DE3039543A1 - Verfahren zur herstellung von pvc-harzen - Google Patents

Verfahren zur herstellung von pvc-harzen

Info

Publication number: DE3039543A1
Authority: DE; Germany
Prior art keywords: acid; polymerization; direct; thiocyanate; water
Prior art date: 1979-10-22
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Withdrawn

Application number

DE19803039543

Other languages

German (de)

English (en)

Inventor

Ken Tokyo Itoh

Ichiro Ibaraki Kaneko

Hajime Ichihara Chiba Kitamura

Toshihide Chiba Shimizu

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Shin Etsu Chemical Co Ltd

Original Assignee

Shin Etsu Chemical Co Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-10-22

Filing date

1980-10-20

Publication date

1981-09-10

1980-10-20 Application filed by Shin Etsu Chemical Co Ltd filed Critical Shin Etsu Chemical Co Ltd

1981-09-10 Publication of DE3039543A1 publication Critical patent/DE3039543A1/de

Status Withdrawn legal-status Critical Current

Links

229920005989 resin Polymers 0.000 title claims description 23
239000011347 resin Substances 0.000 title claims description 23
238000004519 manufacturing process Methods 0.000 title claims description 6
238000006116 polymerization reaction Methods 0.000 claims description 82
238000000576 coating method Methods 0.000 claims description 55
239000011248 coating agent Substances 0.000 claims description 52
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 33
239000000178 monomer Substances 0.000 claims description 32
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 29
238000000034 method Methods 0.000 claims description 29
239000000203 mixture Substances 0.000 claims description 29
150000001451 organic peroxides Chemical class 0.000 claims description 27
239000003505 polymerization initiator Substances 0.000 claims description 24
230000008569 process Effects 0.000 claims description 19
ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 claims description 16
ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 claims description 14
229920000915 polyvinyl chloride Polymers 0.000 claims description 14
239000004800 polyvinyl chloride Substances 0.000 claims description 14
SOIFLUNRINLCBN-UHFFFAOYSA-N ammonium thiocyanate Chemical compound [NH4+].[S-]C#N SOIFLUNRINLCBN-UHFFFAOYSA-N 0.000 claims description 12
239000000975 dye Substances 0.000 claims description 12
239000000126 substance Substances 0.000 claims description 12
239000002253 acid Substances 0.000 claims description 11
-1 alkali metal salt Chemical class 0.000 claims description 11
238000010557 suspension polymerization reaction Methods 0.000 claims description 11
IHZXTIBMKNSJCJ-UHFFFAOYSA-N 3-{[(4-{[4-(dimethylamino)phenyl](4-{ethyl[(3-sulfophenyl)methyl]amino}phenyl)methylidene}cyclohexa-2,5-dien-1-ylidene)(ethyl)azaniumyl]methyl}benzene-1-sulfonate Chemical compound C=1C=C(C(=C2C=CC(C=C2)=[N+](C)C)C=2C=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S(O)(=O)=O)=C1 IHZXTIBMKNSJCJ-UHFFFAOYSA-N 0.000 claims description 9
229910052783 alkali metal Inorganic materials 0.000 claims description 9
150000003567 thiocyanates Chemical class 0.000 claims description 8
150000003863 ammonium salts Chemical class 0.000 claims description 7
238000001035 drying Methods 0.000 claims description 5
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 4
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical group CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 4
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 4
AOMZHDJXSYHPKS-UHFFFAOYSA-L disodium 4-amino-5-hydroxy-3-[(4-nitrophenyl)diazenyl]-6-phenyldiazenylnaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC2=CC(S([O-])(=O)=O)=C(N=NC=3C=CC=CC=3)C(O)=C2C(N)=C1N=NC1=CC=C([N+]([O-])=O)C=C1 AOMZHDJXSYHPKS-UHFFFAOYSA-L 0.000 claims description 4
TWBYWOBDOCUKOW-UHFFFAOYSA-N isonicotinic acid Chemical compound OC(=O)C1=CC=NC=C1 TWBYWOBDOCUKOW-UHFFFAOYSA-N 0.000 claims description 4
JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 4
150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 3
239000003795 chemical substances by application Substances 0.000 claims description 3
YCMOBGSVZYLYBZ-UHFFFAOYSA-L disodium 5-[[4-[4-[(2-amino-8-hydroxy-6-sulfonatonaphthalen-1-yl)diazenyl]phenyl]phenyl]diazenyl]-2-hydroxybenzoate Chemical compound NC1=CC=C2C=C(C=C(O)C2=C1N=NC1=CC=C(C=C1)C1=CC=C(C=C1)N=NC1=CC=C(O)C(=C1)C(=O)O[Na])S(=O)(=O)O[Na] YCMOBGSVZYLYBZ-UHFFFAOYSA-L 0.000 claims description 3
MPCYPRXRVWZKGF-UHFFFAOYSA-J tetrasodium 5-amino-3-[[4-[4-[(8-amino-1-hydroxy-3,6-disulfonatonaphthalen-2-yl)diazenyl]phenyl]phenyl]diazenyl]-4-hydroxynaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].C1=C(S([O-])(=O)=O)C=C2C=C(S([O-])(=O)=O)C(N=NC3=CC=C(C=C3)C3=CC=C(C=C3)N=NC3=C(C=C4C=C(C=C(C4=C3O)N)S([O-])(=O)=O)S([O-])(=O)=O)=C(O)C2=C1N MPCYPRXRVWZKGF-UHFFFAOYSA-J 0.000 claims description 3
WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 claims description 2
ALKYHXVLJMQRLQ-UHFFFAOYSA-N 3-Hydroxy-2-naphthoate Chemical compound C1=CC=C2C=C(O)C(C(=O)O)=CC2=C1 ALKYHXVLJMQRLQ-UHFFFAOYSA-N 0.000 claims description 2
BTXXTMOWISPQSJ-UHFFFAOYSA-N 4,4,4-trifluorobutan-2-one Chemical compound CC(=O)CC(F)(F)F BTXXTMOWISPQSJ-UHFFFAOYSA-N 0.000 claims description 2
SEXWRZHFWPOWFA-VAWYXSNFSA-N 5-(phenylcarbamoylamino)-2-[(e)-2-[4-(phenylcarbamoylamino)-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound C=1C=C(\C=C\C=2C(=CC(NC(=O)NC=3C=CC=CC=3)=CC=2)S(O)(=O)=O)C(S(=O)(=O)O)=CC=1NC(=O)NC1=CC=CC=C1 SEXWRZHFWPOWFA-VAWYXSNFSA-N 0.000 claims description 2
WRSWXNQFTKCPHT-UHFFFAOYSA-N 5-bromo-2-(9-chloro-3-hydroxybenzo[g][1]benzothiol-2-yl)indol-3-one Chemical compound [O-]c1c(sc2c1ccc1cccc(Cl)c21)C1=[NH+]c2ccc(Br)cc2C1=O WRSWXNQFTKCPHT-UHFFFAOYSA-N 0.000 claims description 2
LMKBZNJJQISXRN-UHFFFAOYSA-N 8-hydroxy-7-[[4-[4-[(2-hydroxynaphthalen-1-yl)diazenyl]phenyl]phenyl]diazenyl]naphthalene-1,3,6-trisulfonic acid Chemical compound OC1=CC=C2C=CC=CC2=C1N=NC1=CC=C(C=C1)C1=CC=C(C=C1)N=NC1=C(C=C2C=C(C=C(C2=C1O)S(O)(=O)=O)S(O)(=O)=O)S(O)(=O)=O LMKBZNJJQISXRN-UHFFFAOYSA-N 0.000 claims description 2
JAJIPIAHCFBEPI-UHFFFAOYSA-N 9,10-dioxoanthracene-1-sulfonic acid Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2S(=O)(=O)O JAJIPIAHCFBEPI-UHFFFAOYSA-N 0.000 claims description 2
BQACOLQNOUYJCE-FYZZASKESA-N Abietic acid Natural products CC(C)C1=CC2=CC[C@]3(C)[C@](C)(CCC[C@@]3(C)C(=O)O)[C@H]2CC1 BQACOLQNOUYJCE-FYZZASKESA-N 0.000 claims description 2
RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 2
239000005711 Benzoic acid Substances 0.000 claims description 2
ZGUNAGUHMKGQNY-ZETCQYMHSA-N L-alpha-phenylglycine zwitterion Chemical compound OC(=O)[C@@H](N)C1=CC=CC=C1 ZGUNAGUHMKGQNY-ZETCQYMHSA-N 0.000 claims description 2
JQYMGXZJTCOARG-UHFFFAOYSA-N Reactive blue 2 Chemical compound C1=2C(=O)C3=CC=CC=C3C(=O)C=2C(N)=C(S(O)(=O)=O)C=C1NC(C=C1S(O)(=O)=O)=CC=C1NC(N=1)=NC(Cl)=NC=1NC1=CC=CC(S(O)(=O)=O)=C1 JQYMGXZJTCOARG-UHFFFAOYSA-N 0.000 claims description 2
150000001340 alkali metals Chemical class 0.000 claims description 2
229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
235000010233 benzoic acid Nutrition 0.000 claims description 2
238000005282 brightening Methods 0.000 claims description 2
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
ZBNARPCCDMHDDV-UHFFFAOYSA-N chembl1206040 Chemical compound C1=C(S(O)(=O)=O)C=C2C=C(S(O)(=O)=O)C(N=NC3=CC=C(C=C3C)C=3C=C(C(=CC=3)N=NC=3C(=CC4=CC(=CC(N)=C4C=3O)S(O)(=O)=O)S(O)(=O)=O)C)=C(O)C2=C1N ZBNARPCCDMHDDV-UHFFFAOYSA-N 0.000 claims description 2
BEQIIZJSZSVJJK-UHFFFAOYSA-M chembl2028372 Chemical compound [Na+].OC1=CC=C(S([O-])(=O)=O)C=C1N=NC1=C(O)C=CC2=CC=CC=C12 BEQIIZJSZSVJJK-UHFFFAOYSA-M 0.000 claims description 2
KJPDHFPPVKRMMG-UHFFFAOYSA-L disodium 2,4-diamino-3-[[4-[4-[(2,6-diamino-3-methyl-5-sulfonatophenyl)diazenyl]-3-methylphenyl]-2-methylphenyl]diazenyl]-5-methylbenzenesulfonate Chemical compound [Na+].[Na+].CC1=CC(S([O-])(=O)=O)=C(N)C(N=NC=2C(=CC(=CC=2)C=2C=C(C)C(N=NC=3C(=C(C=C(C)C=3N)S([O-])(=O)=O)N)=CC=2)C)=C1N KJPDHFPPVKRMMG-UHFFFAOYSA-L 0.000 claims description 2
VDRKHPFIMDTBNX-UHFFFAOYSA-L disodium 7-amino-8-[[4-[4-[(2-amino-8-oxido-6-sulfonaphthalen-1-yl)diazenyl]phenyl]phenyl]diazenyl]-3-sulfonaphthalen-1-olate Chemical compound C1=CC(=CC=C1C2=CC=C(C=C2)N=NC3=C(C=CC4=CC(=CC(=C43)[O-])S(=O)(=O)O)N)N=NC5=C(C=CC6=CC(=CC(=C65)[O-])S(=O)(=O)O)N.[Na+].[Na+] VDRKHPFIMDTBNX-UHFFFAOYSA-L 0.000 claims description 2
VSSMQLIMSVAUDK-UHFFFAOYSA-L disodium;5-[(4-ethoxyphenyl)diazenyl]-2-[4-[(4-ethoxyphenyl)diazenyl]-2-sulfonatophenyl]sulfanylbenzenesulfonate Chemical compound [Na+].[Na+].C1=CC(OCC)=CC=C1N=NC(C=C1S([O-])(=O)=O)=CC=C1SC1=CC=C(N=NC=2C=CC(OCC)=CC=2)C=C1S([O-])(=O)=O VSSMQLIMSVAUDK-UHFFFAOYSA-L 0.000 claims description 2
229940060296 dodecylbenzenesulfonic acid Drugs 0.000 claims description 2
SXQCTESRRZBPHJ-UHFFFAOYSA-M lissamine rhodamine Chemical compound [Na+].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=C(S([O-])(=O)=O)C=C1S([O-])(=O)=O SXQCTESRRZBPHJ-UHFFFAOYSA-M 0.000 claims description 2
PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 claims description 2
PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 claims description 2
OARRHUQTFTUEOS-UHFFFAOYSA-N safranin Chemical compound [Cl-].C=12C=C(N)C(C)=CC2=NC2=CC(C)=C(N)C=C2[N+]=1C1=CC=CC=C1 OARRHUQTFTUEOS-UHFFFAOYSA-N 0.000 claims description 2
125000000542 sulfonic acid group Chemical group 0.000 claims description 2
QTTDXDAWQMDLOF-UHFFFAOYSA-J tetrasodium 3-[[4-[[4-[(6-amino-1-hydroxy-3-sulfonatonaphthalen-2-yl)diazenyl]-6-sulfonatonaphthalen-1-yl]diazenyl]naphthalen-1-yl]diazenyl]naphthalene-1,5-disulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].Nc1ccc2c(O)c(N=Nc3ccc(N=Nc4ccc(N=Nc5cc(c6cccc(c6c5)S([O-])(=O)=O)S([O-])(=O)=O)c5ccccc45)c4ccc(cc34)S([O-])(=O)=O)c(cc2c1)S([O-])(=O)=O QTTDXDAWQMDLOF-UHFFFAOYSA-J 0.000 claims description 2
150000004992 toluidines Chemical class 0.000 claims description 2
SWGJCIMEBVHMTA-UHFFFAOYSA-K trisodium;6-oxido-4-sulfo-5-[(4-sulfonatonaphthalen-1-yl)diazenyl]naphthalene-2-sulfonate Chemical compound [Na+].[Na+].[Na+].C1=CC=C2C(N=NC3=C4C(=CC(=CC4=CC=C3O)S([O-])(=O)=O)S([O-])(=O)=O)=CC=C(S([O-])(=O)=O)C2=C1 SWGJCIMEBVHMTA-UHFFFAOYSA-K 0.000 claims description 2
PEAGNRWWSMMRPZ-UHFFFAOYSA-L woodstain scarlet Chemical compound [Na+].[Na+].OC1=CC=C2C=C(S([O-])(=O)=O)C=C(S([O-])(=O)=O)C2=C1N=NC(C=C1)=CC=C1N=NC1=CC=CC=C1 PEAGNRWWSMMRPZ-UHFFFAOYSA-L 0.000 claims description 2
CQPFMGBJSMSXLP-UHFFFAOYSA-M acid orange 7 Chemical compound [Na+].OC1=CC=C2C=CC=CC2=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 CQPFMGBJSMSXLP-UHFFFAOYSA-M 0.000 claims 1
AZOPGDOIOXKJRA-UHFFFAOYSA-L chembl1817788 Chemical compound [Na+].[Na+].C1=C(C([O-])=O)C(O)=CC=C1N=NC1=CC=C(C=2C=CC(=CC=2)N=NC=2C=C(C(O)=CC=2)C([O-])=O)C=C1 AZOPGDOIOXKJRA-UHFFFAOYSA-L 0.000 claims 1
XRPLBRIHZGVJIC-UHFFFAOYSA-L chembl3182776 Chemical compound [Na+].[Na+].NC1=CC(N)=CC=C1N=NC1=CC=C(C=2C=CC(=CC=2)N=NC=2C(=CC3=CC(=C(N=NC=4C=CC=CC=4)C(O)=C3C=2N)S([O-])(=O)=O)S([O-])(=O)=O)C=C1 XRPLBRIHZGVJIC-UHFFFAOYSA-L 0.000 claims 1
CEQFOVLGLXCDCX-WUKNDPDISA-N methyl red Chemical compound C1=CC(N(C)C)=CC=C1\N=N\C1=CC=CC=C1C(O)=O CEQFOVLGLXCDCX-WUKNDPDISA-N 0.000 claims 1
235000012731 ponceau 4R Nutrition 0.000 claims 1
DXRWYIKGBIPGAG-UHFFFAOYSA-N sodium 3-hydroxy-4-[(2-hydroxynaphthalen-1-yl)diazenyl]-7-nitronaphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(=C1)C=CC(=C2N=NC3=C4C=CC(=CC4=C(C=C3O)S(=O)(=O)O)[N+](=O)[O-])O.[Na+] DXRWYIKGBIPGAG-UHFFFAOYSA-N 0.000 claims 1
239000000375 suspending agent Substances 0.000 claims 1
239000000243 solution Substances 0.000 description 30
229920000642 polymer Polymers 0.000 description 24
206010039509 Scab Diseases 0.000 description 8
150000002978 peroxides Chemical class 0.000 description 7
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
238000000465 moulding Methods 0.000 description 6
ZNNZYHKDIALBAK-UHFFFAOYSA-M potassium thiocyanate Chemical compound [K+].[S-]C#N ZNNZYHKDIALBAK-UHFFFAOYSA-M 0.000 description 6
239000012736 aqueous medium Substances 0.000 description 5
238000002474 experimental method Methods 0.000 description 5
239000002609 medium Substances 0.000 description 5
150000003839 salts Chemical class 0.000 description 5
238000012360 testing method Methods 0.000 description 5
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
239000004372 Polyvinyl alcohol Substances 0.000 description 4
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
238000013459 approach Methods 0.000 description 4
150000001875 compounds Chemical class 0.000 description 4
238000002845 discoloration Methods 0.000 description 4
239000000463 material Substances 0.000 description 4
229920002451 polyvinyl alcohol Polymers 0.000 description 4
229910001220 stainless steel Inorganic materials 0.000 description 4
239000010935 stainless steel Substances 0.000 description 4
BEQKKZICTDFVMG-UHFFFAOYSA-N 1,2,3,4,6-pentaoxepane-5,7-dione Chemical compound O=C1OOOOC(=O)O1 BEQKKZICTDFVMG-UHFFFAOYSA-N 0.000 description 3
ALWXETURCOIGIZ-UHFFFAOYSA-N 1-nitropropylbenzene Chemical compound CCC([N+]([O-])=O)C1=CC=CC=C1 ALWXETURCOIGIZ-UHFFFAOYSA-N 0.000 description 3
241000251468 Actinopterygii Species 0.000 description 3
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
150000007513 acids Chemical class 0.000 description 3
239000000654 additive Substances 0.000 description 3
239000008346 aqueous phase Substances 0.000 description 3
239000007864 aqueous solution Substances 0.000 description 3
150000001735 carboxylic acids Chemical class 0.000 description 3
230000000052 comparative effect Effects 0.000 description 3
239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 3
229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 3
235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 3
UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 3
VGTPCRGMBIAPIM-UHFFFAOYSA-M sodium thiocyanate Chemical compound [Na+].[S-]C#N VGTPCRGMBIAPIM-UHFFFAOYSA-M 0.000 description 3
150000003460 sulfonic acids Chemical class 0.000 description 3
239000000725 suspension Substances 0.000 description 3
OESPFRYVCUTRKF-UHFFFAOYSA-N 2-(1,3-dioxo-2,3-dihydro-1h-inden-2-yl)quinoline-6,8-disulfonic acid Chemical compound O=C1C2=CC=CC=C2C(=O)C1C1=NC2=C(S(O)(=O)=O)C=C(S(=O)(=O)O)C=C2C=C1 OESPFRYVCUTRKF-UHFFFAOYSA-N 0.000 description 2
CEQFOVLGLXCDCX-UHFFFAOYSA-N 2-[[4-(dimethylamino)phenyl]diazenyl]benzoic acid Chemical compound C1=CC(N(C)C)=CC=C1N=NC1=CC=CC=C1C(O)=O CEQFOVLGLXCDCX-UHFFFAOYSA-N 0.000 description 2
AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
235000011054 acetic acid Nutrition 0.000 description 2
229910000147 aluminium phosphate Inorganic materials 0.000 description 2
239000007900 aqueous suspension Substances 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
238000004140 cleaning Methods 0.000 description 2
238000001816 cooling Methods 0.000 description 2
238000007334 copolymerization reaction Methods 0.000 description 2
230000007547 defect Effects 0.000 description 2
239000002270 dispersing agent Substances 0.000 description 2
239000006185 dispersion Substances 0.000 description 2
150000002148 esters Chemical class 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
239000012046 mixed solvent Substances 0.000 description 2
239000003960 organic solvent Substances 0.000 description 2
VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 2
229940116357 potassium thiocyanate Drugs 0.000 description 2
235000012752 quinoline yellow Nutrition 0.000 description 2
239000002002 slurry Substances 0.000 description 2
CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 2
BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
RTLULCVBFCRQKI-UHFFFAOYSA-N 1-amino-4-[3-[(4,6-dichloro-1,3,5-triazin-2-yl)amino]-4-sulfoanilino]-9,10-dioxoanthracene-2-sulfonic acid Chemical compound C1=2C(=O)C3=CC=CC=C3C(=O)C=2C(N)=C(S(O)(=O)=O)C=C1NC(C=1)=CC=C(S(O)(=O)=O)C=1NC1=NC(Cl)=NC(Cl)=N1 RTLULCVBFCRQKI-UHFFFAOYSA-N 0.000 description 1
AZYODYPUWJPKOI-UHFFFAOYSA-N 2-(2-bromophenoxy)acetic acid Chemical compound OC(=O)COC1=CC=CC=C1Br AZYODYPUWJPKOI-UHFFFAOYSA-N 0.000 description 1
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
VGZZAZYCLRYTNQ-UHFFFAOYSA-N 2-ethoxyethoxycarbonyloxy 2-ethoxyethyl carbonate Chemical compound CCOCCOC(=O)OOC(=O)OCCOCC VGZZAZYCLRYTNQ-UHFFFAOYSA-N 0.000 description 1
KFGFVPMRLOQXNB-UHFFFAOYSA-N 3,5,5-trimethylhexanoyl 3,5,5-trimethylhexaneperoxoate Chemical compound CC(C)(C)CC(C)CC(=O)OOC(=O)CC(C)CC(C)(C)C KFGFVPMRLOQXNB-UHFFFAOYSA-N 0.000 description 1
ASDREVVGQFYRTH-UHFFFAOYSA-N 3-[[2-acetamido-4-[(4-amino-6-chloro-1,3,5-triazin-2-yl)amino]phenyl]diazenyl]naphthalene-1,5-disulfonic acid Chemical compound C=1C=C(N=NC=2C=C3C(=CC=CC3=C(C=2)S(O)(=O)=O)S(O)(=O)=O)C(NC(=O)C)=CC=1NC1=NC(N)=NC(Cl)=N1 ASDREVVGQFYRTH-UHFFFAOYSA-N 0.000 description 1
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 1
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
108010010803 Gelatin Proteins 0.000 description 1
IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 description 1
YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
229920002125 Sokalan® Polymers 0.000 description 1
239000004147 Sorbitan trioleate Substances 0.000 description 1
PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 description 1
229920002472 Starch Polymers 0.000 description 1
235000021355 Stearic acid Nutrition 0.000 description 1
XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
150000001342 alkaline earth metals Chemical class 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
239000003125 aqueous solvent Substances 0.000 description 1
LKZCRGABYQYUFX-UHFFFAOYSA-L barium(2+);dithiocyanate Chemical compound [Ba+2].[S-]C#N.[S-]C#N LKZCRGABYQYUFX-UHFFFAOYSA-L 0.000 description 1
BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
230000001680 brushing effect Effects 0.000 description 1
239000006229 carbon black Substances 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
239000001768 carboxy methyl cellulose Substances 0.000 description 1
235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
239000008112 carboxymethyl-cellulose Substances 0.000 description 1
229920003086 cellulose ether Polymers 0.000 description 1
238000005119 centrifugation Methods 0.000 description 1
229960000541 cetyl alcohol Drugs 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 1
239000012975 dibutyltin dilaurate Substances 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
238000007720 emulsion polymerization reaction Methods 0.000 description 1
UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
235000019253 formic acid Nutrition 0.000 description 1
229920000159 gelatin Polymers 0.000 description 1
239000008273 gelatin Substances 0.000 description 1
235000019322 gelatine Nutrition 0.000 description 1
235000011852 gelatine desserts Nutrition 0.000 description 1
230000036541 health Effects 0.000 description 1
230000001771 impaired effect Effects 0.000 description 1
230000006872 improvement Effects 0.000 description 1
238000009776 industrial production Methods 0.000 description 1
238000001746 injection moulding Methods 0.000 description 1
229910021432 inorganic complex Chemical class 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
239000004310 lactic acid Substances 0.000 description 1
235000014655 lactic acid Nutrition 0.000 description 1
SXTGAOTXVOMSFW-UHFFFAOYSA-L magnesium;dithiocyanate Chemical class [Mg+2].[S-]C#N.[S-]C#N SXTGAOTXVOMSFW-UHFFFAOYSA-L 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
229920000609 methyl cellulose Polymers 0.000 description 1
239000001923 methylcellulose Substances 0.000 description 1
235000010981 methylcellulose Nutrition 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 description 1
229920005615 natural polymer Polymers 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
235000006408 oxalic acid Nutrition 0.000 description 1
UCUUFSAXZMGPGH-UHFFFAOYSA-N penta-1,4-dien-3-one Chemical class C=CC(=O)C=C UCUUFSAXZMGPGH-UHFFFAOYSA-N 0.000 description 1
230000002085 persistent effect Effects 0.000 description 1
235000002949 phytic acid Nutrition 0.000 description 1
239000000467 phytic acid Substances 0.000 description 1
229940068041 phytic acid Drugs 0.000 description 1
239000000049 pigment Substances 0.000 description 1
239000004584 polyacrylic acid Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
150000004053 quinones Chemical class 0.000 description 1
230000009467 reduction Effects 0.000 description 1
238000005096 rolling process Methods 0.000 description 1
238000007493 shaping process Methods 0.000 description 1
SZKZLHLJJLRYKJ-UHFFFAOYSA-N sodium 4-amino-3-[[4-[4-[(2,4-diaminophenyl)diazenyl]phenyl]phenyl]diazenyl]-5-hydroxy-6-phenyldiazenylnaphthalene-2,7-disulfonic acid Chemical compound C1=CC=C(C=C1)N=NC2=C(C3=C(C(=C(C=C3C=C2S(=O)(=O)O)S(=O)(=O)O)N=NC4=CC=C(C=C4)C5=CC=C(C=C5)N=NC6=C(C=C(C=C6)N)N)N)O.[Na+] SZKZLHLJJLRYKJ-UHFFFAOYSA-N 0.000 description 1
239000002904 solvent Substances 0.000 description 1
229940035044 sorbitan monolaurate Drugs 0.000 description 1
235000019337 sorbitan trioleate Nutrition 0.000 description 1
229960000391 sorbitan trioleate Drugs 0.000 description 1
238000005507 spraying Methods 0.000 description 1
235000019698 starch Nutrition 0.000 description 1
239000008107 starch Substances 0.000 description 1
239000008117 stearic acid Substances 0.000 description 1
YNQRWDDCTKWYJP-UHFFFAOYSA-L strontium;dithiocyanate Chemical compound [Sr+2].[S-]C#N.[S-]C#N YNQRWDDCTKWYJP-UHFFFAOYSA-L 0.000 description 1
230000001629 suppression Effects 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
238000010998 test method Methods 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
231100000331 toxic Toxicity 0.000 description 1
230000002588 toxic effect Effects 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
CMPGARWFYBADJI-UHFFFAOYSA-L tungstic acid Chemical compound O[W](O)(=O)=O CMPGARWFYBADJI-UHFFFAOYSA-L 0.000 description 1
229920001567 vinyl ester resin Polymers 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
229920003170 water-soluble synthetic polymer Polymers 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Polymerisation Methods In General (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

DE19803039543 1979-10-22 1980-10-20 Verfahren zur herstellung von pvc-harzen Withdrawn DE3039543A1 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP54136262A JPS606361B2 (ja)	1979-10-22	1979-10-22	塩化ビニル系単量体の重合方法

Publications (1)

Publication Number	Publication Date
DE3039543A1 true DE3039543A1 (de)	1981-09-10

Family

ID=15171066

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DE19803039543 Withdrawn DE3039543A1 (de)	1979-10-22	1980-10-20	Verfahren zur herstellung von pvc-harzen

Country Status (21)

Country	Link
JP (1)	JPS606361B2 (es)
AT (1)	AT369755B (es)
BE (1)	BE885813A (es)
BR (1)	BR8006772A (es)
CA (1)	CA1193394A (es)
CH (1)	CH645392A5 (es)
CU (1)	CU21471A (es)
DE (1)	DE3039543A1 (es)
DK (1)	DK443880A (es)
ES (1)	ES8107254A1 (es)
FR (1)	FR2467860B1 (es)
GB (1)	GB2061980B (es)
HU (1)	HU191809B (es)
IN (1)	IN151895B (es)
IT (1)	IT1133972B (es)
MX (1)	MX155347A (es)
NL (1)	NL8005812A (es)
NO (1)	NO803099L (es)
PL (1)	PL227440A1 (es)
PT (1)	PT71944B (es)
SE (1)	SE8007331L (es)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS62176245A (ja) *	1986-01-29	1987-08-03	Sekisui Chem Co Ltd	電話機
JPS62219737A (ja) *	1986-03-19	1987-09-28	Matsushita Electric Works Ltd	電話用切り分け器
JPS62219736A (ja) *	1986-03-19	1987-09-28	Matsushita Electric Works Ltd	電話用切り分け器

Citations (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
BE844044A (fr) *	1975-07-18	1976-11-03		Procede ameliore pour la preparation d'homo et de copolymeres de chlorure de vinyle
JPS5224070A (en) *	1975-08-19	1977-02-23	Toshiba Corp	Productio method of magnetron anode
JPS5224953A (en) *	1975-08-22	1977-02-24	Osaka Transformer Co Ltd	Arc welding machine
JPS5228347A (en) *	1975-08-29	1977-03-03	Nippon Kogaku Kk <Nikon>	Position detector unit
US4093788A (en) *	1974-06-24	1978-06-06	Stauffer Chemical Company	Method for the preparation of polyvinyl chloride by suspension or emulsion polymerization
DE2804076A1 (de) *	1977-02-01	1978-08-03	Solvay	Verfahren zur polymerisation von vinylhalogenidmonomeren in waessriger dispersion

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5214688A (en) *	1975-07-24	1977-02-03	Shin Etsu Chem Co Ltd	A process for polymerizing vinyl chloride
JPS548690A (en) *	1977-06-20	1979-01-23	Goodrich Co B F	Method of preventing polymer from adhering on inner surface of polymerization reactor

1979
- 1979-10-22 JP JP54136262A patent/JPS606361B2/ja not_active Expired
1980
- 1980-10-14 IN IN1167/CAL/80A patent/IN151895B/en unknown
- 1980-10-17 NO NO803099A patent/NO803099L/no unknown
- 1980-10-17 CA CA000362647A patent/CA1193394A/en not_active Expired
- 1980-10-20 GB GB8033747A patent/GB2061980B/en not_active Expired
- 1980-10-20 SE SE8007331A patent/SE8007331L/xx unknown
- 1980-10-20 DK DK443880A patent/DK443880A/da not_active Application Discontinuation
- 1980-10-20 DE DE19803039543 patent/DE3039543A1/de not_active Withdrawn
- 1980-10-21 FR FR8022441A patent/FR2467860B1/fr not_active Expired
- 1980-10-21 IT IT25487/80A patent/IT1133972B/it active
- 1980-10-21 ES ES496127A patent/ES8107254A1/es not_active Expired
- 1980-10-21 MX MX184414A patent/MX155347A/es unknown
- 1980-10-21 CU CU35339A patent/CU21471A/es unknown
- 1980-10-21 PT PT71944A patent/PT71944B/pt unknown
- 1980-10-21 BR BR8006772A patent/BR8006772A/pt unknown
- 1980-10-21 BE BE0/202545A patent/BE885813A/fr not_active IP Right Cessation
- 1980-10-22 NL NL8005812A patent/NL8005812A/nl not_active Application Discontinuation
- 1980-10-22 AT AT0521080A patent/AT369755B/de not_active IP Right Cessation
- 1980-10-22 HU HU802567A patent/HU191809B/hu unknown
- 1980-10-22 PL PL22744080A patent/PL227440A1/xx unknown
- 1980-10-22 CH CH788080A patent/CH645392A5/de not_active IP Right Cessation

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4093788A (en) *	1974-06-24	1978-06-06	Stauffer Chemical Company	Method for the preparation of polyvinyl chloride by suspension or emulsion polymerization
BE844044A (fr) *	1975-07-18	1976-11-03		Procede ameliore pour la preparation d'homo et de copolymeres de chlorure de vinyle
JPS5224070A (en) *	1975-08-19	1977-02-23	Toshiba Corp	Productio method of magnetron anode
JPS5224953A (en) *	1975-08-22	1977-02-24	Osaka Transformer Co Ltd	Arc welding machine
JPS5228347A (en) *	1975-08-29	1977-03-03	Nippon Kogaku Kk <Nikon>	Position detector unit
DE2804076A1 (de) *	1977-02-01	1978-08-03	Solvay	Verfahren zur polymerisation von vinylhalogenidmonomeren in waessriger dispersion

Also Published As

Publication number	Publication date
SE8007331L (sv)	1981-04-23
ES496127A0 (es)	1981-10-01
MX155347A (es)	1988-02-22
JPS606361B2 (ja)	1985-02-18
DK443880A (da)	1981-04-23
JPS5659808A (en)	1981-05-23
AT369755B (de)	1983-01-25
ATA521080A (de)	1982-06-15
IT8025487A0 (it)	1980-10-21
CH645392A5 (de)	1984-09-28
IT1133972B (it)	1986-07-24
IN151895B (es)	1983-08-27
CA1193394A (en)	1985-09-10
ES8107254A1 (es)	1981-10-01
CU21471A (en)	1983-10-04
GB2061980B (en)	1983-06-29
PL227440A1 (es)	1981-07-10
PT71944A (en)	1980-11-01
HU191809B (en)	1987-04-28
FR2467860A1 (fr)	1981-04-30
GB2061980A (en)	1981-05-20
FR2467860B1 (fr)	1985-11-15
NL8005812A (nl)	1981-04-24
NO803099L (no)	1981-04-23
BE885813A (fr)	1981-02-16
PT71944B (en)	1981-08-31
BR8006772A (pt)	1981-04-28

Publication	Publication Date	Title
DE2635780C2 (es)	1989-03-09
DE1064719B (de)	1959-09-03	Verfahren zur Herstellung vernetzbarer bzw. vernetzter Polymerer
DE2801219C2 (es)	1988-12-22
DE2531780B2 (de)	1979-05-23	Verfahren zur Herstellung von verpastbaren Polymeren des Vinylchlorids
CH631187A5 (en)	1982-07-30	Process for the polymerisation of vinyl chloride
DE3019390A1 (de)	1980-12-04	Verfahren zur unterdrueckung der bildung von polymerkrusten
DE2757065C2 (de)	1982-03-11	Verfahren zur Polymerisation von Vinylchlorid, allein oder zusammen mit anderen Vinylhalogeniden oder anderen mit Vinylchlorid copolymerisierbaren Comonomeren, in wäßriger Dispersion und Reaktionsgefäß zu dessen Durchführung
DE2548424A1 (de)	1976-05-13	Verfahren zum polymerisieren von vinylchlorid
DE69511134T2 (de)	2000-02-24	Polyvinylidenfluoride Mischungen und ihre Anwendung zur Formulierung hochglänzender Anstriche
DE3039543A1 (de)	1981-09-10	Verfahren zur herstellung von pvc-harzen
EP0072544B1 (de)	1986-01-15	Kontinuierliches Verfahren zur Herstellung von Vinylchloridpolymerisaten in wässriger Suspension
DE1301529B (de)	1969-08-21	Verfahren zur Herstellung von pastenfaehigen Vinylchloridhomo- oder -copolymerisaten
DE68919163T2 (de)	1995-03-09	Verfahren zur Unterdrückung der Bildung von Polymerkrusten.
EP0003035B1 (de)	1982-03-24	Verfahren zur Herstellung von Vinylchlorid-Polymerisaten sowie Polymerisationsgefäss zur Ausführung des Verfahrens
EP0019198A1 (de)	1980-11-26	Verfahren zur Herstellung von Vinylchlorid-Polymerisaten, Mittel zur Beschichtung von Polymerisationsgefässen sowie das damit beschichtete Polymerisationsgefäss
DE2632468C2 (es)	1989-04-20
DE2703280A1 (de)	1978-08-10	Verfahren zur herstellung von vinylchlorid-polymerisation
EP0029181A1 (de)	1981-05-27	Verfahren zur Herstellung von Vinylchlorid-Polymerisaten, Mittel zur Beschichtung von Polymerisationsgefässen und dafür verwendbare Derivate von 1,4-(7H)-Benzoxazin
DD232711A5 (de)	1986-02-05	Verfahren zur verhinderung der abscheidung von polymerkrusten bei der polymerisation von aethylenisch ungesaettigten monomeren und beschichtungszusammensetzung zur durchfuehrung dieses verfahrens
DE69515203T2 (de)	2000-08-24	Verfahren zur Herstellung von Vinylchloridpolymeren
EP0019197B1 (de)	1983-10-12	Verfahren zur Herstellung von Vinylchlorid-Polymerisaten, Mittel zur Beschichtung von Polymerisationsgefässen sowie das damit beschichtete Polymerisationsgefäss
DE2539430C2 (de)	1985-05-23	Verfahren zum Abstoppen der Polymerisation von Vinylchlorid in wäßriger Emulsion oder Suspension
DE2832628A1 (de)	1979-02-01	Verfahren und vorrichtung zur polymerisation von vinylchlorid in suspension
DE3123015C2 (es)	1992-11-05
DE2227887A1 (de)	1973-12-20	Verfahren zur herstellung von vinylchlorid-copolymerisaten in waessriger suspension

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