CN1140578C - 具有改进气味特性的abs模塑组合物 - Google Patents
具有改进气味特性的abs模塑组合物 Download PDFInfo
- Publication number
- CN1140578C CN1140578C CNB971257531A CN97125753A CN1140578C CN 1140578 C CN1140578 C CN 1140578C CN B971257531 A CNB971257531 A CN B971257531A CN 97125753 A CN97125753 A CN 97125753A CN 1140578 C CN1140578 C CN 1140578C
- Authority
- CN
- China
- Prior art keywords
- weight
- mixture
- compound
- styrene
- epoxide group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims description 43
- 238000000465 moulding Methods 0.000 title 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 28
- 150000001875 compounds Chemical class 0.000 claims abstract description 19
- 125000003700 epoxy group Chemical group 0.000 claims abstract description 15
- 239000011787 zinc oxide Substances 0.000 claims abstract description 14
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 12
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 12
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 12
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 24
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 16
- 229920001971 elastomer Polymers 0.000 claims description 16
- 239000005060 rubber Substances 0.000 claims description 16
- 238000002360 preparation method Methods 0.000 claims description 15
- 239000000206 moulding compound Substances 0.000 claims description 13
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 11
- 239000004593 Epoxy Substances 0.000 claims description 10
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 10
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 10
- 229920001169 thermoplastic Polymers 0.000 claims description 9
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 8
- 239000004416 thermosoftening plastic Substances 0.000 claims description 8
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 claims description 7
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 229920000578 graft copolymer Polymers 0.000 claims description 4
- 238000006116 polymerization reaction Methods 0.000 claims description 4
- 125000005907 alkyl ester group Chemical group 0.000 claims description 3
- 230000009477 glass transition Effects 0.000 claims description 3
- 238000010559 graft polymerization reaction Methods 0.000 claims description 3
- 239000000944 linseed oil Substances 0.000 claims description 3
- 235000021388 linseed oil Nutrition 0.000 claims description 3
- 239000003549 soybean oil Substances 0.000 claims description 3
- 235000012424 soybean oil Nutrition 0.000 claims description 3
- 229920005992 thermoplastic resin Polymers 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 229920000642 polymer Polymers 0.000 abstract description 10
- 239000004415 thermoplastic moulding composition Substances 0.000 abstract 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 12
- 238000000034 method Methods 0.000 description 8
- 239000000178 monomer Substances 0.000 description 7
- -1 body Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 230000035943 smell Effects 0.000 description 5
- 238000007720 emulsion polymerization reaction Methods 0.000 description 4
- 229920000800 acrylic rubber Polymers 0.000 description 3
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 3
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 3
- 229920000058 polyacrylate Polymers 0.000 description 3
- HIDBROSJWZYGSZ-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC=C1 HIDBROSJWZYGSZ-UHFFFAOYSA-N 0.000 description 2
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 description 1
- NKKMVIVFRUYPLQ-UHFFFAOYSA-N but-2-enenitrile Chemical compound CC=CC#N NKKMVIVFRUYPLQ-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000012673 precipitation polymerization Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000005199 ultracentrifugation Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1515—Three-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
- Epoxy Resins (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19652958A DE19652958A1 (de) | 1996-12-19 | 1996-12-19 | ABS-Formmassen mit verbessertem Geruchsverhalten |
| DE19652958.1 | 1996-12-19 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1190107A CN1190107A (zh) | 1998-08-12 |
| CN1140578C true CN1140578C (zh) | 2004-03-03 |
Family
ID=7815320
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB971257531A Expired - Fee Related CN1140578C (zh) | 1996-12-19 | 1997-12-19 | 具有改进气味特性的abs模塑组合物 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6297307B1 (es) |
| EP (1) | EP0849317B1 (es) |
| JP (1) | JP4143155B2 (es) |
| CN (1) | CN1140578C (es) |
| AR (1) | AR011040A1 (es) |
| AU (1) | AU743563B2 (es) |
| BR (1) | BR9706378A (es) |
| DE (2) | DE19652958A1 (es) |
| ES (1) | ES2145550T3 (es) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110114403A (zh) * | 2016-12-30 | 2019-08-09 | 乐天尖端材料株式会社 | 热塑性树脂组合物和由其生产的模制品 |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6759484B1 (en) | 1999-09-30 | 2004-07-06 | Kyowa Yuka Co., Ltd. | Method of diminishing odor emission |
| ATE384764T1 (de) * | 2002-03-15 | 2008-02-15 | Lanxess Deutschland Gmbh | Stabilisator-kombinationen für polymersysteme |
| DE10226222A1 (de) * | 2002-06-13 | 2004-01-08 | Bayer Cropscience Ag | Pulver-Formulierungen |
| DE102004024272A1 (de) * | 2004-05-15 | 2005-12-01 | Lanxess Deutschland Gmbh | Pfropfpolymerisathaltige Massen für die Extrusionsverarbeitung |
| EP1752478A1 (en) | 2005-08-08 | 2007-02-14 | Basf Aktiengesellschaft | A process for the production of a graft copolymer having a bimodal particle distribution. |
| CN101121807B (zh) * | 2007-07-20 | 2010-05-26 | 上海金发科技发展有限公司 | 一种本体聚合丙烯腈-丁二烯-苯乙烯的改性复合物及其制备方法 |
| JP2016106160A (ja) | 2013-03-25 | 2016-06-16 | 神島化学工業株式会社 | 酸化マグネシウム粒子、樹脂組成物、ゴム組成物及び成形体 |
| CN103740020B (zh) * | 2013-12-09 | 2016-06-29 | 天津金发新材料有限公司 | 一种低气味玻纤增强as组合物及其制备方法 |
| WO2018080013A1 (ko) | 2016-10-25 | 2018-05-03 | 롯데첨단소재(주) | 열가소성 수지 조성물 및 이로부터 제조된 성형품 |
| WO2018084484A2 (ko) | 2016-11-02 | 2018-05-11 | 롯데첨단소재(주) | 열가소성 수지 조성물 및 이로부터 제조된 성형품 |
| KR101974734B1 (ko) * | 2016-11-02 | 2019-05-03 | 롯데첨단소재(주) | 열가소성 수지 조성물 및 이로부터 제조된 성형품 |
| KR101967961B1 (ko) | 2016-12-22 | 2019-04-10 | 롯데첨단소재(주) | 열가소성 수지 조성물 및 이로부터 제조된 성형품 |
| KR101991584B1 (ko) | 2016-12-23 | 2019-06-20 | 롯데첨단소재(주) | 발포성 수지 조성물, 그 제조방법 및 이를 이용한 발포체 |
| KR101962520B1 (ko) | 2016-12-23 | 2019-03-26 | 롯데첨단소재(주) | 내전리방사선성 열가소성 수지 조성물 및 이를 포함하는 성형품 |
| KR101961994B1 (ko) | 2016-12-27 | 2019-03-25 | 롯데첨단소재(주) | 열가소성 수지 조성물 및 이로부터 제조된 성형품 |
| KR101968014B1 (ko) * | 2016-12-30 | 2019-04-11 | 롯데첨단소재(주) | 열가소성 수지 조성물 |
| KR101967965B1 (ko) | 2016-12-30 | 2019-04-10 | 롯데첨단소재(주) | 열가소성 수지 조성물 및 이로부터 제조된 성형품 |
| KR102161339B1 (ko) | 2017-11-08 | 2020-09-29 | 롯데첨단소재(주) | 열가소성 수지 조성물 및 이로부터 제조된 성형품 |
| EP3856839B1 (en) | 2018-09-25 | 2023-06-14 | INEOS Styrolution Group GmbH | Heat resistant abs composition with reduced odor for automotive interior application |
| KR102236413B1 (ko) | 2018-11-30 | 2021-04-05 | 롯데첨단소재(주) | 열가소성 수지 조성물 및 이로부터 형성된 성형품 |
| EP3680287B1 (en) * | 2019-01-09 | 2025-10-01 | Trinseo Europe GmbH | Extremely low odor styrenic polymer composition |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3496250A (en) * | 1967-02-21 | 1970-02-17 | Borg Warner | Blends of epoxy resins and acrylonitrile butadiene-styrene graft copolymers |
| US4129452A (en) * | 1977-07-11 | 1978-12-12 | American Cyanamid Company | Stabilization of N,N'-[(thiocarbonyl)thio]dimorpholine |
| US4851499A (en) * | 1987-09-29 | 1989-07-25 | Union Carbide Corporation | Process for reducing odor in isotactic polypropylene |
| DE19501998A1 (de) * | 1995-01-24 | 1996-07-25 | Basf Ag | Thermoplastische Polyamidformmassen |
| DE19512407A1 (de) * | 1995-04-03 | 1996-10-10 | Basf Ag | Flammgeschützte thermoplastische Formmassen |
| FR2742442A1 (fr) * | 1995-12-13 | 1997-06-20 | Gen Electric Plastics Abs Euro | Composition de moulage thermoplastique de densite elevee |
-
1996
- 1996-12-19 DE DE19652958A patent/DE19652958A1/de not_active Withdrawn
-
1997
- 1997-12-08 ES ES97121542T patent/ES2145550T3/es not_active Expired - Lifetime
- 1997-12-08 EP EP97121542A patent/EP0849317B1/de not_active Expired - Lifetime
- 1997-12-08 DE DE59701643T patent/DE59701643D1/de not_active Expired - Fee Related
- 1997-12-11 US US08/987,567 patent/US6297307B1/en not_active Expired - Fee Related
- 1997-12-15 AU AU48382/97A patent/AU743563B2/en not_active Ceased
- 1997-12-16 JP JP36340697A patent/JP4143155B2/ja not_active Expired - Fee Related
- 1997-12-17 BR BR9706378A patent/BR9706378A/pt not_active IP Right Cessation
- 1997-12-17 AR ARP970105947A patent/AR011040A1/es not_active Application Discontinuation
- 1997-12-19 CN CNB971257531A patent/CN1140578C/zh not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110114403A (zh) * | 2016-12-30 | 2019-08-09 | 乐天尖端材料株式会社 | 热塑性树脂组合物和由其生产的模制品 |
| CN110114403B (zh) * | 2016-12-30 | 2021-06-29 | 乐天尖端材料株式会社 | 热塑性树脂组合物和由其生产的模制品 |
Also Published As
| Publication number | Publication date |
|---|---|
| BR9706378A (pt) | 1999-06-08 |
| DE59701643D1 (de) | 2000-06-15 |
| AU743563B2 (en) | 2002-01-31 |
| US6297307B1 (en) | 2001-10-02 |
| EP0849317B1 (de) | 2000-05-10 |
| DE19652958A1 (de) | 1998-06-25 |
| JP4143155B2 (ja) | 2008-09-03 |
| EP0849317A3 (en) | 1998-08-05 |
| ES2145550T3 (es) | 2000-07-01 |
| CN1190107A (zh) | 1998-08-12 |
| JPH10182927A (ja) | 1998-07-07 |
| AR011040A1 (es) | 2000-08-02 |
| EP0849317A2 (de) | 1998-06-24 |
| AU4838297A (en) | 1998-06-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: LANXESS DEUTSCHLAND GMBH Free format text: FORMER OWNER: BAYER AG Effective date: 20070525 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20070525 Address after: Germany Leverkusen Patentee after: Lanxess Deutschland GmbH Address before: The Federal Republic of Germany Leverkusen Patentee before: Bayer Aktiengesellschaft |
|
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20040303 Termination date: 20100119 |