LU86975A1 - Modificateur des proprietes au choc des polymeres thermoplastiques,procede pour sa preparation,composition thermoplastique a resistance au choc modifiee le contenant et procede pour sa preparation - Google Patents
Modificateur des proprietes au choc des polymeres thermoplastiques,procede pour sa preparation,composition thermoplastique a resistance au choc modifiee le contenant et procede pour sa preparation Download PDFInfo
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- LU86975A1 LU86975A1 LU86975A LU86975A LU86975A1 LU 86975 A1 LU86975 A1 LU 86975A1 LU 86975 A LU86975 A LU 86975A LU 86975 A LU86975 A LU 86975A LU 86975 A1 LU86975 A1 LU 86975A1
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- 239000000203 mixture Substances 0.000 title claims description 69
- 239000003607 modifier Substances 0.000 title claims description 62
- 229920001169 thermoplastic Polymers 0.000 title claims description 31
- 238000000034 method Methods 0.000 title claims description 27
- 238000002360 preparation method Methods 0.000 title claims description 14
- 239000004416 thermosoftening plastic Substances 0.000 title claims description 12
- 230000008569 process Effects 0.000 title claims description 10
- 229920000642 polymer Polymers 0.000 claims description 200
- 239000000654 additive Substances 0.000 claims description 63
- 230000000996 additive effect Effects 0.000 claims description 63
- 239000000178 monomer Substances 0.000 claims description 59
- 239000000839 emulsion Substances 0.000 claims description 49
- 229920001577 copolymer Polymers 0.000 claims description 47
- 125000000217 alkyl group Chemical group 0.000 claims description 30
- 125000004432 carbon atom Chemical group C* 0.000 claims description 24
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 23
- 239000002253 acid Substances 0.000 claims description 23
- -1 alkyl methacrylate Chemical compound 0.000 claims description 22
- 239000011159 matrix material Substances 0.000 claims description 22
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 20
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 19
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 18
- 239000004609 Impact Modifier Substances 0.000 claims description 16
- 150000008064 anhydrides Chemical class 0.000 claims description 13
- 150000001993 dienes Chemical class 0.000 claims description 13
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 12
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 11
- 239000004952 Polyamide Substances 0.000 claims description 9
- 125000005907 alkyl ester group Chemical group 0.000 claims description 9
- 230000009477 glass transition Effects 0.000 claims description 9
- 229920002647 polyamide Polymers 0.000 claims description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 8
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 8
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 claims description 7
- 125000004429 atom Chemical group 0.000 claims description 4
- CUTWSDAQYCQTGD-UHFFFAOYSA-N 2-prop-2-enoyloxypropanoic acid Chemical compound OC(=O)C(C)OC(=O)C=C CUTWSDAQYCQTGD-UHFFFAOYSA-N 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- MUWOTPLDXQSGQZ-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)propanoic acid Chemical compound OC(=O)C(C)OC(=O)C(C)=C MUWOTPLDXQSGQZ-UHFFFAOYSA-N 0.000 claims description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 2
- CWNNYYIZGGDCHS-UHFFFAOYSA-N 2-methylideneglutaric acid Chemical compound OC(=O)CCC(=C)C(O)=O CWNNYYIZGGDCHS-UHFFFAOYSA-N 0.000 claims description 2
- CSWKHCNUPJQBFH-UHFFFAOYSA-N 5-(2-methylprop-2-enoyloxy)hexanoic acid Chemical compound CC(=C)C(=O)OC(C)CCCC(O)=O CSWKHCNUPJQBFH-UHFFFAOYSA-N 0.000 claims description 2
- WHURCQIVDXZCSY-UHFFFAOYSA-N 5-prop-2-enoyloxyhexanoic acid Chemical compound C=CC(=O)OC(C)CCCC(O)=O WHURCQIVDXZCSY-UHFFFAOYSA-N 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 claims description 2
- 230000000379 polymerizing effect Effects 0.000 claims description 2
- BMQHCCUIUKBSNF-UHFFFAOYSA-N 2-methyl-5-methylidenehexanedioic acid Chemical compound OC(=O)C(C)CCC(=C)C(O)=O BMQHCCUIUKBSNF-UHFFFAOYSA-N 0.000 claims 1
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 claims 1
- 239000004014 plasticizer Substances 0.000 claims 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 claims 1
- 229920001778 nylon Polymers 0.000 description 24
- 229920002292 Nylon 6 Polymers 0.000 description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 19
- 239000000243 solution Substances 0.000 description 18
- 239000004677 Nylon Substances 0.000 description 17
- 239000002245 particle Substances 0.000 description 16
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 14
- 238000002156 mixing Methods 0.000 description 14
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 13
- 239000008187 granular material Substances 0.000 description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 10
- 239000008367 deionised water Substances 0.000 description 10
- 229910021641 deionized water Inorganic materials 0.000 description 10
- 229920001971 elastomer Polymers 0.000 description 10
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 10
- 239000004816 latex Substances 0.000 description 9
- 229920000126 latex Polymers 0.000 description 9
- 238000001694 spray drying Methods 0.000 description 9
- 229920006051 Capron® Polymers 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 238000001125 extrusion Methods 0.000 description 7
- 238000000465 moulding Methods 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 229920002302 Nylon 6,6 Polymers 0.000 description 6
- 238000004132 cross linking Methods 0.000 description 6
- 230000006872 improvement Effects 0.000 description 6
- 238000001746 injection moulding Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 5
- 239000000806 elastomer Substances 0.000 description 5
- 239000000155 melt Substances 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 4
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 4
- 229920009204 Methacrylate-butadiene-styrene Polymers 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000015271 coagulation Effects 0.000 description 4
- 238000005345 coagulation Methods 0.000 description 4
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 4
- 229910021485 fumed silica Inorganic materials 0.000 description 4
- 229920001519 homopolymer Polymers 0.000 description 4
- 230000001965 increasing effect Effects 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 238000002955 isolation Methods 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 239000005060 rubber Substances 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 238000010408 sweeping Methods 0.000 description 4
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 238000007720 emulsion polymerization reaction Methods 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 239000004417 polycarbonate Substances 0.000 description 3
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 3
- 230000009466 transformation Effects 0.000 description 3
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 2
- 229920006045 Akulon® Polymers 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 229920000800 acrylic rubber Polymers 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 125000005395 methacrylic acid group Chemical group 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 238000010899 nucleation Methods 0.000 description 2
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 229920002857 polybutadiene Polymers 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- 239000012815 thermoplastic material Substances 0.000 description 2
- 238000009849 vacuum degassing Methods 0.000 description 2
- GPOGLVDBOFRHDV-UHFFFAOYSA-N (2-nonylphenyl) dihydrogen phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(O)O GPOGLVDBOFRHDV-UHFFFAOYSA-N 0.000 description 1
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- XOJWAAUYNWGQAU-UHFFFAOYSA-N 4-(2-methylprop-2-enoyloxy)butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCOC(=O)C(C)=C XOJWAAUYNWGQAU-UHFFFAOYSA-N 0.000 description 1
- UZDMJPAQQFSMMV-UHFFFAOYSA-N 4-oxo-4-(2-prop-2-enoyloxyethoxy)butanoic acid Chemical compound OC(=O)CCC(=O)OCCOC(=O)C=C UZDMJPAQQFSMMV-UHFFFAOYSA-N 0.000 description 1
- 239000004129 EU approved improving agent Substances 0.000 description 1
- 239000004716 Ethylene/acrylic acid copolymer Substances 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- JLNTWVDSQRNWFU-UHFFFAOYSA-N OOOOOOO Chemical compound OOOOOOO JLNTWVDSQRNWFU-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 125000005399 allylmethacrylate group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 229910052728 basic metal Inorganic materials 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- LKAVYBZHOYOUSX-UHFFFAOYSA-N buta-1,3-diene;2-methylprop-2-enoic acid;styrene Chemical compound C=CC=C.CC(=C)C(O)=O.C=CC1=CC=CC=C1 LKAVYBZHOYOUSX-UHFFFAOYSA-N 0.000 description 1
- PLOYJEGLPVCRAJ-UHFFFAOYSA-N buta-1,3-diene;prop-2-enoic acid;styrene Chemical compound C=CC=C.OC(=O)C=C.C=CC1=CC=CC=C1 PLOYJEGLPVCRAJ-UHFFFAOYSA-N 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 229940064002 calcium hypophosphite Drugs 0.000 description 1
- 229910001382 calcium hypophosphite Inorganic materials 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 229920006038 crystalline resin Polymers 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- CJSBUWDGPXGFGA-UHFFFAOYSA-N dimethyl-butadiene Natural products CC(C)=CC=C CJSBUWDGPXGFGA-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 238000007580 dry-mixing Methods 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 239000013536 elastomeric material Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 150000002148 esters Chemical group 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- YTXCAJNHPVBVDJ-UHFFFAOYSA-N octadecyl propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CC YTXCAJNHPVBVDJ-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001485 poly(butyl acrylate) polymer Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000008237 rinsing water Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- CNALVHVMBXLLIY-IUCAKERBSA-N tert-butyl n-[(3s,5s)-5-methylpiperidin-3-yl]carbamate Chemical compound C[C@@H]1CNC[C@@H](NC(=O)OC(C)(C)C)C1 CNALVHVMBXLLIY-IUCAKERBSA-N 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US90087886A | 1986-08-27 | 1986-08-27 | |
| US90087886 | 1986-08-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| LU86975A1 true LU86975A1 (fr) | 1987-12-16 |
Family
ID=25413229
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| LU86975A LU86975A1 (fr) | 1986-08-27 | 1987-08-27 | Modificateur des proprietes au choc des polymeres thermoplastiques,procede pour sa preparation,composition thermoplastique a resistance au choc modifiee le contenant et procede pour sa preparation |
Country Status (18)
| Country | Link |
|---|---|
| US (2) | US5332782A (nl) |
| EP (1) | EP0259097A3 (nl) |
| JP (1) | JP2651825B2 (nl) |
| KR (1) | KR960010847B1 (nl) |
| AU (1) | AU600967B2 (nl) |
| BE (1) | BE1001093A4 (nl) |
| BR (1) | BR8704317A (nl) |
| CA (1) | CA1332992C (nl) |
| DE (1) | DE3728685A1 (nl) |
| FR (1) | FR2603292A1 (nl) |
| GB (1) | GB2194541A (nl) |
| IL (1) | IL83649A (nl) |
| IT (1) | IT1211373B (nl) |
| LU (1) | LU86975A1 (nl) |
| MX (1) | MX168111B (nl) |
| NL (1) | NL8702010A (nl) |
| NZ (1) | NZ221515A (nl) |
| ZA (1) | ZA876110B (nl) |
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|---|---|---|---|---|
| US5212238A (en) * | 1988-12-22 | 1993-05-18 | Ferro Corporation | Toughened compositions of polyamide and functionalized rubber block or graft copolymers |
| ZA899629B (en) * | 1988-12-22 | 1990-09-26 | Ferro Corp | Toughened compositions of polyamide and functionalized rubber block or graft copolymers |
| CA2015331A1 (en) * | 1989-05-02 | 1990-11-02 | Leslie A. Cohen | Ultraviolet resistant glutarimide |
| CA2027381A1 (en) * | 1989-10-14 | 1991-04-15 | Junji Oshima | Core-shell polymer, resin composition and molded article thereof |
| DE69024779T2 (de) * | 1989-10-23 | 1996-07-18 | Takeda Chemical Industries Ltd | Kern-Schale-Polymer und dessen Anwendung |
| US5132360A (en) * | 1990-05-29 | 1992-07-21 | Shell Oil Company | Polyketone polymer blends |
| GB9222490D0 (en) * | 1992-10-26 | 1992-12-09 | Rohm & Haas | Means for imparting improved adhesion to polypropylene substrates |
| EP0776917B1 (de) * | 1995-11-29 | 2002-05-29 | Vantico AG | Core/Shell-Partikel und diese enthaltende härtbare Epoxidharzzusammensetzungen |
| CN1128844C (zh) * | 1996-06-05 | 2003-11-26 | 埃勒夫阿托化学有限公司 | 多相热塑性树脂组合物 |
| DE19718597C1 (de) * | 1997-05-02 | 1999-01-07 | Roehm Gmbh | Zweistufiges Verfahren zur Entwässerung von Kunststoffdispersionen |
| DE19841234C1 (de) * | 1998-09-09 | 1999-11-25 | Inventa Ag | Reversible thermotrope Kunststoff-Formmasse, Verfahren zu ihrer Herstellung und ihre Verwendung |
| PT1419181E (pt) * | 2001-05-04 | 2007-06-19 | Rhodia | Processo para a preparação de látices utilizando copolímeros em blocos como surfactantes |
| DE10345043A1 (de) | 2003-09-27 | 2005-04-21 | Rhein Chemie Rheinau Gmbh | Mikrogel-enthaltende Zusammensetzung |
| US7557158B2 (en) | 2004-09-15 | 2009-07-07 | Rohm And Haas Company | Gloss reducing polymer composition |
| KR100870199B1 (ko) | 2005-07-12 | 2008-11-24 | 주식회사 엘지화학 | 다층구조의 충격보강제 조성물, 이의 제조방법, 및 이를포함하는 열가소성 수지 조성물 |
| FR2894252B1 (fr) * | 2005-12-07 | 2013-01-04 | Arkema | Composition reticulee comprenant un copolymere coeur ecorce, son procede d'obtention et ses utilisations |
| DE102007038578A1 (de) | 2007-08-16 | 2009-02-19 | Evonik Degussa Gmbh | Verfahren zur Dekorierung von Oberflächen |
| US20090098345A1 (en) * | 2007-10-15 | 2009-04-16 | Brasher Jon H | Polymer-coated construction component and method |
| US8641080B2 (en) * | 2007-12-20 | 2014-02-04 | Dsm Ip Assets B.V. | Air bag container |
| RU2485149C2 (ru) * | 2008-02-08 | 2013-06-20 | Рейн Хеми Рейнау Гмбх | Стойкие к гидролизу смеси полиамид - эластомер, формованные изделия, полученные из них, и их применение |
| DE102008016436A1 (de) * | 2008-03-31 | 2009-10-01 | Ems-Patent Ag | Polyamidformmasse für lackfreie, zähe Gehäuse mit Hochglanz-Oberfläche |
| US20100047553A1 (en) * | 2008-08-20 | 2010-02-25 | Brasher Jon H | Coating Reinforcement Apparatus and Method |
| BR112013000373A2 (pt) * | 2010-07-08 | 2021-03-09 | Dow Global Technologies Llc | Composição termoplástica, método para produzir uma composição termoplástica, artigo e método para formar um artigo |
| CN102382239B (zh) * | 2011-08-18 | 2013-12-25 | 山东圣光化工集团有限公司 | 一种中空聚合物乳液及其制备方法 |
| EP2945994B1 (en) | 2013-01-18 | 2018-07-11 | Basf Se | Acrylic dispersion-based coating compositions |
| CN104804129B (zh) * | 2015-05-18 | 2017-01-25 | 长春工业大学 | 一种原位复合的核壳结构增韧剂及其制备方法 |
| EP3281983B1 (de) * | 2016-08-12 | 2022-06-15 | Evonik Operations GmbH | Zähe polyamidformmasse |
| CN113831729B (zh) * | 2020-06-24 | 2023-04-07 | 合肥杰事杰新材料股份有限公司 | 一种pa6复合材料及其制备方法 |
| JP7769641B2 (ja) * | 2020-12-25 | 2025-11-13 | 株式会社カネカ | ポリアミド樹脂用添加剤及びポリアミド樹脂組成物 |
Family Cites Families (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE638546A (nl) * | 1962-10-16 | |||
| NL302805A (nl) * | 1962-12-31 | |||
| US3845163A (en) * | 1966-01-24 | 1974-10-29 | Du Pont | Blends of polyamides and ionic copolymer |
| US3971835A (en) * | 1970-07-17 | 1976-07-27 | Rohm And Haas Company | Vinyl halide polymer impact modifiers |
| US3796771A (en) * | 1970-09-10 | 1974-03-12 | Rohm & Haas | Acrylic modifiers for polycarbonamides |
| US3668274A (en) * | 1970-09-10 | 1972-06-06 | Rohm & Haas | Acrylic modifiers for polycarbonamides |
| US4148846A (en) * | 1970-09-10 | 1979-04-10 | Rohm And Haas Company | Acrylic modifiers for polycarbonamides |
| US3984497A (en) * | 1971-12-13 | 1976-10-05 | Rohm And Haas Company | Acrylic modifiers for polycarbonamides |
| US3821145A (en) * | 1972-12-22 | 1974-06-28 | Du Pont | Aqueous coating composition of an acrylic graft copolymer,a linear acrylic polymer and a cross-linking agent |
| DE2454770C2 (de) * | 1974-11-19 | 1985-10-03 | Basf Ag, 6700 Ludwigshafen | Thermoplastische Formmassen mit erhöhter Schlagzähigkeit |
| US4172859A (en) * | 1975-05-23 | 1979-10-30 | E. I. Du Pont De Nemours And Company | Tough thermoplastic polyester compositions |
| US4174358A (en) * | 1975-05-23 | 1979-11-13 | E. I. Du Pont De Nemours And Company | Tough thermoplastic nylon compositions |
| US3985703A (en) * | 1975-06-24 | 1976-10-12 | Rohm And Haas Company | Process for manufacture of acrylic core/shell polymers |
| JPS525553A (en) * | 1975-07-02 | 1977-01-17 | Seiko Instr & Electronics Ltd | Method of producing a layer for a molecular orientation of liquid crys tals |
| DE2653143C2 (de) * | 1976-11-23 | 1985-01-31 | Bayer Ag, 5090 Leverkusen | Thermoplastische Formmassen |
| US4440905A (en) * | 1980-03-31 | 1984-04-03 | Rohm And Haas Company | Dunkelspersers |
| US4478978A (en) * | 1980-10-20 | 1984-10-23 | E. I. Du Pont De Nemours And Company | Toughened polyamide blends |
| US4584344A (en) * | 1980-11-03 | 1986-04-22 | Monsanto Company | Tough thermoplastic nylon compositions |
| US4412040A (en) * | 1981-01-02 | 1983-10-25 | Allied Corporation | Low molecular weight copolymer salts as lubricants in plastics |
| US4463131A (en) * | 1981-06-02 | 1984-07-31 | Rohm And Haas Company | Bulk flowable impact modifiers |
| US4410661A (en) * | 1981-08-21 | 1983-10-18 | E. I. Du Pont De Nemours And Company | Toughened polyamide blends |
| US4474927A (en) * | 1981-12-16 | 1984-10-02 | E. I. Du Pont De Nemours And Company | Polyamide compositions toughened with crosslinked acrylic rubber |
| DE3151441A1 (de) * | 1981-12-24 | 1983-07-14 | Bayer Ag, 5090 Leverkusen | Schlagzaehe polyamid-formmassen |
| DE3210284A1 (de) * | 1982-03-20 | 1983-09-29 | Bayer Ag, 5090 Leverkusen | Polycarbonatabmischungen |
| JPS59122513A (ja) * | 1982-12-28 | 1984-07-16 | Mitsubishi Rayon Co Ltd | 多層構造重合体の製造方法 |
| AU551828B2 (en) * | 1983-02-03 | 1986-05-15 | Mitsubishi Rayon Company Limited | Graft copolymer composition |
| AU551905B2 (en) * | 1983-08-31 | 1986-05-15 | Mitsubishi Rayon Company Limited | Multi-stage graft copolymer composition |
| IE57758B1 (en) * | 1983-08-31 | 1993-03-24 | Mitsubishi Rayon Co | Impact modifier and thermoplastic resin compositions using the same |
| JPS6060158A (ja) * | 1983-09-13 | 1985-04-06 | Asahi Chem Ind Co Ltd | ポリアミド樹脂組成物 |
| DE3403576A1 (de) * | 1984-02-02 | 1985-08-08 | Basf Ag, 6700 Ludwigshafen | Elastomere thermoplastische formmassen und deren herstellung |
| JPS6123644A (ja) * | 1984-06-18 | 1986-02-01 | ゼネラル・エレクトリツク・カンパニイ | イオノマ−性ゴムを含むポリフエニレンオキシドブレンド |
| DE3436362A1 (de) * | 1984-10-04 | 1986-04-10 | Basf Ag, 6700 Ludwigshafen | Schlagzaehe polyamid-formmassen mit verminderter spannungsrissanfaelligkeit |
| US4777211A (en) * | 1985-08-21 | 1988-10-11 | Monsanto Company | Rubber-modified nylon composition |
| EP0272241A3 (en) * | 1986-12-19 | 1989-10-18 | Monsanto Company | Color stable polymer blend |
| JPH0660158A (ja) * | 1992-08-11 | 1994-03-04 | Hitachi Ltd | 画像ファイル用記憶媒体および画像ファイル装置 |
-
1987
- 1987-08-13 CA CA000544423A patent/CA1332992C/en not_active Expired - Fee Related
- 1987-08-18 ZA ZA876110A patent/ZA876110B/xx unknown
- 1987-08-18 MX MX007796A patent/MX168111B/es unknown
- 1987-08-20 NZ NZ221515A patent/NZ221515A/xx unknown
- 1987-08-21 BR BR8704317A patent/BR8704317A/pt unknown
- 1987-08-25 IL IL83649A patent/IL83649A/xx not_active IP Right Cessation
- 1987-08-25 AU AU77402/87A patent/AU600967B2/en not_active Ceased
- 1987-08-26 KR KR1019870009327A patent/KR960010847B1/ko not_active Expired - Fee Related
- 1987-08-27 BE BE8700950A patent/BE1001093A4/fr not_active IP Right Cessation
- 1987-08-27 IT IT8767742A patent/IT1211373B/it active
- 1987-08-27 GB GB08720188A patent/GB2194541A/en not_active Withdrawn
- 1987-08-27 NL NL8702010A patent/NL8702010A/nl not_active Application Discontinuation
- 1987-08-27 LU LU86975A patent/LU86975A1/fr unknown
- 1987-08-27 DE DE19873728685 patent/DE3728685A1/de not_active Withdrawn
- 1987-08-27 EP EP87307578A patent/EP0259097A3/en not_active Withdrawn
- 1987-08-27 JP JP62211534A patent/JP2651825B2/ja not_active Expired - Lifetime
- 1987-08-27 FR FR8711970A patent/FR2603292A1/fr active Pending
-
1993
- 1993-02-26 US US08/023,732 patent/US5332782A/en not_active Expired - Fee Related
-
1994
- 1994-05-03 US US08/237,079 patent/US5457156A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| GB2194541A (en) | 1988-03-09 |
| FR2603292A1 (fr) | 1988-03-04 |
| GB8720188D0 (en) | 1987-10-07 |
| AU7740287A (en) | 1988-03-03 |
| EP0259097A3 (en) | 1989-03-15 |
| US5457156A (en) | 1995-10-10 |
| US5332782A (en) | 1994-07-26 |
| ZA876110B (en) | 1988-04-27 |
| DE3728685A1 (de) | 1988-03-10 |
| JPS6361013A (ja) | 1988-03-17 |
| BE1001093A4 (fr) | 1989-07-11 |
| JP2651825B2 (ja) | 1997-09-10 |
| MX168111B (es) | 1993-05-04 |
| NL8702010A (nl) | 1988-03-16 |
| KR880002929A (ko) | 1988-05-12 |
| IL83649A0 (en) | 1988-01-31 |
| BR8704317A (pt) | 1988-04-19 |
| KR960010847B1 (ko) | 1996-08-09 |
| IT1211373B (it) | 1989-10-18 |
| CA1332992C (en) | 1994-11-08 |
| NZ221515A (en) | 1990-09-26 |
| AU600967B2 (en) | 1990-08-30 |
| EP0259097A2 (en) | 1988-03-09 |
| IL83649A (en) | 1991-05-12 |
| IT8767742A0 (it) | 1987-08-27 |
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