CA2611890C - Procede de transformation d'un gaz de synthese en hydrocarbures en presence de mousse de sic - Google Patents
Procede de transformation d'un gaz de synthese en hydrocarbures en presence de mousse de sic Download PDFInfo
- Publication number
- CA2611890C CA2611890C CA2611890A CA2611890A CA2611890C CA 2611890 C CA2611890 C CA 2611890C CA 2611890 A CA2611890 A CA 2611890A CA 2611890 A CA2611890 A CA 2611890A CA 2611890 C CA2611890 C CA 2611890C
- Authority
- CA
- Canada
- Prior art keywords
- catalyst
- foam
- reactor
- implemented
- sic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000006260 foam Substances 0.000 title claims abstract description 82
- 238000000034 method Methods 0.000 title claims abstract description 79
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 43
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 39
- 238000003786 synthesis reaction Methods 0.000 title claims description 24
- 230000015572 biosynthetic process Effects 0.000 title claims description 21
- 239000003054 catalyst Substances 0.000 claims abstract description 85
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims abstract description 53
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 52
- 229910052751 metal Inorganic materials 0.000 claims abstract description 30
- 239000002184 metal Substances 0.000 claims abstract description 30
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 8
- 239000001257 hydrogen Substances 0.000 claims abstract description 8
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910002091 carbon monoxide Inorganic materials 0.000 claims abstract description 5
- 238000006243 chemical reaction Methods 0.000 claims description 40
- 239000007789 gas Substances 0.000 claims description 35
- 230000008569 process Effects 0.000 claims description 31
- 239000004215 Carbon black (E152) Substances 0.000 claims description 19
- 239000011148 porous material Substances 0.000 claims description 11
- 229910017052 cobalt Inorganic materials 0.000 claims description 10
- 239000010941 cobalt Substances 0.000 claims description 10
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- 229910052726 zirconium Inorganic materials 0.000 claims description 7
- 230000001174 ascending effect Effects 0.000 claims description 6
- 150000002739 metals Chemical class 0.000 claims description 6
- 229910052750 molybdenum Inorganic materials 0.000 claims description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 3
- 229910052707 ruthenium Inorganic materials 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 238000001125 extrusion Methods 0.000 claims description 2
- 239000000446 fuel Substances 0.000 claims description 2
- 229910052741 iridium Inorganic materials 0.000 claims description 2
- 229910052763 palladium Inorganic materials 0.000 claims description 2
- 229910052697 platinum Inorganic materials 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 229910052702 rhenium Inorganic materials 0.000 claims description 2
- 229910052703 rhodium Inorganic materials 0.000 claims description 2
- 229910052712 strontium Inorganic materials 0.000 claims description 2
- 229910052721 tungsten Inorganic materials 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- 230000003197 catalytic effect Effects 0.000 description 44
- 239000007788 liquid Substances 0.000 description 34
- 235000013339 cereals Nutrition 0.000 description 24
- 239000012071 phase Substances 0.000 description 21
- 241000894007 species Species 0.000 description 19
- 230000008901 benefit Effects 0.000 description 14
- 239000002002 slurry Substances 0.000 description 11
- 239000003153 chemical reaction reagent Substances 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- 150000003839 salts Chemical class 0.000 description 9
- 239000002826 coolant Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 239000012530 fluid Substances 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- 239000011230 binding agent Substances 0.000 description 6
- 238000009792 diffusion process Methods 0.000 description 6
- 238000005470 impregnation Methods 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 239000002243 precursor Substances 0.000 description 6
- 230000009467 reduction Effects 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 238000001354 calcination Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 238000000151 deposition Methods 0.000 description 4
- -1 distillate Substances 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 102000002322 Egg Proteins Human genes 0.000 description 3
- 108010000912 Egg Proteins Proteins 0.000 description 3
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 210000003278 egg shell Anatomy 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 238000007493 shaping process Methods 0.000 description 3
- 230000001131 transforming effect Effects 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000001413 cellular effect Effects 0.000 description 2
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 210000000056 organ Anatomy 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000007790 solid phase Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 238000006641 Fischer synthesis reaction Methods 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- 244000062793 Sorghum vulgare Species 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000003637 basic solution Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000009172 bursting Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 150000001868 cobalt Chemical class 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000011038 discontinuous diafiltration by volume reduction Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000006261 foam material Substances 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- BTFJIXJJCSYFAL-UHFFFAOYSA-N icosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 235000019713 millet Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910003465 moissanite Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N nitrate group Chemical group [N+](=O)([O-])[O-] NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 230000037074 physically active Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000002470 thermal conductor Substances 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 150000003754 zirconium Chemical class 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/75—Cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/20—Carbon compounds
- B01J27/22—Carbides
- B01J27/224—Silicon carbide
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Carbon And Carbon Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0506523A FR2887545B1 (fr) | 2005-06-27 | 2005-06-27 | Procede de transformation d'un gaz de synthese en hydrocarbures en presence de mousse de sic |
| FR0506523 | 2005-06-27 | ||
| PCT/FR2006/001422 WO2007000506A1 (fr) | 2005-06-27 | 2006-06-22 | Procede de transformation d'un gaz de synthese en hydrocarbures en presence de mousse de sic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2611890A1 CA2611890A1 (fr) | 2007-01-04 |
| CA2611890C true CA2611890C (fr) | 2012-05-08 |
Family
ID=35355591
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2611890A Expired - Fee Related CA2611890C (fr) | 2005-06-27 | 2006-06-22 | Procede de transformation d'un gaz de synthese en hydrocarbures en presence de mousse de sic |
Country Status (12)
| Country | Link |
|---|---|
| EP (1) | EP1907506A1 (es) |
| JP (1) | JP5139277B2 (es) |
| CN (1) | CN101208408B (es) |
| AR (1) | AR055065A1 (es) |
| AU (1) | AU2006263782B2 (es) |
| BR (1) | BRPI0613019B1 (es) |
| CA (1) | CA2611890C (es) |
| FR (1) | FR2887545B1 (es) |
| NO (1) | NO20076608L (es) |
| RU (1) | RU2437918C2 (es) |
| WO (1) | WO2007000506A1 (es) |
| ZA (1) | ZA200710987B (es) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2934174B1 (fr) * | 2008-07-25 | 2010-09-17 | Total Sa | Procede de synthese fischer-tropsch sur plaques catalytiques comprenant un support de mousse de sic |
| RU2497590C2 (ru) * | 2008-12-15 | 2013-11-10 | Сэсол Текнолоджи (Проприетери) Лимитед | Катализаторы |
| FR2965191A1 (fr) * | 2010-09-23 | 2012-03-30 | Centre Nat Rech Scient | Reacteur a plaques pour la synthese fischer-tropsch |
| EP2864044B1 (fr) * | 2012-06-26 | 2019-12-25 | Sicat Catalysts, Inc. | Supports de catalyseur à base de carbure de silicium recouvert de TiO2 pour la synthèse de Fischer-Tropsch |
| FR2992236A1 (fr) * | 2012-06-26 | 2013-12-27 | Sicat Llc | Supports de catalyseur a base de carbure de silicium recouvert de tio2 pour la synthese de fischer-tropsch |
| CN103816904A (zh) * | 2012-11-16 | 2014-05-28 | 亚申科技研发中心（上海）有限公司 | 费托催化剂、其制备方法、应用以及采用该催化剂的费托合成方法 |
| WO2014140973A1 (en) | 2013-03-14 | 2014-09-18 | Sasol Technology (Pty) Limited | A hydrocarbon synthesis process using a cobalt-based catalyst supported on a silicon carbide comprising support |
| WO2014207096A1 (en) | 2013-06-27 | 2014-12-31 | Sicat | Method for manufacturing shaped beta-sic mesoporous products and products obtained by this method |
| ITMI20131439A1 (it) | 2013-09-03 | 2015-03-04 | Eni Spa | Reattore tubolare a letto impaccato per reazioni catalitiche eterogenee esotermiche o endotermiche |
| EA201991052A1 (ru) | 2016-10-27 | 2019-09-30 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ получения углеводородов |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4914070A (en) * | 1987-10-19 | 1990-04-03 | Pechiney Electrometallurgie | Process for the production of silicon carbide with a large specific surface area and use for high-temperature catalytic reactions |
| GB9114314D0 (en) * | 1991-07-02 | 1991-08-21 | British Petroleum Co Plc | Catalyst treatment for fisher-tropsch process |
| FR2684092B1 (fr) * | 1991-11-21 | 1994-03-04 | Pechiney Recherche | Procede de preparation de carbures metalliques a grande surface specifique a partir de mousses de carbone activees. |
| US5648312A (en) * | 1994-12-29 | 1997-07-15 | Intevep, S.A. | Hydrogenation catalyst with improved attrition resistance and heat dissipation |
| DZ2370A1 (fr) * | 1996-12-13 | 2002-12-28 | Shell Int Research | Procédé de préparation d'hydrocarbures |
| US6440895B1 (en) * | 1998-07-27 | 2002-08-27 | Battelle Memorial Institute | Catalyst, method of making, and reactions using the catalyst |
| CA2381156C (en) * | 1999-08-17 | 2011-04-19 | Battelle Memorial Institute | Catalyst structure and method of fischer-tropsch synthesis |
| FR2832415B1 (fr) * | 2001-11-20 | 2005-09-23 | Inst Francais Du Petrole | Procede de conversion de gaz de synthese dans des reacteurs en serie |
| FR2864532B1 (fr) * | 2003-12-31 | 2007-04-13 | Total France | Procede de transformation d'un gaz de synthese en hydrocarbures en presence de sic beta et effluent de ce procede |
-
2005
- 2005-06-27 FR FR0506523A patent/FR2887545B1/fr not_active Expired - Fee Related
-
2006
- 2006-06-22 EP EP06764815A patent/EP1907506A1/fr not_active Ceased
- 2006-06-22 AU AU2006263782A patent/AU2006263782B2/en not_active Ceased
- 2006-06-22 CA CA2611890A patent/CA2611890C/fr not_active Expired - Fee Related
- 2006-06-22 JP JP2008517538A patent/JP5139277B2/ja not_active Expired - Fee Related
- 2006-06-22 BR BRPI0613019A patent/BRPI0613019B1/pt not_active IP Right Cessation
- 2006-06-22 WO PCT/FR2006/001422 patent/WO2007000506A1/fr not_active Ceased
- 2006-06-22 CN CN200680023155.0A patent/CN101208408B/zh not_active Expired - Fee Related
- 2006-06-22 RU RU2008102414/04A patent/RU2437918C2/ru not_active IP Right Cessation
- 2006-06-23 AR ARP060102712 patent/AR055065A1/es active IP Right Grant
-
2007
- 2007-12-14 ZA ZA200710987A patent/ZA200710987B/xx unknown
- 2007-12-27 NO NO20076608A patent/NO20076608L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| ZA200710987B (en) | 2008-11-26 |
| CN101208408B (zh) | 2012-08-22 |
| BRPI0613019A2 (pt) | 2010-12-14 |
| FR2887545A1 (fr) | 2006-12-29 |
| FR2887545B1 (fr) | 2007-08-10 |
| EP1907506A1 (fr) | 2008-04-09 |
| NO20076608L (no) | 2007-12-27 |
| AU2006263782A1 (en) | 2007-01-04 |
| AR055065A1 (es) | 2007-08-01 |
| WO2007000506A1 (fr) | 2007-01-04 |
| CA2611890A1 (fr) | 2007-01-04 |
| JP2008544060A (ja) | 2008-12-04 |
| AU2006263782B2 (en) | 2011-05-12 |
| RU2437918C2 (ru) | 2011-12-27 |
| JP5139277B2 (ja) | 2013-02-06 |
| CN101208408A (zh) | 2008-06-25 |
| BRPI0613019B1 (pt) | 2016-03-15 |
| RU2008102414A (ru) | 2009-08-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |
Effective date: 20220301 |
|
| MKLA | Lapsed |
Effective date: 20200831 |