BR9909588A - Processo de epoxidação - Google Patents
Processo de epoxidaçãoInfo
- Publication number
- BR9909588A BR9909588A BR9909588-2A BR9909588A BR9909588A BR 9909588 A BR9909588 A BR 9909588A BR 9909588 A BR9909588 A BR 9909588A BR 9909588 A BR9909588 A BR 9909588A
- Authority
- BR
- Brazil
- Prior art keywords
- epoxidation
- olefin
- epoxidation process
- zeophil
- arsenic
- Prior art date
Links
- 238000006735 epoxidation reaction Methods 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 2
- 150000001336 alkenes Chemical class 0.000 abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 229910052785 arsenic Inorganic materials 0.000 abstract 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910000510 noble metal Inorganic materials 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 229910052711 selenium Inorganic materials 0.000 abstract 1
- 239000011669 selenium Substances 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/06—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the liquid phase
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Epoxy Compounds (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Patente de Invenção: <B>"PROCESSO DE EPOXIDAçãO"<D>. A seletividade de uma epoxidação de uma olefina catalisada por um zeófilo de titânio ou de vanádio modificado com um metal nobre é bastante aumentada pela adição de um composto de fósforo, enxofre, selênio ou arsênico à mistura de reação. A epoxidação utiliza o hidrogênio e o oxigênio na adição da olefina.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US8193998P | 1998-04-16 | 1998-04-16 | |
| US09/290,100 US6005123A (en) | 1998-04-16 | 1999-04-12 | Epoxidation process |
| PCT/US1999/008250 WO1999052884A1 (en) | 1998-04-16 | 1999-04-15 | Epoxidation process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9909588A true BR9909588A (pt) | 2000-12-19 |
Family
ID=26766152
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9909588-2A BR9909588A (pt) | 1998-04-16 | 1999-04-15 | Processo de epoxidação |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6005123A (pt) |
| EP (1) | EP1077963B1 (pt) |
| JP (1) | JP4440467B2 (pt) |
| KR (1) | KR100559112B1 (pt) |
| CN (1) | CN100339372C (pt) |
| AU (1) | AU3747399A (pt) |
| BR (1) | BR9909588A (pt) |
| CA (1) | CA2327609C (pt) |
| DE (1) | DE69915610T2 (pt) |
| ES (1) | ES2214024T3 (pt) |
| MX (1) | MXPA00010118A (pt) |
| WO (1) | WO1999052884A1 (pt) |
Families Citing this family (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1125891A1 (fr) * | 2000-02-17 | 2001-08-22 | SOLVAY (Société Anonyme) | Procédé de fabrication d'un solide cristallin |
| US6307073B1 (en) * | 2000-07-25 | 2001-10-23 | Arco Chemical Technology, L.P. | Direct epoxidation process using a mixed catalyst system |
| US6281369B1 (en) * | 2000-12-07 | 2001-08-28 | Arco Chemical Technology, L.P. | Epoxidation catalyst and process |
| US6310224B1 (en) * | 2001-01-19 | 2001-10-30 | Arco Chemical Technology, L.P. | Epoxidation catalyst and process |
| US6376686B1 (en) * | 2001-09-05 | 2002-04-23 | Arco Chemical Technology, L.P. | Direct epoxidation process |
| US6417378B1 (en) * | 2001-10-09 | 2002-07-09 | Arco Chemical Technology, L.P. | Direct epoxidation process using pre-treated titanium zeolite |
| US6710192B2 (en) | 2001-10-16 | 2004-03-23 | Arco Chemical Technology, L.P. | Dense phase epoxidation |
| US6960671B2 (en) * | 2002-09-20 | 2005-11-01 | Arco Chemical Technology, L.P. | Process for direct oxidation of propylene to propylene oxide and large particle size titanium silicalite catalysts for use therein |
| US6710194B1 (en) * | 2003-01-23 | 2004-03-23 | Arco Chemical Technology, L.P. | Epoxidation process |
| US6884898B1 (en) | 2003-12-08 | 2005-04-26 | Arco Chemical Technology, L.P. | Propylene oxide process |
| US7182932B2 (en) * | 2004-01-30 | 2007-02-27 | Lyondell Chemical Technology, L.P. | Catalyst preparation |
| US6958405B2 (en) * | 2004-03-09 | 2005-10-25 | Arco Chemical Technology, L.P. | Polymer-encapsulated titanium zeolites for oxidation reactions |
| US7030255B2 (en) * | 2004-03-09 | 2006-04-18 | Lyondell Chemical Technology, L.P. | Oxidation process with in-situ H202 generation and polymer-encapsulated catalysts therefor |
| US6867312B1 (en) | 2004-03-17 | 2005-03-15 | Arco Chemical Technology, L.P. | Propylene oxide process |
| KR20070009605A (ko) * | 2004-04-01 | 2007-01-18 | 다우 글로벌 테크놀로지스 인크. | 마이크로파 가열에 의해 제조된 촉매를 사용한 탄화수소의수소-산화 |
| US7002026B2 (en) * | 2004-06-21 | 2006-02-21 | Lyondell Chemical Technology, L.P. | Removal of propylene glycol and/or propylene glycol ethers from aqueous streams |
| US7026492B1 (en) | 2004-10-29 | 2006-04-11 | Lyondell Chemical Technology, L.P. | Direct epoxidation process using modifiers |
| KR101133410B1 (ko) | 2004-11-12 | 2012-04-09 | 에스케이이노베이션 주식회사 | 올레핀의 에폭시화 방법 |
| US7084284B2 (en) * | 2004-11-16 | 2006-08-01 | Lyondell Chemical Technology, L.P. | Separation process |
| US7138535B1 (en) | 2005-06-01 | 2006-11-21 | Lyondell Chemical Technology, L.P. | Direct epoxidation process |
| US7273826B2 (en) * | 2005-07-26 | 2007-09-25 | Lyondell Chemical Technology, L.P. | Epoxidation catalyst |
| US7671222B2 (en) * | 2006-07-12 | 2010-03-02 | Lyondell Chemical Technology, L.P. | Direct epoxidation process using a mixed catalyst system |
| US7595410B2 (en) * | 2006-07-18 | 2009-09-29 | Lyondell Chemical Technology, L.P. | Direct epoxidation process using improved catalyst composition |
| US7700790B2 (en) * | 2006-10-27 | 2010-04-20 | Lyondell Chemical Technology, L.P. | Alkylene oxide process |
| US20080300417A1 (en) * | 2007-05-31 | 2008-12-04 | Te Chang | Slurry reaction system |
| ATE528298T1 (de) * | 2007-06-21 | 2011-10-15 | Sumitomo Chemical Co | Verfahren zur herstellung von propylenoxid |
| US7453003B1 (en) | 2007-08-29 | 2008-11-18 | Lyondell Chemical Technology, L.P. | Direct epoxidation catalyst and process |
| US7531675B1 (en) * | 2007-10-24 | 2009-05-12 | Lyondell Chemical Technology, L.P. | Direct epoxidation process using improved catalyst composition |
| US7470801B1 (en) | 2007-10-24 | 2008-12-30 | Lyondell Chemical Technology, L.P. | Direct epoxidation process using a mixed catalyst system |
| JP2010095510A (ja) * | 2008-09-19 | 2010-04-30 | Oita Univ | 炭化水素の接触部分酸化法 |
| US7767835B2 (en) * | 2008-12-18 | 2010-08-03 | Lyondell Chemical Technology, L.P. | Direct epoxidation process using improved catalyst |
| JP2010168358A (ja) * | 2008-12-26 | 2010-08-05 | Sumitomo Chemical Co Ltd | プロピレンオキサイドの製造方法 |
| AU2010221662B2 (en) | 2009-03-04 | 2015-04-02 | Chevron Phillips Chemical Company Lp | Selective hydrogenation catalyst and methods of making and using same |
| US20100317880A1 (en) * | 2009-06-11 | 2010-12-16 | Grey Roger A | Direct epoxidation process using modifiers |
| US20110098491A1 (en) * | 2009-10-28 | 2011-04-28 | Bernard Cooker | Direct epoxidation process using alkanoic acid modifier |
| US8124798B2 (en) | 2009-12-17 | 2012-02-28 | Lyondell Chemical Technology, Lp | Direct epoxidation catalyst and process |
| US8440846B2 (en) | 2010-09-30 | 2013-05-14 | Lyondell Chemical Technology, L.P. | Direct epoxidation process |
| SG11202004970XA (en) * | 2017-11-30 | 2020-06-29 | Dalian Inst Chemical Physics Cas | Molecular sieve-based catalyst modification apparatus, and method |
| CN112791744B (zh) * | 2020-12-22 | 2024-03-19 | 上海华峰新材料研发科技有限公司 | 一种改性钛硅分子筛及其制备方法和应用 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1201086A (en) * | 1967-06-29 | 1970-08-05 | Ici Ltd | Process for the production of epoxides |
| US3642834A (en) * | 1968-08-23 | 1972-02-15 | Mitsubishi Chem Ind | Preparation of olefin oxide |
| FR2069850A1 (en) * | 1969-11-13 | 1971-09-10 | Inst Francais Du Petrole | Olefin epoxidation - catalysed by molybdenum - cpd isopropanol or aluminium isopropylate and a phospne |
| IT1127311B (it) * | 1979-12-21 | 1986-05-21 | Anic Spa | Materiale sintetico,cristallino,poroso costituito da ossidi di silicio e titanio,metodo per la sua preparazione e suoi usi |
| JP3044836B2 (ja) * | 1991-05-28 | 2000-05-22 | 東ソー株式会社 | プロピレンオキシドの製法 |
| DE4425672A1 (de) * | 1994-07-20 | 1996-01-25 | Basf Ag | Oxidationskatalysator, Verfahren zu seiner Herstellung und Oxidationsverfahren unter Verwendung des Oxidationskatalysators |
| JPH08269029A (ja) * | 1995-03-29 | 1996-10-15 | Tosoh Corp | プロピレンオキシドの製造方法 |
| JP3837751B2 (ja) * | 1995-03-29 | 2006-10-25 | 東ソー株式会社 | プロピレンオキシドの製法 |
| DE19600709A1 (de) * | 1996-01-11 | 1997-07-17 | Basf Ag | Verfahren zur Herstellung von Epoxiden aus Olefinen, Wasserstoff und Sauerstoff |
| US5599956A (en) * | 1996-02-22 | 1997-02-04 | Uop | Integrated process for the production of propylene oxide |
| DE19623609A1 (de) * | 1996-06-13 | 1997-12-18 | Basf Ag | Oxidationskatalysator und Verfahren zur Herstellung von Epoxiden aus Olefinen, Wasserstoff und Sauerstoff unter Verwendung des Oxidationskatalysators |
-
1999
- 1999-04-12 US US09/290,100 patent/US6005123A/en not_active Expired - Lifetime
- 1999-04-15 DE DE69915610T patent/DE69915610T2/de not_active Expired - Lifetime
- 1999-04-15 CA CA002327609A patent/CA2327609C/en not_active Expired - Fee Related
- 1999-04-15 BR BR9909588-2A patent/BR9909588A/pt not_active Application Discontinuation
- 1999-04-15 CN CNB99805058XA patent/CN100339372C/zh not_active Expired - Lifetime
- 1999-04-15 ES ES99919845T patent/ES2214024T3/es not_active Expired - Lifetime
- 1999-04-15 KR KR1020007011332A patent/KR100559112B1/ko not_active Expired - Fee Related
- 1999-04-15 WO PCT/US1999/008250 patent/WO1999052884A1/en not_active Ceased
- 1999-04-15 JP JP2000543444A patent/JP4440467B2/ja not_active Expired - Fee Related
- 1999-04-15 EP EP99919845A patent/EP1077963B1/en not_active Expired - Lifetime
- 1999-04-15 AU AU37473/99A patent/AU3747399A/en not_active Abandoned
-
2000
- 2000-10-16 MX MXPA00010118 patent/MXPA00010118A/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CA2327609C (en) | 2008-06-17 |
| KR20010042639A (ko) | 2001-05-25 |
| US6005123A (en) | 1999-12-21 |
| CA2327609A1 (en) | 1999-10-21 |
| ES2214024T3 (es) | 2004-09-01 |
| AU3747399A (en) | 1999-11-01 |
| EP1077963A4 (en) | 2003-01-29 |
| CN100339372C (zh) | 2007-09-26 |
| WO1999052884A1 (en) | 1999-10-21 |
| DE69915610T2 (de) | 2005-01-27 |
| DE69915610D1 (de) | 2004-04-22 |
| EP1077963B1 (en) | 2004-03-17 |
| CN1297444A (zh) | 2001-05-30 |
| EP1077963A1 (en) | 2001-02-28 |
| KR100559112B1 (ko) | 2006-03-13 |
| WO1999052884A8 (en) | 2001-03-01 |
| JP4440467B2 (ja) | 2010-03-24 |
| JP2002511454A (ja) | 2002-04-16 |
| MXPA00010118A (es) | 2001-04-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| BR9909588A (pt) | Processo de epoxidação | |
| BR9909606A (pt) | Processo de epoxidação | |
| DE69822117D1 (de) | Verfahren zur Herstellung von olefinischen Epoxiden | |
| BR9802594A (pt) | Granulados que contêm silicalito-1 de titânio. | |
| BR9809834A (pt) | Acelerador de removedor de oxigênio. | |
| ES2136723T3 (es) | Utilizacion de n-aril-metilen-etilen-diamino-triacetatos, n-aril-metilen-imino-diacetatos o n,n'-diaril-metilen-etilen-diamino-acetatos contra el estres oxidante. | |
| BR0008430A (pt) | Sistema catalisador de polimerização de alfa-olfelina que contém um composto silano aromático | |
| BR0214024A (pt) | Derivados de 1,2,4-tiadiazol como moduladores de receptor de melanocortina | |
| ATE314310T1 (de) | Katalysator und dessen verwendung zur herstellung von wasserstoffperoxid | |
| BR9913890A (pt) | Composição de cuidado oral, e, uso de complexos de cobre, zinco, ferro ou estanho divalente ou ferro trivalente, ligados a uma alfa-hidroxicetona cìclica | |
| ATE224909T1 (de) | 1-(2-deoxy-2-fluoro-4-thio-beta-d- arabinofuranosyl)-cytosine | |
| DE60228233D1 (de) | Pyruvat-kinase als einem neuen zielmolekül | |
| BR0111780A (pt) | Agente herbicida | |
| BR0214569A (pt) | Processo de epoxidação direta que usa um sistema misto de catalisador pré-tratado com um agente que contém brometo | |
| BR9809226A (pt) | Processo de epoxidação usando-se um composto de peroxotungstato estabilizado com fosfato como catalisador | |
| BR9808854A (pt) | Processo para preparação de um composto, e, composto | |
| ATE280767T1 (de) | Antidiabetische thiazolidindione und ihre herstellung | |
| BR9914569A (pt) | Processo para a oxidação de um composto orgânico contendo pelo menos uma ligação dupla c-c | |
| CA2336129A1 (en) | Ectoparasiticide agents | |
| BRPI0507865A (pt) | catalisador de epoxidação | |
| BR9908395B1 (pt) | processo de tratamento da mistura da reação proveniente da oxidação direta do ciclo-hexano a ácido adìpico. | |
| BR0115139A (pt) | Compostos bis-heterocìclicos com atividade antitumor e quimiossensibilizante | |
| BR0013292A (pt) | Derivados de benzenamina como anti-coagulantes | |
| BR0012653A (pt) | Processo para a preparação de n-fosfono-metil-glicina ou de um seu sal | |
| BR9916849A (pt) | Análogos de nucleosìdeos antivirais |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
| B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
| B09B | Patent application refused [chapter 9.2 patent gazette] |
Free format text: INDEFIRO O PEDIDO DE ACORDO COM O(S) ARTIGO(S) 8O E 13 DA LPI. |
|
| B09B | Patent application refused [chapter 9.2 patent gazette] |
Free format text: MANTIDO O INDEFERIMENTO UMA VEZ QUE NAO FOI APRESENTADO RECURSO DENTRO DO PRAZO LEGAL. |