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CN1050538A - 杀真菌性吡啶基亚胺组合物及杀真菌方法 - Google Patents

杀真菌性吡啶基亚胺组合物及杀真菌方法 Download PDF

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CN1050538A
CN1050538A CN90104426A CN90104426A CN1050538A CN 1050538 A CN1050538 A CN 1050538A CN 90104426 A CN90104426 A CN 90104426A CN 90104426 A CN90104426 A CN 90104426A CN 1050538 A CN1050538 A CN 1050538A
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唐·罗伯特·贝克
凯瑟·哈维·布朗内尔
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Abstract

新的杀真菌性吡啶基亚胺化物，其通式如图所 示，其中R选自C1～C16烷基，C3～C8环烷基，C2～ C8链烯基，C2～C8取代链烯基，C3～C4羰烷氧烷基， 芳基，具C1～C3烷基的芳烷基，取代芳基和芳烷基 (其取代物为氯，溴，氟和-NO2)，糠基，吡啶基，C1～C6 烷基取代的硫代磷酰基和 (其中R3和R4 为C1～C3烷基且能形成杂环)，R1选自卤素，C1～C3 烷氧基和C1～C3卤代烷氧基，R2选自甲基和氢，X 是S或O；以及其杀真菌性的有机和无机盐类。

Description

真菌对作物如大麦，稻谷，蕃茄，小麦，豆子，玫瑰，葡萄和其它重要的农作物的侵染，会使农产品在质量和数量上均遭到严重损失。因而，急需的是防止，控制或消除真菌生长的方法。在防止真菌固定和生长于重要的农作物方面，已用喷洒市售杀真菌剂作了尝试。另外还需要一种治理性杀真菌剂，当观察到有真菌性侵染时，用它能破坏真菌，并且在作为一种侵染后的治疗性喷洒剂应用时，能消除真菌侵染的有害效应。
本文公开的是通式如下的新的杀真菌性吡啶基亚胺酸酯类化合物及其适用于杀真菌的有机或无机盐类：
其中R选自这样一个组：C1～C16烷基，C3～C8环烷基，C2～C8链烯基，C2～C8取代链烯基，C3～C4烷氧羰烷基，芳基，具C1～C3烷基的芳烷基，取代的芳基和芳烷基（其中的取代基是-Cl，-Br，-F和-NO2），优选的芳基和芳烷基是苯基，苄基，苯乙基和萘基，糠基，吡啶基，C1～C6（优选C1～C4）烷基取代的硫代磷酰基和
Figure 901044261_IMG9
（其中R3和R4是C1～C10烷基，并且能形成一个杂环），R1是选自由下列基团组成的一个组：卤素，如氯，氟和溴，优选氯，C1～C3烷氧基，如丙氧基，乙氧基和甲氧基，优选甲氧基，以及C1～C3卤代烷氧基，R2选自由甲基和氢组成的一个组，X是S或O;它们作为预防性或治疗性杀真菌应用时，均为高效的杀真菌剂。
术语“杀真菌剂”指能防治真菌生长的化合物。“防治”包括阻止、破坏和抑制真菌的生长。术语“治理性”指在侵染后应用时，该杀真菌剂能控制真菌的侵染和防止真菌对宿主作物进一步的有害效应。
本发明的新杀真菌性化合物是通式如下的吡啶亚胺酸酯类化合物及其适用于杀真菌的有机或无机盐：
Figure 901044261_IMG10
其中R选自下面一组基团：C1～C16烷基，C3～C8环烷基，C2～C8链烯基，C2～C8取代链烯基，C3～C4烷氧羰烷基，芳基，具C1～C3烷基的芳烷基，取代的芳基和芳烷基（其中的取代基是-Cl，-Br，-F和-NO2），优选的芳基和芳烷基是苯基，苄基，苯乙基和萘基，糠基，吡啶基，C1～C6（优选C1～C4）烷基取代的硫代磷酰基，以及
Figure 901044261_IMG11
（其中R3和R4为C1～C10烷基并能形成一个杂环），R1选自下面一组基团：卤素，如氯，氟和溴，优选氯，C1～C3烷氧基，如丙氧基，乙氧基和甲氧基，优选甲氧基和C1～C3卤代烷氧基，R2选自甲基和氢，X是S或O。它们在作为预防性或治理性杀真菌剂应用时，均为高效的杀真菌剂。
本发明化合物的一般制备方法是用一种新型适当取代的N-（2-取代-5-吡啶基）环丙烷甲亚胺酰氯进行反应而得到，该化合物具如下通式：
Figure 901044261_IMG12
其中R1和R2定义如上所述，它是由2位上有适当取代基的5-氨基吡啶与环丙烷羰酰氯在有酸净化剂存在的条件下于惰性溶剂如二氯甲烷中反应制得。再使所得到的环丙烷甲酰胺与五氯化磷在惰性溶剂如二氯甲烷中反应得到相应的亚胺酰氯，再使后者与适当取代的硫醇在一惰性溶剂如二氯甲烷中，于一适当的反应器内反应。在反应器中最好保持有酸净化剂如吡啶。该反应一般在室温下进行，但依据硫醇和亚胺酰氯则可在-20至80℃的温度范围内进行。该反应一般在1～3小时内完成。所获产物用常规方法回收，即用碱溶液如NaOH和水洗，用常规干燥剂如硫酸镁干燥，蒸发除去溶剂得到产物。各种吡啶基环丙烷甲亚胺酸酯类化合物的盐可按常规方法用至少一摩尔的路易斯酸与硫代亚胺酸酯化合物反应制成。反应最好在适于硫代亚胺酸酯类化合物的溶剂中进行。所制成的盐类用常规技术从反应混合物中回收得到。
本发明的吡啶基硫代亚胺酸酯类化合物是弱碱性化合物。吡啶环上的未质子化的氮原子可用酸予以质子化，有机酸或无机酸均可。无机酸的代表有盐酸，硝酸，氢溴酸，硫酸，氨基磺酸和磷酸。有机酸的代表有乙酸，三氟乙酸，苯甲酸，苯磺酸，对甲苯磺酸，萘磺酸，苯膦酸和有机磷酸。这样形成的盐类也是杀真菌性的。
实施例1
N-（2-甲氧基-5-吡啶基）-环丙烷甲酰胺的制备
在含有200ml二氯甲烷的反应烧瓶中将5-氨基-2-甲氧基吡啶（12.4g，0.10mole）和10ml吡啶相混合。历时2分钟将9.1ml（0.10mole）环丙烷碳酰氯加到反应混合物中。反应是放热性的，温度升到34℃。让该反应在室温下进行一小时，然后用200ml  5%氢氧化钠和100ml水洗反应混合物。分离所获的有机相，以无水硫酸镁干燥。晶体析出后，将混合物过滤，用300ml丙酮洗，滤液经真空蒸发得到固体物，将其与己烷其研制，干燥后，得16.7克。经红外光谱和核磁共振谱鉴定，该产物确为标题化合物，熔点为130～131℃。该化合物被定为1号化合物。
实施例2
N-（2-甲氧基-5-吡啶基）环丙烷碳亚胺酰氯的制备
50ml二氯甲烷和10.4g（0.05M）五氧化磷在一反应烧瓶中混合。在氮气保护并在搅拌条件下，将9g（0.05M）实施例1的化合物分批加入到反应烧瓶中。反应为放热性，室温下搅拌1小时，然后再加热搅拌回流1小时使反应器中的固体溶解并反应。反应混合物经真空蒸发得到固状产物，用乙醚洗两次（每次用50ml），真空干燥后得12.0g固体，经核磁共振谱鉴定为标题化合物。
实施例3
N-（2-甲氧基-5-吡啶基）环丙烷硫代甲亚胺酸S-乙基酯的制备
在一个300ml单颈圆底烧瓶中，在旋摇下，将3g（0.01mole）实施例2的化合物和0.74ml（0.01mole）乙硫醇溶于150ml二氯甲烷中。加入3.0ml三乙胺。该反应混合物变为紫色，1小时后变为清澈。所获溶液在旋转蒸发器上蒸发后，将得到的油状物与50ml己烷研磨并过滤。己烷提取物经旋转蒸发后得油状物1.6g，用核磁共振谱鉴定为标题化合物。该化合物被称作1号化合物。
表1中给出于本发明的代表化合物及其性质。
Figure 901044261_IMG13
Figure 901044261_IMG14
实施例4
等摩尔预防性喷洒剂的评价程序
叶锈病（LR）
试验前12天将7粒小麦（Anz  A  wheat）种子种入直径2英寸小盆的沙壤土中。试验化合物用50∶50的丙酮/水溶液稀释，制成一浓度在0.004M以下的溶液系列。用喷雾器将试验溶液12ml喷洒到小麦植株上。
隐匿柄锈菌（Puccinia recondita）夏孢子悬浮液由具孢子突起的小麦叶上真空吸来的孢子以105个孢子/ml悬浮于含0.5% Tween 20的去离子水中而制成。用试验化合物溶液处理24小时后，以喷洒方法用孢子悬浮液接种植株至饱和状，让其在叶子上干燥，再重喷洒至饱和状，然后将植株移入到黑暗雾室中。于雾室中放置48小时后，将植株移到地下灌溉温室中。
接种10天后记录结果，根据同未处理对照株植比的病灶区域减少的百分数，将试验结果表示为叶锈病防治百分数。能达到90%疾病控制的化合物浓度（EC90）可由剂量/稀释曲线上确定。
葡萄孢芽枯病（BB）
将两片白玫瑰花瓣放入铺有湿滤纸的培养皿中。试验化合物用50∶50的丙酮/水的溶液稀释成一系列浓度在0.004M以下的溶液。将半毫升试验溶液喷雾到花瓣上，使之干燥。将从在Elliot′s  V-8琼脂上生长了2周的灰葡萄孢（Botrytis  cineria）培养物中获得的5mm孢塞加到10ml无菌蒸馏水+0.5%葡萄汁的液体中制成接种物。将这种接种悬浮液以20微升为一滴加到每片花瓣上。将载有接种过的花瓣的培养皿放入封密的塑料盒中以保持饱和湿度。
接种4天后记录结果，以与丙酮/水的对照组相比在坏死区域减少的百分数来表示。能达到90%疾病控制的化合物浓度（EC90）从剂量/稀释曲线上确定。
表2中给出的结果是以ppm表示的EC90近似值。数字（750）表示在750ppm时的部分控制。
表2
化合物号  LR  BB
1  750  80
2  750  25
3  -  250
4  -  20
5  -  750
6  -  750
7  -  250
8  -  80
9  -  30
10  -  （750）
11  -  （750）
12  -  250
13  -  750
14  -  （750）
15  -  250
16  -  80
17  -  50
18  -  30
19  -  40
20  -  （750）
21  -  （750）
22  -  （750）
23  -  20
24  -  20
25  -  35
26  （750）  （750）
27  -  70
28  -  80
29  -  30
30  -  250
实施例5
治理性喷洒剂的评价程序
叶锈病（LR）
试验前12天将7粒小麦（Anza wheat）种子植入直径2英寸小盒的沙壤土中。隐匿柄锈菌（Puccinia recondita）夏孢子悬浮液是由具孢子突起的小麦叶上真空吸来的孢子以105个孢子/ml悬浮于去离子水+0.5% Tween 20而制成。喷洒孢子悬浮液接种植株至饱和状，让其在叶子上干燥，再喷洒至饱和状，然后将植株移入雾室。雾室中放置48小时后，将植株移入地下灌溉温室中。
将试验化合物用50∶50的丙酮/水的溶液稀释以得到一由0.0075%开始降低的浓度系列。接种植株50小时后，将植株放在一个旋转盘上，并用喷雾器将试验溶液喷至近于饱和状（接种时间是从植株放入雾室时起来计算的）。
接种10天后记录结果，以同未处理对照植株相比在病灶区减少的百分数为基础得到叶锈病控制百分数。
表3
化合物号  叶锈病
1  100
2  100
本发明化合物对葡萄孢芽枯病特别有效，并且与用作葡萄孢菌的预防性和治理性的标准市售化合物相比是更为有效的预防性叶面喷洒剂和治理性叶面喷洒剂。本发明化合物对之特别有效的另一真菌是隐匿柄锈菌（Puccinia  recondita）。
本发明的化合物可用作杀真菌剂，特别是作为防护性或治理性杀真菌剂，并且可以不同方式和不同浓度应用。一般说来，这些化合物及其制剂可以直接用于作物叶片，植株生长于其中的土壤及植株或土壤的灌溉水中。实际上，鉴于一种毒素的剂型和使用方式可能影响某一应用中各种物质的活性这一事实，此处所限定的化合物是以有效杀真菌剂量与通常用于促进在农业上的活性成分更好分散的赋形剂和载体一起混合制成杀真菌性组合物。例如，这些活性的杀真菌化合物可根据所需的应用方式而制成可湿性粉剂，可乳化的浓缩液，粉尘剂，溶液或其他的已知剂型。优选的用在预防性或治疗性杀真菌方面的剂型是可湿性粉剂和可乳化的浓缩液。这些剂型所含的活性成分可少至0.5%（重量），也可多至95%（重量）或更多。有效的杀真菌剂量依据所要处理的种子及植物的性质而定，使用量可为约每英亩0.05至25磅，优选约每英亩0.1至10磅。
可湿性粉剂的型式是细颗粒状的，它能在水或其它分散剂中迅速分散。可湿性粉剂最终用于土壤和植物时，是作为干粉尘或作为分散体于水或其它液体中的悬浮体应用的。对可湿性粉剂而言，典型的载体包括漂白土，高岭土，硅石和其它易湿的有机或无机稀释剂。一般制备的可湿性粉剂含约5%至95%的活性成分，并且通常含有小量的润湿剂，分散剂或乳化剂，以促进润滑和分散。
干流动性的或水分散性的颗粒是附聚的可湿性粉剂，是由盘式粒化床或流化床制成的。干流动性颗粒最终用于土壤或植物时是作为分散物存在于水或其它液体中。这些颗粒不含粉尘，当干燥时可自由流动，当稀释于水中时，形成均一的分散剂。对干流动性颗粒而言，典型的载体包括漂白土，高岭土，粘土，硅石和其它易湿的有机或无机稀释物。常规制备的干流动性颗粒含有约5%至95%的活性成分，并且一般还含有少量的润湿剂，分散剂或乳化剂，以促进润湿和分散。
可乳化浓缩液均质液体组合物，可分散于水或其它分散剂中，它可仅由活性化合物以及液体或固体乳化剂组成，或者还可以含有液体载体，如二甲苯，重芳石脑油，异佛尔酮及其他非挥发性有机溶剂。用于杀真菌时，这些浓缩物分散于水或其它液体载体，通常以喷洒液的形式施用于被处理的地区。基本活性组分的重量百分比要依该组合物的应用方式来决定，但一般而言，活性成分的含量约为杀真菌组合物重量的0.1%至95%。
农用剂型中所用的润湿剂，分散剂和乳化剂的典型例子有磺酸烷基酯，磺酰烷芳基酯，硫酸烷基酯，硫酸烷芳基酯及其钠盐，多羟基醇，其它类型的表面活性剂，其中大多数均有市售。当使用表面活性剂时，其含量一般占杀真菌组合物重量的0.1%至15%。
粉剂是由活性成分与微细的固体如滑石，粘土，面粉和其它对该活性成分起分散剂和载体作用的有机以及无机固体形成的自由流动混合物，该粉剂是很有用的剂型。
由细微固体药物分散于液体载体如水或油中制成的均质悬浮液一糊浆，是用于特殊目的。这种剂型通常含有约5%至95%的活性成分（重量），并且还可含有少量的润湿剂，分散剂或乳化剂以促进分散。应用时，糊浆通常经稀释作为一种喷洒剂施于作业区。
典型剂型的实例
油剂
成分  重量%
1号化合物  1
油溶剂-重芳石脑油  99
-
合计  100
可乳化浓缩液
2号化合物  50
煤油  45
乳化剂（长链乙氧基化的聚醚与  5
长链磺酸盐的混合物）
合计  100
可乳化浓缩液
3号化合物  90
煤油  5
乳化剂（长链乙氧基化的聚醚与  5
长链磺酸盐的混合物）
合计  100
粉尘剂和/或粉剂
成分  重量%  重量%  重量%
1号化合物  0.5  50.0  90.0
美国活性白土粉  93.5  44.0  4.0
木素磺酸钠  5.0  5.0  5.0
二辛基磺基丁二酸钠  1.0  1.0  1.0
合计  100.0  100.0  100.0
其它有用的杀真菌剂型包括活性成分以所需浓度完全溶于分散剂中而形成的简单溶液，这些分散剂有丙酮，烷基化萘，二甲苯和其它有机溶剂。借助于低沸点分散溶剂载体如氟利昂的汽化作用而使活性成分很好地分散于其中的压力喷洒液，典型的是汽溶胶，也可以使用。
本发明的杀真菌组合物按常规方法施用于植物。例如，粉剂和液剂可用动力洒粉器，臂式及手摇式喷洒器和喷粉器施于植物。这些组合物可以粉剂和喷洒剂的形式由飞机喷洒，因为在低剂量时也是有效的。

Claims (5)

1、一种杀真菌剂组合物，其特征在于含有0.5-95%(重量)作为活性组分的通式如下的化合物或其适用于杀真菌的有机或无机盐以及惰性稀释剂载体
Figure 901044261_IMG3
式中R选自C1-C16烷基，C3-C8环烷基，C2-C8链烯基，C2-C8取代链烯基，C3-C4烷氧羰基烷基，芳基，含C1-C3烷基的芳烷基，取代的芳基和芳烷基(其中取代基是-CI、-Br、F和-NO2)，糠基，吡啶基，C1-C6烷基取代的硫代磷酰基和 (其中R3和R4是C1-C3烷基并能形成杂环)；R1选自卤素，C1-C3烷氧基和C1-C3卤代烷氧基，R2是氢；X是S或O。
2、防治真菌的方法，包括向需要防治的区域施用含有有效杀菌量的下式化合物或有机和无机盐的杀真菌组合物：
Figure 901044261_IMG5
式中R选自C1-C16烷基，C3-C8环烷基，C2-C8链烯基，C2-C8取代链烯基，C3-C4烷氧羰基烷基，芳基，含C1-C3烷基的芳烷基，取代的芳基和芳烷基（其中取代基是-Cl、-Br、F和-NO2），糠基，吡啶基，C1-C6烷基取代的硫代磷酰基和
Figure 901044261_IMG6
（其中R3和R4是C1-C4烷基并能形成杂环）;R1选自卤素，C1-C3烷氧基和C1-C3卤代烷氧基;R2是氢;X是S或O。
3、根据权利要求2的方法，其中施用的组合物中的有效化合物是该式中R是-C（CH3）3，R1是-OCH3，R2是-H，X是-O的化合物。
4、根据权利要求2的方法，其中施用的组合物中的有效化合物是该式中R是-P〔OCH2CH（CH3）2〕2，R1是-OCH3，R2是-H，X是-S的化合物。
5、根据权利要求2的方法，其中施用的组合物中的有效化合物是该式中R是 ，R1是-OCH3，R2是-H，X是-O的化合物。
CN90104426A 1986-05-02 1987-04-29 杀真菌性吡啶基亚胺组合物及杀真菌方法 Pending CN1050538A (zh)

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Families Citing this family (382)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI86418C (fi) * 1986-05-02 1992-08-25 Stauffer Chemical Co Fungicidiska pyridylcyklopropankarboxamider.
US4994473A (en) * 1987-11-17 1991-02-19 Ici Americas Inc. Pyridyl containing insecticides
GB9000130D0 (en) * 1990-01-04 1990-03-07 Ici Plc Fungicides
DE19745376A1 (de) 1997-10-14 1999-04-15 Bayer Ag Thiomide
WO2010103065A1 (en) 2009-03-11 2010-09-16 Basf Se Fungicidal compositions and their use
EP2413691A2 (en) 2009-04-02 2012-02-08 Basf Se Method for reducing sunburn damage in plants
BRPI1009073A2 (pt) 2009-06-12 2016-03-01 Basf Se compostos de triazol das fórmulas i e ii, compostos das fórmulas i e ii, composição agrícola, uso de um composto da fórmula i ou ii, método para controlar fungos nocivos, semente, composição farmacêutica, uso de um composto da fórmula i ou ii e método para tratar câncer ou infecções por vírus ou para combater fungos patogênicos para seres humanos e para animais
WO2010146032A2 (de) 2009-06-16 2010-12-23 Basf Se Fungizide mischungen
CN102459201A (zh) 2009-06-18 2012-05-16 巴斯夫欧洲公司 杀真菌的1，2，4-三唑衍生物
WO2010146116A1 (en) 2009-06-18 2010-12-23 Basf Se Triazole compounds carrying a sulfur substituent
WO2010146115A1 (en) 2009-06-18 2010-12-23 Basf Se Triazole compounds carrying a sulfur substituent
AU2010261822A1 (en) 2009-06-18 2012-01-19 Basf Se Triazole compounds carrying a sulfur substituent
BRPI1009688A2 (pt) 2009-06-18 2015-10-27 Basf Se mistura fungicida, fungicida, azolilmetiloxirano da fórmula 1, composto da fórmula 1a, composição agroquímica, semente e método para controlar fungos fitopatogênicos
CN102803232A (zh) 2009-06-18 2012-11-28 巴斯夫欧洲公司 杀真菌的具有5-硫取代基的1,2,4-三唑衍生物
EP2443098A1 (en) 2009-06-18 2012-04-25 Basf Se Antifungal 1, 2, 4-triazolyl derivatives
WO2010149758A1 (en) 2009-06-25 2010-12-29 Basf Se Antifungal 1, 2, 4-triazolyl derivatives
BR112012001001A2 (pt) 2009-07-14 2016-11-16 Basf Se compositos azol das formulas i e ii, compostos das formulas i e i, compostos de formula ix, composição agricola, uso de um composto farmaceutica, metodo para tratar infecções de câncer ou virus para combater fungos zoopatigênicos ou humanopatogenicos
BR112012001595B1 (pt) 2009-07-28 2018-06-05 Basf Se Composição de suspo-emulsão pesticida, método para preparar a composição de suspo-emulsão pesticida, uso de uma composição de suspo- emulsão, métodos para combater fungos fitopatogênicos e método para tratar sementes
WO2011026796A1 (en) 2009-09-01 2011-03-10 Basf Se Synergistic fungicidal mixtures comprising lactylates and method for combating phytopathogenic fungi
WO2011069912A1 (de) 2009-12-07 2011-06-16 Basf Se Triazolverbindungen, ihre verwendung sowie sie enthaltende mittel
WO2011069894A1 (de) 2009-12-08 2011-06-16 Basf Se Triazolverbindungen, ihre verwendung sowie sie enthaltende mittel
WO2011069916A1 (de) 2009-12-08 2011-06-16 Basf Se Triazolverbindungen, ihre verwendung als fungizide sowie sie enthaltende mittel
WO2011110583A2 (en) 2010-03-10 2011-09-15 Basf Se Fungicidal mixtures comprising triazole derivatives
EP2366289A1 (en) 2010-03-18 2011-09-21 Basf Se Synergistic fungicidal mixtures
US9288996B2 (en) 2010-03-18 2016-03-22 Basf Se Fungicidal compositions comprising a phosphate solubilizing microorganism and a fungicidally active compound
DE102011017669A1 (de) 2010-04-29 2011-11-03 Basf Se Synergistische fungizide Mischungen
DE102011017716A1 (de) 2010-04-29 2011-11-03 Basf Se Synergistische fungizide Mischungen
DE102011017541A1 (de) 2010-04-29 2011-11-10 Basf Se Synergistische fungizide Mischungen
DE102011017715A1 (de) 2010-04-29 2012-03-08 Basf Se Synergistische fungizide Mischungen
DE102011017670A1 (de) 2010-04-29 2011-11-03 Basf Se Synergistische fungizide Mischungen
EP2402345A1 (en) 2010-06-29 2012-01-04 Basf Se Pyrazole fused bicyclic compounds
EP2402336A1 (en) 2010-06-29 2012-01-04 Basf Se Pyrazolopyridine compounds
EP2402339A1 (en) 2010-06-29 2012-01-04 Basf Se Pyrazolopyridine compounds
EP2402340A1 (en) 2010-06-29 2012-01-04 Basf Se Pyrazolopyridine compounds
EP2402335A1 (en) 2010-06-29 2012-01-04 Basf Se Pyrazolopyridine compounds
EP2402344A1 (en) 2010-06-29 2012-01-04 Basf Se Pyrazole fused bicyclic compounds
EP2402343A1 (en) 2010-06-29 2012-01-04 Basf Se Pyrazole-fused bicyclic compounds
EP2401915A1 (en) 2010-06-29 2012-01-04 Basf Se Pyrazolopyridine compounds
EP2402338A1 (en) 2010-06-29 2012-01-04 Basf Se Pyrazolopyridine compounds
EP2402337A1 (en) 2010-06-29 2012-01-04 Basf Se Pyrazolopyridine compounds
MX2013001161A (es) 2010-08-03 2013-03-22 Basf Se Composicion fungicida.
EP2447262A1 (en) 2010-10-29 2012-05-02 Basf Se Pyrrole, furane and thiophene derivatives and their use as fungicides
EP2447261A1 (en) 2010-10-29 2012-05-02 Basf Se Pyrrole, furane and thiophene derivatives and their use as fungicides
EP2465350A1 (en) 2010-12-15 2012-06-20 Basf Se Pesticidal mixtures
EP2481284A3 (en) 2011-01-27 2012-10-17 Basf Se Pesticidal mixtures
CN103442567B (zh) 2011-03-23 2016-02-10 巴斯夫欧洲公司 含有包含咪唑鎓基团的聚合离子型化合物的组合物
EP2696689A1 (en) 2011-04-15 2014-02-19 Basf Se Use of substituted dithiine-tetracarboximides for combating phytopathogenic fungi
CN103501615A (zh) 2011-04-15 2014-01-08 巴斯夫欧洲公司 取代的二噻烯-二羧酰亚胺在防治植物病原性真菌中的用途
CN103491775A (zh) 2011-04-21 2014-01-01 巴斯夫欧洲公司 3,4-二取代的吡咯-2,5-二酮及其作为杀真菌剂的用途
AR086961A1 (es) 2011-06-17 2014-02-05 Basf Se Mezclas fungicidas sinergicas que comprenden 2,3,5,6-tetraciano-[1,4]ditiina
EA026736B1 (ru) 2011-07-13 2017-05-31 Басф Агро Б.В. Фунгицидные замещенные 2-[2-галогеналкил-4-(фенокси)фенил]-1-[1,2,4]триазол-1-ил-этанольные соединения
US9137996B2 (en) 2011-07-15 2015-09-22 Basf Se Fungicidal alkyl- and aryl-substituted 2[-2-chloro-4-(dihalo-phenoxy)-phenyl]-1-[1,2,4]triazol-1-yl-ethanol compounds
EP2731438B1 (en) 2011-07-15 2015-04-08 Basf Se Fungicidal alkyl-substituted 2-[2-chloro-4-(4-chloro-phenoxy)-phenyl]-1-[1,2,4]triazol-1-yl-ethanol compounds
JP2014520833A (ja) 2011-07-15 2014-08-25 ビーエーエスエフ ソシエタス・ヨーロピア 殺菌性フェニルアルキル−置換２−［２−クロロ−４−（４−クロロ−フェノキシ）−フェニル］−１−［１，２，４］トリアゾール−１−イル−エタノール化合物
US20140187423A1 (en) 2011-08-15 2014-07-03 Basf Se Fungicidal substituted 1--1H-[1,2,4]triazole compounds
EA201400234A1 (ru) 2011-08-15 2014-07-30 Басф Се Фунгицидные замещенные 1-{2-[2-галоген-4(4-галогенфенокси)фенил]-2-алкинилоксиэтил}-1н-[1,2,4]триазолные соединения
US20140162876A1 (en) 2011-08-15 2014-06-12 Basf Se Fungicidal substituted 1--1H-[1,2,4]triazole compounds
EP2744791B1 (en) 2011-08-15 2015-10-28 Basf Se Fungicidal substituted 1-{2-[2-halo-4-(4-halogen-phenoxy)-phenyl]-2-alkoxy-3-methyl-butyl}-1h-[1,2,4]triazole compounds
WO2013024080A1 (en) 2011-08-15 2013-02-21 Basf Se Fungicidal substituted 1-{2-[2-halo-4-(4-halogen-phenoxy)-phenyl ]-2-alkoxy-2-cyclyl-ethyl}-1h [1,2,4]triazole compounds
EP2559688A1 (en) 2011-08-15 2013-02-20 Basf Se Fungicidal substituted 1-{2-[2-halo-4-(4-halogen-phenoxy)-phenyl]-2-butoxy-ethyl}-1h [1,2,4]triazole compounds
CA2842861A1 (en) 2011-08-15 2013-02-21 Basf Se Fungicidal substituted 1-{2-[2-halo-4-(4-halogen-phenoxy)-phenyl]-2-alkoxy-2-alkynyl/alkenyl-ethyl}-1h-[1,2,4]triazole compounds
EP2744794B1 (en) 2011-08-15 2015-12-30 Basf Se Fungicidal substituted 1-{2-cyclyloxy-2-[2-halo-4-(4-halogen-phenoxy)-phenyl]-ethyl}-1h-[1,2,4]triazole compounds
LT2776038T (lt) 2011-11-11 2018-04-25 Gilead Apollo, Llc Acc inhibitoriai ir jų panaudojimas
WO2013092224A1 (en) 2011-12-21 2013-06-27 Basf Se Use of strobilurin type compounds for combating phytopathogenic fungi resistant to qo inhibitors
WO2013113778A1 (en) 2012-02-03 2013-08-08 Basf Se Fungicidal pyrimidine compounds
WO2013113773A1 (en) 2012-02-03 2013-08-08 Basf Se Fungicidal pyrimidine compounds
AR089884A1 (es) 2012-02-03 2014-09-24 Basf Se Compuestos fungicidas de pirimidina
WO2013113776A1 (en) 2012-02-03 2013-08-08 Basf Se Fungicidal pyrimidine compounds
WO2013113716A1 (en) 2012-02-03 2013-08-08 Basf Se Fungicidal pyrimidine compounds
IN2014DN07224A (zh) 2012-02-03 2015-04-24 Basf Se
WO2013113782A1 (en) 2012-02-03 2013-08-08 Basf Se Fungicidal pyrimidine compounds
WO2013113719A1 (en) 2012-02-03 2013-08-08 Basf Se Fungicidal pyrimidine compounds ii
WO2013113720A1 (en) 2012-02-03 2013-08-08 Basf Se Fungicidal pyrimidine compounds
WO2013113787A1 (en) 2012-02-03 2013-08-08 Basf Se Fungicidal pyrimidine compounds
WO2013113781A1 (en) 2012-02-03 2013-08-08 Basf Se Fungicidal pyrimidine compounds i
WO2013124250A2 (en) 2012-02-20 2013-08-29 Basf Se Fungicidal substituted thiophenes
WO2013135672A1 (en) 2012-03-13 2013-09-19 Basf Se Fungicidal pyrimidine compounds
JP2015512891A (ja) 2012-03-13 2015-04-30 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 殺菌性ピリミジン化合物
WO2013144223A1 (en) 2012-03-30 2013-10-03 Basf Se N-substituted pyrimidinylidene compounds and derivatives for combating animal pests
US9334238B2 (en) 2012-03-30 2016-05-10 Basf Se N-substituted pyridinylidenes for combating animal pests
WO2013149940A1 (en) 2012-04-02 2013-10-10 Basf Se Acrylamide compounds for combating invertebrate pests
MX2014011995A (es) 2012-04-03 2015-09-04 Basf Se Compuestos de furanona heterobicíclicos n-sustituidos y derivados para combatir plagas de animales.
WO2013150115A1 (en) 2012-04-05 2013-10-10 Basf Se N- substituted hetero - bicyclic compounds and derivatives for combating animal pests
AU2013255894A1 (en) 2012-05-04 2014-11-13 Basf Se Substituted pyrazole-containing compounds and their use as pesticides
JP6242872B2 (ja) 2012-05-24 2017-12-06 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Ｎ−チオ−アントラニルアミド化合物、及び殺有害生物剤としてのそれらの使用
JP2015525223A (ja) 2012-06-14 2015-09-03 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 動物有害生物を駆除するための置換３−ピリジルチアゾール化合物および誘導体を使用する有害生物防除方法
WO2014009293A1 (en) 2012-07-13 2014-01-16 Basf Se New substituted thiadiazoles and their use as fungicides
US20150208656A1 (en) 2012-07-13 2015-07-30 Basf Se Substituted thiadiazoles and their use as fungicides
MX2015004175A (es) 2012-10-01 2015-06-10 Basf Se Uso de compuestos de n-tio-antranilamida en plantas cultivadas.
WO2014053401A2 (en) 2012-10-01 2014-04-10 Basf Se Method of improving plant health
US20150250175A1 (en) 2012-10-01 2015-09-10 Basf Se Pesticidally active mixtures comprising anthranilamide compounds
WO2014053403A1 (en) 2012-10-01 2014-04-10 Basf Se Method of controlling insecticide resistant insects
WO2014053407A1 (en) 2012-10-01 2014-04-10 Basf Se N-thio-anthranilamide compounds and their use as pesticides
CN104768377A (zh) 2012-10-01 2015-07-08 巴斯夫欧洲公司 包含邻氨基苯甲酰胺类化合物的农药活性混合物
US20150237858A1 (en) 2012-10-01 2015-08-27 Basf Se Method of controlling ryanodine-modulator insecticide resistant insects
WO2014056780A1 (en) 2012-10-12 2014-04-17 Basf Se A method for combating phytopathogenic harmful microbes on cultivated plants or plant propagation material
WO2014079820A1 (en) 2012-11-22 2014-05-30 Basf Se Use of anthranilamide compounds for reducing insect-vectored viral infections
EP2928873A1 (en) 2012-11-27 2015-10-14 Basf Se Substituted 2-[phenoxy-phenyl]-1-[1,2,4]triazol-1-yl-ethanol compounds and their use as fungicides
WO2014082871A1 (en) 2012-11-27 2014-06-05 Basf Se Substituted 2-[phenoxy-phenyl]-1-[1,2,4]triazol-1-yl-ethanol compounds and their use as fungicides
US20150313229A1 (en) 2012-11-27 2015-11-05 Basf Se Substituted [1,2,4] Triazole Compounds
WO2014082879A1 (en) 2012-11-27 2014-06-05 Basf Se Substituted [1,2,4]triazole compounds
WO2014086856A1 (en) 2012-12-04 2014-06-12 Basf Agro B.V., Arnhem (Nl) Compositions comprising a quillay extract and a biopesticide
WO2014086601A1 (en) 2012-12-04 2014-06-12 Basf Se New substituted 1,4-dithiine derivatives and their use as fungicides
WO2014086850A1 (en) 2012-12-04 2014-06-12 Basf Agro B.V., Arnhem (Nl) Compositions comprising a quillay extract and a fungicidal inhibitor of respiratory complex ii
WO2014086854A1 (en) 2012-12-04 2014-06-12 Basf Agro B.V., Arnhem (Nl) Compositions comprising a quillay extract and a plant growth regulator
WO2014095534A1 (en) 2012-12-19 2014-06-26 Basf Se New substituted triazoles and imidazoles and their use as fungicides
EP2745691A1 (en) 2012-12-19 2014-06-25 Basf Se Substituted imidazole compounds and their use as fungicides
WO2014095548A1 (en) 2012-12-19 2014-06-26 Basf Se Substituted [1,2,4]triazole compounds and their use as fungicides
EP2746274A1 (en) 2012-12-19 2014-06-25 Basf Se Substituted [1,2,4]triazole compounds
EP2746277A1 (en) 2012-12-19 2014-06-25 Basf Se Fungicidal imidazolyl and triazolyl compounds
WO2014095381A1 (en) 2012-12-19 2014-06-26 Basf Se Fungicidal imidazolyl and triazolyl compounds
EP2746276A1 (en) 2012-12-19 2014-06-25 Basf Se New substituted triazoles and imidazoles and their use as fungicides
EP2746256A1 (en) 2012-12-19 2014-06-25 Basf Se Fungicidal imidazolyl and triazolyl compounds
EP2746262A1 (en) 2012-12-19 2014-06-25 Basf Se Substituted [1,2,4]triazole and imidazole compounds for combating phytopathogenic fungi
EP2746278A1 (en) 2012-12-19 2014-06-25 Basf Se Substituted [1,2,4]triazole and imidazole compounds
EP2746264A1 (en) 2012-12-19 2014-06-25 Basf Se Substituted [1,2,4]triazole and imidazole compounds
EP2746266A1 (en) 2012-12-19 2014-06-25 Basf Se New substituted triazoles and imidazoles and their use as fungicides
US20150307460A1 (en) 2012-12-19 2015-10-29 Basf Se Substituted Triazoles and Imidazoles and Their Use as Fungicides
EP2746263A1 (en) 2012-12-19 2014-06-25 Basf Se Alpha-substituted triazoles and imidazoles
WO2014095672A1 (en) 2012-12-19 2014-06-26 Basf Se Substituted [1,2,4]triazole compounds and their use as fungicides
EP2746255A1 (en) 2012-12-19 2014-06-25 Basf Se Substituted [1,2,4]triazole and imidazole compounds
EP2746275A1 (en) 2012-12-19 2014-06-25 Basf Se New substituted triazoles and imidazoles and their use as fungicides
EP2746279A1 (en) 2012-12-19 2014-06-25 Basf Se Fungicidal imidazolyl and triazolyl compounds
WO2014095555A1 (en) 2012-12-19 2014-06-26 Basf Se New substituted triazoles and imidazoles and their use as fungicides
EP2934147B1 (en) 2012-12-20 2019-11-27 BASF Agro B.V. Compositions comprising a triazole compound
EP2746260A1 (en) 2012-12-21 2014-06-25 Basf Se Substituted [1,2,4]triazole and imidazole compounds
EP2746257A1 (en) 2012-12-21 2014-06-25 Basf Se Substituted [1,2,4]triazole and imidazole compounds
EP2746259A1 (en) 2012-12-21 2014-06-25 Basf Se Substituted [1,2,4]triazole and imidazole compounds
EP2746258A1 (en) 2012-12-21 2014-06-25 Basf Se Substituted [1,2,4]triazole and imidazole compounds
BR112015015503A2 (pt) 2012-12-27 2017-07-11 Basf Se composto substituído, composição veterinária, utilização de um composto, método para o controle de pragas de invertebrados e para o tratamento ou proteção de um animal e material de propagação do vegetal
WO2014118099A1 (en) 2013-01-30 2014-08-07 Basf Se Fungicidal naphthoquinones and derivatives
WO2014124850A1 (en) 2013-02-14 2014-08-21 Basf Se Substituted [1,2,4]triazole and imidazole compounds
BR112015018853B1 (pt) 2013-03-20 2021-07-13 Basf Corporation Mistura, composição agroquímica, método para controlar fungos fitopatogênicos, método para proteção do material de propagação dos vegetais e semente revestida
US20160270405A1 (en) 2013-03-20 2016-09-22 Basf Corporation Synergistic Compositions Comprising a Bacillus Subtilis Strain and a Pesticide
EP2783569A1 (en) 2013-03-28 2014-10-01 Basf Se Compositions comprising a triazole compound
WO2014170300A1 (en) 2013-04-19 2014-10-23 Basf Se N-substituted acyl-imino-pyridine compounds and derivatives for combating animal pests
CA2911818A1 (en) 2013-05-10 2014-11-13 Nimbus Apollo, Inc. Acc inhibitors and uses thereof
EP2813499A1 (en) 2013-06-12 2014-12-17 Basf Se Substituted [1,2,4]triazole and imidazole compounds
EP2815647A1 (en) 2013-06-18 2014-12-24 Basf Se Novel strobilurin-type compounds for combating phytopathogenic fungi
EP2815649A1 (en) 2013-06-18 2014-12-24 Basf Se Fungicidal mixtures II comprising strobilurin-type fungicides
BR112015031439A2 (pt) 2013-06-21 2017-07-25 Basf Se métodos para o combate ou controle das pragas, para o tratamento, prevenção e proteção de culturas de soja, para o controle e proteção do material de propagação dos vegetais de soja, para o combate ou controle das pragas e utilização de um composto de fórmula i
EP3022185B1 (en) 2013-07-15 2017-09-06 Basf Se Pesticide compounds
WO2015011615A1 (en) 2013-07-22 2015-01-29 Basf Corporation Mixtures comprising a trichoderma strain and a pesticide
EP2835052A1 (en) 2013-08-07 2015-02-11 Basf Se Fungicidal mixtures comprising pyrimidine fungicides
EP2839745A1 (en) 2013-08-21 2015-02-25 Basf Se Agrochemical formulations comprising a 2-ethyl-hexanol alkoxylate
CN105722833A (zh) 2013-09-16 2016-06-29 巴斯夫欧洲公司 杀真菌的嘧啶化合物
WO2015036059A1 (en) 2013-09-16 2015-03-19 Basf Se Fungicidal pyrimidine compounds
EA201600270A1 (ru) 2013-09-19 2016-08-31 Басф Се N-ацилимино гетероциклические соединения
CN106061254B (zh) 2013-10-18 2019-04-05 巴斯夫农业化学品有限公司 农药活性羧酰胺衍生物在土壤和种子施用和处理方法中的用途
BR112016013263B1 (pt) 2013-12-12 2020-08-25 Basf Se compostos, composição, uso de um composto e método para o combate dos fungos fitopatogênicos
EP3083581A1 (en) 2013-12-18 2016-10-26 Basf Se N-substituted imino heterocyclic compounds
WO2015091645A1 (en) 2013-12-18 2015-06-25 Basf Se Azole compounds carrying an imine-derived substituent
WO2015104422A1 (en) 2014-01-13 2015-07-16 Basf Se Dihydrothiophene compounds for controlling invertebrate pests
MX2016012540A (es) 2014-03-26 2017-01-09 Basf Se Compuestos de [1,2,4]triazol e imidazol sustituidos, como fungicidas.
EP2924027A1 (en) 2014-03-28 2015-09-30 Basf Se Substituted [1,2,4]triazole and imidazole fungicidal compounds
EP2949216A1 (en) 2014-05-30 2015-12-02 Basf Se Fungicidal substituted alkynyl [1,2,4]triazole and imidazole compounds
EP2949649A1 (en) 2014-05-30 2015-12-02 Basf Se Fungicide substituted [1,2,4]triazole and imidazole compounds
EP2952512A1 (en) 2014-06-06 2015-12-09 Basf Se Substituted [1,2,4]triazole compounds
EP2952507A1 (en) 2014-06-06 2015-12-09 Basf Se Substituted [1,2,4]triazole compounds
AR100743A1 (es) 2014-06-06 2016-10-26 Basf Se Compuestos de [1,2,4]triazol sustituido
EP2952506A1 (en) 2014-06-06 2015-12-09 Basf Se Substituted [1,2,4]triazole and imidazole compounds
BR122021017872B1 (pt) 2014-06-06 2021-11-23 Basf Se Uso dos compostos, composição agroquímica e método para o combate dos fungos fitopatogênicos
EP2979549A1 (en) 2014-07-31 2016-02-03 Basf Se Method for improving the health of a plant
EP3204390B1 (en) 2014-10-06 2019-06-05 Basf Se Substituted pyrimidinium compounds for combating animal pests
RU2707051C2 (ru) 2014-10-24 2019-11-21 Басф Се Неамфолитные, кватернизируемые и водорастворимые полимеры для модифицирования поверхностного заряда твердых частиц
BR112017009513A2 (pt) 2014-11-06 2018-02-06 Basf Se utilização de um composto heterobicíclico, utilização dos compostos i, compostos, composição agrícola ou veterinária, método para o combate ou controle de pragas, método para a proteção de culturas e sementes
EP3028573A1 (en) 2014-12-05 2016-06-08 Basf Se Use of a triazole fungicide on transgenic plants
CN107207443A (zh) 2015-02-06 2017-09-26 巴斯夫欧洲公司 作为硝化抑制剂的吡唑化合物
WO2016128240A1 (en) 2015-02-11 2016-08-18 Basf Se Pesticidal mixture comprising a pyrazole compound and two fungicides
EP3255990B1 (en) 2015-02-11 2020-06-24 Basf Se Pesticidal mixture comprising a pyrazole compound, an insecticide and a fungicide
WO2016162371A1 (en) 2015-04-07 2016-10-13 Basf Agrochemical Products B.V. Use of an insecticidal carboxamide compound against pests on cultivated plants
JP6806981B2 (ja) 2015-05-12 2021-01-06 ビーエイエスエフ・ソシエタス・エウロパエアＢａｓｆ Ｓｅ 硝化阻害剤としてのチオエーテル化合物
WO2016198611A1 (en) 2015-06-11 2016-12-15 Basf Se N-(thio)acylimino heterocyclic compounds
WO2016198613A1 (en) 2015-06-11 2016-12-15 Basf Se N-(thio)acylimino compounds
WO2017016883A1 (en) 2015-07-24 2017-02-02 Basf Se Process for preparation of cyclopentene compounds
US11142514B2 (en) 2015-10-02 2021-10-12 Basf Se Imino compounds with a 2-chloropyrimidin-5-yl substituent as pest-control agents
EP3359530A1 (en) 2015-10-05 2018-08-15 Basf Se Pyridine derivatives for combating phytopathogenic fungi
EP3371177A1 (en) 2015-11-02 2018-09-12 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
EP3165094A1 (en) 2015-11-03 2017-05-10 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
US20180317490A1 (en) 2015-11-04 2018-11-08 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
EP3165093A1 (en) 2015-11-05 2017-05-10 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
EP3167716A1 (en) 2015-11-10 2017-05-17 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
WO2017081310A1 (en) 2015-11-13 2017-05-18 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
BR112018009579A2 (pt) 2015-11-13 2018-11-06 Basf Se composto da fórmula i, mistura, composição agroquímica, uso de composto e método de combate a fungos
MX2018006244A (es) 2015-11-19 2018-11-09 Basf Se Oxadiazoles sustituidos para combatir hongos fitopatogenos.
CR20180332A (es) 2015-11-19 2018-10-18 Basf Se Oxadiazoles sustituidos para combatir hongos fitopatógenos
EA201890913A1 (ru) 2015-11-25 2018-11-30 Джилид Аполло, Ллс Пиразоловые соединения в качестве ингибиторов акк и их применение
WO2017091602A1 (en) 2015-11-25 2017-06-01 Gilead Apollo, Llc Ester acc inhibitors and uses thereof
MX2018006287A (es) 2015-11-25 2018-09-07 Gilead Apollo Llc Inhibidores de acc de triazol y usos de los mismos.
CN113303339A (zh) 2015-11-30 2021-08-27 巴斯夫欧洲公司 顺式-茉莉酮和解淀粉芽孢杆菌的混合物
BR112018010140A8 (pt) 2015-12-01 2019-02-26 Basf Se compostos de fórmula, composição, utilização de um composto de fórmula, método para o combate de fungos fitopatogênicos e semente
EP3383849B1 (en) 2015-12-01 2020-01-08 Basf Se Pyridine compounds as fungicides
EP3205208A1 (en) 2016-02-09 2017-08-16 Basf Se Mixtures and compositions comprising paenibacillus strains or fusaricidins and chemical pesticides
BR112018068034A2 (pt) 2016-03-09 2019-01-08 Basf Se compostos espiro da fórmula i, composição, composição agrícola para combater pragas animais, método de combate ou controle de pragas invertebradas, método de proteção de plantas, semente e uso dos compostos
WO2017153200A1 (en) 2016-03-10 2017-09-14 Basf Se Fungicidal mixtures iii comprising strobilurin-type fungicides
WO2017153218A1 (en) 2016-03-11 2017-09-14 Basf Se Method for controlling pests of plants
PE20181898A1 (es) 2016-04-01 2018-12-11 Basf Se Compuestos biciclicos
US10986839B2 (en) 2016-04-11 2021-04-27 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
WO2017198588A1 (en) 2016-05-18 2017-11-23 Basf Se Capsules comprising benzylpropargylethers for use as nitrification inhibitors
WO2018050421A1 (en) 2016-09-13 2018-03-22 Basf Se Fungicidal mixtures i comprising quinoline fungicides
WO2018054721A1 (en) 2016-09-26 2018-03-29 Basf Se Pyridine compounds for controlling phytopathogenic harmful fungi
WO2018054711A1 (en) 2016-09-26 2018-03-29 Basf Se Pyridine compounds for controlling phytopathogenic harmful fungi
WO2018054723A1 (en) 2016-09-26 2018-03-29 Basf Se Pyridine compounds for controlling phytopathogenic harmful fungi
WO2018065182A1 (en) 2016-10-04 2018-04-12 Basf Se Reduced quinoline compounds as antifuni agents
WO2018073110A1 (en) 2016-10-20 2018-04-26 Basf Se Quinoline compounds as fungicides
KR20190092539A (ko) 2016-12-16 2019-08-07 바스프 에스이 살충 화합물
WO2018114393A1 (en) 2016-12-19 2018-06-28 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
EP3339297A1 (en) 2016-12-20 2018-06-27 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
EP3338552A1 (en) 2016-12-21 2018-06-27 Basf Se Use of a tetrazolinone fungicide on transgenic plants
BR112019014061A2 (pt) 2017-01-23 2020-02-04 Basf Se compostos de fórmula i, intermediários b, intermediários c, intermediários ii e intermediários d, composição, uso, método para combater fungos fitopatogênicos, semente e processo para a síntese dos compostos de fórmula i
WO2018149754A1 (en) 2017-02-16 2018-08-23 Basf Se Pyridine compounds
BR112019015338B1 (pt) 2017-02-21 2023-03-14 Basf Se Compostos de fórmula i, composição agroquímica, semente revestida, uso dos compostos e método para combater fungos nocivos fitopatogênicos
WO2018162312A1 (en) 2017-03-10 2018-09-13 Basf Se Spirocyclic derivatives
WO2018166855A1 (en) 2017-03-16 2018-09-20 Basf Se Heterobicyclic substituted dihydroisoxazoles
KR102596592B1 (ko) 2017-03-28 2023-10-31 바스프 에스이 살충 화합물
CN110461854A (zh) 2017-03-31 2019-11-15 巴斯夫欧洲公司 制备手性2,3-二氢噻唑并[3,2-a]嘧啶-4-鎓化合物的方法
BR112019020879A2 (pt) 2017-04-06 2020-04-28 Basf Se compostos, composição, uso de um composto de formula i, método para combater fungos fitopatogênicos, semente e intermediários
WO2018192793A1 (en) 2017-04-20 2018-10-25 Basf Se Substituted rhodanine derivatives
CA3059301A1 (en) 2017-04-20 2018-10-25 Pi Industries Ltd. Novel phenylamine compounds
EP3618629A1 (en) 2017-05-02 2020-03-11 Basf Se Fungicidal mixture comprising substituted 3-phenyl-5-(trifluoromethyl)-1,2,4-oxadiazoles
WO2018202737A1 (en) 2017-05-05 2018-11-08 Basf Se Fungicidal mixtures comprising triazole compounds
EP3625215B1 (en) 2017-05-18 2023-09-13 PI Industries Ltd Formimidamidine compounds useful against phytopathogenic microorganisms
WO2018219797A1 (en) 2017-06-02 2018-12-06 Basf Se Substituted oxadiazoles for combating phytopathogenic fungi
EP3638677A1 (en) 2017-06-16 2020-04-22 Basf Se Mesoionic imidazolium compounds and derivatives for combating animal pests
EP3642203A1 (en) 2017-06-19 2020-04-29 Basf Se Substituted pyrimidinium compounds and derivatives for combating animal pests
WO2018234139A1 (en) 2017-06-19 2018-12-27 Basf Se 2-[[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]aryloxy](thio)acetamides for combating phytopathogenic fungi
WO2018234488A1 (en) 2017-06-23 2018-12-27 Basf Se Substituted cyclopropyl derivatives
WO2019002158A1 (en) 2017-06-30 2019-01-03 Basf Se SUBSTITUTED TRIFLUOROMETHYLOXADIAZOLES FOR THE CONTROL OF PHYTOPATHOGENIC FUNGI
WO2019025250A1 (en) 2017-08-04 2019-02-07 Basf Se SUBSTITUTED TRIFLUOROMETHYLOXADIAZOLES FOR COMBATING PHYTOPATHOGENIC FUNGI
WO2019038042A1 (en) 2017-08-21 2019-02-28 Basf Se SUBSTITUTED TRIFLUOROMETHYLOXADIAZOLES FOR THE CONTROL OF PHYTOPATHOGENIC FUNGI
EP3915379A1 (en) 2017-08-29 2021-12-01 Basf Se Pesticidal mixtures
WO2019042932A1 (en) 2017-08-31 2019-03-07 Basf Se METHOD FOR CONTROLLING RICE PARASITES IN RICE
EP3453706A1 (en) 2017-09-08 2019-03-13 Basf Se Pesticidal imidazole compounds
US11076596B2 (en) 2017-09-18 2021-08-03 Basf Se Substituted trifluoromethyloxadiazoles for combating phytopathogenic fungi
WO2019057660A1 (en) 2017-09-25 2019-03-28 Basf Se INDOLE AND AZAINDOLE COMPOUNDS HAVING 6-CHANNEL SUBSTITUTED ARYL AND HETEROARYL CYCLES AS AGROCHEMICAL FUNGICIDES
US11399543B2 (en) 2017-10-13 2022-08-02 Basf Se Substituted 1,2,3,5-tetrahydroimidazo[1,2-a]pyrimidiniumolates for combating animal pests
US11147275B2 (en) 2017-11-23 2021-10-19 Basf Se Substituted trifluoromethyloxadiazoles for combating phytopathogenic fungi
WO2019115511A1 (en) 2017-12-14 2019-06-20 Basf Se Fungicidal mixture comprising substituted 3-phenyl-5-(trifluoromethyl)-1,2,4-oxadiazoles
EP3723485A1 (en) 2017-12-15 2020-10-21 Basf Se Fungicidal mixture comprising substituted pyridines
CN111670180A (zh) 2017-12-20 2020-09-15 Pi工业有限公司 氟烯基化合物，制备方法及其用途
WO2019121143A1 (en) 2017-12-20 2019-06-27 Basf Se Substituted cyclopropyl derivatives
UA127604C2 (uk) 2017-12-21 2023-11-01 Басф Се Пестицидні сполуки
AU2019211978B2 (en) 2018-01-09 2024-08-22 Basf Se Silylethynyl hetaryl compounds as nitrification inhibitors
WO2019137995A1 (en) 2018-01-11 2019-07-18 Basf Se Novel pyridazine compounds for controlling invertebrate pests
CA3090133A1 (en) 2018-01-30 2019-08-08 Pi Industries Ltd. Oxadiazoles for use in controlling phytopathogenic fungi
WO2019150311A1 (en) 2018-02-02 2019-08-08 Pi Industries Ltd. 1-3 dithiol compounds and their use for the protection of crops from phytopathogenic microorganisms
CN111683933A (zh) 2018-02-07 2020-09-18 巴斯夫欧洲公司 新型吡啶羧酰胺类
WO2019154665A1 (en) 2018-02-07 2019-08-15 Basf Se New pyridine carboxamides
EP3530118A1 (en) 2018-02-26 2019-08-28 Basf Se Fungicidal mixtures
EP3530116A1 (en) 2018-02-27 2019-08-28 Basf Se Fungicidal mixtures comprising xemium
KR102730587B1 (ko) 2018-02-28 2024-11-14 바스프 에스이 질화작용 저해제로서의 n-관능화 알콕시 피라졸 화합물의 용도
WO2019166558A1 (en) 2018-02-28 2019-09-06 Basf Se Use of pyrazole propargyl ethers as nitrification inhibitors
WO2019166252A1 (en) 2018-02-28 2019-09-06 Basf Se Fungicidal mixtures comprising fenpropidin
PE20211753A1 (es) 2018-02-28 2021-09-06 Basf Se Uso de alcoxipirazoles como inhibidores de la nitrificacion
EA202092018A1 (ru) 2018-03-01 2021-02-01 Басф Агро Б.В. Фунгицидные композиции мефентрифлуконазола
EP3533333A1 (en) 2018-03-02 2019-09-04 Basf Se Fungicidal mixtures comprising pydiflumetofen
EP3533331A1 (en) 2018-03-02 2019-09-04 Basf Se Fungicidal mixtures comprising pydiflumetofen
EP3536150A1 (en) 2018-03-06 2019-09-11 Basf Se Fungicidal mixtures comprising fluxapyroxad
EP3762367A1 (en) 2018-03-09 2021-01-13 PI Industries Ltd. Heterocyclic compounds as fungicides
WO2019175712A1 (en) 2018-03-14 2019-09-19 Basf Corporation New uses for catechol molecules as inhibitors to glutathione s-transferase metabolic pathways
WO2019175713A1 (en) 2018-03-14 2019-09-19 Basf Corporation New catechol molecules and their use as inhibitors to p450 related metabolic pathways
WO2019185413A1 (en) 2018-03-27 2019-10-03 Basf Se Pesticidal substituted cyclopropyl derivatives
WO2019202459A1 (en) 2018-04-16 2019-10-24 Pi Industries Ltd. Use of 4-substituted phenylamidine compounds for controlling disease rust diseases in plants
WO2019219464A1 (en) 2018-05-15 2019-11-21 Basf Se Substituted trifluoromethyloxadiazoles for combating phytopathogenic fungi
KR102727205B1 (ko) 2018-05-15 2024-11-06 바스프 에스이 벤즈피리목산 및 옥사조술필을 포함하는 혼합물 및 이의 용도 및 이의 적용 방법
WO2019224092A1 (en) 2018-05-22 2019-11-28 Basf Se Pesticidally active c15-derivatives of ginkgolides
WO2020002472A1 (en) 2018-06-28 2020-01-02 Basf Se Use of alkynylthiophenes as nitrification inhibitors
CN112424147B (zh) 2018-07-23 2023-06-30 巴斯夫欧洲公司 取代噻唑烷化合物作为硝化抑制剂的用途
PL3826983T3 (pl) 2018-07-23 2024-09-09 Basf Se Zastosowanie podstawionych 2-tiazolin jako inhibitorów nitryfikacji
AR115984A1 (es) 2018-08-17 2021-03-17 Pi Industries Ltd Compuestos de 1,2-ditiolona y sus usos
EP3613736A1 (en) 2018-08-22 2020-02-26 Basf Se Substituted glutarimide derivatives
EP3628158A1 (en) 2018-09-28 2020-04-01 Basf Se Pesticidal mixture comprising a mesoionic compound and a biopesticide
AU2019348280A1 (en) 2018-09-28 2021-04-22 Basf Se Method of controlling pests by seed treatment application of a mesoionic compound or mixture thereof
EP3628156A1 (en) 2018-09-28 2020-04-01 Basf Se Method for controlling pests of sugarcane, citrus, rapeseed, and potato plants
EP3628157A1 (en) 2018-09-28 2020-04-01 Basf Se Method of controlling insecticide resistant insects and virus transmission to plants
KR20210098949A (ko) 2018-10-01 2021-08-11 피아이 인더스트리스 엘티디. 새로운 옥사디아졸
KR20210098946A (ko) 2018-10-01 2021-08-11 피아이 인더스트리스 엘티디. 살진균제로서의 옥사디아졸
EP3643705A1 (en) 2018-10-24 2020-04-29 Basf Se Pesticidal compounds
WO2020095161A1 (en) 2018-11-05 2020-05-14 Pi Industries Ltd. Nitrone compounds and use thereof
US12459934B2 (en) 2018-11-28 2025-11-04 Basf Se Pesticidal compounds
EP3670501A1 (en) 2018-12-17 2020-06-24 Basf Se Substituted [1,2,4]triazole compounds as fungicides
WO2020126591A1 (en) 2018-12-18 2020-06-25 Basf Se Substituted pyrimidinium compounds for combating animal pests
EP3696177A1 (en) 2019-02-12 2020-08-19 Basf Se Heterocyclic compounds for the control of invertebrate pests
AU2020270549A1 (en) 2019-04-08 2021-09-30 Pi Industries Limited Novel oxadiazole compounds for controlling or preventing phytopathogenic fungi
CA3131995A1 (en) 2019-04-08 2020-10-15 Pi Industries Limited Novel oxadiazole compounds for controlling or preventing phytopathogenic fungi
JP7550786B2 (ja) 2019-04-08 2024-09-13 ピーアイ インダストリーズ リミテッド 植物病原性真菌を制御又は予防するための新規オキサジアゾール化合物、組成物、および方法
EP3730489A1 (en) 2019-04-25 2020-10-28 Basf Se Heteroaryl compounds as agrochemical fungicides
EP3769623A1 (en) 2019-07-22 2021-01-27 Basf Se Mesoionic imidazolium compounds and derivatives for combating animal pests
BR112021019416A2 (pt) 2019-05-29 2021-12-07 Basf Se Compostos, composição, métodos de proteção de safras e de combate, controle, prevenção ou proteção contra infestações, método não terapêutico de tratamento de animais infestados, semente e uso
WO2020244968A1 (en) 2019-06-06 2020-12-10 Basf Se Fungicidal n-(pyrid-3-yl)carboxamides
WO2020244969A1 (en) 2019-06-06 2020-12-10 Basf Se Pyridine derivatives and their use as fungicides
WO2020244970A1 (en) 2019-06-06 2020-12-10 Basf Se New carbocyclic pyridine carboxamides
EP3766879A1 (en) 2019-07-19 2021-01-20 Basf Se Pesticidal pyrazole derivatives
AR119774A1 (es) 2019-08-19 2022-01-12 Pi Industries Ltd Compuestos de oxadiazol que contienen un anillo heteroaromático de 5 miembros para controlar o prevenir hongos fitopatogénicos
WO2021063736A1 (en) 2019-10-02 2021-04-08 Basf Se Bicyclic pyridine derivatives
WO2021063735A1 (en) 2019-10-02 2021-04-08 Basf Se New bicyclic pyridine derivatives
AR120374A1 (es) 2019-11-08 2022-02-09 Pi Industries Ltd Compuestos de oxadiazol que contienen anillos de heterociclilo fusionados para controlar o prevenir hongos fitopatogénicos
JP7785003B2 (ja) 2019-12-23 2025-12-12 ビーエーエスエフ ソシエタス・ヨーロピア 酵素によって増強された農薬化合物の根からの取り込み
WO2021170463A1 (en) 2020-02-28 2021-09-02 BASF Agro B.V. Methods and uses of a mixture comprising alpha-cypermethrin and dinotefuran for controlling invertebrate pests in turf
BR112022017563A2 (pt) 2020-03-04 2022-10-18 Basf Se Uso de compostos, composição agroquímica e método para combater fungos fitopatogênicos nocivos
BR112022020612A2 (pt) 2020-04-14 2022-11-29 Basf Se Mistura fungicida, composição agroquímica, uso não terapêutico da mistura e método para controlar fungos fitopatogênicos nocivos
EP3903582A1 (en) 2020-04-28 2021-11-03 Basf Se Use of strobilurin type compounds for combating phytopathogenic fungi containing an amino acid substitution f129l in the mitochondrial cytochrome b protein conferring resistance to qo inhibitors ii
BR112022021631A2 (pt) 2020-04-28 2022-12-06 Basf Se Compostos, composição, métodos para combater ou controlar pragas invertebradas, para proteger plantas em crescimento e para tratar ou proteger um animal, semente e uso de um composto
EP3903581A1 (en) 2020-04-28 2021-11-03 Basf Se Use of strobilurin type compounds for combating phytopathogenic fungi containing an amino acid substitution f129l in the mitochondrial cytochrome b protein conferring resistance to qo inhibitors i
EP3903583A1 (en) 2020-04-28 2021-11-03 Basf Se Use of strobilurin type compounds for combating phytopathogenic fungi containing an amino acid substitution f129l in the mitochondrial cytochrome b protein conferring resistance to qo inhibitors iii
EP3903584A1 (en) 2020-04-28 2021-11-03 Basf Se Use of strobilurin type compounds for combating phytopathogenic fungi containing an amino acid substitution f129l in the mitochondrial cytochrome b protein conferring resistance to qo inhibitors iv
EP3909950A1 (en) 2020-05-13 2021-11-17 Basf Se Heterocyclic compounds for the control of invertebrate pests
WO2021249800A1 (en) 2020-06-10 2021-12-16 Basf Se Substituted [1,2,4]triazole compounds as fungicides
EP3945089A1 (en) 2020-07-31 2022-02-02 Basf Se Use of strobilurin type compounds for combating phytopathogenic fungi containing an amino acid substitution f129l in the mitochondrial cytochrome b protein conferring resistance to qo inhibitors v
EP3960727A1 (en) 2020-08-28 2022-03-02 Basf Se Use of strobilurin type compounds for combating phytopathogenic fungi containing an amino acid substitution f129l in the mitochondrial cytochrome b protein conferring resistance to qo inhibitors vi
EP3939961A1 (en) 2020-07-16 2022-01-19 Basf Se Strobilurin type compounds and their use for combating phytopathogenic fungi
WO2022017836A1 (en) 2020-07-20 2022-01-27 BASF Agro B.V. Fungicidal compositions comprising (r)-2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1- (1,2,4-triazol-1-yl)propan-2-ol
EP3970494A1 (en) 2020-09-21 2022-03-23 Basf Se Use of strobilurin type compounds for combating phytopathogenic fungi containing an amino acid substitution f129l in the mitochondrial cytochrome b protein conferring resistance to qo inhibitors viii
AR123264A1 (es) 2020-08-18 2022-11-16 Pi Industries Ltd Nuevos compuestos heterocíclicos para combatir los hongos fitopatógenos
UY39423A (es) 2020-09-15 2022-03-31 Pi Industries Ltd Nuevos compuestos de picolinamida para combatir hongos fitopatógenos
AR123502A1 (es) 2020-09-15 2022-12-07 Pi Industries Ltd Nuevos compuestos de picolinamida para combatir hongos fitopatógenos
TW202229241A (zh) 2020-09-26 2022-08-01 印度商皮埃企業有限公司 殺線蟲化合物及其用途
US20230397607A1 (en) 2020-10-27 2023-12-14 BASF Agro B.V. Compositions comprising mefentrifluconazole
WO2022090071A1 (en) 2020-11-02 2022-05-05 Basf Se Use of mefenpyr-diethyl for controlling phytopathogenic fungi
WO2022090069A1 (en) 2020-11-02 2022-05-05 Basf Se Compositions comprising mefenpyr-diethyl
WO2022106304A1 (en) 2020-11-23 2022-05-27 BASF Agro B.V. Compositions comprising mefentrifluconazole
EP4018830A1 (en) 2020-12-23 2022-06-29 Basf Se Pesticidal mixtures
EP4288398A1 (en) 2021-02-02 2023-12-13 Basf Se Synergistic action of dcd and alkoxypyrazoles as nitrification inhibitors
EP4043444A1 (en) 2021-02-11 2022-08-17 Basf Se Substituted isoxazoline derivatives
TW202309047A (zh) 2021-05-05 2023-03-01 印度商皮埃企業有限公司 用以防治植物病原真菌的新穎稠合雜環化合物
BR112023023592A2 (pt) 2021-05-11 2024-03-12 Basf Se Mistura fungicida, composição agroquímica, uso da mistura e método para controlar fungos nocivos fitopatogênicos
US20240270727A1 (en) 2021-05-18 2024-08-15 Basf Se New substituted pyridines as fungicide
CN117355520A (zh) 2021-05-18 2024-01-05 巴斯夫欧洲公司 用作杀真菌剂的新型取代喹啉类
WO2022243107A1 (en) 2021-05-18 2022-11-24 Basf Se New substituted pyridines as fungicides
US20240270658A1 (en) 2021-05-21 2024-08-15 Basf Se Use of an N-Functionalized Alkoxy Pyrazole Compound as Nitrification Inhibitor
US20240351959A1 (en) 2021-05-21 2024-10-24 Basf Se Use of ethynylpyridine compounds as nitrification inhibitors
UY39780A (es) 2021-05-26 2022-11-30 Pi Industries Ltd Composición fungicida que contiene compuestos de oxadiazol
EP4094579A1 (en) 2021-05-28 2022-11-30 Basf Se Pesticidal mixtures comprising metyltetraprole
CA3223077A1 (en) 2021-06-21 2022-12-29 Barbara Nave Metal-organic frameworks with pyrazole-based building blocks
EP4119547A1 (en) 2021-07-12 2023-01-18 Basf Se Triazole compounds for the control of invertebrate pests
AU2022321882A1 (en) 2021-08-02 2024-02-15 Basf Se (3-pirydyl)-quinazoline
US20250019361A1 (en) 2021-08-02 2025-01-16 Basf Se (3-quinolyl)-quinazoline
EP4140986A1 (en) 2021-08-23 2023-03-01 Basf Se Pyrazine compounds for the control of invertebrate pests
EP4140995A1 (en) 2021-08-27 2023-03-01 Basf Se Pyrazine compounds for the control of invertebrate pests
EP4151631A1 (en) 2021-09-20 2023-03-22 Basf Se Heterocyclic compounds for the control of invertebrate pests
WO2023072670A1 (en) 2021-10-28 2023-05-04 Basf Se Use of strobilurin type compounds for combating phytopathogenic fungi containing an amino acid substitution f129l in the mitochondrial cytochrome b protein conferring resistance to qo inhibitors x
WO2023072671A1 (en) 2021-10-28 2023-05-04 Basf Se Use of strobilurin type compounds for combating phytopathogenic fungi containing an amino acid substitution f129l in the mitochondrial cytochrome b protein conferring resistance to qo inhibitors ix
EP4194453A1 (en) 2021-12-08 2023-06-14 Basf Se Pyrazine compounds for the control of invertebrate pests
EP4198033A1 (en) 2021-12-14 2023-06-21 Basf Se Heterocyclic compounds for the control of invertebrate pests
EP4198023A1 (en) 2021-12-16 2023-06-21 Basf Se Pesticidally active thiosemicarbazone compounds
AR127972A1 (es) 2021-12-17 2024-03-13 Pi Industries Ltd Novedosos compuestos de piridina carboxamida bicíclica sustituida fusionada para combatir hongos fitopatogénicos
EP4238971A1 (en) 2022-03-02 2023-09-06 Basf Se Substituted isoxazoline derivatives
WO2023203066A1 (en) 2022-04-21 2023-10-26 Basf Se Synergistic action as nitrification inhibitors of dcd oligomers with alkoxypyrazole and its oligomers
CA3250199A1 (en) 2022-04-25 2023-11-02 Basf Se EMULSIFIABLE CONCENTRATE HAVING A BENZALDEHYDE-BASED (SUBSTITUTED) SOLVENT SYSTEM
AU2023317620A1 (en) 2022-08-02 2025-02-13 Basf Se Pyrazolo pesticidal compounds
EP4342885A1 (en) 2022-09-20 2024-03-27 Basf Se N-(3-(aminomethyl)-phenyl)-5-(4-phenyl)-5-(trifluoromethyl)-4,5-dihydroisoxazol-3-amine derivatives and similar compounds as pesticides
EP4361126A1 (en) 2022-10-24 2024-05-01 Basf Se Use of strobilurin type compounds for combating phytopathogenic fungi containing an amino acid substitution f129l in the mitochondrial cytochrome b protein conferring resistance to qo inhibitors xv
WO2024104813A1 (en) 2022-11-14 2024-05-23 Basf Se Fungicidal mixture comprising substituted pyridines
CN120202195A (zh) 2022-11-16 2025-06-24 巴斯夫欧洲公司 作为杀真菌剂的取代的苯并二氮杂䓬类
EP4619393A1 (en) 2022-11-16 2025-09-24 Basf Se Substituted benzodiazepines as fungicides
WO2024104822A1 (en) 2022-11-16 2024-05-23 Basf Se Substituted tetrahydrobenzodiazepine as fungicides
EP4619399A1 (en) 2022-11-16 2025-09-24 Basf Se New substituted tetrahydrobenzoxazepine
AU2023381249A1 (en) 2022-11-16 2025-05-29 Basf Se Fungicidal mixture comprising substituted pyridines
EP4389210A1 (en) 2022-12-21 2024-06-26 Basf Se Heteroaryl compounds for the control of invertebrate pests
WO2024165343A1 (en) 2023-02-08 2024-08-15 Basf Se New substituted quinoline compounds for combatitng phytopathogenic fungi
AU2024238668A1 (en) 2023-03-17 2025-09-25 Basf Se Substituted pyridyl/pyrazidyl dihydrobenzothiazepine compounds for combatting phytopathogenic fungi
EP4455137A1 (en) 2023-04-24 2024-10-30 Basf Se Pyrimidine compounds for the control of invertebrate pests
CN121335882A (zh) 2023-04-26 2026-01-13 巴斯夫欧洲公司 嗜球果伞素型化合物用于对抗含有线粒体细胞色素b蛋白中赋予对Qo抑制剂XVI的抗性的氨基酸取代F129L的植物病原真菌的用途
EP4467535A1 (en) 2023-05-25 2024-11-27 Basf Se Lactam pesticidal compounds
WO2025008227A1 (en) 2023-07-05 2025-01-09 Basf Se Substituted pyridyl/pyrazinyl dihydropyrrolotriazine compounds for combatting phytopath-ogenic fungi
WO2025008226A1 (en) 2023-07-05 2025-01-09 Basf Se Substituted quinolyl/quinoxalyl dihydropyrrolotriazine compounds for combatting phyto-pathogenic fungi
EP4488273A1 (en) 2023-07-06 2025-01-08 Basf Se Triazole compounds for the control of invertebrate pests
EP4488269A1 (en) 2023-07-06 2025-01-08 Basf Se Triazole compounds for the control of invertebrate pests
EP4488270A1 (en) 2023-07-06 2025-01-08 Basf Se Triazole compounds for the control of invertebrate pests
WO2025031843A1 (en) 2023-08-09 2025-02-13 Basf Se New substituted benzoxazine picolinonitrile compounds for combatting phytopathogenic fungi
WO2025031842A1 (en) 2023-08-09 2025-02-13 Basf Se New substituted benzoxazepine picolinonitrile compounds for combatting phytopathogenic fungi
WO2025078181A1 (en) 2023-10-09 2025-04-17 Basf Se Fungicidal mixture comprising substituted pyridines
WO2025078183A1 (en) 2023-10-09 2025-04-17 Basf Se Fungicidal mixture comprising substituted quinazolyl quinolines
EP4574819A1 (en) 2023-12-22 2025-06-25 Basf Se Diazinone compounds for the control of invertebrate pests
WO2025180964A1 (en) 2024-03-01 2025-09-04 Basf Se New substituted benzoxazepine compounds for combatting phytopathogenic fungi
EP4640052A1 (en) 2024-04-24 2025-10-29 Basf Se Mixtures of strobilurin type compounds for combating phytopathogenic fungi containing an amino acid substitution f129l in the mitochondrial cytochrome b protein conferring resistance to qo inhibitors with at least one further pesticide i
WO2025223904A1 (en) 2024-04-24 2025-10-30 Basf Se Mixtures of strobilurin type compounds for combating phytopathogenic fungi containing an amino acid substitution f129l in the mitochondrial cytochrome b protein conferring resistance to qo inhibitors with at least one further pesticide i
WO2026012814A1 (en) 2024-07-10 2026-01-15 Basf Se Compositions and methods to enhance crop yield and plant health
WO2026021911A1 (en) 2024-07-23 2026-01-29 Basf Se New substituted benzothiazine pyridine compounds for combatting phytopathogenic fungi
WO2026021909A1 (en) 2024-07-23 2026-01-29 Basf Se New substituted benzothiazine pyridine compounds for combatting phytopathogenic fungi
WO2026021910A1 (en) 2024-07-23 2026-01-29 Basf Se New substituted benzothiazine pyridine compounds for combatting phytopathogenic fungi
WO2026021912A1 (en) 2024-07-23 2026-01-29 Basf Se New substituted benzothiazine pyridine compounds for combatting phytopathogenic fungi

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1437425A (fr) * 1964-12-29 1966-05-06 Pechiney Progil Sa Nouveaux produits fongicides à usage agricole dérivés de l'aldéhyde salicylique
GB1192995A (en) * 1967-04-12 1970-05-28 Egyt Gyogyszervegyeszeti Gyar Formimino Ethers
CA967960A (en) * 1971-04-30 1975-05-20 Sumitomo Chemical Company Isothiourea compounds and their production and use

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AU7244387A (en) 1987-11-05
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HU205903B (en) 1992-07-28
EP0243970A1 (en) 1987-11-04
AU608221B2 (en) 1991-03-28
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