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AR101214A1 - Ciano-cicloalquilpenta-2,4-dienos, ciano-cicloalquilpent-2-en-4-inas, ciano-heterociclilpenta-2,4-dienos y ciano-heterociclilpent-2-en-4-inas sustituidos como principios activos contra el estrés abiótico de plantas - Google Patents

Ciano-cicloalquilpenta-2,4-dienos, ciano-cicloalquilpent-2-en-4-inas, ciano-heterociclilpenta-2,4-dienos y ciano-heterociclilpent-2-en-4-inas sustituidos como principios activos contra el estrés abiótico de plantas

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Publication number
AR101214A1
AR101214A1 ARP150102254A ARP150102254A AR101214A1 AR 101214 A1 AR101214 A1 AR 101214A1 AR P150102254 A ARP150102254 A AR P150102254A AR P150102254 A ARP150102254 A AR P150102254A AR 101214 A1 AR101214 A1 AR 101214A1
Authority
AR
Argentina
Prior art keywords
alkyl
bis
alkoxy
aryl
silyl
Prior art date
Application number
ARP150102254A
Other languages
English (en)
Inventor
Pedro Ruiz-Santaella Moreno Juan
Jeffrey Hills Martin
Schmutzler Dirk
Dr Dittgen Jan
Dr Willms Lothar
Dr Frackenpohl Jens
Original Assignee
Bayer Cropscience Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Cropscience Ag filed Critical Bayer Cropscience Ag
Publication of AR101214A1 publication Critical patent/AR101214A1/es

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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/45—Carboxylic acid nitriles having cyano groups bound to carbon atoms of rings other than six-membered aromatic rings
    • C07C255/46—Carboxylic acid nitriles having cyano groups bound to carbon atoms of rings other than six-membered aromatic rings to carbon atoms of non-condensed rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/34—Nitriles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom not containing sulfur-to-oxygen bonds, e.g. polysulfides
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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/20—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom three- or four-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
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    • A01N55/02—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur containing metal atoms
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    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/04—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D207/10—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
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    • C07D211/36—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
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    • C07D239/26—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
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    • C07D265/28—1,4-Oxazines; Hydrogenated 1,4-oxazines
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    • C07D279/10—1,4-Thiazines; Hydrogenated 1,4-thiazines
    • C07D279/12—1,4-Thiazines; Hydrogenated 1,4-thiazines not condensed with other rings
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    • C07D305/04—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D305/08—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring atoms
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    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
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    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Cultivation Of Plants (AREA)
  • Epoxy Compounds (AREA)

Abstract

Su uso para aumentar la tolerancia al estrés en plantas frente al estrés abiótico, y/o para aumentar el rendimiento de las plantas. E intermediarios para su preparación. Reivindicación 1: Ciano-cicloalquilpenta-2,4-dienos, ciano-cicloalquilpent-2-en-4-inas, ciano-heterociclilpenta-2,4-dienos y ciano-heterociclilpent-2-en-4-inas de la fórmula general (1) o sus sales, en donde [X-Y] representa los grupos del grupo de fórmulas (4); Q representa los grupos del grupo de fórmulas (5), en donde R⁵, R⁶, R⁷, R⁸, R⁹, R¹⁰ y R¹¹ tienen en cada caso el significado de acuerdo con las definiciones siguientes y la flecha representa una unión con el grupo respectivo [X-Y]; R¹ representa hidrógeno, alquilo, arilo, heteroarilo, heterociclilo, cicloalquilo, alquenilo, alquinilo, alquinilalquilo, alcoxialquilo, hidroxialquilo, haloalquilo, haloalquenilo, haloalcoxialquilo, alquiltioalquilo, arilalquilo, heterociclilalquilo, halocicloalquilo, cicloalquenilo, alcoxialcoxialquilo, cicloalquilalquilo, cicloalquenilalquilo, haloalquinilo, alquilsulfinilalquilo, alquilsulfonilalquilo, halocicloalquilalquilo cicloalquilsulfinilalquilo, cicloalquilsulfonilalquilo, arilsulfinilalquilo, arilsulfonilalquilo, ariltioalquilo, cicloalquiltioalquilo, alcoxihaloalquilo, haloalcoxihaloalquilo; R² representa hidrógeno, alquilo, alcoxialquilo, alcoxialcoxialquilo, alquenilo, alquinilo, alquilcarbonilo, arilcarbonilo, heteroarilcarbonilo, cicloalquilcarbonilo, alquenilcarbonilo, heterociclilcarbonilo, alcoxicarbonilo, alqueniloxicarbonilo, ariloxialquilo, arilalcoxicarbonilo, cicloalcoxicarbonilo, cicloalquilalcoxicarbonilo, arilalcoxialquilo, arilalquilo, alcoxialcoxialquilo, alquiltioalquilo, trialquilsililo, alquil(bis-alquil)sililo, alquil(bis-aril)sililo, aril(bis-alquil)sililo, cicloalquil(bis-alquil)sililo, halo(bis-alquil)sililo, trialquilsililalcoxialquilo, trialquilsililalquilo, alquiniloxicarbonilo, cicloalquilo, cicloalquilalquilo, aminocarbonilo, alquilaminocarbonilo, bis-alquilaminocarbonilo, cicloalquilaminocarbonilo, alquilsulfonilo, haloalquilsulfonilo, arilsulfonilo, heteroarilsulfonilo, cicloalquilsulfonilo; A¹, A², V, W independientemente entre sí representan un grupo CR³R⁴, oxígeno o azufre, estando presentes en cada caso como máximo 2 átomos de oxígeno o 2 átomos de azufre en el anillo formado por los grupos A¹, A², V, W y el átomo de carbono al que están unidos y no estando adyacentes en cada caso los átomos de oxígeno o azufre; m representa 0, 1, 2; n representa 0, 1, 2; R³ y R⁴ independientemente entre sí representan hidrógeno, alquilo, halógeno, cicloalquilo, alcoxi, arilo, heterociclilo, heteroarilo, arilalquilo, alquiltio, haloalquilo, haloalquiloxi, haloalquiltio, alcoxialquilo, alquiltioalquilo, heteroarilalquilo, heterociclilalquilo, cicloalquilalquilo, cicloalquenilo, alquinilo, alquenilo, haloalquenilo, haloalquinilo, alquilsulfinilo, alquilsulfonilo, cicloalquilsulfinilo, cicloalquilsulfonilo, arilsulfinilo, arilsulfonilo, alcoxihaloalquilo, haloalcoxihaloalquilo, R³ y R⁴ con el átomo al que están unidos forman un anillo de 3 a 6 miembros totalmente saturado, dado el caso interrumpido por heteroátomos y que dado el caso presenta más sustituciones; R⁵ y R⁶ independientemente entre sí representan hidrógeno, halógeno, alquilo, haloalquilo, cicloalquilo, cicloalquilalquilo; R⁷ representa hidrógeno, halógeno, alquilo, haloalquilo, haloalcoxi, haloalcoxialquilo, haloalcoxihaloalquilo, alcoxihaloalquilo, alquiniloxihaloalquilo, alqueniloxihaloalquilo, alquiltio, haloalquiltio, arilo, arilalquilo, heteroarilo, heteroarilalquilo, heterociclilo, alcoxi, hidroxi, alquilcarboniloxi, arilcarboniloxi, cicloalquilcarboniloxi, trisalquilsililoxi, bis-alquil(alquil)sililoxi, alquil(bis-aril)sililoxi, aril(bis-alquil)sililoxi, cicloalquil(bis-alquil)sililoxi, halo(bis-alquil)sililoxi, trialquilsililalcoxialquiloxi, trialquilsililalquiloxi, alquilsulfinilo, alquilsulfonilo, cicloalquilsulfinilo, cicloalquilsulfonilo, arilsulfinilo, arilsulfonilo, cicloalquilo, cicloalquilalquilo, R⁶ y R⁷ con los átomos a los que están unidos forman un anillo de 3 a 6 miembros totalmente saturado, dado el caso interrumpido por heteroátomos y que dado el caso presenta más sustituciones; R⁸ representa hidrógeno, alquilo, alcoxialquilo, cicloalquilo, cicloalquilalquilo, arilo, arilalquilo, heteroarilalquilo, bis-arilalquilo, tris-arilalquilo, alquenilo, cicloalquenilalquilo, alquinilalquilo, trialquilsililalcoxialquilo, alcoxialcoxialquilo, alquiltioalquilo, haloalquilo, arilsulfonilalquilo, trialquilsililo, alquil-(bis-aril)sililo, alquil-(bis-alquil)sililo, bis-alquilaminoalquilo, heterociclilalquilo, alquinilo, cianoalquilo, heterociclilo, cicloalquenilo; R⁹ representa hidrógeno, alquilo, cicloalquilo, halógeno, alquinilalquilo, haloalquilo, alquinilo, alquenilo, cianoalquilo, cicloalquilalquilo, arilalquilo, heteroarilalquilo, alquilcarbonilo, alcoxicarbonilo, alqueniloxicarbonilo, alquenilalquiloxicarbonilo, arilalquiloxicarbonilo, cicloalcoxicarbonilo, cicloalquilalcoxicarbonilo, alquilsulfonilo, arilsulfonilo, cicloalquilsulfonilo, alquilsulfinilo, arilsulfinilo, cicloalquilsulfinilo, alcoxicarbonilalquilo, hidroxicarbonilalquilo, arilalcoxicarbonilalquilo, cicloalquilalcoxicarbonilalquilo, alcoxicarbonilcicloalquilo, hidroxicarbonilcicloalquilo, arilalcoxicarbonilcicloalquilo, alqueniloxicarbonilcicloalquilo, aminocarbonilcicloalquilo, alquilaminocarbonilcicloalquilo, cicloalquilaminocarbonilcicloalquilo, alcoxicarbonilcicloalquenilo, hidroxicarbonilcicloalquenilo, bis-alquilaminoalquilo, hidroxicarbonilheterociclilo, alcoxicarbonilheterociclilo, alqueniloxicarbonilheterociclilo, alquenilalcoxicarbonilheterociclilo, arilalcoxicarbonilheterociclilo, cicloalcoxicarbonilheterociclilo, cicloalquilalcoxicarbonilheterociclilo, aminocarbonilheterociclilo, alquilaminocarbonilheterociclilo, bis-alquilaminocarbonilheterociclilo, cicloalquilaminocarbonilheterociclilo, arilalquilaminocarbonilheterociclilo, alquenilaminocarbonilheterociclilo, hidroxicarbonilheterociclilalquilo, alcoxicarbonilheterociclilalquilo, hidroxicarbonilcicloalquilalquilo, alcoxicarbonilcicloalquilalquilo, hidroxi, alcoxi, heterociclilo, heterociclilalquilo, arilo, cicloalquenilo, cicloalquenilalquilo; R¹⁰ representa hidrógeno, alquilo, cicloalquilo, halógeno, haloalquilo, alquinilo, alquenilo, cianoalquilo, arilalquilo, heteroarilalquilo, alquilcarbonilo, alcoxicarbonilo, alquilsulfonilo, arilsulfonilo, cicloalquilsulfonilo, alquilsulfinilo, arilsulfinilo, cicloalquilsulfinilo, alcoxicarbonilalquilo, o R⁹ y R¹⁰ con el nitrógeno al que están unidos forman un anillo de tres a ocho miembros dado el caso sustituido con halógeno, alquilo, haloalquilo, alcoxi, alcoxicarbonilo, cicloalcoxicarbonilo, cicloalquilalcoxicarbonilo, alqueniloxicarbonilo, hidroxicarbonilo, aminocarbonilo, alquilaminocarbonilo, cicloalquilaminocarbonilo, arilalquilaminocarbonilo, y que dado el caso está interrumpido por O, S o N, o R⁹ y R¹⁰ juntos son parte de un grupo dado el caso sustituido de sulfilimina o amidina o forman un iminofosforano; y R¹¹ representa hidrógeno, alquilo, cicloalquilo, haloalquilo, alcoxialquilo, alquiltioalquilo. Reivindicación 14: Compuestos de la fórmula general (2), o sus sales en donde R¹ representa hidrógeno, alquilo C₁₋₈, arilo, heteroarilo, heterociclilo, cicloalquilo C₃₋₈, alquenilo C₂₋₈, alquinilo C₂₋₈, alquinil C₂₋₈-alquilo C₁₋₈, alcoxi C₁₋₈-alquilo C₁₋₈, hidroxi-alquilo C₁₋₈, haloalquilo C₁₋₈, haloalquenilo C₂₋₈, haloalcoxi C₁₋₈-alquilo C₁₋₈, alquiltio C₁₋₈-alquilo C₁₋₈, aril-alquilo C₁₋₈, heterociclil-alquilo C₁₋₈, halocicloalquilo C₃₋₈, cicloalquenilo C₄₋₈, alcoxi C₁₋₈-alcoxi C₁₋₈-alquilo C₁₋₈, alcoxi C₁₋₈-haloalquilo C₁₋₈, haloalcoxi C₁₋₈-haloalquilo C₁₋₈, cicloalquil C₃₋₈-alquilo C₁₋₈; R² representa hidrógeno, alquilo C₁₋₈, alcoxi C₁₋₈-alquilo C₁₋₈, alcoxi C₁₋₈-alcoxi C₁₋₈-alquilo C₁₋₈, alquenilo C₂₋₈, alquinilo C₂₋₈, alquilcarbonilo C₁₋₈, arilcarbonilo, heteroarilcarbonilo, cicloalquilcarbonilo C₃₋₈, alquenilcarbonilo C₂₋₈, heterociclilcarbonilo, alcoxicarbonilo C₁₋₈, alqueniloxicarbonilo C₂₋₈, ariloxi-alquilo C₁₋₈, aril-alcoxicarbonilo C₁₋₈, cicloalcoxicarbonilo C₃₋₈, cicloalquil C₃₋₈-alcoxicarbonilo C₁₋₈, aril-alcoxi C₁₋₈-alquilo C₁₋₈, aril-alquilo C₁₋₈, alcoxi C₁₋₈-alcoxi C₁₋₈-alquilo C₁₋₈, alquiltio C₁₋₈-alquilo C₁₋₈, tris[alquil C₁₋₈]sililo, alquil C₁₋₈-bis-[alquil C₁₋₈]sililo, alquil C₁₋₈-bis(aril)sililo, aril-bis[alquil C₁₋₈]sililo, cicloalquil C₃₋₈-bis[alquil C₁₋₈]sililo, halo-bis[alquil C₁₋₈]sililo, tris[alquil C₁₋₈]silil-alcoxi C₁₋₈-alquilo C₁₋₈, tris[alquil C₁₋₈]silil-alquilo C₁₋₈; A¹ A², V, W independientemente entre sí representan un grupo CR³R⁴, oxígeno o azufre, estando presentes en cada caso como máximo 2 átomos de oxígeno o 2 átomos de azufre en el anillo formado por los grupos A¹, A², V, W y el átomo de carbono al que están unidos y no estando adyacentes en cada caso los átomos de oxígeno o azufre; m representa 0, 1, 2; n representa 0, 1, 2; R³ y R⁴ independientemente entre sí representan hidrógeno, alquilo C₁₋₈, halógeno, cicloalquilo C₃₋₈, alcoxi C₁₋₈, arilo, heterociclilo, heteroarilo, aril-alquilo C₁₋₈, alquiltio C₁₋₈, haloalquilo C₁₋₈, haloalquiloxi C₁₋₈, haloalquiltio C₁₋₈, alcoxi C₁₋₈-alquilo C₁₋₈, alquiltio C₁₋₈-alquilo C₁₋₈, heteroaril-alquilo C₁₋₈, heterociclil-alquilo C₁₋₈, alcoxi C₁₋₈-haloalquilo C₁₋₈, haloalcoxi C₁₋₈-haloalquilo C₁₋₈, alquenilo C₂₋₈, alquinilo C₂₋₈ y R³ y R⁴ con el átomo al que están unidos forman un anillo de 3 a 6 miembros totalmente saturado, dado el caso interrumpido por heteroátomos y que dado el caso presenta más sustituciones. Reivindicación 16: Compuestos de la fórmula general (3), o sus sales en donde R¹ representa hidrógeno, alquilo C₁₋₈, arilo, heteroarilo, heterociclilo, cicloalquilo C₃₋₈, alquenilo C₂₋₈, alquinilo C₂₋₈, alquinil C₂₋₈-alquilo C₁₋₈, alcoxi C₁₋₈-alquilo C₁₋₈, hidroxi-alquilo C₁₋₈, haloalquilo C₁₋₈, haloalquenilo C₂₋₈, haloalcoxi C₁₋₈-alquilo C₁₋₈, alquiltio C₁₋₈-alquilo C₁₋₈, aril-alquilo C₁₋₈, heterociclil-alquilo C₁₋₈, halocicloalquilo C₃₋₈, cicloalquenilo C₄₋₈, alcoxi C₁₋₈-alcoxi C₁₋₈-alquilo C₁₋₈, alcoxi C₁₋₈-haloalquilo C₁₋₈, haloalcoxi C₁₋₈-haloalquilo C₁₋₈; R² representa hidrógeno, alquilo C₁₋₈, alcoxi C₁₋₈-alquilo C₁₋₈, alcoxi C₁₋₈-alcoxi C₁₋₈-alquilo C₁₋₈, alquenilo C₂₋₈, alquinilo C₂₋₈, alquilcarbonilo C₁₋₈, arilcarbonilo, heteroarilcarbonilo, cicloalquilcarbonilo C₃₋₈, alquenilcarbonilo C₂₋₈, heterociclilcarbonilo, alcoxicarbonilo C₁₋₈, alqueniloxicarbonilo C₂₋₈, ariloxi-alquilo C₁₋₈, aril-alcoxicarbonilo C₁₋₈, cicloalcoxicarbonilo C₃₋₈, cicloalquil C₃₋₈-alcoxicarbonilo C₁₋₈, aril-alcoxi C₁₋₈-alquilo C₁₋₈, aril-alquilo C₁₋₈, alcoxi C₁₋₈-alcoxi C₁₋₈-alquilo C₁₋₈, alquiltio C₁₋₈-alquilo C₁₋₈, tris[alquil C₁₋₈]sililo, alquil C₁₋₈-bis-[alquil C₁₋₈]sililo, alquil C₁₋₈-bis(aril)sililo, aril-bis[alquil C₁₋₈]sililo, cicloalquil C₃₋₈-bis[alquil C₁₋₈]sililo, halo-bis[alquil C₁₋₈]sililo, tris[alquil C₁₋₈]silil-alcoxi C₁₋₈-alquilo C₁₋₈, tris[alquil C₁₋₈]silil-alquilo C₁₋₈; A¹ A², V, W independientemente entre sí representa un grupo CR³R⁴, oxígeno o azufre, estando presentes en cada caso como máximo 2 átomos de oxígeno o 2 átomos de azufre en el anillo formado por los grupos A¹, A², V, W y el átomo de carbono al que están unidos y no estando adyacentes en cada caso los átomos de oxígeno o azufre; m representa 0, 1, 2; n representa 0, 1, 2; R³ y R⁴ independientemente entre sí representan hidrógeno, alquilo C₁₋₈, halógeno, cicloalquilo C₃₋₈, alcoxi C₁₋₈, arilo, heterociclilo, heteroarilo, aril-alquilo C₁₋₈, alquiltio C₁₋₈, haloalquilo C₁₋₈, haloalquiloxi C₁₋₈, haloalquiltio C₁₋₈, alcoxi C₁₋₈-alquilo C₁₋₈, alquiltio C₁₋₈-alquilo C₁₋₈, heteroaril-alquilo C₁₋₈, heterociclil-alquilo C₁₋₈, alcoxi C₁₋₈-haloalquilo C₁₋₈, haloalcoxi C₁₋₈-haloalquilo C₁₋₈, alquenilo C₂₋₈, alquinilo C₂₋₈, R³ y R⁴ con el átomo al que están unidos forman un anillo de 3 a 6 miembros totalmente saturado, dado el caso interrumpido por heteroátomos y que dado el caso presenta más sustituciones; y [M] representa tris-[alquil C₁₋₆]estanilo, tris-[cicloalquil C₃₋₈]estanilo, tris-[alquil C₁₋₆]germanilo, tris-[cicloalquil C₃₋₈]germanilo, bis-(ciclopentadienil)circonilo, bis-(1,2,3,4,5-pentametilciclopentadienil)circonilo, bis-(ciclopentadienil)hafnilo, bis-(1,2,3,4,5-pentametilciclopentadienil)hafnilo, bis-(hidroxi)borilo, bis-[alcoxi C₁₋₆]-borilo, alquil C₁₋₆-1,3,2-dioxaborolan-2-ilo, bis-[alquil C₁₋₆]-1,3,2-dioxaborolan-2-ilo, tetrakis-[alquil C₁₋₆]-1,3,2-dioxaborolan-2-ilo, 1,3,2-dioxaborinan-2-ilo, bis-[alquil C₁₋₆]-1,3,2-dioxaborinan-2-ilo, alquil C₁₋₆-1,3,2- dioxaborinan-2-ilo, tris-[alquil C₁₋₆]-1,3,2-dioxaborinan-2-ilo, 2,6,7-trioxa-1-boranuidabiciclo[2,2,2]octanilo, alquil C₁₋₆-2,6,7-trioxa-1-boranuidabiciclo[2,2,2]octanilo, tris-[alquil C₁₋₆]plumbanilo, tris-[C₃₋₈-cicloalquil]plumbanilo, tris-[alquilcarboniloxi C₁₋₆]plumbanilo, tris-aril-plumbanilo, bis-[alquilcarboniloxi C₁₋₆]-arilplumbanilo, bis-[alquil C₁₋₆]-alanilo, bis-[cicloalquil C₁₋₆]-alanilo, dicloralanilo, cloromagnesilo, bromomagnesilo, clorozincilo, clorhidrargilo, bromhidrargilo, alquilhidrargilo C₁₋₆, cicloalquilhidrargilo C₃₋₆, tris-[alquil C₁₋₆]sililo, alquil C₁₋₆-[bis-alquil C₁₋₆]sililo, alquil C₁₋₆-bis-(aril)sililo, aril-bis-[alquil C₁₋₆]sililo, cicloalquil C₃₋₇-bis-[alquil C₁₋₆] sililo.
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EP2740356A1 (de) * 2012-12-05 2014-06-11 Bayer CropScience AG Substituierte (2Z)-5(1-Hydroxycyclohexyl)pent-2-en-4-insäure-Derivate
WO2016008862A1 (de) * 2014-07-18 2016-01-21 Bayer Cropscience Aktiengesellschaft Substituierte vinyl- und alkinyl-cyanocycloalkanole sowie vinyl- und alkinyl-cyanoheterocyclylalkanole als wirkstoffe gegen abiotischen pflanzenstress

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AU2015294110A1 (en) 2017-02-02
CA2955798A1 (en) 2016-01-28
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WO2016012362A1 (de) 2016-01-28

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