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RU2018118562A - Изделия из стекла со смешанными полимерными и металлоксидными покрытиями - Google Patents

Изделия из стекла со смешанными полимерными и металлоксидными покрытиями Download PDF

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RU2018118562A
RU2018118562A RU2018118562A RU2018118562A RU2018118562A RU 2018118562 A RU2018118562 A RU 2018118562A RU 2018118562 A RU2018118562 A RU 2018118562A RU 2018118562 A RU2018118562 A RU 2018118562A RU 2018118562 A RU2018118562 A RU 2018118562A
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coating
metal oxide
compositions
pharmaceutical packaging
pharmaceutical
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RU2018118562A
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RU2018118562A3 (ru
RU2729081C2 (ru
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Давид Анри
Валери Клодин ЛАКАРРЬЕР
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Корнинг Инкорпорейтед
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D23/00—Details of bottles or jars not otherwise provided for
    • B65D23/08—Coverings or external coatings
    • B65D23/0807—Coatings
    • B65D23/0814—Coatings characterised by the composition of the material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D1/00—Rigid or semi-rigid containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material or by deep-drawing operations performed on sheet material
    • B65D1/40—Details of walls
    • B65D1/42—Reinforcing or strengthening parts or members
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61J—CONTAINERS SPECIALLY ADAPTED FOR MEDICAL OR PHARMACEUTICAL PURPOSES; DEVICES OR METHODS SPECIALLY ADAPTED FOR BRINGING PHARMACEUTICAL PRODUCTS INTO PARTICULAR PHYSICAL OR ADMINISTERING FORMS; DEVICES FOR ADMINISTERING FOOD OR MEDICINES ORALLY; BABY COMFORTERS; DEVICES FOR RECEIVING SPITTLE
    • A61J1/00—Containers specially adapted for medical or pharmaceutical purposes
    • A61J1/14—Details; Accessories therefor
    • A61J1/1468—Containers characterised by specific material properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D1/00—Rigid or semi-rigid containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material or by deep-drawing operations performed on sheet material
    • B65D1/09—Ampoules
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/001—General methods for coating; Devices therefor
    • C03C17/003—General methods for coating; Devices therefor for hollow ware, e.g. containers
    • C03C17/005—Coating the outside
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
    • C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
    • C03C17/23—Oxides
    • C03C17/25—Oxides by deposition from the liquid phase
    • C03C17/256—Coating containing TiO2
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
    • C03C17/32—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with synthetic or natural resins
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/42—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating of an organic material and at least one non-metal coating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D179/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09D161/00 - C09D177/00
    • C09D179/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • C09D179/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/20—Materials for coating a single layer on glass
    • C03C2217/21—Oxides
    • C03C2217/212—TiO2
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/20—Materials for coating a single layer on glass
    • C03C2217/21—Oxides
    • C03C2217/214—Al2O3
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/20—Materials for coating a single layer on glass
    • C03C2217/21—Oxides
    • C03C2217/22—ZrO2
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00—Methods for coating glass
    • C03C2218/10—Deposition methods
    • C03C2218/11—Deposition methods from solutions or suspensions
    • C03C2218/111—Deposition methods from solutions or suspensions by dipping, immersion
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00—Methods for coating glass
    • C03C2218/30—Aspects of methods for coating glass not covered above
    • C03C2218/32—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1039—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors comprising halogen-containing substituents
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1046—Polyimides containing oxygen in the form of ether bonds in the main chain
    • C08G73/105—Polyimides containing oxygen in the form of ether bonds in the main chain with oxygen only in the diamino moiety
    • C—CHEMISTRY; METALLURGY
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    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1067—Wholly aromatic polyimides, i.e. having both tetracarboxylic and diamino moieties aromatically bound
    • C08G73/1071—Wholly aromatic polyimides containing oxygen in the form of ether bonds in the main chain
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    • C08K3/00—Use of inorganic substances as compounding ingredients
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    • C08K3/20—Oxides; Hydroxides
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    • C08K3/00—Use of inorganic substances as compounding ingredients
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  • Medical Preparation Storing Or Oral Administration Devices (AREA)
  • Details Of Rigid Or Semi-Rigid Containers (AREA)
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Claims (48)

1. Фармацевтическая упаковка, содержащая:
- стеклянную емкость, имеющую первую поверхность и вторую поверхность, противоположную первой поверхности, причем первая поверхность является наружной поверхностью стеклянной емкости, и
- покрытие, размещающееся на по меньшей мере одном участке первой поверхности стеклянной емкости, причем покрытие содержит:
- одну или более полиимидных композиций и
- одну или более металлоксидных композиций,
причем эти одна или более полиимидных композиций и одна или более металлоксидных композиций смешаны в покрытии.
2. Фармацевтическая упаковка по п. 1, в которой весовое отношение одной или более металлоксидных композиций к одной или более полиимидных композиций составляет от примерно 20/80 до примерно 95/5.
3. Фармацевтическая упаковка по п. 1, в которой полное количество одной или более металлоксидных композиций в покрытии составляет от примерно 20 вес.% до примерно 95 вес.%.
4. Фармацевтическая упаковка по п. 1, в которой полное количество одной или более полиимидных композиций в покрытии составляет от примерно 5 вес.% до примерно 80 вес.%.
5. Фармацевтическая упаковка по п. 1, в которой комбинация полиимидов и оксидов металлов в покрытии составляет по меньшей мере примерно 50 вес.% покрытия.
6. Фармацевтическая упаковка по п. 1, в которой по меньшей мере одна из указанных одной или более металлоксидных композиций является оксидом циркония, оксидом алюминия или оксидом титана.
7. Фармацевтическая упаковка по п. 1, в которой покрытие имеет толщину 100 нм или меньше.
8. Фармацевтическая упаковка по п. 1, в которой указанная, одна или более, полиимидная композиция является фторированной.
9. Фармацевтическая упаковка по п. 1, причем покрытие связано с по меньшей мере одним участком первой поверхности стеклянной емкости.
10. Фармацевтическая упаковка по п. 1, в которой указанный участок первой поверхности стеклянной емкости с покрытием имеет коэффициент трения меньше или равный примерно 0,7.
11. Фармацевтическая упаковка по п. 10, в которой участок первой поверхности стеклянной емкости с покрытием сохраняет коэффициент трения меньше или равный примерно 0,7 после термообработки при температуре по меньшей мере примерно 250°C в течение 30 минут.
12. Фармацевтическая упаковка по п. 1, причем светопропускание через фармацевтическую упаковку больше или равно примерно 55% от светопропускания через фармацевтическую упаковку без покрытия для всех длин волн из диапазона от примерно 400 нм до примерно 700 нм.
13. Фармацевтическая упаковка по п. 12, причем фармацевтическая упаковка сохраняет светопропускание через фармацевтическую упаковку больше или равную примерно 55% от светопропускания через фармацевтическую упаковку без покрытия для всех длин волн из диапазона от примерно 400 нм до примерно 700 нм после термообработки при температуре по меньшей мере примерно 250°C в течение 30 минут.
14. Фармацевтическая упаковка по п. 1, в которой весовое отношение одной или более металлоксидных композиций к одной или более полиимидных композиций составляет 90:10 или больше.
15. Фармацевтическая упаковка по п. 1, в которой весовое отношение одной или более металлоксидных композиций к одной или более полиимидных композиций составляет примерно 35/65 или больше.
16. Фармацевтическая упаковка по п. 1, в которой весовое отношение одной или более металлоксидных композиций к одной или более полиимидных композиций составляет примерно 50/50 или больше.
17. Фармацевтическая упаковка по п. 1, в которой весовое отношение одной или более металлоксидных композиций к одной или более полиимидных композиций составляет примерно 75/25 или больше.
18. Фармацевтическая упаковка по п. 1, в которой комбинация полиимидов и оксидов металлов в покрытии составляет по меньшей мере примерно 90 вес.% покрытия.
19. Фармацевтическая упаковка по п. 1, в которой комбинация полиимидов и оксидов металлов в покрытии составляет по меньшей мере примерно 95 вес.% покрытия.
20. Фармацевтическая упаковка по п. 1, в которой комбинация полиимидов и оксидов металлов в покрытии составляет по меньшей мере примерно 99 вес.% покрытия.
21. Способ получения фармацевтической упаковки, причем способ включает:
- осаждение смеси для покрытия на первую площадь наружной поверхности стеклянной емкости, причем смесь для покрытия содержит:
- один или более предшественников оксидов металлов и
- одну или более полимерных композиций, один или более предшественников полимеров или то и другое, и
- нагревание смеси для покрытия, чтобы образовать покрытие на наружной поверхности стеклянной емкости, причем покрытие содержит:
- одну или более полимерных композиций и
- одну или более металлоксидных композиций.
22. Способ по п. 21, в котором по меньшей мере один предшественник оксида металла выбран из титаната, цирконата, алюмината циркония, алюмината или их гидролизатов или олигомеров.
23. Способ по п. 21, в котором по меньшей мере один предшественник оксида металла выбран из тетраортотитаната, гексакоординированного хелатного титаната, полимерного титаната или их гидролизатов или олигомеров.
24. Способ по п. 21, в котором по меньшей мере один предшественник оксида металла является тетраортотитанатом или его гидролизатом или олигомером, выбранным из тетраэтилортотитаната, тетраметилортотитаната, тетраизопропилортотитаната, тетрапентилортотитаната, тетраоктилортотитаната, тетрадодецилортотитаната, тетра-2-этилгексилортотитаната тетрабензилортотитаната, тетрациклогексилортотитаната, тетрафенилортотитаната, тетраэтоксиэтилортотитаната, тетра-н-бутилтитаната, тетракис(2-этилгексил)титаната, тетра-β-нафтилортотитаната или их гидролизатов или олигомеров.
25. Способ по п. 21, в котором по меньшей мере один предшественник оксида металла представляет собой гексакоординированный хелатный титанат, его гидролизат или олигомер, выбранный из титанацетилацетоната, диизопропоксититан бис(ацетилацетонат)а, ацетилацетонат-бис(пентан-2,4-дионато-O,O')бис(алканолато)титана, диизопропокси-бис(этилацетоацетато)титаната, (триэтаноламинато)изопропоксида титана(IV) или их гидролизатов или олигомеров.
26. Способ по п. 21, в котором по меньшей мере один предшественник оксида металла является цирконий-содержащим предшественником оксида металла.
27. Способ по п. 26, в котором цирконий-содержащий предшественник оксида металла выбран из ацетилацетоната циркония трет-бутоксида циркония, гексафторацетилацетоната циркония, нафтената циркония, пропоксида циркония, изопропоксида циркония, алюминатов циркония, тетра-(2,2-диаллилоксиметил)бутил,ди(дитридецил)-фосфитоцирконата, неопентил(диаллил)окси,три(неодеканоил)цирконата, неопентил(диаллил)окси,три(додецил)бензолсульфоцирконата, неопентил(диаллил)окси,три(диоктил)фосфатоцирконата, неопентил(диаллил)окси,три(диоктил)пирофосфатоцирконата, неопентил(диаллил)окси,три(N-этилендиамино)этилцирконата, неопентил(диаллил)окси,три(м-амино)фенилцирконата, неопентил(диаллил)окси,триметакрилцирконата, неопентил(диаллил)окси,триакрилцирконата, динеопентил(диаллил)окси,дипараминобензоилцирконата, динеопентил(диаллил)окси,ди(3-меркапто)пропионового цирконата, или их гидролизатов или олигомеров.
28. Способ по п. 21, причем по меньшей мере один предшественник оксида металла является тетракоординированным алюминатным предшественником оксида металла.
29. Фармацевтическая упаковка, содержащая:
- стеклянную емкость, имеющую первую поверхность и вторую поверхность, противоположную первой поверхности, причем первая поверхность является наружной поверхностью стеклянной емкости, и
- покрытие, размещающееся на по меньшей мере одном участке первой поверхности стеклянной емкости, причем покрытие содержит:
- одну или более полимерных композиций и
- одну или более металлоксидных композиций,
причем эти одна или более полимерных композиций и одна или более металлоксидных композиций смешаны в покрытии,
причем весовое отношение одной или более металлоксидных композиций к одной или более полимерных композиций составляет от примерно 20/80 до примерно 95/5, и
причем комбинация полимеров и оксидов металлов в покрытии составляет по меньшей мере примерно 95 вес.% покрытия.
30. Фармацевтическая упаковка по п. 29, в которой одна или больше из указанной одной или более полимерных композиций является полиимидом.
RU2018118562A 2015-10-30 2016-10-28 Изделия из стекла со смешанными полимерными и металлоксидными покрытиями RU2729081C2 (ru)

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