=C1 QHHKLPCQTTWFSS-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 206010052143 Ocular discomfort Diseases 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- AQLMHYSWFMLWBS-UHFFFAOYSA-N arsenite(1-) Chemical compound O[As](O)[O-] AQLMHYSWFMLWBS-UHFFFAOYSA-N 0.000 description 1
- 208000003464 asthenopia Diseases 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Natural products C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- ANSXAPJVJOKRDJ-UHFFFAOYSA-N furo[3,4-f][2]benzofuran-1,3,5,7-tetrone Chemical compound C1=C2C(=O)OC(=O)C2=CC2=C1C(=O)OC2=O ANSXAPJVJOKRDJ-UHFFFAOYSA-N 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000011146 organic particle Substances 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C59/00—Surface shaping of articles, e.g. embossing; Apparatus therefor
- B29C59/02—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
- B29C59/04—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing using rollers or endless belts
- B29C59/046—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing using rollers or endless belts for layered or coated substantially flat surfaces
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
- C08L79/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
- C08L79/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2079/00—Use of polymers having nitrogen, with or without oxygen or carbon only, in the main chain, not provided for in groups B29K2061/00 - B29K2077/00, as moulding material
- B29K2079/08—PI, i.e. polyimides or derivatives thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/0005—Condition, form or state of moulded material or of the material to be shaped containing compounding ingredients
- B29K2105/0032—Pigments, colouring agents or opacifiyng agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0018—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2379/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups C08J2361/00 - C08J2377/00
- C08J2379/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
- C08J2379/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2479/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups C08J2461/00 - C08J2477/00
- C08J2479/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
- C08J2479/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Thermal Sciences (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Shaping Of Tube Ends By Bending Or Straightening (AREA)
Abstract
本發明係提供一種低光澤之聚醯亞胺膜及其製造方法，其包括有提供一二胺單體與二酐單體進行聚合之聚醯胺酸及溶劑，以形成一聚醯亞胺前驅體溶液；將該聚醯亞胺前驅體溶液形成於一載體上，以形成一聚醯亞胺濕膜；將該聚醯亞胺濕膜在100℃以上，壓力1kg以上之壓花滾輪上輾壓，使其表面形成有規則之凹凸形狀；及將該聚醯亞胺濕膜進行高溫烘烤，以形成一聚醯亞胺膜。該聚醯亞胺膜包括於其表面形成規則之凹凸形狀；及一消光劑，其係添加於該聚醯亞胺膜內，使該聚醯亞胺膜具有小於60度之光澤值。
Description
本發明係關於一種低光澤之聚醯亞胺膜之製造方法，特別係指一種以壓花滾輪輾壓方式於聚醯亞胺濕膜上形成凹凸表面，再行加熱乾燥後成為低光澤之聚醯亞胺膜者。
可撓性銅箔積層板(Flexible copper clad laminate,FCCL)係廣泛應用於電子產業中作為電路基板(PCB)，FCCL除了具有輕、薄及可撓的優點外，用聚醯亞胺膜還具有電性能及熱性能優良的特點外，其較低的介電常數(Dk)性，使得電信號得到快速的傳遞，良好的熱性能，可使組件易於降溫，較高的玻璃化溫度(Tg)，可使組件在較高的溫度下良好運行。
然而，聚醯亞胺膜通常具有高表面平坦度，使得大多數的入射光線被反射而產生高光澤度。又，高光澤度的膜面可能會造成視覺上不舒適或長時間觀看時容易使得眼睛疲勞。尤其，具有顏色的高光澤度聚醯亞胺膜，例如：黑色、白色、藍色、紅色等聚醯亞胺薄膜，照射於其表面所產生的大量反射光在視覺上更為顯著。另外，低透光性及低光澤度PI膜常用於軟性電路板(flexible printed circuit boards)的基材及覆蓋層(coverlay)等，低透光性係用以遮蓋電路板上的電路設計，防止電路板上的線路被抄襲，此等軟性電路板廣泛應用於3C產品、光學鏡頭模組、LCD模組等。低 光澤度可使元件外觀更具有質感與美觀。
一種降低聚醯亞胺膜光澤度之方法，係添加聚醯亞胺有機粒子作為消光劑，有增加材料成本的問題之外，添加大量消光劑又會導致聚醯亞胺膜材本身性質易脆裂，為了減少成本、又不會降低聚醯亞胺膜材本身的機械強度實為業界思考的問題。
本發明係提供一種低光澤度之聚醯亞胺膜製造方法，其包括有提供一二胺單體與二酐單體進行聚合之聚醯胺酸及溶劑，以形成一聚醯亞胺前驅體溶液；將該聚醯亞胺前驅體溶液塗佈於一載體上，以形成一聚醯亞胺濕膜；將該聚醯亞胺濕膜在100℃以上，壓力1kg以上之壓花滾輪上輾壓，使其表面形成有凹凸形狀；及將該聚醯亞胺濕膜進行高溫烘烤，以形成一聚醯亞胺膜。該聚醯亞胺膜包括於表面形成有規則之凹凸形狀；及一消光劑，其係添加於該聚醯亞胺膜內，使該聚醯亞胺膜具有小於60度之光澤值。
10‧‧‧載體
12‧‧‧聚醯亞胺濕膜
14‧‧‧壓花滾輪
16‧‧‧凹凸形狀
18‧‧‧圖騰
20‧‧‧聚醯亞胺膜
第1圖係本發明低光擇之聚醯亞胺膜製造方法之步驟圖。
第2圖係本發明可離型之軟性基板製造方法的第一示意圖。
第3圖係本發明可離型之軟性基板製造方法的第二示意圖。
第4圖係本發明可離型之軟性基板製造方法的第三示意圖。
請參閱第1，本發明低光澤之聚醯亞胺膜製造方法，其包括有下列步驟。
提供一二胺單體與二酐單體進行聚合之聚醯胺酸及溶劑溶液(S1)，該溶劑含量為20-50%，於實施例中，該二胺單體可為4,4'-二胺基二苯醚(4,4'-oxydianiline(4,4'-ODA))、對苯二胺(phenylenediamine(p-PDA))、2,2’-雙(三氟甲基)聯苯胺(2,2'-Bis(trifluoromethyl)benzidine(TFMB))、1,3-雙(4'-胺基苯氧基)苯(1,3-bis(4-aminophenoxy)benzene(TPER))、1,4-雙(4-胺基苯氧基)苯(1,4-bis(4-aminophenoxy)benzene(TPEQ))、4,4’-二胺基-2,2’-二甲基-1,1’-聯苯(2,2'-dimethyl[1,1'-biphenyl]-4,4'-diamine(m-TB-HG))、1,3-雙(3-胺基苯氧基)苯(1,3’-Bis(3-aminophenoxy)benzene(APBN))、3,5-二胺基三氟甲苯(3,5-Diaminobenzotrifluoride(DABTF))、2,2'-雙[4-(4-胺基苯氧基苯基)]丙烷(2,2'-bis[4-(4-aminophenoxy)phenyl]propane(BAPP))、6-胺基-2-(4-胺基苯基)-苯并噁唑(6-amino-2-(4-aminophenyl)benzoxazole(6PBOA))、5-胺基-2-(4-胺基苯基)-苯并噁唑(5-amino-2-(4-aminophenyl)benzoxazole(5PBOA))等，可單獨使用或組合使用。
於實施例中，該二酐單體可為3,3',4,4'-聯苯四羧酸二酸酐(3,3',4,4'-biphenyltetracarboxylic dianhydride(BPDA))、2,2-雙[4-(3,4-二羧基苯氧基)苯基]丙烷二酸酐(2,2-bis[4-(3,4dicarboxyphenoxy)phenyl]propane dianhydride(BPADA))、均苯四甲酸二酸酐(pyromellitic dianhydride(PMDA))、4,4'-(六氟異丙烯)二酞酸酐(2,2'-Bis-(3,4-Dicarboxyphenyl) hexafluoropropane dianhydride(6FDA))、二苯醚四甲酸二酸酐(4,4-Oxydiphthalic anhydride(ODPA))、苯酮四羧酸二酸酐(Benzophenonetetracarboxylic dianhydride(BTDA))、3,3',4,4'-二環己基四甲酸二酐(3,3',4,4'-dicyclohexyltetracarboxylic acid dianhydride(HBPDA)等，可單獨使用或組合使用。
聚醯亞胺前驅體溶液亦可添加無機消光劑，如氧化矽、氧化鋁、碳酸鈣、硫酸鋇、二氧化鈦等，或有機消光劑，如聚碳酸酯(PC)、聚苯乙烯(PS)、聚甲基丙烯酸甲酯(PMMA)、聚乙烯、聚丙烯、聚對苯二甲酸乙二酯(PET)、環氧樹脂等，及黑色顏料，如碳黑、鈦黑、骨炭(bone black)、花青黑(cyanine black)、乙炔黑、燈黑、石墨、鐵黑、苯胺黑、花菁黑等，可單獨使用或組合使用。
請配合參閱第2-4圖，將該聚醯亞胺前驅體溶塗佈於一載體10上(S2)，如鋼帶，以形成一聚醯亞胺濕膜12。
將聚醯亞胺濕膜12自載體10上剝離後，經過具有凹凸形狀及圖騰之壓花滾輪14輾壓(S3)，使聚醯亞胺濕膜12表面形成有凹凸形狀16及圖騰18。
將該輾壓後之聚醯亞胺濕膜進行加熱烘烤(S4)，以形成具有凹凸形狀16及圖騰18之聚醯亞胺膜20，如是，可有效降低聚醯亞胺膜20之光澤度，使聚醯亞胺膜20具有60度以下之光澤值。
以下實施例詳述本發明。
將二胺單體與二酐單體在溶劑下進行聚合，以形成聚醯胺酸，以形成聚醯亞胺前驅體溶液。
將上述具有20%溶劑含量之聚醯亞胺前驅體溶液與6wt%含量之聚醯亞胺粉體之消光劑混合，將其塗佈於鋼帶上以形成聚醯亞胺濕膜，將聚醯亞胺濕膜自鋼帶上剝離後經過具有凹凸面之壓花滾輪輾壓，該壓花滾輪之溫度為100℃，壓花滾輪壓力為1KG，再經過加熱烘烤，所得之聚醯亞胺膜光澤度值為55GU。
重複實施例1之步驟，溶劑含量20%，該壓花滾輪之溫度為140℃，壓花滾輪壓力為1KG，再經過加熱烘烤，所得之聚醯亞胺膜光澤度值為52GU。
重複實施例1之步驟，溶劑含量20%，該壓花滾輪之溫度為180℃，壓花滾輪壓力為1KG，再經過加熱烘烤，所得之聚醯亞胺膜光澤度值為50GU。
重複實施例1之步驟，溶劑含量20%，該壓花滾輪之溫度為250℃，壓花滾輪壓力為10KG，再經過加熱烘烤，所得之聚醯亞胺膜光澤度值為17GU。
重複實施例1之步驟，溶劑含量50%，該壓花滾輪之溫度為100℃，壓花滾輪壓力為1KG，再經過加熱烘烤，所得之聚醯亞胺膜光澤度值為53GU。
重複實施例1之步驟，溶劑含量50%，該壓花滾輪之溫度為140℃，壓花滾輪壓力為1KG，再經過加熱烘烤，所得之聚醯亞胺膜光澤度值為49GU。
重複實施例1之步驟，溶劑含量50%，該壓花滾輪之溫度為180℃，壓花滾輪壓力為1KG，再經過加熱烘烤，所得之聚醯亞胺膜光澤度值為45GU。
重複實施例1之步驟，溶劑含量50%，該壓花滾輪之溫度為250℃，壓花滾輪壓力為10KG，再經過加熱烘烤，所得之聚醯亞胺膜光澤度值為12GU。
重複實施例1之步驟，溶劑含量20%，該壓花滾輪之溫度為90℃，壓花滾輪壓力為0.8KG，再經過加熱烘烤，所得之聚醯亞胺膜光澤度值為85GU。
重複實施例1之步驟，溶劑含量50%，該壓花滾輪之溫度為180℃，壓花滾輪壓力為0.8KG，再經過加熱烘烤，所得之聚醯亞胺膜光澤度值為80GU。
如上述之實施例與比較例，本發明係在溫度160-190℃，壓力在4-8Kg為較佳操作條件。
以手持式光澤度計(型號為Micro Tri Gloss-BYK Gardner)進行檢測，取3個獨立測量值之平均值。
比較表
上述特定實施例之內容係為了詳細說明本發明，然而，該等實施例係僅用於說明，並非意欲限制本發明。熟習本領域之技藝者可理解，在不悖離後附申請專利範圍所界定之範疇下針對本發明所進行之各種變化或修改係落入本發明之一部分。
Claims (10)
- 一種低光澤之聚醯亞胺膜製造方法，係包括：提供一二胺單體與二酐單體在溶劑下進行聚合，以形成一聚醯亞胺前驅體溶液；將該聚醯亞胺前驅體溶液形成於一載體上，以形成一聚醯亞胺濕膜；將該聚醯亞胺濕膜在溫度100℃以上，壓力1kg以上之壓花滾輪上輾壓，使其表面形成有凹凸形狀；及將該聚醯亞胺濕膜進行高溫烘烤，以形成一聚醯亞胺膜。
- 如申請專利範圍第1項所述之低光澤之聚醯亞胺膜製造方法，其中，該聚醯胺酸係由選自4,4'-二胺基二苯醚(4,4'-ODA)、對苯二胺(p-PDA)、2,2’-雙(三氟甲基)聯苯胺(TFMB)所成群組之二胺及選自由均苯四甲酸二酐(PMDA)、3,3',4,4'-聯苯四羧酸二酐(BPDA)、2,2-雙[4-(3,4-二羧基苯氧基)苯基]丙烷二酐(BPADA)所成群組之二酐反應而得。
- 如申請專利範圍第1項所述之低光澤之聚醯亞胺膜製造方法，其中，該壓輪係在溫度160-190℃，壓力為4-8KG操作為較佳者。
- 如申請專利範圍第1項所述之低光澤之聚醯亞胺膜製造方法，其中，其中，該聚醯亞胺前驅體溶液之溶劑含量為20-50%。
- 如申請專利範圍第1項所述之低光澤之聚醯亞胺膜製造方法，其中，該聚醯亞胺前驅體溶液更包括有消光劑，使該聚醯亞胺膜具有60度以下之光澤值。
- 如申請專利範圍第1項所述之低光澤之聚醯亞胺膜製造方法，其中，該 聚醯亞胺前驅體更包括有黑色顏料，如碳黑、鈦黑、骨炭(bone black)、花青黑(cyanine black)、乙炔黑、燈黑、石墨、鐵黑、苯胺黑、花菁黑等，可單獨使用或組合使用，使該聚醯亞胺膜具有60度以下之光澤值。
- 如申請專利範圍第1項所述之低光澤之聚醯亞胺膜製造方法，其中，壓輪表面形成有凹凸形狀。
- 一種低光澤之聚醯亞胺膜，其包括有：一聚醯亞胺膜，其係由二胺單體及二酐單體聚合而得，其表面形成有規則之凹凸形狀；及一消光劑，其係添加於該聚醯亞胺膜內，使該聚醯亞胺膜具有小於60度之光澤值。
- 如申請專利範圍第8項所述之低光澤之聚醯亞胺膜，其中更包括有黑色顏料，如碳黑、鈦黑、骨炭(bone black)、花青黑(cyanine black)、乙炔黑、燈黑、石墨、鐵黑、苯胺黑、花菁黑等，可單獨使用或組合使用。
- 如申請專利範圍第8項所述之低光澤之聚醯亞胺膜，其中，該消光劑為聚醯亞胺粉體。
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW105133667A TW201815909A (zh) | 2016-10-19 | 2016-10-19 | 低光澤之聚醯亞胺膜及其製造方法 |
| CN201610947719.5A CN106957445A (zh) | 2016-10-19 | 2016-10-26 | 低光泽的聚酰亚胺膜及其制造方法 |
| US15/365,679 US20180105657A1 (en) | 2016-10-19 | 2016-11-30 | Polyimide film having low gloss and manufacture thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW105133667A TW201815909A (zh) | 2016-10-19 | 2016-10-19 | 低光澤之聚醯亞胺膜及其製造方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW201815909A true TW201815909A (zh) | 2018-05-01 |
Family
ID=59481663
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW105133667A TW201815909A (zh) | 2016-10-19 | 2016-10-19 | 低光澤之聚醯亞胺膜及其製造方法 |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US20180105657A1 (zh) |
| CN (1) | CN106957445A (zh) |
| TW (1) | TW201815909A (zh) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI842563B (zh) * | 2022-06-13 | 2024-05-11 | 南韓商聚酰亞胺先端材料有限公司 | 黑色聚醯亞胺膜、其製造方法、包括其的覆蓋膜及電子裝置 |
| TWI858831B (zh) * | 2023-07-20 | 2024-10-11 | 達邁科技股份有限公司 | 降低光澤度之聚醯亞胺膜製造方法 |
| TWI859154B (zh) * | 2018-08-24 | 2024-10-21 | 日商三菱瓦斯化學股份有限公司 | 聚醯亞胺樹脂、聚醯亞胺清漆以及聚醯亞胺薄膜 |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108070102A (zh) * | 2017-12-15 | 2018-05-25 | 桂林电器科学研究院有限公司 | 一种多层低光泽黑色聚酰亚胺薄膜制备方法 |
| CN107964109A (zh) * | 2017-12-15 | 2018-04-27 | 桂林电器科学研究院有限公司 | 一种消光黑色聚酰亚胺薄膜制备方法 |
| CN108034062A (zh) * | 2017-12-15 | 2018-05-15 | 桂林电器科学研究院有限公司 | 一种黑色消光型聚酰亚胺薄膜制备方法 |
| CN107987529A (zh) * | 2017-12-15 | 2018-05-04 | 桂林电器科学研究院有限公司 | 一种亚黑聚酰亚胺薄膜制备方法 |
| CN108047717A (zh) * | 2017-12-15 | 2018-05-18 | 桂林电器科学研究院有限公司 | 一种黑色低光泽聚酰亚胺薄膜制备方法 |
| CN108017910A (zh) * | 2017-12-15 | 2018-05-11 | 桂林电器科学研究院有限公司 | 一种亚光黑色聚酰亚胺薄膜制备方法 |
| CN107936556A (zh) * | 2017-12-15 | 2018-04-20 | 桂林电器科学研究院有限公司 | 一种黑色消光聚酰亚胺薄膜制备方法 |
| CN107987528A (zh) * | 2017-12-15 | 2018-05-04 | 桂林电器科学研究院有限公司 | 一种亚光表面的黑色聚酰亚胺薄膜制备方法 |
| CN108752626A (zh) * | 2018-06-27 | 2018-11-06 | 桂林电器科学研究院有限公司 | 用于黑色聚酰亚胺薄膜的填料分散液及其制备方法 |
| CN109438703B (zh) * | 2018-11-05 | 2021-06-15 | 株洲时代华鑫新材料技术有限公司 | 黑色聚酰亚胺微球及其制备方法及含其薄膜的制备方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100226016A1 (en) * | 2007-07-25 | 2010-09-09 | Nippon Shokubai Co., Ltd. | Light-shielding film |
| JP6815984B2 (ja) * | 2015-02-23 | 2021-01-20 | 日本ペイント・オートモーティブコーティングス株式会社 | 真空成形用３次元成型品加飾用積層フィルム、その製造方法及び３次元成型品加飾方法 |
| CN104742461B (zh) * | 2015-04-16 | 2017-05-24 | 达迈科技股份有限公司 | 低光泽度的双层聚酰亚胺膜及其制造方法 |
| CN205086428U (zh) * | 2015-04-16 | 2016-03-16 | 达迈科技股份有限公司 | 低光泽度的双层聚酰亚胺膜 |
-
2016
- 2016-10-19 TW TW105133667A patent/TW201815909A/zh unknown
- 2016-10-26 CN CN201610947719.5A patent/CN106957445A/zh active Pending
- 2016-11-30 US US15/365,679 patent/US20180105657A1/en not_active Abandoned
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI859154B (zh) * | 2018-08-24 | 2024-10-21 | 日商三菱瓦斯化學股份有限公司 | 聚醯亞胺樹脂、聚醯亞胺清漆以及聚醯亞胺薄膜 |
| TWI842563B (zh) * | 2022-06-13 | 2024-05-11 | 南韓商聚酰亞胺先端材料有限公司 | 黑色聚醯亞胺膜、其製造方法、包括其的覆蓋膜及電子裝置 |
| TWI858831B (zh) * | 2023-07-20 | 2024-10-11 | 達邁科技股份有限公司 | 降低光澤度之聚醯亞胺膜製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20180105657A1 (en) | 2018-04-19 |
| CN106957445A (zh) | 2017-07-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TW201815909A (zh) | 低光澤之聚醯亞胺膜及其製造方法 | |
| JP6544055B2 (ja) | ポリイミド膜の製造方法 | |
| JP5648630B2 (ja) | 多層ポリイミドフィルム | |
| TWI510529B (zh) | 聚醯亞胺膜、其製造方法及包含其之聚醯亞胺膜積層板 | |
| TWI498364B (zh) | 低介電常數及低光澤度之聚醯亞胺膜及其製備方法 | |
| JP7222089B2 (ja) | 樹脂フィルム、金属張積層体及びその製造方法 | |
| JP5782924B2 (ja) | ポリアミドイミドフィルムの製造方法 | |
| TWI595024B (zh) | 聚醯胺酸、覆銅板及電路板 | |
| TW201502176A (zh) | 聚醯亞胺膜 | |
| JP5383343B2 (ja) | 白色ポリイミドフィルム | |
| TW201607749A (zh) | 聚醯亞胺膜及其製成和組合方法 | |
| JP2018028053A (ja) | 透明ポリイミドフィルムの製造方法 | |
| TW202016174A (zh) | 透明聚醯亞胺膜 | |
| KR20070053799A (ko) | 접착성이 개량된 신규한 폴리이미드 필름 | |
| JP7317122B2 (ja) | ポリアミド酸組成物の製造方法、ポリアミド酸組成物、これを用いたポリイミドフィルムの製造方法及びその製造方法によって製造されたポリイミドフィルム | |
| JP5383286B2 (ja) | 白色ポリイミドの製造方法 | |
| CN104742461B (zh) | 低光泽度的双层聚酰亚胺膜及其制造方法 | |
| TWI709592B (zh) | 聚醯亞胺膜以及聚醯亞胺膜的製造方法 | |
| CN205086428U (zh) | 低光泽度的双层聚酰亚胺膜 | |
| KR101357236B1 (ko) | 컬러 폴리이미드 조성물 및 그 제조방법 | |
| CN105131320A (zh) | 超薄聚酰亚胺膜及其制造和组合方法 | |
| CN205099611U (zh) | 超薄聚酰亚胺膜 | |
| JP6522395B2 (ja) | ポリイミドフィルム、フレキシブル金属張積層板、およびフレキシブルプリント配線板の製造方法 | |
| TW200835720A (en) | Polyimide film and process for producing the same | |
| TWI656973B (zh) | 低光澤度之雙層聚醯亞胺膜及其製造方法 |