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CL2009001427A1 - Procesos de deshidrogenacion oxidativa de una corriente de hc que comprende: alimentar una corriente de hc a reactores de deshidrogenacion; alimentar co2 en razon co2/alimentacion total 0,1 a 10; alimentar o2 en razon molar o2/alimentacion total 0,01 a10; deshidrogenar la alimentacion de hc; y recuperar hc deshidrogenados. - Google Patents

Procesos de deshidrogenacion oxidativa de una corriente de hc que comprende: alimentar una corriente de hc a reactores de deshidrogenacion; alimentar co2 en razon co2/alimentacion total 0,1 a 10; alimentar o2 en razon molar o2/alimentacion total 0,01 a10; deshidrogenar la alimentacion de hc; y recuperar hc deshidrogenados.

Info

Publication number
CL2009001427A1
CL2009001427A1 CL2009001427A CL2009001427A CL2009001427A1 CL 2009001427 A1 CL2009001427 A1 CL 2009001427A1 CL 2009001427 A CL2009001427 A CL 2009001427A CL 2009001427 A CL2009001427 A CL 2009001427A CL 2009001427 A1 CL2009001427 A1 CL 2009001427A1
Authority
CL
Chile
Prior art keywords
feed
stream
dehydrogenation
total
ratio
Prior art date
Application number
CL2009001427A
Other languages
English (en)
Inventor
Chuen Yuan Yeh
Anne Mae Gaffney
Stephen C Arnold
Johannes Hendrik Koegler
Ruozhi Song
Original Assignee
Lummus Technology Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lummus Technology Inc filed Critical Lummus Technology Inc
Publication of CL2009001427A1 publication Critical patent/CL2009001427A1/es

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    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
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    • C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/02—Preparation of oxygen
    • C01B13/0229—Purification or separation processes
    • C01B13/0248—Physical processing only
    • C01B13/0251—Physical processing only by making use of membranes
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    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Multi-step processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
    • C07C15/42—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic
    • C07C15/44—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic the hydrocarbon substituent containing a carbon-to-carbon double bond
    • C07C15/46—Styrene; Ring-alkylated styrenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
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    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Catalysts (AREA)

Abstract

SE PROPORCIONAN PROCESOS PARA UTILIZAR UNA COMBINACIÓN DE DIÓXIDO DE CARBONO Y OXIGENO EN LA DESHIDROGENACIÓN<br /> DE HIDROCARBUROS. SE ALIMENTA UNA ALIMENTACIÓN DE HIDROCARBUROS, DIÓXIDO DE CARBONO Y OXIGENO HACIA UN SISTEMA<br /> DE REACTORES DE DESHIDROGENACIÓN OXIDATIVA QUE CONTIENE UNO O MÁS CATALIZADORES QUE PROMUEVEN LA<br /> DESHIDROGENACIÓN DE LA ALIMENTACIÓN DE HIDROCARBUROS PARA PRODUCIR UN PRODUCTO DE HIDROCARBUROS DESHIDROGENADOS.<br /> LOS PROCESOS DE LA PRESENTE INVENCIÓN PUEDEN SER UTILIZADOS, POR EJEMPLO, PARA PRODUCIR ESTIRENO MONOMÉRICO<br /> MEDIANTE DESHIDROGENACIÓN DE ETILBENCENO USANDO DIÓXIDO DE CARBONO Y OXÍGENO COMO OXIDANTES<br />  
CL2009001427A 2008-06-19 2009-06-16 Procesos de deshidrogenacion oxidativa de una corriente de hc que comprende: alimentar una corriente de hc a reactores de deshidrogenacion; alimentar co2 en razon co2/alimentacion total 0,1 a 10; alimentar o2 en razon molar o2/alimentacion total 0,01 a10; deshidrogenar la alimentacion de hc; y recuperar hc deshidrogenados. CL2009001427A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US12/142,738 US8237000B2 (en) 2008-06-19 2008-06-19 Combined carbon dioxide and oxygen process for ethylbenzene dehydrogenation to styrene

Publications (1)

Publication Number Publication Date
CL2009001427A1 true CL2009001427A1 (es) 2010-01-04

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CL2009001427A CL2009001427A1 (es) 2008-06-19 2009-06-16 Procesos de deshidrogenacion oxidativa de una corriente de hc que comprende: alimentar una corriente de hc a reactores de deshidrogenacion; alimentar co2 en razon co2/alimentacion total 0,1 a 10; alimentar o2 en razon molar o2/alimentacion total 0,01 a10; deshidrogenar la alimentacion de hc; y recuperar hc deshidrogenados.

Country Status (15)

Country Link
US (2) US8237000B2 (es)
EP (1) EP2303812A4 (es)
JP (1) JP2011524913A (es)
KR (1) KR20110033229A (es)
CN (1) CN102159524A (es)
AR (1) AR074153A1 (es)
BR (1) BRPI0915723A2 (es)
CA (1) CA2727286A1 (es)
CL (1) CL2009001427A1 (es)
MX (1) MX2010013804A (es)
NO (1) NO20101712A1 (es)
SG (2) SG192418A1 (es)
TW (2) TWI439449B (es)
WO (1) WO2009155219A1 (es)
ZA (1) ZA201100417B (es)

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