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DE69911195D1 - Verfahren zur direktoxidation von olefinen zu olefinoxiden - Google Patents

Verfahren zur direktoxidation von olefinen zu olefinoxiden

Info

Publication number
DE69911195D1
DE69911195D1 DE69911195T DE69911195T DE69911195D1 DE 69911195 D1 DE69911195 D1 DE 69911195D1 DE 69911195 T DE69911195 T DE 69911195T DE 69911195 T DE69911195 T DE 69911195T DE 69911195 D1 DE69911195 D1 DE 69911195D1
Authority
DE
Germany
Prior art keywords
olefinoxides
olefines
direct oxidation
oxidation
direct
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69911195T
Other languages
English (en)
Other versions
DE69911195T2 (de
Inventor
Alex Kuperman
G Bowman
W Clark
E Hartwell
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
Original Assignee
Dow Global Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies LLC filed Critical Dow Global Technologies LLC
Application granted granted Critical
Publication of DE69911195D1 publication Critical patent/DE69911195D1/de
Publication of DE69911195T2 publication Critical patent/DE69911195T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/085—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B01J29/26—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/50—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952
    • B01J29/58—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B01J29/69—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
DE69911195T 1998-04-15 1999-04-07 Verfahren zur direktoxidation von olefinen zu olefinoxiden Expired - Lifetime DE69911195T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US8182698P 1998-04-15 1998-04-15
US81826P 1998-04-15
PCT/US1999/007714 WO1999052883A1 (en) 1998-04-15 1999-04-07 Process for the direct oxidation of olefins to olefin oxides

Publications (2)

Publication Number Publication Date
DE69911195D1 true DE69911195D1 (de) 2003-10-16
DE69911195T2 DE69911195T2 (de) 2004-07-15

Family

ID=22166643

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69911195T Expired - Lifetime DE69911195T2 (de) 1998-04-15 1999-04-07 Verfahren zur direktoxidation von olefinen zu olefinoxiden

Country Status (11)

Country Link
US (1) US6362349B1 (de)
EP (1) EP1073649B1 (de)
JP (1) JP4578679B2 (de)
KR (1) KR100565026B1 (de)
CN (1) CN100334079C (de)
AU (1) AU3387099A (de)
BR (1) BR9909604B1 (de)
DE (1) DE69911195T2 (de)
ES (1) ES2203109T3 (de)
ID (1) ID26171A (de)
WO (1) WO1999052883A1 (de)

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US6323351B1 (en) 1997-06-30 2001-11-27 The Dow Chemical Company Process for the direct oxidation of olefins to olefin oxides
US6562986B2 (en) * 1997-06-30 2003-05-13 Dow Global Technologies, Inc. Process for the direct oxidation of olefins to olefin oxides
ID29813A (id) 1998-12-16 2001-10-11 Dow Chemical Co Proses untuk oksidasi langsung olefin menjadi olefin oksida
US6821923B1 (en) 1999-04-08 2004-11-23 Dow Global Technologies Inc. Method of preparing a catalyst containing gold and titanium
DE60008235T2 (de) 1999-04-08 2004-12-02 Dow Global Technologies, Inc., Midland Verfahren für die oxidierung von olefinen zu olefinoxiden unter verwendung eines oxidierten gold-katalysators
US6063942A (en) * 1999-09-27 2000-05-16 Arco Chemical Technology, L.P. Catalyst preparation and epoxidation process
KR100746941B1 (ko) * 2000-02-22 2007-08-07 아르코 케미컬 테크날러쥐. 엘.피. 개선된 촉매 조성물을 이용한 직접적 에폭시화 방법
US6534621B2 (en) 2000-05-18 2003-03-18 Dow Global Technologies Inc. Process for manufacturing a hydroxyester derivative intermediate and epoxy resins prepared therefrom
US6281369B1 (en) * 2000-12-07 2001-08-28 Arco Chemical Technology, L.P. Epoxidation catalyst and process
AU2002317607A1 (en) 2001-08-01 2003-02-17 Dow Global Technologies Inc. Method of increasing the lifetime of a hydro-oxidation catalyst
DE10201241A1 (de) * 2002-01-15 2003-07-24 Bayer Ag Katalysator
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US7615654B2 (en) * 2005-10-20 2009-11-10 Lyondell Chemical Technology, L.P. Direct epoxidation process
US7649101B2 (en) * 2005-10-25 2010-01-19 University Of Kansas Process for selective oxidation of olefins to epoxides
US7432384B2 (en) * 2005-10-25 2008-10-07 Lyondell Chemical Technology, L.P. Direct epoxidation process
US7459589B2 (en) 2005-12-22 2008-12-02 Shell Oil Company Process for the preparation of an alkylene glycol
US8357812B2 (en) 2005-12-22 2013-01-22 Shell Oil Company Process for preparing a rejuvenated epoxidation catalyst
US7704908B2 (en) 2005-12-22 2010-04-27 Shell Oil Company Method for reusing rhenium from a donor spent epoxidation catalyst
US7365217B2 (en) * 2006-01-25 2008-04-29 Lyondell Chemical Technology, L.P. Oxidation process
US7238817B1 (en) 2006-02-22 2007-07-03 Lyondell Chemical Technology, L.P. Direct epoxidation process
US7595410B2 (en) * 2006-07-18 2009-09-29 Lyondell Chemical Technology, L.P. Direct epoxidation process using improved catalyst composition
MX2009005173A (es) * 2006-11-17 2009-05-25 Dow Global Technologies Inc Proceso de hidroxidacion usando un catalizador peprarado a partir de un complejo de grupo oro.
US7381675B1 (en) 2006-12-19 2008-06-03 Lyondell Chemical Technology, L.P. Direct epoxidation catalyst
US7563740B2 (en) * 2006-12-19 2009-07-21 Lyondell Chemical Technology, L.P. Direct epoxidation process
JP5542659B2 (ja) 2007-05-09 2014-07-09 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー エポキシ化触媒、触媒を調製する方法、および酸化オレフィン、１，２−ジオール、１，２−ジオールエーテル、１，２−カーボネートまたはアルカノールアミンの製造方法
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KR101629037B1 (ko) 2008-05-07 2016-06-09 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 에폭시화 방법의 스타트업 방법, 산화에틸렌, 1,2-디올, 1,2-디올 에테르, 1,2-카보네이트 또는 알칸올아민의 생산방법
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WO2013025316A1 (en) * 2011-08-17 2013-02-21 Sumitomo Chemical Company, Limited Process for producing olefin oxide
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CN107960063B (zh) * 2015-08-28 2021-08-24 利安德化学技术有限公司 环氧化工艺及其使用的催化剂
BR112019011162B1 (pt) 2016-12-02 2022-08-16 Shell Internationale Research Maatschappij B.V. Método para o condicionamento de um catalisador de epoxidação de etileno e método para melhorar a seletividade do referido catalisador em um processo de epoxidação de etileno
CN107570208B (zh) * 2017-08-31 2020-08-25 昆明理工大学 一种环氧化反应催化剂的制备方法及应用
CN110964131B (zh) * 2018-09-29 2022-11-22 诺维新材有限公司 含有多羟基的聚合物及其制备方法和用途
CN113912568B (zh) * 2020-07-10 2023-12-29 中国石油化工股份有限公司 可提高极限氧含量的制环氧丙烷的方法
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Also Published As

Publication number Publication date
DE69911195T2 (de) 2004-07-15
BR9909604B1 (pt) 2011-10-18
EP1073649B1 (de) 2003-09-10
ES2203109T3 (es) 2004-04-01
AU3387099A (en) 1999-11-01
BR9909604A (pt) 2000-11-21
CN1297443A (zh) 2001-05-30
US6362349B1 (en) 2002-03-26
KR20010042699A (ko) 2001-05-25
JP4578679B2 (ja) 2010-11-10
ID26171A (id) 2000-11-30
KR100565026B1 (ko) 2006-03-30
CN100334079C (zh) 2007-08-29
WO1999052883A1 (en) 1999-10-21
JP2002511453A (ja) 2002-04-16
EP1073649A1 (de) 2001-02-07

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