RU2006120080A - Цветная маркировка лазером - Google Patents
Цветная маркировка лазером Download PDFInfo
- Publication number
- RU2006120080A RU2006120080A RU2006120080/12A RU2006120080A RU2006120080A RU 2006120080 A RU2006120080 A RU 2006120080A RU 2006120080/12 A RU2006120080/12 A RU 2006120080/12A RU 2006120080 A RU2006120080 A RU 2006120080A RU 2006120080 A RU2006120080 A RU 2006120080A
- Authority
- RU
- Russia
- Prior art keywords
- polymer component
- layer
- energy absorber
- plastic
- polyesters
- Prior art date
Links
- 238000000034 method Methods 0.000 claims abstract 13
- 229920000642 polymer Polymers 0.000 claims abstract 9
- 239000004033 plastic Substances 0.000 claims abstract 8
- 229920003023 plastic Polymers 0.000 claims abstract 8
- 239000006096 absorbing agent Substances 0.000 claims abstract 5
- 238000002372 labelling Methods 0.000 claims 5
- 239000000975 dye Substances 0.000 claims 4
- 239000000203 mixture Substances 0.000 claims 3
- 239000002245 particle Substances 0.000 claims 3
- 229920000728 polyester Polymers 0.000 claims 3
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims 2
- 239000004952 Polyamide Substances 0.000 claims 2
- 229910004298 SiO 2 Inorganic materials 0.000 claims 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 claims 2
- 239000011230 binding agent Substances 0.000 claims 2
- 229920002678 cellulose Polymers 0.000 claims 2
- 239000001913 cellulose Substances 0.000 claims 2
- 229910044991 metal oxide Inorganic materials 0.000 claims 2
- 150000004706 metal oxides Chemical class 0.000 claims 2
- 229920002647 polyamide Polymers 0.000 claims 2
- 239000007787 solid Substances 0.000 claims 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 229910019142 PO4 Inorganic materials 0.000 claims 1
- 239000004642 Polyimide Substances 0.000 claims 1
- 229920002367 Polyisobutene Polymers 0.000 claims 1
- 239000004793 Polystyrene Substances 0.000 claims 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims 1
- 239000000654 additive Substances 0.000 claims 1
- 125000004063 butyryl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- -1 chlorovinyl Chemical group 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 claims 1
- 239000003822 epoxy resin Substances 0.000 claims 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 230000007774 longterm Effects 0.000 claims 1
- 239000010445 mica Substances 0.000 claims 1
- 229910052618 mica group Inorganic materials 0.000 claims 1
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 claims 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 claims 1
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 claims 1
- 235000021317 phosphate Nutrition 0.000 claims 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims 1
- 239000000049 pigment Substances 0.000 claims 1
- 229920000058 polyacrylate Polymers 0.000 claims 1
- 229920000515 polycarbonate Polymers 0.000 claims 1
- 239000004417 polycarbonate Substances 0.000 claims 1
- 229920000647 polyepoxide Polymers 0.000 claims 1
- 229920001721 polyimide Polymers 0.000 claims 1
- 229920000193 polymethacrylate Polymers 0.000 claims 1
- 229920000098 polyolefin Polymers 0.000 claims 1
- 229920006324 polyoxymethylene Polymers 0.000 claims 1
- 229920002223 polystyrene Polymers 0.000 claims 1
- 229920002451 polyvinyl alcohol Polymers 0.000 claims 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims 1
- 230000005855 radiation Effects 0.000 claims 1
- 150000004760 silicates Chemical class 0.000 claims 1
- 229920001897 terpolymer Polymers 0.000 claims 1
- 150000003568 thioethers Chemical class 0.000 claims 1
- 229920002554 vinyl polymer Polymers 0.000 claims 1
- 239000003086 colorant Substances 0.000 abstract 1
- 238000010330 laser marking Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/382—Contact thermal transfer or sublimation processes
- B41M5/392—Additives, other than colour forming substances, dyes or pigments, e.g. sensitisers, transfer promoting agents
- B41M5/395—Macromolecular additives, e.g. binders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/398—Processes based on the production of stickiness patterns using powders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/41—Base layers supports or substrates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/382—Contact thermal transfer or sublimation processes
- B41M5/385—Contact thermal transfer or sublimation processes characterised by the transferable dyes or pigments
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/46—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography characterised by the light-to-heat converting means; characterised by the heat or radiation filtering or absorbing means or layers
- B41M5/465—Infrared radiation-absorbing materials, e.g. dyes, metals, silicates, C black
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
Claims (12)
1. Способ нанесения долговременных и износостойких цветных надписей или маркировки на пластмассы, отличающийся тем, что используют систему слоев, состоящую из двух слоев, лежащих друг на друге и разделенных поддерживающей пленкой, где первый слой состоит из пластмассы, которая содержит поглотитель энергии внутри или в виде слоя, а второй слой, нанесенный на поддерживающую пленку, служит в качестве среды для маркировки и содержит краситель и полимерный компонент, где полимерный компонент приваривается к поверхности пластмассы под действием лазерного излучения в ходе нанесения надписи/маркировки.
2. Способ по п.1, отличающийся тем, что первый слой состоит из одного или более поддерживающих слоев, а поглотитель энергии расположен на или между этими поддерживающими слоями.
3. Способ по п.1 или 2, отличающийся тем, что поглотитель энергии выбирают из группы, состоящей из углерода, оксидов металлов, силикатов, чешуек SiO2, покрытых оксидом металла чешуек слюды и/или SiO2, проводящих пигментов, сульфидов, фосфатов, BiOCl, антрацена, периленов, риленов, пентаэритрита или их смесей.
4. Способ по п.1 или 2, отличающийся тем, что слой пластмассы содержит 0,01-20 мас.% поглотителя энергии.
5. Способ по п.1 или 2, отличающийся тем, что среда для маркировки по существу состоит из связующего компонента, красителей, полимерного компонента и, необязательно, добавок.
6. Способ по п.1 или 2, отличающийся тем, что связующий компонент выбирают из группы, состоящей из целлюлозы, производных целлюлозы, поливиниловых спиртов, поливинилпирролидонов, полиакрилатов, полиметакрилатов, эпоксидных смол, полиэстеров, полиэфиров, полиизобутилена, полиамида, поливинилбутиралей и их смесей.
7. Способ по п.1 или 2, отличающийся тем, что среда для маркировки содержит полимерный компонент в растворенном виде и/или в виде твердых частиц в количествах 30-90 мас.%.
8. Способ по п.1 или 2, отличающийся тем, что полимерный компонент в виде твердых частиц имеет размеры частиц 10 нм - 100 мкм.
9. Способ по п.1 или 2, отличающийся тем, что полимерный компонент состоит из полиэстеров, поликарбонатов, полиолефинов, полистрирола, полиимидов, полиамидов, полиацеталей и кополимеров упомянутых полимеров, и терполимеров хлорвинила, дикарбоксилатов и винилацетата или гидроксил/метилакрилата либо их смесей.
10. Способ по п.1 или 2, отличающийся тем, что среда для маркировки содержит органические и/или неорганические красители.
11. Способ по п.1 или 2, отличающийся тем, что среда для маркировки содержит 0,1-30 мас.% красителей на основании фракции полимерного компонента.
12. Пластмассы, на которые были нанесены маркировка или надписи лазером способом согласно п.1.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10352857.1 | 2003-11-10 | ||
| DE10352857 | 2003-11-10 | ||
| DE102004026336.1 | 2004-05-26 | ||
| DE102004026336 | 2004-05-26 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2006120080A true RU2006120080A (ru) | 2007-12-27 |
| RU2356741C2 RU2356741C2 (ru) | 2009-05-27 |
Family
ID=34575427
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2006120080/12A RU2356741C2 (ru) | 2003-11-10 | 2004-10-15 | Цветная маркировка лазером |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20070080146A1 (ru) |
| EP (1) | EP1682356B1 (ru) |
| JP (1) | JP5296317B2 (ru) |
| KR (1) | KR101121316B1 (ru) |
| AT (1) | ATE431257T1 (ru) |
| BR (1) | BRPI0416383A (ru) |
| DE (2) | DE502004009490D1 (ru) |
| RU (1) | RU2356741C2 (ru) |
| TW (1) | TWI326639B (ru) |
| WO (1) | WO2005047010A1 (ru) |
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|---|---|---|---|---|
| BRPI0509290B8 (pt) | 2004-03-30 | 2013-02-19 | processo para inscriÇço e/ou marcaÇço de plÁsticos colorida resistente À abrasço e permanente, e plÁsticos. | |
| DE102004018547A1 (de) | 2004-04-14 | 2005-02-03 | Basf Ag | Verfahren zum Schweißverbinden von Kunststoffteilen mit Hilfe von Laserstrahlung |
| CN100567016C (zh) * | 2005-02-21 | 2009-12-09 | 大科能树脂有限公司 | 激光标记用叠层体 |
| JP2007031491A (ja) * | 2005-07-22 | 2007-02-08 | Dainichiseika Color & Chem Mfg Co Ltd | レーザー溶着用樹脂組成物 |
| DE102005035914A1 (de) * | 2005-07-28 | 2007-02-01 | Chemische Fabrik Budenheim Kg | Laserschweißverfahren und -material |
| KR20080073750A (ko) * | 2005-11-22 | 2008-08-11 | 메르크 파텐트 게엠베하 | 전사 요소를 사용하는 액정 필름의 열 전사 방법 |
| DE102005057474A1 (de) | 2005-11-30 | 2007-05-31 | Merck Patent Gmbh | Lasertransfer von Sicherheitsmerkmalen |
| DE102006062269A1 (de) * | 2006-12-22 | 2008-06-26 | Eckart Gmbh & Co. Kg | Verwendung von sphärischen Metallpartikeln als Lasermarkierungs- oder Laserschweißbarkeitsmittel sowie lasermarkierbarer und/oder laserschweißbarer Kunststoff |
| DE102007005885A1 (de) * | 2007-02-01 | 2008-08-07 | Leonhard Kurz Gmbh & Co. Kg | Verfahren und Prägefolie zum selektiven Übertragen einer Farbschicht auf ein Substrat |
| DE102007005917A1 (de) | 2007-02-01 | 2008-08-07 | Leonhard Kurz Gmbh & Co. Kg | Farbige Markierung und Beschriftung mittels energiereicher Strahlung |
| JP4853340B2 (ja) * | 2007-03-13 | 2012-01-11 | 凸版印刷株式会社 | フイルム材へのレーザーマーキング方法及び紙容器へのレーザーマーキング方法 |
| ES2355764T3 (es) * | 2007-05-09 | 2011-03-30 | Actega Ds Gmbh | Uso de partículas metálicas esféricas como aditivos de marcación con láser para materiales de sellado, de obturación o de recubrimiento o lacas. |
| FI20075474A0 (fi) * | 2007-06-20 | 2007-06-20 | Valtion Teknillinen | Menetelmä muovin pinnan kuvioimiseksi |
| FR2918959B1 (fr) * | 2007-07-19 | 2010-12-10 | Laselec | Procede et dispositif de fabrication d'un manchon autour d'un cable et d'identification d'un cable |
| ATE447476T1 (de) * | 2007-11-30 | 2009-11-15 | Eckart Gmbh | Verwendung einer mischung mit sphärischen metallpartikeln und metallflakes als lasermarkierungs- oder laserschweissbarkeitsmittel sowie lasermarkierbarer und/oder laserschweissbarer kunststoff |
| US7829258B2 (en) * | 2008-01-22 | 2010-11-09 | Appleton Papers Inc. | Laser coloration of coated substrates |
| DE102009001216A1 (de) * | 2008-02-29 | 2009-09-03 | Mobil-Mark Gmbh | Verfahren zum strukturierten Aufbringen eines Markierungsmaterials |
| JP5467670B2 (ja) * | 2008-03-31 | 2014-04-09 | 株式会社ニデック | 染色方法及び染色装置 |
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| JP4215816B1 (ja) * | 2008-05-26 | 2009-01-28 | 日本カラリング株式会社 | レーザーマーキング多層シート |
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| WO2010029276A1 (en) * | 2008-09-10 | 2010-03-18 | Datalase Ltd. | Laser imaging and its use in security applications |
| EP2199357A1 (en) * | 2008-12-22 | 2010-06-23 | 3M Innovative Properties Company | Layered Material Containing Polyvinyl Butyral |
| JP2010189557A (ja) * | 2009-02-19 | 2010-09-02 | Mitsubishi Plastics Inc | ポリエステルフィルム |
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| EP2414130B2 (en) * | 2009-03-30 | 2019-04-24 | Boegli-Gravures S.A. | Method and device for structuring a solid body surface with a hard coating with a first laser with pulses in the nanosecond field and a second laser with pulses in the pico- or femtosecond field ; packaging foil |
| DE102010027145A1 (de) * | 2010-07-09 | 2012-01-12 | Faurecia Innenraum Systeme Gmbh | Verfahren zum Einbringen einer unsichtbaren Schwächung in eine Dekorschicht sowie Verfahren zur Herstellung einer Airbagabdeckung mit einer so geschwächten Dekorschicht |
| CN103249572B (zh) * | 2010-10-26 | 2016-06-22 | 沙特基础全球技术有限公司 | 具有全部颜色性能的激光直接结构化材料 |
| JP5912704B2 (ja) * | 2011-03-18 | 2016-04-27 | 三菱エンジニアリングプラスチックス株式会社 | 熱可塑性樹脂組成物、樹脂成形品、及びメッキ層付樹脂成形品の製造方法 |
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| RU2550179C1 (ru) * | 2013-11-26 | 2015-05-10 | Общество с ограниченной ответственностью "Флуоресцентные информационные технологии" ООО "Флуринтек" | Полимерная композиция, способ изготовления маркировки прямого нанесения с полимерной композицией и маркировка прямого нанесения |
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| JP2023042499A (ja) * | 2021-11-17 | 2023-03-27 | 株式会社キーエンス | レーザマーキング装置、マーキング方法および印字設定装置 |
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| WO1999025562A1 (en) | 1997-11-14 | 1999-05-27 | Cerdec Corporation | Laser marking method and material |
| US5950542A (en) * | 1998-01-29 | 1999-09-14 | Kodak Polychrome Graphics Llc | Direct write waterless imaging member with improved ablation properties and methods of imaging and printing |
| DE19942316A1 (de) | 1999-09-04 | 2001-03-08 | Poesl Rudolf | Verfahren zum Beschriften von Kunststoff usw. |
| JP2001199170A (ja) * | 2000-01-21 | 2001-07-24 | Konica Corp | レーザー熱転写フィルム |
| DE10008851A1 (de) * | 2000-02-25 | 2001-08-30 | Giesecke & Devrient Gmbh | Verfahren zur Herstellung laserbeschriftbarer Datenträger und damit hergestellte Datenträger |
| DE10018600A1 (de) * | 2000-04-14 | 2001-10-25 | Merck Patent Gmbh | Lasermarkierbare Kunststoffe |
| WO2002068192A1 (de) * | 2001-02-26 | 2002-09-06 | Trespaphan Gmbh | Lasermarkierbares laminat |
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| DE10136479A1 (de) | 2001-07-27 | 2003-02-06 | Merck Patent Gmbh | Farbige Beschriftung und Markierung von Kunststoffen und Lacken |
| DE10213110A1 (de) * | 2002-03-23 | 2003-10-02 | Tesa Ag | Mehrschichtige Laser-Transferfolie zum dauerhaften Beschriften von Bauteilen |
| DE10227188A1 (de) * | 2002-06-18 | 2004-01-08 | Basf Drucksysteme Gmbh | Verfahren zur Herstellung von Flexodruckformen mittels Laser-Direktgravur |
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-
2004
- 2004-10-14 US US10/578,771 patent/US20070080146A1/en not_active Abandoned
- 2004-10-15 WO PCT/EP2004/011583 patent/WO2005047010A1/de not_active Ceased
- 2004-10-15 DE DE502004009490T patent/DE502004009490D1/de not_active Expired - Lifetime
- 2004-10-15 JP JP2006538681A patent/JP5296317B2/ja not_active Expired - Fee Related
- 2004-10-15 KR KR1020067010204A patent/KR101121316B1/ko not_active Expired - Fee Related
- 2004-10-15 EP EP04790439A patent/EP1682356B1/de not_active Expired - Lifetime
- 2004-10-15 AT AT04790439T patent/ATE431257T1/de not_active IP Right Cessation
- 2004-10-15 BR BRPI0416383-4A patent/BRPI0416383A/pt active Search and Examination
- 2004-10-15 RU RU2006120080/12A patent/RU2356741C2/ru not_active IP Right Cessation
- 2004-11-02 DE DE102004053376A patent/DE102004053376A1/de not_active Withdrawn
- 2004-11-05 TW TW093133868A patent/TWI326639B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| DE102004053376A1 (de) | 2005-06-09 |
| DE502004009490D1 (de) | 2009-06-25 |
| WO2005047010A1 (de) | 2005-05-26 |
| KR101121316B1 (ko) | 2012-03-09 |
| RU2356741C2 (ru) | 2009-05-27 |
| US20070080146A1 (en) | 2007-04-12 |
| TWI326639B (en) | 2010-07-01 |
| JP5296317B2 (ja) | 2013-09-25 |
| TW200518949A (en) | 2005-06-16 |
| EP1682356B1 (de) | 2009-05-13 |
| BRPI0416383A (pt) | 2007-02-21 |
| EP1682356A1 (de) | 2006-07-26 |
| KR20060122870A (ko) | 2006-11-30 |
| ATE431257T1 (de) | 2009-05-15 |
| JP2007510547A (ja) | 2007-04-26 |
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| Date | Code | Title | Description |
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| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20131016 |