DE60308661T2 - Prozess zur behandlung von textilen fasermaterialien - Google Patents

Prozess zur behandlung von textilen fasermaterialien Download PDF

Info

Publication number: DE60308661T2
Authority: DE; Germany
Prior art keywords: alkyl; unsubstituted; substituted; hydrogen; formula
Prior art date: 2002-02-25
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

DE60308661T

Other languages

German (de)

English (en)

Other versions

DE60308661D1 (de

Inventor

Jürgen Kaschig

Robert Hochberg

Oliver Becherer

Georges Metzger

Claude Eckhardt

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BASF Schweiz AG

Original Assignee

Ciba Spezialitaetenchemie Holding AG

Ciba SC Holding AG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2002-02-25

Filing date

2003-02-18

Publication date

2007-08-09

2003-02-18 Application filed by Ciba Spezialitaetenchemie Holding AG, Ciba SC Holding AG filed Critical Ciba Spezialitaetenchemie Holding AG

2006-11-09 Publication of DE60308661D1 publication Critical patent/DE60308661D1/de

2007-08-09 Application granted granted Critical

2007-08-09 Publication of DE60308661T2 publication Critical patent/DE60308661T2/de

2023-02-19 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000004753 textile Substances 0.000 title claims description 17
238000000034 method Methods 0.000 title claims description 14
239000002657 fibrous material Substances 0.000 title 1
150000001875 compounds Chemical class 0.000 claims description 56
239000000203 mixture Substances 0.000 claims description 53
239000003599 detergent Substances 0.000 claims description 30
229910052739 hydrogen Inorganic materials 0.000 claims description 29
239000001257 hydrogen Substances 0.000 claims description 29
NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical class C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 claims description 26
-1 hydroxy, carboxy Chemical group 0.000 claims description 26
YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Natural products C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 22
150000002978 peroxides Chemical class 0.000 claims description 19
125000000217 alkyl group Chemical group 0.000 claims description 16
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 15
229910052757 nitrogen Inorganic materials 0.000 claims description 15
RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical class C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 claims description 14
229920000742 Cotton Polymers 0.000 claims description 13
125000004433 nitrogen atom Chemical group N* 0.000 claims description 13
239000011734 sodium Substances 0.000 claims description 13
150000002780 morpholines Chemical class 0.000 claims description 12
150000002431 hydrogen Chemical class 0.000 claims description 11
102000004190 Enzymes Human genes 0.000 claims description 10
108090000790 Enzymes Proteins 0.000 claims description 10
239000012190 activator Substances 0.000 claims description 10
239000007844 bleaching agent Substances 0.000 claims description 10
229940088598 enzyme Drugs 0.000 claims description 10
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 10
229910052708 sodium Inorganic materials 0.000 claims description 9
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 8
125000004093 cyano group Chemical group *C#N 0.000 claims description 8
239000002736 nonionic surfactant Substances 0.000 claims description 8
210000002268 wool Anatomy 0.000 claims description 8
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 7
239000000463 material Substances 0.000 claims description 7
125000004209 (C1-C8) alkyl group Chemical group 0.000 claims description 6
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 6
108091005804 Peptidases Proteins 0.000 claims description 6
239000004952 Polyamide Substances 0.000 claims description 6
239000004365 Protease Substances 0.000 claims description 6
229910052784 alkaline earth metal Inorganic materials 0.000 claims description 6
239000003945 anionic surfactant Substances 0.000 claims description 6
229920002647 polyamide Polymers 0.000 claims description 6
125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims description 6
150000001342 alkaline earth metals Chemical class 0.000 claims description 5
125000003545 alkoxy group Chemical group 0.000 claims description 5
150000001768 cations Chemical group 0.000 claims description 5
125000000113 cyclohexyl group Chemical class [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 5
229910052736 halogen Inorganic materials 0.000 claims description 5
150000002367 halogens Chemical class 0.000 claims description 5
239000003054 catalyst Substances 0.000 claims description 4
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
102000013142 Amylases Human genes 0.000 claims description 3
108010065511 Amylases Proteins 0.000 claims description 3
102000004882 Lipase Human genes 0.000 claims description 3
239000004367 Lipase Substances 0.000 claims description 3
108090001060 Lipase Proteins 0.000 claims description 3
239000003513 alkali Substances 0.000 claims description 3
235000019418 amylase Nutrition 0.000 claims description 3
125000000753 cycloalkyl group Chemical group 0.000 claims description 3
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
235000019421 lipase Nutrition 0.000 claims description 3
230000002087 whitening effect Effects 0.000 claims description 2
102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims 2
239000004382 Amylase Substances 0.000 claims 1
108010059892 Cellulase Proteins 0.000 claims 1
229940106157 cellulase Drugs 0.000 claims 1
230000003287 optical effect Effects 0.000 claims 1
235000019419 proteases Nutrition 0.000 claims 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 27
238000005406 washing Methods 0.000 description 24
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
239000012459 cleaning agent Substances 0.000 description 13
239000000835 fiber Substances 0.000 description 13
125000004432 carbon atom Chemical group C* 0.000 description 11
239000000843 powder Substances 0.000 description 11
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 10
239000004744 fabric Substances 0.000 description 10
238000002360 preparation method Methods 0.000 description 10
239000011541 reaction mixture Substances 0.000 description 10
239000002253 acid Substances 0.000 description 8
239000003826 tablet Substances 0.000 description 7
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
229910052783 alkali metal Inorganic materials 0.000 description 6
239000003795 chemical substances by application Substances 0.000 description 6
239000007788 liquid Substances 0.000 description 6
239000000047 product Substances 0.000 description 6
102000005575 Cellulases Human genes 0.000 description 5
108010084185 Cellulases Proteins 0.000 description 5
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
150000007513 acids Chemical class 0.000 description 5
150000001340 alkali metals Chemical group 0.000 description 5
239000002244 precipitate Substances 0.000 description 5
239000011780 sodium chloride Substances 0.000 description 5
125000001424 substituent group Chemical group 0.000 description 5
229920002994 synthetic fiber Polymers 0.000 description 5
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 4
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 4
102000035195 Peptidases Human genes 0.000 description 4
229920000297 Rayon Polymers 0.000 description 4
229910052801 chlorine Inorganic materials 0.000 description 4
239000000460 chlorine Substances 0.000 description 4
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Natural products OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 4
229910052751 metal Inorganic materials 0.000 description 4
239000002184 metal Substances 0.000 description 4
229920000642 polymer Polymers 0.000 description 4
125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 4
150000003839 salts Chemical class 0.000 description 4
159000000000 sodium salts Chemical class 0.000 description 4
239000012209 synthetic fiber Substances 0.000 description 4
REJHVSOVQBJEBF-OWOJBTEDSA-N 5-azaniumyl-2-[(e)-2-(4-azaniumyl-2-sulfonatophenyl)ethenyl]benzenesulfonate Chemical compound OS(=O)(=O)C1=CC(N)=CC=C1\C=C\C1=CC=C(N)C=C1S(O)(=O)=O REJHVSOVQBJEBF-OWOJBTEDSA-N 0.000 description 3
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
229920002134 Carboxymethyl cellulose Polymers 0.000 description 3
REJHVSOVQBJEBF-UHFFFAOYSA-N DSD-acid Natural products OS(=O)(=O)C1=CC(N)=CC=C1C=CC1=CC=C(N)C=C1S(O)(=O)=O REJHVSOVQBJEBF-UHFFFAOYSA-N 0.000 description 3
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
239000001768 carboxy methyl cellulose Substances 0.000 description 3
235000010948 carboxy methyl cellulose Nutrition 0.000 description 3
239000008112 carboxymethyl-cellulose Substances 0.000 description 3
229920002678 cellulose Polymers 0.000 description 3
239000001913 cellulose Substances 0.000 description 3
MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 3
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
239000000975 dye Substances 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 3
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
239000007787 solid Substances 0.000 description 3
XDFFTQFZNBRIQC-TZLZSRMRSA-N (18R,19S,20R,21R)-18,19,20-trihexadecyl-18,19,20,21-tetrahydroxy-21-(hydroxymethyl)heptatriacontan-17-one Chemical compound C(CCCCCCCCCCCCCCC)[C@@]([C@]([C@@]([C@](C(=O)CCCCCCCCCCCCCCCC)(O)CCCCCCCCCCCCCCCC)(O)CCCCCCCCCCCCCCCC)(O)CCCCCCCCCCCCCCCC)(O)CO XDFFTQFZNBRIQC-TZLZSRMRSA-N 0.000 description 2
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 2
MIJDSYMOBYNHOT-UHFFFAOYSA-N 2-(ethylamino)ethanol Chemical compound CCNCCO MIJDSYMOBYNHOT-UHFFFAOYSA-N 0.000 description 2
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 2
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
0 C*CC([C@@](C)*)C(C=Cc(cc1)ccc1-c1ccc(C=CC2=C(CC3OC3)C=C*(*)C=C2)cc1)=CC=CCC=* Chemical compound C*CC([C@@](C)*)C(C=Cc(cc1)ccc1-c1ccc(C=CC2=C(CC3OC3)C=C*(*)C=C2)cc1)=CC=CCC=* 0.000 description 2
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
241000208202 Linaceae Species 0.000 description 2
235000004431 Linum usitatissimum Nutrition 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
229910021536 Zeolite Inorganic materials 0.000 description 2
239000002671 adjuvant Substances 0.000 description 2
150000008051 alkyl sulfates Chemical class 0.000 description 2
229910000323 aluminium silicate Inorganic materials 0.000 description 2
150000001412 amines Chemical class 0.000 description 2
229940025131 amylases Drugs 0.000 description 2
210000000077 angora Anatomy 0.000 description 2
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
229910052794 bromium Inorganic materials 0.000 description 2
150000007942 carboxylates Chemical class 0.000 description 2
210000000085 cashmere Anatomy 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
238000001816 cooling Methods 0.000 description 2
235000014113 dietary fatty acids Nutrition 0.000 description 2
230000000694 effects Effects 0.000 description 2
125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 2
239000000194 fatty acid Substances 0.000 description 2
229930195729 fatty acid Natural products 0.000 description 2
229910052731 fluorine Inorganic materials 0.000 description 2
239000011737 fluorine Substances 0.000 description 2
238000009472 formulation Methods 0.000 description 2
238000007429 general method Methods 0.000 description 2
235000011187 glycerol Nutrition 0.000 description 2
239000008187 granular material Substances 0.000 description 2
125000000623 heterocyclic group Chemical group 0.000 description 2
WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
239000004615 ingredient Substances 0.000 description 2
239000003446 ligand Substances 0.000 description 2
210000000050 mohair Anatomy 0.000 description 2
UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 2
229920002239 polyacrylonitrile Polymers 0.000 description 2
229920005646 polycarboxylate Polymers 0.000 description 2
229920000728 polyester Polymers 0.000 description 2
229910052700 potassium Inorganic materials 0.000 description 2
239000002964 rayon Substances 0.000 description 2
150000003333 secondary alcohols Chemical class 0.000 description 2
150000004760 silicates Chemical class 0.000 description 2
239000004094 surface-active agent Substances 0.000 description 2
239000000725 suspension Substances 0.000 description 2
239000008399 tap water Substances 0.000 description 2
235000020679 tap water Nutrition 0.000 description 2
URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 2
235000013311 vegetables Nutrition 0.000 description 2
239000010457 zeolite Substances 0.000 description 2
DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
FFLHFURRPPIZTQ-UHFFFAOYSA-N (5-acetyloxy-2,5-dihydrofuran-2-yl) acetate Chemical compound CC(=O)OC1OC(OC(C)=O)C=C1 FFLHFURRPPIZTQ-UHFFFAOYSA-N 0.000 description 1
ZQEOKONOFKQRIR-NUEKZKHPSA-N (5R,6R,7R)-3,5,6-triacetyl-3,5,6,7-tetrahydroxy-7-(hydroxymethyl)nonane-2,4,8-trione Chemical compound C(C)(=O)[C@@]([C@]([C@@](C(C(O)(C(C)=O)C(C)=O)=O)(O)C(C)=O)(O)C(C)=O)(O)CO ZQEOKONOFKQRIR-NUEKZKHPSA-N 0.000 description 1
125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
LYPVKWMHGFMDPD-UHFFFAOYSA-N 1,5-diacetyl-1,3,5-triazinane-2,4-dione Chemical compound CC(=O)N1CN(C(C)=O)C(=O)NC1=O LYPVKWMHGFMDPD-UHFFFAOYSA-N 0.000 description 1
JTXMVXSTHSMVQF-UHFFFAOYSA-N 2-acetyloxyethyl acetate Chemical compound CC(=O)OCCOC(C)=O JTXMVXSTHSMVQF-UHFFFAOYSA-N 0.000 description 1
MHKLKWCYGIBEQF-UHFFFAOYSA-N 4-(1,3-benzothiazol-2-ylsulfanyl)morpholine Chemical compound C1COCCN1SC1=NC2=CC=CC=C2S1 MHKLKWCYGIBEQF-UHFFFAOYSA-N 0.000 description 1
KFDYZSPFVRTLML-UHFFFAOYSA-N 5-[(4-chloro-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[2-[4-[(4-chloro-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound C=1C=C(C=CC=2C(=CC(NC=3N=C(N=C(Cl)N=3)N3CCOCC3)=CC=2)S(O)(=O)=O)C(S(=O)(=O)O)=CC=1NC(N=1)=NC(Cl)=NC=1N1CCOCC1 KFDYZSPFVRTLML-UHFFFAOYSA-N 0.000 description 1
244000025254 Cannabis sativa Species 0.000 description 1
RKWGIWYCVPQPMF-UHFFFAOYSA-N Chloropropamide Chemical compound CCCNC(=O)NS(=O)(=O)C1=CC=C(Cl)C=C1 RKWGIWYCVPQPMF-UHFFFAOYSA-N 0.000 description 1
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
GUBGYTABKSRVRQ-CUHNMECISA-N D-Cellobiose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-CUHNMECISA-N 0.000 description 1
FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
PHOQVHQSTUBQQK-SQOUGZDYSA-N D-glucono-1,5-lactone Chemical compound OC[C@H]1OC(=O)[C@H](O)[C@@H](O)[C@@H]1O PHOQVHQSTUBQQK-SQOUGZDYSA-N 0.000 description 1
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
229930195725 Mannitol Natural products 0.000 description 1
WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
150000001204 N-oxides Chemical class 0.000 description 1
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
WFRXSOIFNFJAFL-UHFFFAOYSA-N P1(OCCCCO1)=O.C(CN)N Chemical class P1(OCCCCO1)=O.C(CN)N WFRXSOIFNFJAFL-UHFFFAOYSA-N 0.000 description 1
235000019482 Palm oil Nutrition 0.000 description 1
XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Natural products P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 1
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
239000004902 Softening Agent Substances 0.000 description 1
229920002472 Starch Polymers 0.000 description 1
CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
229930006000 Sucrose Natural products 0.000 description 1
239000013543 active substance Substances 0.000 description 1
239000000654 additive Substances 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
229910000318 alkali metal phosphate Inorganic materials 0.000 description 1
229910052910 alkali metal silicate Inorganic materials 0.000 description 1
229910052915 alkaline earth metal silicate Inorganic materials 0.000 description 1
125000003342 alkenyl group Chemical group 0.000 description 1
150000004996 alkyl benzenes Chemical class 0.000 description 1
125000005263 alkylenediamine group Polymers 0.000 description 1
125000003277 amino group Chemical group 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
239000002216 antistatic agent Substances 0.000 description 1
238000010936 aqueous wash Methods 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
229940077388 benzenesulfonate Drugs 0.000 description 1
125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
239000008280 blood Substances 0.000 description 1
210000004369 blood Anatomy 0.000 description 1
239000000872 buffer Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
125000002843 carboxylic acid group Chemical group 0.000 description 1
239000000969 carrier Substances 0.000 description 1
150000001860 citric acid derivatives Chemical class 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
238000000576 coating method Methods 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
239000008367 deionised water Substances 0.000 description 1
229910021641 deionized water Inorganic materials 0.000 description 1
150000001991 dicarboxylic acids Chemical class 0.000 description 1
HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
238000001035 drying Methods 0.000 description 1
230000008030 elimination Effects 0.000 description 1
238000003379 elimination reaction Methods 0.000 description 1
230000002255 enzymatic effect Effects 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
239000000945 filler Substances 0.000 description 1
239000000834 fixative Substances 0.000 description 1
239000012530 fluid Substances 0.000 description 1
239000006260 foam Substances 0.000 description 1
239000004088 foaming agent Substances 0.000 description 1
239000003205 fragrance Substances 0.000 description 1
235000015203 fruit juice Nutrition 0.000 description 1
235000012209 glucono delta-lactone Nutrition 0.000 description 1
229960003681 gluconolactone Drugs 0.000 description 1
239000008103 glucose Substances 0.000 description 1
239000001087 glyceryl triacetate Substances 0.000 description 1
235000013773 glyceryl triacetate Nutrition 0.000 description 1
125000001046 glycoluril group Chemical group [H]C12N(*)C(=O)N(*)C1([H])N(*)C(=O)N2* 0.000 description 1
238000005469 granulation Methods 0.000 description 1
230000003179 granulation Effects 0.000 description 1
125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
239000013067 intermediate product Substances 0.000 description 1
PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
150000002505 iron Chemical class 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
239000008101 lactose Substances 0.000 description 1
230000031700 light absorption Effects 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
229910052748 manganese Inorganic materials 0.000 description 1
239000011572 manganese Substances 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
239000000594 mannitol Substances 0.000 description 1
235000010355 mannitol Nutrition 0.000 description 1
235000013336 milk Nutrition 0.000 description 1
239000008267 milk Substances 0.000 description 1
210000004080 milk Anatomy 0.000 description 1
DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
238000010979 pH adjustment Methods 0.000 description 1
239000002540 palm oil Substances 0.000 description 1
125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
150000004965 peroxy acids Chemical class 0.000 description 1
JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
229910000073 phosphorus hydride Inorganic materials 0.000 description 1
239000000049 pigment Substances 0.000 description 1
229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 1
229920002006 poly(N-vinylimidazole) polymer Polymers 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
229920000151 polyglycol Polymers 0.000 description 1
239000010695 polyglycol Substances 0.000 description 1
229920005862 polyol Polymers 0.000 description 1
150000003077 polyols Chemical class 0.000 description 1
229920000166 polytrimethylene carbonate Polymers 0.000 description 1
229920002717 polyvinylpyridine Polymers 0.000 description 1
229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
239000011591 potassium Substances 0.000 description 1
239000002243 precursor Substances 0.000 description 1
125000000075 primary alcohol group Chemical group 0.000 description 1
150000003138 primary alcohols Chemical class 0.000 description 1
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
235000013772 propylene glycol Nutrition 0.000 description 1
102000004169 proteins and genes Human genes 0.000 description 1
108090000623 proteins and genes Proteins 0.000 description 1
125000000719 pyrrolidinyl group Chemical class 0.000 description 1
230000000630 rising effect Effects 0.000 description 1
125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
229910021647 smectite Inorganic materials 0.000 description 1
239000000344 soap Substances 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
235000019832 sodium triphosphate Nutrition 0.000 description 1
239000002689 soil Substances 0.000 description 1
239000013042 solid detergent Substances 0.000 description 1
239000002195 soluble material Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000000600 sorbitol Substances 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
238000010186 staining Methods 0.000 description 1
239000008107 starch Substances 0.000 description 1
235000019698 starch Nutrition 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000005720 sucrose Substances 0.000 description 1
150000005846 sugar alcohols Polymers 0.000 description 1
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
239000000375 suspending agent Substances 0.000 description 1
230000008961 swelling Effects 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 description 1
238000012546 transfer Methods 0.000 description 1
229960002622 triacetin Drugs 0.000 description 1
150000003918 triazines Chemical class 0.000 description 1
UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Detergent Compositions (AREA)
Cleaning By Liquid Or Steam (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

DE60308661T 2002-02-25 2003-02-18 Prozess zur behandlung von textilen fasermaterialien Expired - Lifetime DE60308661T2 (de)

Applications Claiming Priority (5)

Application Number	Priority Date	Filing Date	Title
EP02405136		2002-02-25
EP02405136		2002-02-25
EP02405876		2002-10-11
EP02405876		2002-10-11
PCT/EP2003/001618 WO2003070869A1 (en)	2002-02-25	2003-02-18	Process for the treatment of textile fibre materials

Publications (2)

Publication Number	Publication Date
DE60308661D1 DE60308661D1 (de)	2006-11-09
DE60308661T2 true DE60308661T2 (de)	2007-08-09

Family

ID=27758773

Family Applications (2)

Application Number	Title	Priority Date	Filing Date
DE60308661T Expired - Lifetime DE60308661T2 (de)	2002-02-25	2003-02-18	Prozess zur behandlung von textilen fasermaterialien
DE60308485T Expired - Lifetime DE60308485T2 (de)	2002-02-25	2003-02-18	Prozess zum behandeln von textilen fasermaterialien

Family Applications After (1)

Application Number	Title	Priority Date	Filing Date
DE60308485T Expired - Lifetime DE60308485T2 (de)	2002-02-25	2003-02-18	Prozess zum behandeln von textilen fasermaterialien

Country Status (12)

Country	Link
EP (4)	EP1485460B1 (zh)
JP (2)	JP4567975B2 (zh)
CN (2)	CN1294247C (zh)
AR (3)	AR038582A1 (zh)
AT (2)	ATE340242T1 (zh)
AU (2)	AU2003208870B2 (zh)
BR (3)	BR0306187A (zh)
DE (2)	DE60308661T2 (zh)
ES (3)	ES2556971T3 (zh)
TW (2)	TWI324177B (zh)
WO (2)	WO2003070869A1 (zh)
ZA (2)	ZA200402941B (zh)

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US7863236B2 (en) *	2003-03-24	2011-01-04	Ciba Specialty Chemicals Corp.	Detergent compositions
WO2005068597A1 (en) *	2004-01-20	2005-07-28	Ciba Specialty Chemicals Holding Inc.	Triazinylaminostilbene disulphonic acid mixtures
KR20070011437A (ko) *	2004-04-20	2007-01-24	시바 스폐셜티 케미칼스 홀딩 인코포레이티드	세제 배합물 중 양쪽성 형광 증백제
KR101253657B1 (ko) *	2004-08-30	2013-04-10	시바 홀딩 인코포레이티드	셰이딩 방법
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CN104801511B (zh) *	2014-01-26	2018-09-18	艺康美国股份有限公司	原位清洗工艺和原位清洗系统
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CN107857738A (zh) *	2017-11-28	2018-03-30	贺州学院	十六烷基氨基三嗪衍生物的合成与应用

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2003
- 2003-02-18 JP JP2003569763A patent/JP4567975B2/ja not_active Expired - Fee Related
- 2003-02-18 CN CNB038016044A patent/CN1294247C/zh not_active Expired - Lifetime
- 2003-02-18 WO PCT/EP2003/001618 patent/WO2003070869A1/en not_active Ceased
- 2003-02-18 BR BR0306187-6A patent/BR0306187A/pt active IP Right Grant
- 2003-02-18 EP EP03702652A patent/EP1485460B1/en not_active Expired - Lifetime
- 2003-02-18 EP EP06118792.8A patent/EP1715029B1/en not_active Expired - Lifetime
- 2003-02-18 AT AT03706527T patent/ATE340242T1/de active
- 2003-02-18 DE DE60308661T patent/DE60308661T2/de not_active Expired - Lifetime
- 2003-02-18 DE DE60308485T patent/DE60308485T2/de not_active Expired - Lifetime
- 2003-02-18 AU AU2003208870A patent/AU2003208870B2/en not_active Ceased
- 2003-02-18 BR BRPI0306187-6A patent/BRPI0306187B1/pt unknown
- 2003-02-18 ES ES06118792.8T patent/ES2556971T3/es not_active Expired - Lifetime
- 2003-02-18 ES ES03702652T patent/ES2271529T3/es not_active Expired - Lifetime
- 2003-02-18 BR BRPI0306184-1B1A patent/BR0306184B1/pt active IP Right Grant
- 2003-02-18 CN CNB038016168A patent/CN1294248C/zh not_active Expired - Lifetime
- 2003-02-18 WO PCT/EP2003/001619 patent/WO2003070870A1/en not_active Ceased
- 2003-02-18 EP EP03706527A patent/EP1478724B1/en not_active Expired - Lifetime
- 2003-02-18 JP JP2003569764A patent/JP4567976B2/ja not_active Expired - Fee Related
- 2003-02-18 AU AU2003205777A patent/AU2003205777B2/en not_active Ceased
- 2003-02-18 EP EP06118810A patent/EP1724333A1/en not_active Withdrawn
- 2003-02-18 AT AT03702652T patent/ATE340847T1/de active
- 2003-02-18 ES ES03706527T patent/ES2271534T3/es not_active Expired - Lifetime
- 2003-02-21 AR ARP030100572A patent/AR038582A1/es active IP Right Grant
- 2003-02-21 AR ARP030100573A patent/AR038583A1/es active IP Right Grant
- 2003-02-24 TW TW092103773A patent/TWI324177B/zh not_active IP Right Cessation
- 2003-02-24 TW TW092103771A patent/TWI332045B/zh not_active IP Right Cessation
2004
- 2004-04-19 ZA ZA2004/02941A patent/ZA200402941B/en unknown
- 2004-04-19 ZA ZA2004/02942A patent/ZA200402942B/en unknown
2007
- 2007-08-14 AR ARP070103604A patent/AR067835A2/es active IP Right Grant

Also Published As

Publication number	Publication date
BR0306184B1 (pt)	2013-08-27
ES2271529T3 (es)	2007-04-16
BRPI0306187B1 (pt)	2021-01-12
AU2003205777B2 (en)	2008-01-31
BR0306187A (pt)	2004-10-19
EP1478724B1 (en)	2006-09-20
BR0306184A (pt)	2004-10-19
EP1715029A3 (en)	2009-04-01
CN1294247C (zh)	2007-01-10
EP1715029A2 (en)	2006-10-25
TW200303386A (en)	2003-09-01
CN1596299A (zh)	2005-03-16
DE60308485D1 (de)	2006-11-02
AR038583A1 (es)	2005-01-19
AR038582A1 (es)	2005-01-19
TWI332045B (en)	2010-10-21
TW200303358A (en)	2003-09-01
ES2271534T3 (es)	2007-04-16
JP2005517801A (ja)	2005-06-16
ATE340242T1 (de)	2006-10-15
ZA200402941B (en)	2005-02-23
JP4567976B2 (ja)	2010-10-27
DE60308661D1 (de)	2006-11-09
ES2556971T3 (es)	2016-01-21
AU2003208870A1 (en)	2003-09-09
EP1485460B1 (en)	2006-09-27
TWI324177B (en)	2010-05-01
JP4567975B2 (ja)	2010-10-27
EP1724333A1 (en)	2006-11-22
JP2005517800A (ja)	2005-06-16
AR067835A2 (es)	2009-10-28
WO2003070869A1 (en)	2003-08-28
AU2003208870B2 (en)	2008-05-15
ZA200402942B (en)	2005-02-23
CN1294248C (zh)	2007-01-10
AU2003205777A1 (en)	2003-09-09
WO2003070870A1 (en)	2003-08-28
EP1715029B1 (en)	2015-09-23
EP1485460A1 (en)	2004-12-15
DE60308485T2 (de)	2007-09-06
EP1478724A1 (en)	2004-11-24
ATE340847T1 (de)	2006-10-15
CN1596300A (zh)	2005-03-16

Publication	Publication Date	Title
DE602004004904T2 (de)	2007-10-31	Nuancierungsmittel
DE602004005839T2 (de)	2007-09-06	Waschmittelzusammensetzungen
DE60308661T2 (de)	2007-08-09	Prozess zur behandlung von textilen fasermaterialien
EP2024480B1 (en)	2010-09-29	A detergent composition for textile fibre materials
EP1592675B1 (en)	2008-10-08	Crystalline modifications of triazinylaminostilbenes
BRPI0712671B1 (pt)	2017-08-08	Detergent composition for textile fiber materials, process for the treatment of domestic washing of textile fiber material, and process for the fluorescent blanking of textile materials

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Date	Code	Title	Description
2007-11-15	8364	No opposition during term of opposition
2008-10-16	8327	Change in the person/name/address of the patent owner	Owner name: CIBA HOLDING INC., BASEL, CH