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RU2008116310A - Диспергаторы в композитах - Google Patents

Диспергаторы в композитах Download PDF

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Publication number
RU2008116310A
RU2008116310A RU2008116310/04A RU2008116310A RU2008116310A RU 2008116310 A RU2008116310 A RU 2008116310A RU 2008116310/04 A RU2008116310/04 A RU 2008116310/04A RU 2008116310 A RU2008116310 A RU 2008116310A RU 2008116310 A RU2008116310 A RU 2008116310A
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RU
Russia
Prior art keywords
component
composition according
amount
weight
contained
Prior art date
Application number
RU2008116310/04A
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English (en)
Other versions
RU2435802C2 (ru
Inventor
Грэм МОАД (AU)
Грэм МОАД
Гуосинь ЛИ (AU)
Гуосинь ЛИ
Джонатан КАМПБЕЛЛ (AU)
Джонатан КАМПБЕЛЛ
Хендрик ВЕРМТЕР (DE)
Хендрик ВЕРМТЕР
Рудольф ПФЭНДНЕР (DE)
Рудольф ПФЭНДНЕР
Original Assignee
Полимерс Си-Эр-К Лимитед (Au)
Полимерс Си-Эр-К Лимитед
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Publication of RU2008116310A publication Critical patent/RU2008116310A/ru
Application granted granted Critical
Publication of RU2435802C2 publication Critical patent/RU2435802C2/ru

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
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    • B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
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Abstract

1. Композиция, включающая ! (а) синтетический полимер, ! (б) тальк в качестве наполнителя, где частицы талька обладают средним размером от 0,4 до 25 мкм и содержатся в количестве от 0,1 до 10% в пересчете на массу компонента (а), и ! (в) диспергатор, который основан на неионогенном поверхностно-активном веществе или амфифильном статистическом, блочном или гребнеобразном сополимере; ! при условии, что когда синтетический полимер (а) представляет собой полиамид, он содержится в количестве меньше 55% в пересчете на массу (а), (б) и (в). ! 2. Композиция по п.1, в которой компонент (б) содержится в количестве от 1 до 10% в пересчете на массу компонента (а). ! 3. Композиция по п.1 или 2, в которой компонент (а) представляет собой полиолефин. ! 4. Композиция по п.1 или 2, в которой компонент (а) представляет собой полиэтилен или полипропилен, или их сополимеры, или их смеси. ! 5. Композиция по п.1 или 2, в которой компонент (б) содержится в количестве от 0,1 до 40%, предпочтительно от 0,1 до 20%, в пересчете на массу компонента (а). ! 6. Композиция по п.5, в которой компонент (б) содержится в количестве от 1 до 10%, предпочтительно от 2,5 до 7,5%, в пересчете на массу компонента (а). ! 7. Композиция по п.1 или 2, в которой компонент (б) представляет собой немодифицированный тальковый наполнитель. ! 8. Композиция по п.1 или 2, в которой компонент (б) обладает средним размером частиц от 0,4 до 10 мкм, предпочтительно 0,6 до 10 мкм. ! 9. Композиция по п.1 или 2, в которой компонент (в) представляет собой неионогенное поверхностно-активное вещество. ! 10. Композиция по п.9, в которой компонент (в) представляет собой сорбитановый сложный эфир, диметилсилоксан-этиленоксидный блок-сополимер, полиметилметакрилат-по

Claims (23)

1. Композиция, включающая
(а) синтетический полимер,
(б) тальк в качестве наполнителя, где частицы талька обладают средним размером от 0,4 до 25 мкм и содержатся в количестве от 0,1 до 10% в пересчете на массу компонента (а), и
(в) диспергатор, который основан на неионогенном поверхностно-активном веществе или амфифильном статистическом, блочном или гребнеобразном сополимере;
при условии, что когда синтетический полимер (а) представляет собой полиамид, он содержится в количестве меньше 55% в пересчете на массу (а), (б) и (в).
2. Композиция по п.1, в которой компонент (б) содержится в количестве от 1 до 10% в пересчете на массу компонента (а).
3. Композиция по п.1 или 2, в которой компонент (а) представляет собой полиолефин.
4. Композиция по п.1 или 2, в которой компонент (а) представляет собой полиэтилен или полипропилен, или их сополимеры, или их смеси.
5. Композиция по п.1 или 2, в которой компонент (б) содержится в количестве от 0,1 до 40%, предпочтительно от 0,1 до 20%, в пересчете на массу компонента (а).
6. Композиция по п.5, в которой компонент (б) содержится в количестве от 1 до 10%, предпочтительно от 2,5 до 7,5%, в пересчете на массу компонента (а).
7. Композиция по п.1 или 2, в которой компонент (б) представляет собой немодифицированный тальковый наполнитель.
8. Композиция по п.1 или 2, в которой компонент (б) обладает средним размером частиц от 0,4 до 10 мкм, предпочтительно 0,6 до 10 мкм.
9. Композиция по п.1 или 2, в которой компонент (в) представляет собой неионогенное поверхностно-активное вещество.
10. Композиция по п.9, в которой компонент (в) представляет собой сорбитановый сложный эфир, диметилсилоксан-этиленоксидный блок-сополимер, полиметилметакрилат-полиоксиэтиленовый блок-сополимер или соединение формулы (1)
Figure 00000001
в которой m обозначает 1 или 2,
n обозначает 1 или 2,
х превышает или равен 1,
y превышает или равен 1,
z превышает или равен 0, а
R1 обозначает водородный атом или С1-С25алкил.
11. Композиция по п.1 или 2, в которой компонент (в) представляет собой амфифильный акриловый статистический, блочный или гребнеобразный сополимер.
12. Композиция по п.11, в которой компонент (в) основан на длинноцепочечном алкил(мет)акрилате.
13. Композиция по п.12, в которой компонент (в) основан на С12-С32алкил(мет)акрилате.
14. Композиция по п.1 или 2, в которой компонент (в) содержится в количестве от 0,01 до 10%, предпочтительно от 0,01 до 5%, в пересчете на массу компонента (а).
15. Композиция по п.1 или 2, включающая, кроме того, помимо компонентов (а), (б) и (в), дополнительные добавки.
16. Композиция по п.15, включающая в качестве дополнительных добавок фенольные антиоксиданты, светостабилизаторы, стабилизаторы для переработки, пигменты, красители, пластификаторы, агенты, улучшающие совместимость, добавки, повышающие ударную прочность и/или модифицирующие добавки, повышающие ударную прочность.
17. Композиция по п.1 или 2 в форме маточной смеси или концентрата, включающая компонент (а) в количестве от 5 до 90%, компонент (б) в количестве от 5 до 80% и компонент (в) в количестве от 0,5 до 50 мас.%.
18. Способ получения синтетического полимерного материала, который включает смешение в расплаве смеси
(а) синтетического полимера,
(б) талька в качестве наполнителя, где частицы талька обладают средним размером от 0,4 до 25 мкм и содержатся в количестве от 0,1 до 10% в пересчете на массу компонента (а), и
(в) диспергатора, который основан на неионогенном поверхностно-активном веществе или амфифильном статистическом, блочном или гребнеобразном сополимере;
при условии, что когда синтетический полимер (а) представляет собой полиамид, он содержится в количестве меньше 55% в пересчете на массу (а), (б) и (в).
19. Способ по п.18, в котором компонент (б) содержится в количестве от 1 до 10% в пересчете на массу компонента (а).
20. Способ по п.18, в котором смешение в расплаве проводят при температуре в пределах от 150 до 290°С.
21. Синтетический полимерный композит, полученный согласно способу по одному из пп.18-20.
22. Применение диспергатора (в), который основан на неионогенном поверхностно-активном веществе или амфифильном статистическом, блочном или гребнеобразном сополимере для диспергирования талькового наполнителя (б), где частицы талька обладают средним размером от 0,4 до 25 мкм и содержатся в количестве от 0,1 до 10% в пересчете на массу синтетической полимерной матрицы (а), в упомянутой синтетической полимерной матрице (а) с получением композитного материала при условии, что когда синтетический полимер (а) представляет собой полиамид, он содержится в количестве меньше 55% в пересчете на массу (а), (б) и (в).
23. Применение по п.22, при котором компонент (б) содержится в количестве от 1 до 10% в пересчете на массу компонента (а).
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US8110626B2 (en) 2012-02-07
MY145626A (en) 2012-03-15
WO2007039435A1 (en) 2007-04-12
CN101321817B (zh) 2012-06-27
DE602006021334D1 (de) 2011-05-26
RU2435802C2 (ru) 2011-12-10
US20100069557A1 (en) 2010-03-18
KR20080051143A (ko) 2008-06-10
TW200718744A (en) 2007-05-16
EP1940935A1 (en) 2008-07-09
EP1940935B1 (en) 2011-04-13
CA2623229A1 (en) 2007-04-12
NZ567223A (en) 2010-12-24
AU2006298825A1 (en) 2007-04-12
ATE505513T1 (de) 2011-04-15
ES2364762T3 (es) 2011-09-13
BRPI0616717A2 (pt) 2011-08-23

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