BR9909270A - Composição lìquida curável por radiação, especialmente para a produção de artigos curados flexìveis por estereolitografia - Google Patents
Composição lìquida curável por radiação, especialmente para a produção de artigos curados flexìveis por estereolitografiaInfo
- Publication number
- BR9909270A BR9909270A BR9909270-0A BR9909270A BR9909270A BR 9909270 A BR9909270 A BR 9909270A BR 9909270 A BR9909270 A BR 9909270A BR 9909270 A BR9909270 A BR 9909270A
- Authority
- BR
- Brazil
- Prior art keywords
- production
- radiation
- cured articles
- articles
- cationic
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 6
- 230000005855 radiation Effects 0.000 title abstract 3
- 239000007788 liquid Substances 0.000 title 1
- 239000003607 modifier Substances 0.000 abstract 4
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 3
- 125000002091 cationic group Chemical group 0.000 abstract 3
- 229920000570 polyether Polymers 0.000 abstract 3
- 229920005862 polyol Polymers 0.000 abstract 3
- 150000003077 polyols Chemical class 0.000 abstract 3
- 239000003999 initiator Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/0037—Production of three-dimensional images
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y10/00—Processes of additive manufacturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
- B33Y70/10—Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C9/00—Stereo-photographic or similar processes
- G03C9/08—Producing three-dimensional images
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/038—Macromolecular compounds which are rendered insoluble or differentially wettable
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- General Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Ceramic Engineering (AREA)
- Civil Engineering (AREA)
- Composite Materials (AREA)
- Structural Engineering (AREA)
- Epoxy Resins (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Patente de Invenção: <B>"COMPOSIçãO LìQUIDA CURáVEL POR RADIAçãO, ESPECIALMENTE PARA A PRODUçãO DE ARTIGOS CURADOS FLEXìVEIS POR ESTEREOLITOGRAFIA"<D>. A presente invenção refere-se a composições estereolitográficas contendo uma substância orgânica curável por radiação actínica e cationicamente polimerizável, um iniciador catiónico, um fotoiniciador radical, e pelo menos um modificador reativo catiónico contendo pelo menos dois grupos reativos por molécula ou pelo menos um poliéter poliol ou misturas destes. O modificador reativo catiónico tem pelo menos um segmento de extensão de cadeia com um peso molecular de pelo menos cerca de 100 e não mais do que cerca de 2000. O poliéter poliol tem um peso molecular maior ou igual a cerca de 4000. O uso de modificadores cationicamente reativos e modificadores de poliéter poliol substancialmente aumenta a flexibilidade e dureza dos artigos curados sem comprometer a fotovelocidade, a precisão e a recorbertura úmida das composições. A presente invenção ainda refere-se a um método de produzir um produto curado, particularmente artigos moldados tridimensionais mediante o tratamento da composição descrita acima com radiação actínica.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/050,279 US6136497A (en) | 1998-03-30 | 1998-03-30 | Liquid, radiation-curable composition, especially for producing flexible cured articles by stereolithography |
| PCT/EP1999/001844 WO1999050711A1 (en) | 1998-03-30 | 1999-03-19 | Liquid, radiation-curable composition, especially for producing flexible cured articles by stereolithography |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9909270A true BR9909270A (pt) | 2000-11-21 |
Family
ID=21964363
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9909270-0A BR9909270A (pt) | 1998-03-30 | 1999-03-19 | Composição lìquida curável por radiação, especialmente para a produção de artigos curados flexìveis por estereolitografia |
Country Status (14)
| Country | Link |
|---|---|
| US (3) | US6136497A (pt) |
| EP (1) | EP1080392B1 (pt) |
| JP (1) | JP4798845B2 (pt) |
| KR (1) | KR100653732B1 (pt) |
| CN (1) | CN1191498C (pt) |
| AT (1) | ATE399335T1 (pt) |
| AU (1) | AU3518699A (pt) |
| BR (1) | BR9909270A (pt) |
| CA (1) | CA2326128C (pt) |
| DE (1) | DE69938966D1 (pt) |
| IL (1) | IL138301A0 (pt) |
| TR (1) | TR200002776T2 (pt) |
| TW (1) | TWI221850B (pt) |
| WO (1) | WO1999050711A1 (pt) |
Families Citing this family (79)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE69940916D1 (de) * | 1998-02-18 | 2009-07-09 | Dsm Ip Assets Bv | Fotohärtbare flüssige Harzzusammensetzung |
| US6100007A (en) * | 1998-04-06 | 2000-08-08 | Ciba Specialty Chemicals Corp. | Liquid radiation-curable composition especially for producing cured articles by stereolithography having high heat deflection temperatures |
| US6762002B2 (en) | 1998-07-10 | 2004-07-13 | Dsm Desotech, Inc. | Solid imaging compositions for preparing polypropylene-like articles |
| US6287748B1 (en) * | 1998-07-10 | 2001-09-11 | Dsm N.V. | Solid imaging compositions for preparing polyethylene-like articles |
| US20060154175A9 (en) * | 1998-07-10 | 2006-07-13 | Lawton John A | Solid imaging compositions for preparing polypropylene-like articles |
| US6379866B2 (en) * | 2000-03-31 | 2002-04-30 | Dsm Desotech Inc | Solid imaging compositions for preparing polypropylene-like articles |
| JP4350832B2 (ja) * | 1999-04-19 | 2009-10-21 | Jsr株式会社 | 立体造形用光硬化性樹脂組成物およびこれを硬化してなる造形物 |
| DE60141886D1 (de) * | 2000-02-08 | 2010-06-02 | Huntsman Adv Mat Switzerland | Flüssige, strahlenhärtbare zusammensetzung insbesondere für stereolithographie |
| US20030207959A1 (en) * | 2000-03-13 | 2003-11-06 | Eduardo Napadensky | Compositions and methods for use in three dimensional model printing |
| US6569373B2 (en) | 2000-03-13 | 2003-05-27 | Object Geometries Ltd. | Compositions and methods for use in three dimensional model printing |
| US7300619B2 (en) * | 2000-03-13 | 2007-11-27 | Objet Geometries Ltd. | Compositions and methods for use in three dimensional model printing |
| US8481241B2 (en) | 2000-03-13 | 2013-07-09 | Stratasys Ltd. | Compositions and methods for use in three dimensional model printing |
| US6574523B1 (en) * | 2000-05-05 | 2003-06-03 | 3D Systems, Inc. | Selective control of mechanical properties in stereolithographic build style configuration |
| US6485306B1 (en) * | 2001-07-10 | 2002-11-26 | Aiptek International Inc. | Locus-recordable portable handwriting device |
| GB0103752D0 (en) * | 2001-02-15 | 2001-04-04 | Vantico Ltd | Three-Dimensional printing |
| KR100737723B1 (ko) * | 2001-07-27 | 2007-07-10 | 주식회사 동진쎄미켐 | 감광성 수지 조성물 |
| US20030149124A1 (en) * | 2001-11-27 | 2003-08-07 | Thommes Glen A. | Radiation curable resin composition for making colored three dimensional objects |
| WO2003068870A1 (en) * | 2002-02-18 | 2003-08-21 | Kansai Paint Co., Ltd. | Coating compositions and method of forming coating film |
| US7495034B2 (en) * | 2002-02-22 | 2009-02-24 | Henkel Corporation | Deformable soft molding compositions |
| DE60309853T2 (de) * | 2002-04-25 | 2007-09-20 | Ashland Licensing and Intellectual Property LLC, Dublin | Oberflächenverbesserer für verstärkte verbundstoffzusammensetzungen |
| US20040054025A1 (en) * | 2002-06-20 | 2004-03-18 | Lawton John A. | Compositions comprising a benzophenone photoinitiator |
| US6989225B2 (en) * | 2002-07-18 | 2006-01-24 | 3D Systems, Inc. | Stereolithographic resins with high temperature and high impact resistance |
| US6833231B2 (en) * | 2002-07-31 | 2004-12-21 | 3D Systems, Inc. | Toughened stereolithographic resin compositions |
| US20040077745A1 (en) * | 2002-10-18 | 2004-04-22 | Jigeng Xu | Curable compositions and rapid prototyping process using the same |
| TWI223736B (en) * | 2002-12-19 | 2004-11-11 | Ind Tech Res Inst | Hybrid photoresist with multi reaction models and process for forming pattern using the same |
| US20040137368A1 (en) * | 2003-01-13 | 2004-07-15 | 3D Systems, Inc. | Stereolithographic resins containing selected oxetane compounds |
| US20040161704A1 (en) * | 2003-02-18 | 2004-08-19 | Jianbing Huang | Method of making a flexographic printing plate by lithographic transfer of an energy-curable composition |
| US6881533B2 (en) | 2003-02-18 | 2005-04-19 | Kodak Polychrome Graphics Llc | Flexographic printing plate with ink-repellent non-image areas |
| US20040170923A1 (en) * | 2003-02-27 | 2004-09-02 | 3D Systems, Inc. | Colored stereolithographic resins |
| US6856283B2 (en) * | 2003-02-28 | 2005-02-15 | Raytheon Company | Method and apparatus for a power system for phased-array radar |
| JP4161858B2 (ja) * | 2003-06-03 | 2008-10-08 | コニカミノルタエムジー株式会社 | 感光性組成物、感光性平版印刷版、及び平版印刷版の作製方法 |
| US7354643B2 (en) | 2003-06-24 | 2008-04-08 | Cmet Inc. | Three-dimensional object and method of producing the same |
| US20050040562A1 (en) * | 2003-08-19 | 2005-02-24 | 3D Systems Inc. | Nanoparticle-filled stereolithographic resins |
| US7569260B2 (en) * | 2003-08-21 | 2009-08-04 | Asahi Kasei Chemicals Corporation | Photosensitive composition and cured products thereof |
| US7120512B2 (en) * | 2003-08-25 | 2006-10-10 | Hewlett-Packard Development Company, L.P. | Method and a system for solid freeform fabricating using non-reactive powder |
| US7232850B2 (en) | 2003-10-03 | 2007-06-19 | Huntsman Advanced Materials Americas Inc. | Photocurable compositions for articles having stable tensile properties |
| JP2007514805A (ja) * | 2003-11-06 | 2007-06-07 | ディーエスエム アイピー アセッツ ビー.ブイ. | 硬化性組成物およびそれを用いるラピッドプロトタイピング法 |
| US7820275B2 (en) * | 2003-11-06 | 2010-10-26 | Huntsman Advanced Materials Americas Llc | Photocurable composition for producing cured articles having high clarity and improved mechanical properties |
| US20050101684A1 (en) * | 2003-11-06 | 2005-05-12 | Xiaorong You | Curable compositions and rapid prototyping process using the same |
| US20050165127A1 (en) * | 2003-12-31 | 2005-07-28 | Dsm Desotech, Inc. | Solid imaging compositions for preparing polyethylene-like articles |
| DE102004012682A1 (de) | 2004-03-16 | 2005-10-06 | Degussa Ag | Verfahren zur Herstellung von dreidimensionalen Objekten mittels Lasertechnik und Auftragen eines Absorbers per Inkjet-Verfahren |
| CN100581792C (zh) * | 2004-03-22 | 2010-01-20 | 亨斯迈先进材料(瑞士)有限公司 | 可光致固化组合物 |
| DE102004020452A1 (de) * | 2004-04-27 | 2005-12-01 | Degussa Ag | Verfahren zur Herstellung von dreidimensionalen Objekten mittels elektromagnetischer Strahlung und Auftragen eines Absorbers per Inkjet-Verfahren |
| DE102004034416A1 (de) * | 2004-07-15 | 2006-02-02 | "Stiftung Caesar" (Center Of Advanced European Studies And Research) | Flüssige, strahlunghärtende Zusammensetzungen |
| JP4490798B2 (ja) * | 2004-08-30 | 2010-06-30 | Jsr株式会社 | 光ファイバアップジャケット用液状硬化性樹脂組成物 |
| TWI367214B (en) * | 2004-09-15 | 2012-07-01 | Dongjin Semichem Co Ltd New | Photoresist monomer having spiro cyclic ketal group, polymer thereof and photoresist composition including the same |
| US7423073B2 (en) * | 2004-11-23 | 2008-09-09 | Lexmark International, Inc. | Radiation curable compositions having improved flexibility |
| US20060172230A1 (en) * | 2005-02-02 | 2006-08-03 | Dsm Ip Assets B.V. | Method and composition for reducing waste in photo-imaging applications |
| US20070116311A1 (en) * | 2005-11-16 | 2007-05-24 | Henkel Corporation | High strength curable compositions for the solid freeform fabrication of hearing aids |
| TWI432904B (zh) * | 2006-01-25 | 2014-04-01 | Dow Corning | 用於微影技術之環氧樹脂調配物 |
| JP4929784B2 (ja) * | 2006-03-27 | 2012-05-09 | 富士通株式会社 | 多層配線基板、半導体装置およびソルダレジスト |
| US9676899B2 (en) * | 2006-05-01 | 2017-06-13 | Dsm Ip Assets B.V. | Radiation curable resin composition and rapid three dimensional imaging process using the same |
| US20080103226A1 (en) * | 2006-10-31 | 2008-05-01 | Dsm Ip Assets B.V. | Photo-curable resin composition |
| TWI447939B (zh) * | 2007-06-15 | 2014-08-01 | 納美仕有限公司 | Led用導電性晶粒黏著劑 |
| DE102007043559B4 (de) * | 2007-09-13 | 2012-05-31 | Carl Zeiss Vision Gmbh | Verwendung eines lichthärtenden thermoplastischen Epoxidharzklebstoffs zum Blocken oder Kleben von optischen Bauelementen |
| JP5881948B2 (ja) * | 2007-11-27 | 2016-03-09 | スリーディー システムズ インコーポレーテッド | 高透明性を有する三次元物品を製造するための光硬化型樹脂組成物 |
| EP2098367A1 (en) * | 2008-03-05 | 2009-09-09 | Eastman Kodak Company | Sensitizer/Initiator Combination for Negative-Working Thermal-Sensitive Compositions Usable for Lithographic Plates |
| WO2010043274A1 (en) * | 2008-10-17 | 2010-04-22 | Huntsman Advanced Materials (Switzerland) Gmbh | Improvements for rapid prototyping apparatus |
| US20100190881A1 (en) | 2009-01-28 | 2010-07-29 | 3D Systems, Incorporated | Radiation Curable Compositions Useful in Solid Freeform Fabrication Systems |
| EP2406318B1 (en) | 2009-03-13 | 2021-04-21 | DSM IP Assets B.V. | Radiation curable resin composition and rapid three-dimensional imaging process using the same |
| EP2436510A1 (en) | 2010-10-04 | 2012-04-04 | 3D Systems, Inc. | System and resin for rapid prototyping |
| WO2012126695A1 (en) | 2011-03-23 | 2012-09-27 | Huntsman Advanced Materials (Switzerland) Gmbh | Stable curable thiol-ene composition |
| KR20130139134A (ko) | 2012-06-12 | 2013-12-20 | 제일모직주식회사 | 접착제 조성물, 이를 이용한 편광판, 그 제조 방법 및 이를 포함하는 광학 부재 |
| JP6414411B2 (ja) | 2013-08-09 | 2018-10-31 | ディーエスエム アイピー アセッツ ビー.ブイ.Dsm Ip Assets B.V. | 積層造形用の低粘度液状放射線硬化型歯科アライナー成形型用樹脂組成物 |
| CN105482513B (zh) * | 2014-10-11 | 2017-12-26 | 中国科学院宁波材料技术与工程研究所 | 油墨用玻璃粉和颜料的改性分散方法及耐高温油墨 |
| US10773512B2 (en) * | 2015-03-11 | 2020-09-15 | Stratasys Ltd. | Support material formulation and additive manufacturing processes employing same |
| ES2879637T3 (es) * | 2015-03-23 | 2021-11-22 | Dow Global Technologies Llc | Composiciones fotocurables para impresión tridimensional |
| CN104914675B (zh) * | 2015-04-08 | 2019-04-23 | 乐道战略材料有限公司 | 一种用于三维快速成型的含光敏性硅氧烷和超支化聚醚多元醇的光敏树脂组合物 |
| DE102015014925B4 (de) * | 2015-11-17 | 2017-09-28 | Ronald Hüner | Reibschichten mit Kanalstruktur |
| EP3181357B1 (en) * | 2015-12-15 | 2018-10-10 | Agfa Nv | Additive manufacturing method using dynamic light projection for flexographic print masters |
| US20190077073A1 (en) * | 2016-03-14 | 2019-03-14 | Dsm Ip Assets, B.V. | Radiation curable compositions for additive fabrication with improved toughness and high temperature resistance |
| US20190153226A1 (en) | 2016-04-08 | 2019-05-23 | Solvay Specialty Polymers Usa, Llc | Photocurable polymers, photocurable polymer compositions and lithographic processes including the same |
| ES2685280B2 (es) * | 2017-03-31 | 2019-06-21 | Centro Tecnologico De Nanomateriales Avanzados S L | Composición de resina curable por radiación y procedimiento para su obtención |
| CN111051469B (zh) | 2017-06-05 | 2024-06-04 | 昭荣化学工业株式会社 | 量子点-树脂浓缩物和预混物的酸稳定化 |
| WO2019169211A1 (en) * | 2018-03-02 | 2019-09-06 | Formlabs, Inc. | Latent cure resins and related methods |
| JP7214981B2 (ja) * | 2018-05-31 | 2023-01-31 | 味の素株式会社 | 樹脂組成物、シート状積層材料、プリント配線板及び半導体装置 |
| EP3914043A1 (en) | 2020-05-20 | 2021-11-24 | Henkel IP & Holding GmbH | Post processing of 3d printed materials via microwave enhanced chemistry |
| SE545292C2 (en) * | 2020-07-08 | 2023-06-20 | Perstorp Ab | A radiation curable composition comprising a biobased reactive diluent |
| US20220411634A1 (en) | 2021-06-24 | 2022-12-29 | Henkel Ag & Co. Kgaa | Silicone formulation with high temperature stability and clarity |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4318766A (en) * | 1975-09-02 | 1982-03-09 | Minnesota Mining And Manufacturing Company | Process of using photocopolymerizable compositions based on epoxy and hydroxyl-containing organic materials |
| US5434196A (en) * | 1988-02-19 | 1995-07-18 | Asahi Denka Kogyo K.K. | Resin composition for optical molding |
| JP2538652B2 (ja) * | 1988-09-19 | 1996-09-25 | 旭電化工業株式会社 | 光学的造形用樹脂組成物 |
| WO1992015620A1 (en) * | 1991-02-27 | 1992-09-17 | Allied-Signal Inc. | Stereolithography using vinyl ether based polymers |
| US5510226A (en) * | 1991-05-01 | 1996-04-23 | Alliedsignal Inc. | Stereolithography using vinyl ether-epoxide polymers |
| DE4138309C2 (de) * | 1991-11-21 | 1995-02-09 | Eos Electro Optical Syst | Durch Einwirkung elektromagnetischer Strahlung vernetzbares Kunststoffmaterial |
| CA2092131A1 (en) * | 1992-03-27 | 1993-09-28 | Victor Kadziela (Nmi) | Low viscosity self-toughening acrylate composition |
| DE69315003T2 (de) * | 1992-07-17 | 1998-03-12 | Ethicon Inc | Strahlenhärtbare Urethan-Acrylatprepolymere und vernetzte Polymere |
| TW269017B (pt) * | 1992-12-21 | 1996-01-21 | Ciba Geigy Ag | |
| JPH0760843A (ja) * | 1993-08-26 | 1995-03-07 | Olympus Optical Co Ltd | 三次元構造体の製造方法 |
| ES2147777T3 (es) * | 1993-09-16 | 2000-10-01 | Ciba Sc Holding Ag | Compuestos vinileter con grupos funcionales adicionales, distintos de vinileter, y su utilizacion en la formulacion de compuestos reticulables. |
| US5705116A (en) * | 1994-06-27 | 1998-01-06 | Sitzmann; Eugene Valentine | Increasing the useful range of cationic photoinitiators in stereolithography |
| US5494618A (en) * | 1994-06-27 | 1996-02-27 | Alliedsignal Inc. | Increasing the useful range of cationic photoinitiators in stereolithography |
| DE69520222T2 (de) * | 1994-10-31 | 2001-08-23 | Minnesota Mining And Mfg. Co., Saint Paul | Mit sichtbarem licht härtbares epoxysystem mit verbesserter härtungstiefe |
| DE69629809T2 (de) * | 1995-05-12 | 2004-07-15 | Asahi Denka Kogyo K.K. | Stereolithographisches verfahren und kunststoffharz dazu |
| JP3668310B2 (ja) * | 1996-01-22 | 2005-07-06 | 三菱レイヨン株式会社 | 光学的立体造形用樹脂組成物 |
| JPH09217004A (ja) * | 1996-02-09 | 1997-08-19 | Takemoto Oil & Fat Co Ltd | 光学的立体造形用光硬化性組成物 |
| JP3849989B2 (ja) * | 1996-04-09 | 2006-11-22 | 株式会社Adeka | 光学的立体造形用樹脂組成物および光学的立体造形法 |
| JP3626275B2 (ja) * | 1996-04-09 | 2005-03-02 | Jsr株式会社 | 光硬化性樹脂組成物 |
| ATE191090T1 (de) * | 1996-07-29 | 2000-04-15 | Ciba Sc Holding Ag | Flüssige, strahlungshärtbare zusammensetzung, insbesondere für die stereolithographie |
| JP3844824B2 (ja) * | 1996-11-26 | 2006-11-15 | 株式会社Adeka | エネルギー線硬化性エポキシ樹脂組成物、光学的立体造形用樹脂組成物及び光学的立体造形方法 |
| EP0960354A1 (en) * | 1997-02-14 | 1999-12-01 | Alliedsignal Inc. | High temperature performance polymers for stereolithography |
| JP4204113B2 (ja) * | 1997-12-04 | 2009-01-07 | 株式会社Adeka | 新規な芳香族スルホニウム化合物、これからなる光酸発生剤およびこれを含む光重合性組成物、光造形用樹脂組成物ならびに光学的立体造形法 |
-
1998
- 1998-03-30 US US09/050,279 patent/US6136497A/en not_active Expired - Lifetime
-
1999
- 1999-03-19 EP EP99916836A patent/EP1080392B1/en not_active Expired - Lifetime
- 1999-03-19 BR BR9909270-0A patent/BR9909270A/pt not_active IP Right Cessation
- 1999-03-19 WO PCT/EP1999/001844 patent/WO1999050711A1/en not_active Ceased
- 1999-03-19 CN CNB998048062A patent/CN1191498C/zh not_active Expired - Lifetime
- 1999-03-19 IL IL13830199A patent/IL138301A0/xx unknown
- 1999-03-19 KR KR1020007010875A patent/KR100653732B1/ko not_active Expired - Lifetime
- 1999-03-19 CA CA002326128A patent/CA2326128C/en not_active Expired - Lifetime
- 1999-03-19 TR TR2000/02776T patent/TR200002776T2/xx unknown
- 1999-03-19 DE DE69938966T patent/DE69938966D1/de not_active Expired - Lifetime
- 1999-03-19 JP JP2000541560A patent/JP4798845B2/ja not_active Expired - Lifetime
- 1999-03-19 AT AT99916836T patent/ATE399335T1/de active
- 1999-03-19 AU AU35186/99A patent/AU3518699A/en not_active Abandoned
- 1999-03-29 TW TW088104905A patent/TWI221850B/zh not_active IP Right Cessation
-
2000
- 2000-08-25 US US09/645,944 patent/US6413697B1/en not_active Expired - Lifetime
-
2002
- 2002-06-13 US US10/167,436 patent/US20020177073A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| TR200002776T2 (tr) | 2001-02-21 |
| CA2326128C (en) | 2008-07-15 |
| US6136497A (en) | 2000-10-24 |
| CN1191498C (zh) | 2005-03-02 |
| WO1999050711A1 (en) | 1999-10-07 |
| KR100653732B1 (ko) | 2006-12-05 |
| US6413697B1 (en) | 2002-07-02 |
| TWI221850B (en) | 2004-10-11 |
| KR20010042325A (ko) | 2001-05-25 |
| JP4798845B2 (ja) | 2011-10-19 |
| US20020177073A1 (en) | 2002-11-28 |
| ATE399335T1 (de) | 2008-07-15 |
| DE69938966D1 (de) | 2008-08-07 |
| JP2002509982A (ja) | 2002-04-02 |
| HK1032635A1 (en) | 2001-07-27 |
| AU3518699A (en) | 1999-10-18 |
| IL138301A0 (en) | 2001-10-31 |
| CA2326128A1 (en) | 1999-10-07 |
| CN1296577A (zh) | 2001-05-23 |
| EP1080392A1 (en) | 2001-03-07 |
| EP1080392B1 (en) | 2008-06-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| BR9909270A (pt) | Composição lìquida curável por radiação, especialmente para a produção de artigos curados flexìveis por estereolitografia | |
| BR9811802A (pt) | Composições contendo fìler, estabilizadas à sedimentação, curáveis por radiação | |
| DE3584868D1 (de) | Ungesaettigte polysiloxane, polymerisierbare zusammensetzungen und kontaktlinsen daraus. | |
| BRPI0510511A (pt) | composições fotocrÈmicas e artigos que compreendem siloxano, alquileno ou oligÈmeros de alquileno substituìdo | |
| DE69604909D1 (de) | Flüssige photohärtbare zusammensetzungen | |
| BR9901799A (pt) | Restaurativo dentário, composição restaurativa dentária, e, processo para restaurar um dente. | |
| BRPI0414789A (pt) | microgéis em meios orgánicos reticuláveis | |
| NO20052399D0 (no) | Taksaner som er kovalent bundet til hyaluronsyre eller hyaluronsyrederivater. | |
| BR0109520A (pt) | Composição de revestimento | |
| DE60141886D1 (de) | Flüssige, strahlenhärtbare zusammensetzung insbesondere für stereolithographie | |
| BR0004831A (pt) | Composição curável, processo para formar um filme, produto, e, composição fotocurável | |
| MX171398B (es) | Composicion lubricante para camaras de aire, para el moldeo de llantas | |
| BR0212246A (pt) | Composição indutora da resistência a doença de planta, método para controlar uma doença de planta, e, processo para a produção de uma composição | |
| BR9812841A (pt) | Lente oftálmica, processo para a produção da mesma, e, uso de um oligÈmero de ciclo-hexil dialil éster | |
| ATE439385T1 (de) | Photohärtbare harzzusammensetzung | |
| EP0363071A3 (en) | Uv curable gels | |
| BRPI0503158A (pt) | composição para uso na produção de uma espuma de poliuretano, método de produzir uma espuma de poliuretano, e composição de poliuretano, e composição para uso na fabricação de uma espuma de poliuretano | |
| FR2363598A1 (fr) | Composition photo-durcissable et son application | |
| BR0101229A (pt) | Material dentário à base de monÈmerospolimerizáveis cationicamente | |
| TW200616993A (en) | Radical polymerizable sulfur-containing compound and radical polymerizable sulfur-containing polymer | |
| DE69215335D1 (de) | Verfahren zur Erniedrigung der Dilatierung eines Latex | |
| ES2089603T3 (es) | Nuevos productos de revestimiento solubles en agua. |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE AS 6A, 7A E 8A ANUIDADES |
|
| B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 1907 DE 24/07/2007. |